Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 30-12-18
Time: 09:00 AM to12:00 Noon CODE-C Max.Marks:360
KEY SHEET
PHYSICS
1 1 2 1 3 2 4 2 5 3
6 4 7 1 8 2 9 2 10 3
11 2 12 1 13 1 14 3 15 2
16 4 17 3 18 3 19 3 20 1
21 4 22 4 23 2 24 3 25 2
26 1 27 2 28 4 29 3 30 2

MATHS
31 2 32 1 33 2 34 1 35 1
36 1 37 2 38 3 39 4 40 3
41 2 42 3 43 4 44 2 45 1
46 3 47 4 48 4 49 2 50 2
51 3 52 4 53 3 54 2 55 3
56 3 57 2 58 1 59 3 60 2
CHEMISTRY
61 3 62 3 63 3 64 4 65 3
66 1 67 3 68 2 69 2 70 3
71 4 72 4 73 3 74 3 75 3
76 3 77 3 78 2 79 2 80 3
81 1 82 3 83 1 84 1 85 3
86 2 87 3 88 4 89 2 90 1
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
SOLUTIONS
PHYSICS
Mass  M
1. Density, d 
Volume  v 
Here m = 2.42g, m  0.01g
v  4.7cm3 V  0.1cc
d
Maximum error in density,  100
d
 m   V   0.01   0.1 
  100    100    100    100  0.413%  2.127%  2.54%
 m   V   2.42   4.7 
2. vA0  0
l1 3

l2 2
VA1 3 3
 
VA 2 3  2 5
v
v A1  3x  0.6v
5
3. Conceptual
4. The acceleration of the horizontal movable pulley will be 6m/s2. So for the block B.
3aB  6, aB  2m / s 2
5. Free body diagram of the two bodies are as follows
F1  2N
2kg
f

F2  20 N
4kg f

Maximum friction between the two blocks is fmax  mg , where m = 2kg
 fmax  (0.5)(2)(10)  10N

Let acceleration of both the blocks be a towards left. Then

f  2 20  f
a 
2 4
 2f  4  20  f  f  8N

Now since, f  fmax i.e., static region of 2kg on 4kg, hence friction force between the
two blocks is 8 N.
6. Conceptual
7. From work energy theorem W  K 
1 2
Pt  mv
2
2 Pt
Or v  ...(1)
m
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s

ds 2 P 1/2
 t
dt m
s 2 P t 1/2
 ds  t dt
m 0
Or
0

2 2 P 3/2
Or s  t ....  2 
3 m
s 2
From Eqs.(1) and (2)  t
v 3
8. From parallel axis theorem.

X CM

ML2
I1 
12
I 2  I1  Mx 2
2
ML2  3L 
 M 
12  2 2 
11ML2

24
9. About point of contact
  I
mgr  3mg  0   8mr 2   
g

8r

mg

2g
10. O  g  Rw2 cos 2 450  w 
R
11. If an bubble is formed, its radius is equal to that of capillary

Sec: Sr. ICON ALL Page 3

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
 Required pressure =    gh  2s
0
r
P
12. P  T    ,
T
P
o o
To
3Po 3
 B  o
2To 2
13. PT 3  Constant
V
P  Constant
T
VT 2  Constant
TV 1/2  Constant
1
   1     1.5
2
14. Apparent Frequency of direct waves received by observer is
 V 
v1  v  
 V  Vs 
 V 
Apparent frequency of reflected waves received by the observer is v2  v  
 V  Vs 
No.of beats per second v  v1  v2 .
15. The wave pulse is travelling along positive x –a xis. Hence at and bx should have
opposite signs. Further wave speed
Coefficient of t
v
Coeffic int of x
Coefficient of t
 4
1
 Coefficient of t  4 s 1
16. S-Force of interaction
2 pq  1 1 
 3
 3
4 0   d  1  d  l  
17. Conceptual
18. E   / 2 0 r ', where  is the linear charged density of the inner cylinder.
b
 b
And V   Ed   ln  
a
2 0  a 
   
Now, l   J .dA    E.dA

Sec: Sr. ICON ALL Page 4

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s

 2 r dr
2 0 r
19.

