29-12-18 - SR - ICON ALL - Jee-Main - GTM-6 - Key & Sol's PDF

Sri Chaitanya IIT Academy.
, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 29-12-18
Time: 09:00 AM to12:00 Noon CODE-A Max.Marks:360
KEY SHEET
MATHS
1 1 2 2 3 2 4 1 5 4
6 1 7 4 8 2 9 3 10 1
11 2 12 2 13 3 14 2 15 3
16 2 17 1 18 2 19 2 20 1
21 2 22 1 23 4 24 2 25 3
26 4 27 2 28 4 29 2 30 2
PHYSICS
31 2 32 3 33 1 34 2 35 3
36 1 37 3 38 2 39 1 40 4
41 1 42 2 43 2 44 4 45 3
46 3 47 2 48 2 49 3 50 1
51 1 52 4 53 4 54 1 55 4
56 4 57 1 58 3 59 2 60 3
CHEMISTRY
61 3 62 4 63 2 64 3 65 3
66 1 67 3 68 1 69 2 70 3
71 1 72 1 73 3 74 1 75 3
76 3 77 1 78 1 79 2 80 2
81 4 82 2 83 1 84 3 85 4
86 3 87 1 88 4 89 1 90 2
Sri Chaitanya IIT Academy 29-12-18_Sr.ICON ALL_JEE-Main_GTM-6_Code-A_Key & Sol’s
SOLUTIONS
MATHS
1. Conceptual
1 2 n
2
2. Sin  xn 1  xn   3 sin xn sin xn 1
1 2 n
sin xn1  xn 
 3 2
sin xn sin xn1
1 2 n
2
cot xn1  cot xn  3

Lt xn 
n  6
3.
1
4. 1  sin x ax 2
 bx  c dx
0
1 2
1  sin x ax  bx  cdx 1  sin x ax 2  bx  cdx
2
0 1
Atleast one root between (1, 2)

2017
5. C0 2017 C1  .......... 2017 C1008  22016
  21008  833  1201

Remainder = 25
6. e x  cos x  1  e x  sin x  xdx

 e x  sin x  x
 log e e x  sin x  x  x  C
 f  x  e x  sin x  x; g  x   x
7. Reflexive, symmetric and not transitive
2 1 1
8.  1 2 0
2 1 3
2 3  2   3  1  2  0
3 2  3  2  0
 1  2 2 1
    
 2 3 4
 1 2 y2 1
Conic is  x    
 2 3 4
Eccentricity = 2
 4! 
9. No. of ways = 2.   4!  36
 2! 2!
  
10. x  sin   sin 1 x     , 
 2 2
y  sin 1 sin 2
 1
  2sin 1 x  , 1 x  
 2

 1 1 1
  2sin 1 x,  x non diff at x 
 2 2 2

 1
  2sin 1 x ,  x 1
 2
2
11.  f x
'
 f  x f ''  x  0

d  f  x 
 '   constant
dx  f  x 
f  x 1

f '  x 2
f  x   e2 x
e2 x  x 2  1 solution
Sec: Sr. ICON ALL Page 3

12.
5 30 3
tan   , tan 2  , x5
x x 2
13.
P ,  Q ,  R ,  S ,  T , 
1
4  2     187
2
  11;   2
2 2 1 2
14.  x  1   y  1  3 x  4 y
25
Parabola ; Directrix 3 x  4 y  0
Perpendicular distance from 2, 1 to 3x-4y=0 is 2

15. Mean of wi=(mean of yi) + k
55=48L+k
Standard deviation of wi = standard deviation of yi
15=12L
L=1.25, k=-5
16. 2ae=13; b2=36
4a2e2=169
4(a2-b 2)=169
13
e=
313
8!
17.  560
3! 2! 3!
18. Conceptual
19. From graph 1  ,  2    1   2
20.
P is midpoint of AB, A(2x,0) B(0,2y)

dy  y

dx x
xy  c  c  6
21. Given compound statement is always false. Hence it’s a contradiction
22.      ,   
  1,   2
y  2 1 1
1  y  2  1  1
0 y2  2
2  y  2  2
4  y  0 y  2
y  4,0  2
23. Conceptual
     
