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Applied Thermal Engineering 67 (2014) 579e586

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Applied Thermal Engineering


journal homepage: www.elsevier.com/locate/apthermeng

Exergy analysis of parabolic trough solar receiver


Ricardo Vasquez Padilla a, *, Armando Fontalvo a, Gokmen Demirkaya b, Arnold Martinez a,
Arturo Gonzalez Quiroga a
a
Department of Mechanical Engineering, Universidad del Norte, Barranquilla, Colombia
b
Clean Energy Research Center, University of South Florida, 4202 E. Fowler Av., ENB 118, Tampa, FL 33620, USA

h i g h l i g h t s g r a p h i c a l a b s t r a c t

 A comprehensive exergy balance of a


parabolic trough is performed.
 The thermal and exergy efficiency
showed an opposite trend.
 The highest exergy destruction takes
place at the absorber.
 The highest exergy losses are due to
optical errors.

a r t i c l e i n f o a b s t r a c t

Article history: This paper presents an exergy analysis to study the effects of operational and environmental parameters
Received 15 November 2013 on the performance of Parabolic Trough Collectors. The exergy analysis is based on a previous heat
Accepted 22 March 2014 transfer model published by the authors. The main parameters considered for the analysis are: inlet
Available online 1 April 2014
temperature and mass flow rate of heat transfer fluid, wind speed, pressure or vacuum in annulus and
solar irradiance. The results showed that inlet temperature of heat transfer fluid, solar irradiance, and
Keywords:
vacuum in annulus have a significant effect on the thermal and exergetic performance, but the effect of
Solar receiver
wind speed and mass flow rate of heat transfer fluid is negligible. It was obtained that inlet temperature
Parabolic trough
Exergy analysis
of heat transfer fluid cannot be optimized to achieve simultaneously maximum thermal and exergetic
efficiency because they exhibit opposite trends. Finally, it was found that the highest exergy destruction
is due to the heat transfer between the sun and the absorber while for exergy losses is due to optical
error.
Ó 2014 Elsevier Ltd. All rights reserved.

1. Introduction transform it into useful energy by increasing the temperature of a


Heat Transfer Fluid (HTF). The performance of PTCs depends on
Solar Parabolic Trough Collectors (PTCs) are currently used for the combination of several operation parameters under different
electricity generation and applications with temperatures up to meteorological conditions. In this context, this paper presents an
400  C [1]. PTCs concentrate solar radiation onto a focal line to exergy analysis to determine the performance of PTCs in terms of
work potential and location, type, and magnitude of exergy
losses.
* Corresponding author. CSIRO Energy Technology, PO Box 330, Newcastle, NSW This research is based on a detailed and validated heat transfer
2300, Australia. Tel.: þ61 2 4960 6293.
E-mail addresses: Ricardo.Vasquezpadilla@csiro.au (R.V. Padilla), aefontalvo@
model [2] that takes into account all heat transfer mechanism
uninorte.edu.co (A. Fontalvo), gdemirka@mail.usf.edu (G. Demirkaya), arnoldg@ among collector components and includes the thermal interaction
uninorte.edu.co (A. Martinez), arturoq@uninorte.edu.co (A.G. Quiroga). with the environment. Results of the heat transfer model are in

http://dx.doi.org/10.1016/j.applthermaleng.2014.03.053
1359-4311/Ó 2014 Elsevier Ltd. All rights reserved.
580 R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586

Nomenclature Greek symbols


d Sun’s cone angle
Aa cross sectional area of absorber [m2] ho peak optical efficiency
Ib solar irradiance [W/m2] j maximum useful work available from radiation
Cp specific heat capacity [kJ/kg K] r heat transfer fluid density [kg/m3]
e specific exergy [kJ/kg] HCE heat collection element
h specific enthalpy [kJ/kg]
s specific entropy [kJ/kg K] Subscripts
v specific volume [m3/kg] a absorber
E exergy [kJ] cv control volume
E_ d exergy destroyed rate [kW] f heat transfer fluid
E_ loss Exergy loss rate [kW] e exit
E_ qj exergy of heat transfer rate [kW] i inlet, surface i
g gravity [m/s2] j surface j, Element j
m_ mass flow rate [kg/s] gain gained
P annulus gas pressure [Torr], heat transfer fluid o surroundings
pressure [bar] opt optical
Q_ heat transfer rate [kW] q heat transfer
T temperature [ C, K] sr solar radiation
t time [s]
V heat transfer fluid velocity [m/s] Superscripts
W _ cv work rate [kW] average
z height, axial length [m]

