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A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 29-12-18
Time: 09:00 AM to12:00 Noon CODE-C Max.Marks:360
KEY SHEET
PHYSICS
1 1 2 3 3 1 4 3 5 2
6 1 7 1 8 4 9 1 10 4
11 4 12 4 13 3 14 4 15 1
16 4 17 3 18 2 19 3 20 4
21 1 22 3 23 4 24 1 25 3
26 4 27 3 28 2 29 1 30 4
CHEMISTRY
31 3 32 1 33 1 34 4 35 3
36 3 37 1 38 1 39 1 40 1
41 2 42 2 43 3 44 4 45 4
46 4 47 3 48 2 49 2 50 1
51 3 52 3 53 2 54 2 55 1
56 2 57 1 58 1 59 1 60 1
MATHS
61 2 62 3 63 4 64 1 65 2
66 2 67 1 68 1 69 3 70 1
71 4 72 4 73 2 74 1 75 4
76 1 77 4 78 1 79 4 80 2
81 2 82 3 83 1 84 1 85 4
86 2 87 4 88 3 89 3 90 2
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
SOLUTIONS
PHYSICS
RS 10x4 20
1. G
R S 10 4 3
v v
2. vw = i+ j
2 2
v m = at j
v v
v wm = -at j
2 2
It appears due east when,
v
-at 0
2
v
t
2a
m
3. v x =u cos 45o =10 2 cos 45o =10
s
m
v y = v 2 -v 2x 125 100 5
s
v y = u y gt
We have, t
u y vy
5 5 1.0 s
g 10
4. Let acceleration of mass m relative to wedge down the plane is ar. Its absolute
acceleration in horizontal direction is arcos 60o-a (towards right). Hence, let N be the
normal reaction between the mass and the wedge. Then
N sin θ = Ma = m (ar cos 60o – a)
Or ar
M m a 2 M m a
m cos 60o m
5. Maximum frictional force between A and B could be
f1 1mA g 0.2 2 10 N
f1 4 N
Hence, maximum common acceleration till both the blocks move with same
acceleration is
f1 4
a 2m / s 2
mA 2
Now, taking (A + B) as the system
F – 24 = (m A + mB)a = 6 x 2 = 12
F = 36 N
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
6. Taking point of suspension as the reference point for gravitational potential energy
(where h = 0)
l 3l 7
Ui = - mg +2mg = - mgl
2 2 2
l 3l 5
U f = - 2mg +mg = - mgl
2 2 2
U=U f - U i mgl
7. Ei – Ef = work done against friction
1 2 1 2
mv Kx mg x
2 2
Substituting the values we get, x = 1m
8. OP 2m
Lz m vxy OP 2 2 2 2
= - 8 kgm2/s
9. Just after collision velocity of disc will become u (elastic collision between equal
masses)
Now maximum friction will act backwards and this will convert forward slipping into
pure rolling. Till then torque of friction about bottommost point will remain zero and
angular momentum will remain conserved.
Li = Lf
muR = mvR + lω
1
Putting v = Rω and l = mR 2
2
2u
We get,
3R
10. Density of given material
M 3M
3
4
2 R R 28 R
3 3
3
Vwhole = V hole + Vremaining
V remaining = Vwhole - Vhole
3 GM 1 GM 2
… (1)
2 2R R
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
4 3 8
Here, M 1 2 R M
3 7
4 3 M
and M 2 R
3 7
Substituting in Eq. (1), we get
9GM
Vremaining
14 R
11. Hydrostatic force is perpendicular to the cylindrical surface.
Therefore it passes through O, or its torque about O is zero.
Therefore no force (F = 0) is required to counter balance this torque.
12.
RT / M 5
3RT / M 9
5 5
or
3 9 3
Hence the given gas is monoatomic
PT = constant
PV
P = constant
nR
Or PV1/2 = constant
Comparing with PVx = constant … (1)
1
We have, x
2
Molar heat capacity in equation (1) is given by
R 3 R 7R
C CV R
1 x 2 1 2
1
2
k 54
13. 3 rad/s
m 6
Maximum friction between 1 kg and 2 kg blocks can be 0.6 x 1 x 10 = 6 N.
6
Therefore, maximum acceleration of 1 kg block can be 6m/s 2 . Maximum force of
1
friction between 2 kg and 3 kg blocks can be 0.4 x 3 x 10 = 12 N. Therefore maximum
12
acceleration of 1 kg and 2 kg blocks jointly can be 4m/s 2 .
3
So, maximum acceleration of the whole system, so that there is no slipping between
any of blocks is 4 m/s2.
Now , 2 Amax 4
4 4
Or Amax 2 m
9
14. First assume reflecting surface, as the observer. Frequency received by it is:
Here, C=A.B=A+B
=A+B
Here, output C is equivalent to OR gate.
For, lower part
C=A.B A.B
In this case output C is equivalent to AND gate.