24. d .a  d .b  d .c  0
abccos y  sin x  2  0

x , y
2
25. Normal to plane containing (2,3, 1) (1, 1, 2) is 5i  j  k 
5 i  j  kˆ . xiˆ  yjˆ  zkˆ
   1
cos 90    cot   2  sin  
5 3 x2  y 2  z 2 3
yz  x  y  z
26. f  x  f  2 x   x  R
f(x) is constant function
12 4
27. Twelve cubes have two faces painted P   
27 9
28. ax+by+c=0, family of lines passes through (1, -2)
2b=a+c
Hence required circle is of the form
2 2 2 2
 x  1   y  2   is orthogonal to x  y  4 x  4 y  1  0    8
      1  2  18  7
29. log 2 1  6 x  x 2  8  0
 
6 x  x2  8  0
2 x4
f '  x  x 2  2 x  2  0 x  R
x3
f(x) is strictly  in [2,4], f  x   x 2  2 x
3
32 136
a  f 2  , b  f 4 
3 3
a + b = 56
30. n  1 n  n  1 n! Tn  n 2  1 n !  n n  1!  n  1n!
 Sn  n n  1!
T10 101

S10 110

PHYSICS
31. Since normal is impulsive friction will also be impulsive and it will reduce  and give
some horizontal velocity to C.M. v  r friction cannot act when there is no tendency
of relative motion.
32. After collision end of the rod which is at hinge A try to move left so hinge provide
force to the rod towards right.
33. Lfinal = 0
2
Lfinal = mR 20  mv0 R
5
5v0 5  v0
0  or 0   5rad/s
2R 2 0.05
34. Torque about left end
mg
 mg  l cos    F l sin   F 
 
2  2 tan 
4
35. P  S cos   10Pa
r
 2
36. T  2  s
k 3
T 3T 5T
Now, t  , , etc.
4 4 4
37. VShell  Vmetallic sphere  0
KQ Kqe
 0
R r
Qr
qe  
R
KQr 1 Qr
EP  2

Rd 4 0 Rd 2
3Q
38. Initial charge on the inner surface of the neutral plate .
2
Before neutral closing the switch
2Q
Final charge on the inner surface of the neutral plate =
3
After closing the switch
5Q
Amount of the charge through switches = .
6
39. V  l  b  h , The answer should have 3 significant digits.
40. Co-ordinates of point P are R,  h . These co-ordinates should satisfy the equation of
projectile. i.e.
gR 2
 h  R tan   1  tan 2 
22ag 
or R 2 tan 2   4aR tan   R 2  4ah  0
for  to be real 4aR 2   4 R 2 R 2  4ah
or 4a 2  R 2  4ah
or R 2  4a a  h
or R 2  2 a a  h
The maximum range is Rmax  2 a a  h .

43. Reflection from denser medium produces a phase difference of  .
44. Resolving the given dipole into two component dipoles with dipole moments
p  p 
p1  i and p2   j . The point P is on the equatorial line of p1 and axial line of
2 2
p2. Therefore the net field at p will be E  E1  E2 .
45. Effective resistance of the circuit = 3R.
E 12
i   4mA
3R 3K 
46. In adiabatic compression slope of curve is more w.r.t. isothermal process.
47. lT  FL / AY
49. QAB  U AB  WAB

WAB  0
f f 5
U AB  nRT  PV  U AB  PV 
2 2 2
QAB  2.5 PV
0 0 Q BC  1.4 PV
0 0
51. Conceptual
52.
y  
  