excellent agreement with experimental data obtained at Sandia for the temperature range of operation. Most of the incoming solar
National Laboratory [3], and also showed improvements when radiation has wavelengths below 3 mm which reduces the radiation
compared with prior models [4,5]. losses because of the emittance of the absorber [19]. The stainless
Most of the previous research on exergy analysis of PTCs has tube is covered by an evacuated glass tube (glass envelope) which
been focused on heat and power production systems. In these prevents oxidation and minimizes the heat losses to the environ-
systems, the exergy analysis is used either to find optimal operation ment. Glass to metal seals and metal bellows are employed to
conditions or to evaluate the performance of the system [6e13]. achieve the vacuum inside the envelope and compensate the
Some applications involve the optimization of the coupling condi- thermal expansion difference [20]. Bellows also allow extending
tions between the heat transfer fluid and the power cycle [6e8]. the absorber to extend beyond the glass envelope so that the HCE
Other applications have used the exergy analysis to minimize the can form a continuous receiver (see Fig. 1).
use of fossil fuels in polygeneration units [9e13]. Exergy analysis The heat transfer model is an energy balance between the heat
has also been used in desalination processes that rely on thermal transfer fluid and its surroundings. Fig. 2 shows the heat transfer
solar power obtained from PTCs [14,15]. It is important to highlight resistance model in a cross section of the HCE. Readers are
that in this last application, PTCs are only a component of the sys- encouraged to consult the details and assumptions of the heat
tem under analysis, and what it is optimized is the coupling be- transfer model developed by the authors in Ref. [2]. The heat
tween PTCs in the solar field with the thermal desalination system. transfer model was compared with experimental data obtained
Some studies on exergy analysis of PTCs have been focused on the from Sandia National Laboratory (SNL) [3] and compared with
performance evaluation of the collectors to maximize the use of the other solar receiver models [4,5]. Experimental results used in the
incoming solar energy. Previous studies have reported the depen- model validation were taken from LS-2 module placed at the
dence of exergy efficiency on the length of the collector and HTF AZTRAK rotating platform located at the SNL.
temperature [16]; the influence of mass flow of HTF, solar intensity
and concentration ratio on energy and exergy efficiencies [17]; and
the effect of the collector length, absorber tube diameter, working 3. Exergy analysis model
temperature and pressure on the energy and exergy efficiencies [18].
In this paper, a comprehensive exergetic balance of a PTC based An exergy balance was applied to the control volume shown in
on a control volume analysis is performed. This analysis is based on Fig. 1. It should be noted that the same assumptions of the heat
a previous heat transfer model developed by the authors [2]. This transfer model are used. The partial differential equation of the
analysis shows the effect of inlet temperature and mass flow rate of exergy balance is as follows [21]:
the heat transfer fluid, solar irradiance, annulus condition (vacuum
or air) and wind speed on the thermal and exergetic performance of dEcv X X X
the PTC. The exergetic balance is very useful to identify the irre- ¼ _ cv þ
E_ qj  W _ i efi 
m _ e efe  E_ d  E_ loss
m (1)
dt j i e
versibility sources which can be used to redesign and improve the
thermal performance of PTCs. with:
!
To _
2. Solar receiver model E_ qj ¼ 1 Qj (2)
Tj
The solar receiver consists of a heat collection element
composed of a stainless steel tube with a selective absorber surface, V2
ef ¼ h  ho  To ðs  so Þ þ þg z (3)
which has high values of absorptance and low values of emittance 2
R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586 581

Expansion Absorber tube with Vacuum between


Glass Envelope
bellows selective coating envelope and absorber

Fig. 1. Parts of a heat collection element (HCE) and control volume used for the heat transfer analysis. Adapted from [27].