30. A = 2πRh = (2)(π)(6.4 x 106)(150)m2
= 1.92 π x 10 9 m2
= 1.92 π x 10 3 km2
CHEMISTRY
31. Conceptual
32. The balanced equation is
2MnO4 5C2O42 16 H 2Mn 2 10CO2 8 H 2O
33. Pm = dRT
PAmB d A RT
PB mB d B RT
PA 1
x 2
PB 3
PA : PB 6 :1
CaCO3 s CaO s CO2 g
34.
K c = PCO2, therefore, Kc only depends upon concentration of CO2 as long as
temperature remains constant and both CaCO3(s) and CaO(s) are present.
35. K spMS = [M2+][S2-]
5 x 10-21 = (0.05)[S2-]
For precipitation Qsp = Ksp
5x1021
S 2 2
1019
5x10
For H2S:
H2S H HS K1
HS H S 2 K 2
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
2
H S 2
K1xK 2
H 2S
2
H 1019
107 x1014
0.1
2
H 10 3 ,
[Taking negative logarithm both sides]
2log H 3
3
pH 1.5
2
36. ΔG = ΔH – T ΔS
Entropy decreases during absorption. Entropy factor is disfavouring, therefore the
enthalpy factor must favour spontaneity, so it must be exothermic and ΔH must be
negative.
37. WA CH 3COOH is titrated with SB(NaOH) and 20% of the WA is neutralized, so 20%
of the salt of WA/SB (CH3COONa) is formed and 80% of the WA(CH3COOH) is left.
So an acidic buffer if formed.
[Acid] = 80; [Salt] = 20
Salt
pH pK a log
Acid
Salt
4.7447 log
Acid
1
4.7447 log
4
4.7447 2log 2 4.7447 2x0.3010 4.14
38. i. Edge length = AB = AD = BC = CD = a
2
ii. AC AB BC a a 2a
2 2 2
2
iii. AG AC CG 2a a 3a
2 2 2
41. Conceptual
42. It follows first order kinetics sinceT50 is independent of concentration.
46. Conceptual
HCl
HO H C CH 3 H OH
H 2O
CH 3
OH C OH
CH 3
47.
48. Metal sulphides reduction with carbon is not possible since f G for the reaction is not
compensated.
49. Conceptual
50. Conceptual
2
51. Co NH 3 5 Cl Cl2
H 2O
Co NH 3 5 Cl 2Cl
2 AgNO3 2Cl 2 AgCl 2 NO3
52. Let B be the original base.
2B H 2 PtCl6 B2 H 2 PtCl6 Pt
Ew of B2 H 2 PtCl6 2 B 2 195 6x35.5
= 2B + 410
weight of chloroplatinate Eq. wt. of salt
Weight of Pt Eq. wt. of Pt
0.3 2 B 410
0.09 195
B(Ew) of base = 120
Molecular weight of base = Ew x Acidity
= 120 x 2 =240
53. Conceptual
54. Hydrolysis of 3o RX is independent of nucleophilic concentration (SN1 reaction)
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-C(9th Jan)_Key & Sol’s
Me Me
Me
OH
Cl OH
Me Me Me
Me Me Me
O
Me O O CH 2
Me3COK Me3C OH O O3 /Red Me
Me
Me Bulky base
(Hofmann elimination)
Less-substituted alkene H
Br Propanal Methanal
55.
56. Conceptual
57. Conceptual
58. More the e -withdrawing group, more is the NA reactivity
Cl3C CHO HCHO PhCHO MeCOMe
Chloral
CH 2OH
OH
* O
* OH *
*
HO *
59. OH Five chiral centres
60. Reaction of (X) with Br2 + KOH suggests that (X) is an amide. Carbylamine test and
coupling reaction of (Y) suggest that (Y) is 1o aromatic amine.
Br2 KOH NaNO2 HCl Phenol
PhCONH 2 Hofmann
PhNH 2 Ph N N Cl Azo dye
bromamide
X reaction Y
CHCl3 KOH
Ph N C
MATHS
61. Solving we get x 4 x 32 0 x 2, 2
4 2
2 x2
dx
8
The area is S 2
2 x 4 4
62. Number divisible by 2 and 3 is divisible by 6 case (i) delete 0
i) fix 2 in units place ----> 4!
ii) fix 4 in units place ----> 4!
Case (ii) delete 3
i) fix 0 in units place ------>4!
ii) fix 2 in units place ------> 4!-3! iii) fix 4 in units place ----> 4! – 3!
63. C20 C12 ....... C2n 2n Cn 1000
P 3 P 2Q Q 3 Q 2 P
P 2 P Q Q 2 P Q
d d ex d c
y
x 3
ex c
y
1, x 1
84. f 1 x 2
3 x , x 1
In 1, f is increasing in ,1 f is decreasing f has min. at x 1
f 1 f 1 a 1 1 1 0
a 1 0 a 1
85. Equation is true only when sin 2 y 1 tan 4 x 1
x , y
4 2
86.
6mt
h
2 3
x