The current through ammeter

I  I 4  I 3  I 2  I1
 6  0   8  6   6  4  14  6 
    
 2   4  4 8
1 1
 3   1  3 1  2 A
2 2
When only 4 resistance is shunted ig  i / 5
20. G  i / 5  4   4 / 5  or G  16 

21. For a circular wire

22. Conceptual
23. The emf induced in a conductor does not depend on its shape but only on its end
points. We replace the actual conductor by an imaginary straight conductor joining its
two ends.
hc hc 2hc
24. eV0   
0 0 0
3
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
1 Q 2 hc
e . 
4 0 R 0
25. Conceptual
26. If screen is perpendicular to the line joining the sources the fringes will be circular and
central fringe will be bright if S1S2  n
27. When light passes through a medium of refractive index , the optical path it travels is
t
Path difference   t  b      b      1 
For a small element ‘dx’, path difference,
x  1  ax   1 dx  axdx
For the whole length,

at 2
x   axdx 
0
2
For a minima to be at’O’,

x   2n  1
2
at 2 
   2n  1
2 2
For minimum ‘a’, n = 0
at 2  
  a 2
2 2 
28. When a real object is placed 25 cm from a lens, a real image is formed. Mark the is
INCORRECT statement from the following.
1) The lens is a converging lens
2) The image may be magnified or diminished
3) The focal length of the lens is less than 25 cm
4) The focal length of the lens may be greater than 25
29. CONCEPTUAL
 9  108
30. v   1.5  108 ms 1
k 6
c 3 108
Refractive index n   2
v 1.5 108
Also n  r r For a non – magnetic medium  r  1.
Therefore
n  r r  4

Sec: Sr. ICON ALL Page 6

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
MATHS
x2 y2
31.  1
5 5cos 2 
2 b2 5cos 2 
e1  1  2
= 1   1  cos 2  ;  ly encentricity of the elipse
a 5
2 2
x y 2 25cos 2  2 2
2
  1 is e 2  1   sin 2  ; put e1  3 e2  e 1  3e 2
25cos  25 25
1
 1  cos 2   3sin 2   2  4sin 2   sin   ]
2
32. conceptual
x4 2
33. 2A=XY sin  ; 4 A2  x 2 y 2 sin 2  ; f ( x )  ; f '( x )  0  x  ]
2x  1 3
x3 x5
34. Use sin x expansion, sin x  x    .......
3! 5!
 3 4   3 4  1 0 
35. BC      BC  0 1   I
 2 3   2 3   
 A  A
t r ( A)  tr    tr  2  +……….
2 2 
1 1
t r ( A)  tr ( A)  2 tr  A   ......
2 2
t ( A)
 r  2tr ( A)  2(2  1)  6
1  (1 / 2)
36. Conceptual
37. (1  2 X  5 X 2  10 X 3 )[C0  C1 X  C2 X 2  ......]  1  a1 x  a2 x 2  ......
n(n  1)
a1  n  2 and a2   2n  5
2
2
Put a 1
 2a2
(n  2) 2  n( n  1)  4n  10
n 2  4n  4  n2  5n  10
n6
38. CONCEPTUAL
39. Lines are x  y  1  0; 4 x  3 y  4  0 and x   y    0 where  2   2  2
1 1 1
4 3 4 =0
1  

Sec: Sr. ICON ALL Page 7

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
1  3 – 4  – 1  4 – 4   1  4  – 3   3  – 4  – 4  4  4 – 3
 –   1  0   1

         1           ]
40. Conceptual
41. Conceptual
t  3x  x2 ( x  4)(3  2 x )  (t  3 x  x 2 )
42. f (x) = ; f ' (x) =
x4 ( x  4) 2
for maximum or minimum, f ' (x) = 0
– 2x2 + 11x – 12 – t – 3x + x2 = 0
– x2 + 8x – (12 + t) = 0
43. Shifting the origin at A equation is
X2 = – 8Y
Now (x – 2)2 = – 8(y – 2)