3.1. Exergy input


 
4 To 1 To 4
The exergy input includes the exergy inflow rate coming from j ¼ 1 þ (5)
the heat transfer fluid and the exergy of the solar radiation. The 3 Ts 3 Ts
total exergy input is:
2 3 where Ts is the equivalent temperature of the sun as a black body
ZTi ZTi (w5800 K). Parrot [23] introduced the effect of the sun’s cone angle
Cp ðTÞ V 27
_6
E_ i ¼ m4 Cp ðTÞdT þ nðPi  Po Þ  To dT þ i 5 (d w 0.005 rad) on the limiting efficiency for utilization of solar
T 2 (4)
To To energy, the expression obtained was:
þ Ib Aa j

 
For an ideal process, the relative potential of the maximum 4 To 1=4 1 To 4
j ¼ 1 ð1  cosdÞ þ (6)
useful work available from radiation, j, is calculated with Petela’s 3 Ts 3 Ts
formula [22]:

(a)

(b)
Fig. 2. Heat transfer and thermal resistance model in a cross section at the heat collection element (HCE). (a) Heat transfer, (b) thermal circuit. Adapted from [3,4].
582 R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586

!
3.2. Exergy output X To
E_ loss;q ¼ Q_ j;loss 1  (15)
j
Ta;j
The exergy output only includes the exergy outflow rate coming
from the heat transfer fluid exiting the solar receiver. The total
exergy output is as follows: 3.4. Exergy destruction

2 3 In the solar receiver, exergy destruction is caused by two


ZTe ZTe
Cp ðTÞ V 27
_6
E_ e ¼ m4 Cp ðTÞdT þ nðPe  Po Þ  To dT þ e 5 (7)
mechanism: friction of the viscous fluid (HTF) and heat transfer
T 2 from high to low temperatures [25]. The friction of the heat transfer
To To fluid generates a pressure drop through the solar receiver. The
The exergy gained by the heat transfer due to the incident ra- entropy generation (exergy destruction) during this process is as
diation on the solar collector is given by: follows [21]:
  
2 3 X DPj ln Te;j Ti;j
ZTe ZTe E_ d;DP ¼ To m
_f (16)
Cp ðTÞ
_6
E_ gain ¼ m4 Cp ðTÞdT  To
7
dT  nDP 5 (8)
rj Te;j  Ti;j
j
T
Ti Ti Exergy destruction due to heat transfer process is present on the
absorber surface. The first process is the heat transfer from the sun
where the first two terms represent the exergy gain as result of an to the absorber surface, in this case the entropy generation is given
increase in the heat transfer fluid temperature due to the solar by [26]:
insolation and flow friction and the last term represents the
decrease of mechanical energy due to flow friction. The exergy ef- !
X To
ficiency is defined as the ratio of gain exergy to solar radiation E_ d;q1 ¼ ho Ib Aa j  ho Ib0 DzAa 1 (17)
exergy: j
Ta;j

E_ The second heat transfer process is between the absorber and


hex ¼ gain (9) the HTF. The exergy destruction by heat conduction from the
E_ sr absorber to the fluid is [25]:
then: 2 3
ZTe ZTe;j
2 3 dT X 1
Z Te Z Te
_ f6
E_ d;q2 ¼ To m 4 Cp ðTÞ 
7
Cp ðTÞdT 5 (18)
Cp ðTÞ
_6 7 T Ta;j
m4 Cp ðTÞdT  To dT  nDP 5 Ti
j
Ti;j
Ti Ti T
hex ¼ (10) Then, the total exergy destruction is:
Ib Aa j
The last equation does not present the terms of loss and E_ d ¼ E_ d;DP þ E_ d;q1 þ E_ d;q2 (19)
destroyed exergy which are useful to identify the causes and
Replacing all terms Eq. (13)e(18), the exergy efficiency can be
location of thermal losses. The exergy losses include heat transfer 0
rewritten by introducing dimensionless exergy term (E_ ¼ E=_ E_ sr ):
losses to the surroundings while the exergy destruction is caused
by internal irreversibilities [24]. For steady state conditions
0
 0 0 0 0

(dEcv =dt ¼ 0), Eq. (10) can be rewritten as: hex ¼ 1  E_ d;DP þ E_ d;q1 þ E_ d;q2 þ E_ loss;opt þ E_ loss;q (20)

E_ d þ E_ loss
hex ¼ 1  (11) with:
Ib Aa j
0
E_ loss;opt ¼ ð1  ho Þ (21)
3.3. Exergy losses
P _  
Q j;loss 1  TTa;jo
In this paper exergy losses are due to optical error and heat 0
E_ loss;q ¼
j
transfer losses from the solar receiver to the ambient [25]. (22)
Ib Aa j