 θ r  v0
  θ
   A
  
x
 O  v0 
x
mv0
r
qB0
x 3
Since,   sin 
r 2
T m
   600  t0 A  
6 3qB0
m
Therefore, X co-ordinate of particle at any time t  is
3qB0
3 mv0  m 
 cos  60 
0
x  v0  t 
2 qB0  3qB0 
3 mv0 v0  m 
 x  t  
2 qB0 2  3qB0 
53. eVs  hv   0
h 
Vs  v 0
e e
h 1.656
Now, = Slope = 14
 0.414  10 14 Vs
e 4  10
 4.14  10 15Vs
1 2 1 2 p2 1 4mZe 2 1
55. K  mv    mv   . Therefore r0  . . Thus r0
2 2m 2m 4 0 p2 P2
when p is doubled, r0 becomes one fourth.
L D  20  25 
M 1    1  
56. f0 e 5 10
 4(1  2.5)  4  3.5  14
 S 0.22
i  o  S1    0.0157
14 14 14
 0.02
57. x  n
(   1)t  n n = 1, 2, 3………….
n
t
(   1)
For minimum value of t, n = 1
 
t   2
(  1) (1.5  1)
59. For equilibrium,
 k1 x1 sin 600  kx3 sin 60 0
 x1  x3
0 0
and  k1 x1 cos60  k 0 x2  kx3 cos 60  mg or kx1  k 0 x2  mg  100 N
5
 kx1  100  kx2  100  1000  50 N
100
After breaking,
kx1 sin 600 50 3 5 3 2 mg  kx1 cos 60 0  k 0 x2
ax   m / s and a y 
m 2  10 2 m
100  25  50 25
ay    2.5 m / s 2
10 10
75
 a  a x2  a 2y   6.25  25  5 m / s 2
4
60. 5.5  I B RB  VB E
5.5  10mA  500  VB  E
0.5V  VB  E

CHEMISTRY
61. Penetration results in less shielding from nuclear charge and therefore lower energy.
62. Anti bonding MOs have more character of the atom having less electronegative i.e.
orbitals having more energy.
63. In the reaction with alkali metals dihydrogen oxidizes alkali metals forming saline
hydrides. On burning in O2, F2, Cl2 dihydrogen reduces the non metals and also it can
reduce several metal oxides. It is also used as fuel. It reactivity towards halogens
decreases from F to I.
64. CaCl2 forms addition compound with ammonia. So cannot be used to dry ammonia.
The remaining three can be used
Na2CO3 is efflorescent cannot be used.
CaO  H 2O  Ca  OH  2
Mg  ClO4  2  H 2O  Mg  OH  2  HClO4
Mg  ClO4  2  H 2O  Mg  OH  2  HClO4 bing acidic react with NH3
66. XeF6 react with silica but not XeF2 and XeF4
67. If two Cl  enter into coordination sphere it converts into  Pt  en Cl4  which is not an
isomer of  Pt  en 2 Cl2  Cl2
69. Cu  NO3  2 , Ni  NO3  2 and Cr  NO3 3 give same colour in borax bead test and in water
Ni  NO3  2 gives brown colour in borax bead test but green colour in water
70.
In P4O 10 the P-O bonds in P-O-P bridges are one type and the terminal P=O are other
type but in P4O 6 terminal P=O bonds are absent so all P-O bonds in P-O-P briges
have same length. Due to the more repulsion by lone in on phosphorus atom in P4O6
compared to repulsion by double bonded oxygen in P4O10 O-P-O angle in P4O 6 is less
than in P4O10 . When O-P-O bond angle decreases automatically P-O-P bond angle
increases in P4O6. Both contain four six membered heterocyclic rings.
72. sp3 nitrogen with more +I effect
73. I st molecule has Z configuration and II and molecule has E configuration
74. Etard reaction + EAS + Wolf kischner reduction
* PCC
H3C OH H3C * O
CH 2Cl2
CH3 CH3
75.
76. HVZ reaction,If enol content is hugher no need of lewis acid.
77. Hofmann bromamide reaction
O NH2
NH2
CH3 Br2 CH3

NaOH
1-phenylethan-1-amine
78. Stability of transition state

79. Ester
80. Diatereomeres differ only at anomeric carbon
1
81. Using the relation,  , we get
K.E.
1   and K.E.1=E (initial)
 2  0.9
10
[10% decrease from 1 ,  2     =  1  0.1  0.9 ]
100
We are required to find K.E.2=?
12 2
 K.E.2  2  K.E.1   K.E.1
2  0.9  2
 2  100
  E  K.E.1  E 
81 2