44. q 2 - 4 p r = 0, p > 0, p > 0

f(x) = log (px 3 + (p + q) x 2 + (q + r) x + r)
Let g(x) = px 3 + (p + q) x 2 + (q + r) x + r
g(x) = (x + 1) (px 2 + qx + r)
Discreminant of px 2 + qx + r = q 2 – 4pr = 0
Domain (x + 1) (px 2 + qx + r) > 0
2
 q 
 x  
2p 
 p(x + 1)  >2
 x  – and x > – 1
 q
 
 x  R – [(–  , –1]   2p 

1
45. f is not differentiable at x =
2
g is not continuous in [0, 1] at x = 0
h is not continuous in [0, 1] at x = 1 & 0
ln 5
k (x) = (x  3) 2 = (x + 3)p where 2 < p < 3 ]
46. x = cos  ,   [0,  ]
   
 cos cos   sin sin   
cos–1(cos  ) + cos–1  3 3 =
3
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
   
cos  + cos–1cos     = can hold only if 0  –  
3  3 3
 2 1  
–  –  – x   ,1 0 0    ]
3 3 2  3
47. No of integral solutions x1 x2 x2 x4  2 * 5 * 7 *11
CASE-I ALL xi  0
No of solutions = (4!) 4
CASE-II All xi  0
No of solutions = (4!) 4
CASE –III Two positive two negative 4C2 = 6 COMBINATIONS
No of solutions = 6* (4!) 4
Total no of integral solutions = 8* (4!) 4
48. Hint : find ‘c’ assuming the line is the tangent to the circle. And plot the inequalities
on x-y plane.
49. 22 + (x1 – 1)2 = x 12
4 + x12 + 1 – 2x1 = x12
5 = 2x1 or x1 = 5/2
Equation of (1) from (2, 5/2) to the given base
y – 5/2 = 2 (x – 2)

2y – 5 = 4 (x – 2)
at y = 1 –3/4 = x – 2 or x = 5/4 ]
f (x  h)  f (x) f (h ) | x | h  xh 2
Lim  Lim
50. f '(x) = h 0 h h 0 h
 f (h )  f (0) 
Lim   | x |  xh 
Q f (0) = 0 Þ f ' (x) = h 0  h 

f ' (x) = f ' (0) + | x | = | x | ]

51. Conceptual
2a 2a
x 1  x2 1   a2 1   a 2 1 
  6  x 2  dx      
12 x   3 2a   12 a 
52. [Hint :A = a = a = 
2 a 1
a 1
 
f(a) = 4 2a now f '(a) = 2 2a 2 =0 Þ a3 = 1 Þ a=1
53. Conceptual
54. Conceptual
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
55. Conceptual
56. Conceptual
1
ln ( x  1)
 x 2 1
dx
57. u= 0 put x = tan q
4 4 4
 1  tan   2 
 ln (1  tan ) d  ln  1   d
 1  tan  
 ln 1  tan  d
= 0 = 0 = 0 = 4 ln 2 – u
 
u= 8 ln 2  4u = 2 ln 2 ....(1)
2  2
1
2 0
 ln (sin 2x) dx ln (sin t ) dt  ln(sin t) dx
again v = 0 (put 2x = t) ; v= = 0

v = – ln 2 ....(2)
(1) + (2) Þ 4u + v = 0 ]
58. Conceptual
59. x2 y = c3
dy dy 2y

x2 dx + 2xy = 0 = dx = x
equation of tangent at (x,y)
2y
 (X  x )
Y–y= x
3x
Y = 0, gives , X = 2 =a
9x 2 27 2 27 3
. 3y x y c 
and X = 0 , gives , Y = 3y = b Now a2b = 4 = 4 4 ]
60. Conceptual
CHEMISTRY
61. Meq of salt = Meq of Na 2SO3
50  0.1 n  25  0.1 2
 n 1 changein  O.N.
 M3  e  
 M 2