E_ loss ¼ E_ loss;opt þ E_ loss;q ; (12)


P DP j lnðTe;j =Ti;j Þ
The exergy leakage due to optical errors is as follows: rj Te;j Ti;j
0
E_ d;DP
j
_f
¼ To m (23)
E_ loss;opt ¼ ð1  ho ÞIb Aa j (13) I b Aa j

ho is defined as the optical efficiency of the solar collector. The 2 0 13


exergy loss due to heat transfer from absorber to the ambient is X To
1 D z
given by [25]:
0
Ed;q1 ¼ h o 41 þ @  1A5 (24)
j Lc j Ta;j

XZ
Ta;i
To Z Z
E_ loss;q ¼ Q_ i;loss 2 dT (14) Te
dT X 1 Te;j
i
T Cp ðTÞ  Cp ðTÞdT
To
0 Ti T Ta;j Ti;j
E_ d;q2
j
_f
¼ To m (25)
Ib Aa j
where Q_ i;loss are the thermal losses. Simplifying:
R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586 583

4. Results and discussion Table 2


Summary of the parameters assumed for the analysis.

A parametric study was performed by using a LS-3 parabolic Parameters Values Units
trough solar collector in order to study the effect of some operating HTF mass flow rate 4, 7, 10 kg/s
and environmental parameters on the collector efficiency and Solar irradiance 250, 500, 750, 1000 W/m2
collector exergy efficiency. The geometrical parameters of the LS-3 Wind speed 0, 5 m/s
collector are listed in Table 1. The variations of exergy leakages and Vacuum in annulus P < 1 Torr (vacuum)
P  1 Torr (pressure in annulus)
exergy destruction with these parameters were also studied.
Table 2 shows the operating conditions used for the parametric
analysis.
Figs. 3e8 shows the effect of HTF inlet temperature (Ti), mass efficiency of any collector, which is defined as the ratio of ‘useful
flow rate ðmÞ_ and solar irradiance (Ib) on Collector Efficiency (hc) energy output’ to that of ‘incident solar energy’ during the same
and Collector Exergy Efficiency (hex). Collector Exergy Efficiency is time period. In this work, the performance of PTCs is examined
strongly dependent on HTF inlet temperature. This result may be from the standpoint of exergy, which is a useful method to com-
explained by the influence of exergy leakage due to thermal losses, plement, not to replace the energy analysis. Exergy analysis quan-
and exergy destruction due to heat transfer from the sun to the tifies the collection and useful consumption of exergy and
absorber, which are strongly dependent of HTF temperature. Ac- pinpoints the unrecoverable losses, leading the way to improve the
cording to Figs. 3e6, an increase in the HTF inlet temperature leads system. Results show that collector efficiency and collector exergy
to a significant increase in Collector Exergy Efficiency, but it causes efficiency are increasing functions of mass flow rate for a given
a reduction in Collector Efficiency. When HTF inlet temperature value of solar intensity. On the other hand, for low values of solar
increases, Collector Efficiency shows an average reduction of 15.5% intensity (I < 500 W/m2) and a given mass flow rate, collector
and 7.6% for irradiance levels of 250 and 500 W/m2 respectively exergy efficiency exhibits a maximum as inlet temperature
according to Figs. 3 and 4, whereas the average reduction of Col- increases. Collector efficiency is a decreasing function of inlet
lector Efficiency for irradiances of 750 and 1000 W/m2 are 4.7% and temperature over the whole solar intensity range studied (100 W/
3.25% respectively, as it is shown in Figs. 5 and 6. m2 < I < 1000 W/m2). However the influence of inlet temperature
On the other hand, Figs. 3 and 4 showed an average increase of on collector efficiency significantly diminishes at high solar
6.9% and 7.9% in Collector Exergy Efficiency for solar irradiance intensities.
levels of 250 and 500 W/m2, respectively. For high solar irradiance, The effect of wind speed and vacuum in annulus on both Col-
according to Figs. 5 and 6, the average increase was 7.3% and 7.7% lector Efficiency and Collector Exergy Efficiency is shown in Figs. 7e
for solar irradiance of 750 and 1000 W/m2, respectively. The 10. According to Figs. 7 and 8, results indicate that vacuum in
maximum Collector Exergy Efficiency, under vacuum condition, annulus reduces the effect of wind speed because both efficiencies
was between 30.3% and 36.6%, for irradiance levels of 250 W/m2 showed no significant variation with wind speed. However, in
and 1000 W/m2, respectively. Results described above allows to absence of vacuum, the increase of wind speed leads to average
conclude that in days with low irradiance levels (250500 W/m2) reductions of 5% and 4% for Collector Efficiency and Collector
the increase of HTF inlet temperature to achieve maximum Col- Exergy Efficiency, respectively. According to Figs. 9 and 10, when
lector Exergy Efficiency would significantly penalize the Collector pressure in annulus is below 1 Torr, convective heat transfer inside
Efficiency, but in days with high irradiance levels (750e1000 W/ the annulus is not significant, consequently its contribution to the
m2) the maximum or near maximum Collector Exergy Efficiency exergy loss due to heat transfer from absorber to the surroundings
can be achieved with a less severe impact on Collector Efficiency. is also reduced. On the other hand, if pressure in annulus is above
However, it is clear that a simultaneous maximization of both 1 Torr, convective heat transfer inside the annulus is increased
efficiencies is not possible by just adjusting the HTF inlet temper- thereby increasing its contribution to the exergy loss due to heat
ature. This opposite trend of Collector Efficiency and Collector
Exergy Efficiency is explained by the behavior of the exergy
destruction due to heat transfer between the absorber and the HTF,
and the thermal losses due to heat transfer from absorber to the
environment. An increase in HTF inlet temperature would increase
the thermal losses and a decrease in exergy destruction due to heat
transfer between the absorber and the HTF, as it can be seen in
Figs. 9 and 10, causing a decrease in Collector Efficiency and an
increase in Collector exergy efficiency.
The optimum operating conditions for PTCs can be assessed by
means of collector efficiency analysis and collector exergy effi-
ciency analysis. The common aim is to optimize the thermal