100
 E [More than K.E.1 i.e., increases]
81
100
Now increase in K.E.=K.E.2– K.E.1= EE
81
100
EE
% increase of K.E.= 81  100
E
19
  100  23.4%
81
82. Given, CP = 10 cals at 1000 K.
T1=1000 K, T2=100 K
m=32 g
S =?
At constant pressure
T2
S  C P ln
T1
T2
 2.303  C P log
T1
100
 2.303  10log
1000
 23.03caldeg 1
2.165  103
83. Fraction of unoccupied sites in NaCl crystal = 1 
2.178  103
2.178  10 3  2.165  10 3 0.13  10 3
 
2.178  103 2.178  10 3
130
  5.69  10 3
2178
84. van’t Hoff factor (i) and the degree of association are related as below:
 1
i  1   1  
 n
 1
0.9  1  0.2  1  
 n

On solving,
 1 1
1   
n 2
1 1 1
 1 
n 2 2
n  2
n m
85. Rate1= k  A  B 
m
1  n
Rate2= k  2 A  B 
2 
m
1  n
k  2 A  B 
Rate 2 2 
  n m
Rate1 k  A  B 
m
= 2 n . 2   2 n m
86. Sols of Al2O3 and even inorganic lyophilic sols e.g. silica, stannic oxide show no
difference in surface tension as compared to water. If protein is dissolved in water it
will lower the surface tension to some extent.
Cu  2 H 2 SO4  aq   CuSO4  aq   2 H 2 O  SO2  g 
87.
1 mole 2 mole 1 mole
From the above equation we find that 1 mole of Cu reacts with 2 mole of H2SO 4. Since
we have only 1 mole of H2SO4 so it is the limiting reagent. Now
Since 2 moles of H2SO 4 react with Cu to produce SO2 = 1 mole
1
1 mole of H2SO4 reacts with Cu to produce SO2 = mole
2
Now 1 mole of SO2= 6.023  10 23 molecules of SO2
1 6.023  10 23
 mole of SO2 = molecules of SO2
2 2
= 3  10 23 molecules of SO2
88. Expected equilibrium vapour pressure is calculated from raoults law. Equilibrium total
vapour pressure should be in between 23.77 torr and 59.02 torr.
89. K H  100 kbar = 10 5 bar, P  1 bar

P 1
xA   3
 10 5
K H 100  10
1000
Moles of water = = 55.5
18
Weight of water = 1000 g ( 1000 mL = 1000 g)
x
Mole fraction = 10 –5 =
55.5  x
As 55.5 >>> x, thus neglecting x from denominator
x
10 5   x  55.5  10 5 moles Or 0.555 millimoles.
55.5
90. NH 2 COONH 4  s   2 NH 3  g   CO2  g 
2
KP 
 PNH 3  P   P   P 
CO2 2
NH 3 CO2
PNH 2COONH 4  s
As evident by the reaction, NH3 and CO2 are formed in molar ratio of 2:1. Thus if P is
the total pressure of the system at equilibrium, then
2 P 1 P
PNH 3  PCO2 
3 3
2
 2P  P 4P3
KP     
 3  3 27
Given K P  2.9  10 5
4P 3
5
 2.9  10 
27
5
2.9  10  27
P3 
4
1
 2.9  10 5  27  3
P   5.82  10 2 atm.
 4

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Sri Chaitanya IIT Academy.

Atleast one root between (1, 2)

  21008  833  1201

6. e x  cos x  1  e x  sin x  xdx

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P ,  Q ,  R ,  S ,  T , 

Perpendicular distance from 2, 1 to 3x-4y=0 is 2

P is midpoint of AB, A(2x,0) B(0,2y)

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The maximum range is Rmax  2 a a  h .

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Mg  ClO4  2  H 2O  Mg  OH  2  HClO4 bing acidic react with NH3

isomer of  Pt  en 2 Cl2  Cl2

CH3 Br2 CH3

78. Stability of transition state

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