62. Polarity in a molecule gives rise to an increase in forces of attraction among molecules
and thus, the boiling point increases.
w w
63. Let w g of each be taken, then initial mole of P ;molof Q 
10 20
w1 4w1
Final mole of P Final mole of Q
5 10 20  5
PN0 Q N0
For P  e1t For Q  e 2 t
PN QN
w  5 10 w  20  5
 For P  e 1 20 For Q  e 2 20
10  w 2 20  w1  4
By Eqs. (i) and (ii) 4  e   20  20  1   2   loge 4
1 2
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
 
or 20  0.693  0.693   log e 4  t 
 10 t1/ 2 

64. Higher vapour pressure of H 2 O in atmosphere will derive H 2 O vapours to the solute
particles
65. phenomenon of conversion of freshly precipitated mass into colloidal state by the
action of solute or solvent is called peptization
d  N 2 O 5  1 d  NO 2  2d  O 2 
66.  
dt 2 dt dt
k
 k1  N 2 O5   2  N 2 O5   2k 3  N 2O5 
2
2 2

Kc 
 NO2    2  103 / 2  1 10 5
67.  N 2O4   0.2 
 2 

68. For NaX,


 HX  OH 
X  H 2 O 
1 h h h

Kh Kw 10 14
h  
C Ka  C 10 5  0.1

 108  10 4
 %H  104  100  102  0.01
69. T  300K, V  10  1  9L
H  E  pV  E  2  RT
 0  2  8.314  300  4.98kJ
 E=0 for isothermal process 
 
70. This gives rise to higher e nuclear charge in Na and the size of Na becomes smaller
due to more effective pull of valence shells towards nucleus.
71. Allotropes of an element have the same chemical properties but have different
arrangement of atoms and physical properties
72. N a  is soluble in NaOH whereas cFe  OH 3  is insoluble.

73. FeSO4  7H2 O   FeSO4  7H 2O;

2FeSO4   Fe 2O3  SO2  SO3
74. HO SO2OH  PCl5 
 Cl SO2 Cl  POCl3  2HCl
75. The solubility of nobel gases increases with increase in molecular weight due to
increase in van der Waals’ forces. However, these are sparingly soluble.
76. According to Werner’s theory, only those ions are precipitated which are attached to
the metal atoms with ionic bonds and are present outside the coordination sphere.
77. PbS is black and S2 reacts with K 2Cr2O7 to give Cr2 SO 4 3 solution which is green.
0.059 H    pH I
78. E cell for the given change = log   2  2
2 p H2 II   H 
1

Sec: Sr. ICON ALL Page 11

Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
Thus, for positive E cell PH2 I  PH 2 II

79.

80. In D-(+)-tartaric acid, the (+) is due to positive optical rotation and is derived from
D     glyceraldehydes.
81. It undergoes dehydration easily as the product obtained is conjugated, and is more
stable.
82. H2O
CaC2   C2 H 2  H2O
Hg 2  catalyst 
H2
 CH 3CHO 
Ni
 CH3CH 2OH

83.
H2 O Br2
CH3 C  CH 
H  .Hg2 
 CH 3COCH 3 
 NaOH
CHBr3  CH3 COONa

Since, B and D are different, thus B is CH3CH2CHO and so A is CH3CH2CHCl2 .

84. Must be a tertiary alcohol as it gives alkene on treatment with Cu. Thus, C4 H8O is a
ketone.
85. Follow applications of inductive effect. The negative charge on carboxylate ion is
dispersed more due to  IE of F atom.

The carboxylate ion thus becomes more stable and the acid becomes more reactive.

86.
Sri Chaitanya IIT Academy 30-12-18_Sr.ICON ALL_JEE-Main_GTM-7_Code-C(12th Jan)Key & Sol’s
87.

88.

89. DNA has deoxyribose sugar; RNA has ribose sugar with three bases common as
adenine, guanine and cytosine, DNA has fourth base thymine; RNA has uracil
90. Bakelite is a step-growth polymer i.e., the condensation involving the reaction of
functional group e.g. terylene, Bakelite etc.