Table 1
Geometrical and optical data for the LS-3 parabolic trough col-
lector. Adapted from [20].

Parameter Value

Aperture width (m) 5.76


Focal length (m) 1.71
Length per element (m) 12
Length per collector (m) 99
Receiver diameter (m) 0.07
Geometric concentration 82:1
Fig. 3. Collector efficiency and collector exergy efficiency vs HTF inlet temperature for
Peak optical efficiency (%) 80
different values of mass flow. I ¼ 250 W/m2.
584 R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586

Fig. 4. Collector efficiency and collector exergy efficiency vs HTF inlet temperature for Fig. 6. Collector efficiency and collector exergy efficiency vs HTF inlet temperature for
different values of mass flow. I ¼ 500 W/m2. different values of mass flow. I ¼ 1000 W/m2.

transfer from absorber to the surroundings, which is the exergy exergy destruction diminishes because the temperature difference
waste that can be affected by the wind speed. is lower. However, the exergy losses to the surroundings increase as
For mass flow rate, Figs. 3e6 shows that both Collector Effi- the HTF inlet temperature raises as a consequence of the temper-
ciency and Collector Exergy Efficiency have small variations with ature difference. The combine effect of exergy destruction due to
mass flow rate and the optimum value for both efficiencies was heat transfer between the sun and the absorber and exergy losses
practically the same for the three mass flow rates considered. to the surroundings is accountable for an optimum exergy effi-
Figs. 11 and 12 show that exergy losses and exergy destruction are ciency point. After this point is reached, exergy losses to sur-
almost independent from mass flow rate because exergy destruc- roundings accounts for 5%e10% of the total exergy wasted and
tion due to the friction of the HTF and heat transfer between the increase more rapidly than the decrease of exergy destruction due
absorber and the HTF are the ones that have a noticeable variation to heat transfer.
with mass flow rate, but their contribution to the total exergy losses
and destruction is less than 0.5%. 5. Conclusions
Figs. 9 and 10 illustrate the effect of HTF inlet temperature on
the exergy destruction due to heat transfer between the sun and An exergy analysis of parabolic trough solar receiver was carried
the absorber. This exergy destruction accounts for 35%e40% of the out based on a heat transfer model proposed by the authors. The
total exergy wasted. When HTF inlet temperature increases, the performance of the solar receiver was simulated for a fixed values

Fig. 5. Collector efficiency and collector exergy efficiency vs HTF inlet temperature for Fig. 7. Collector efficiency and collector exergy efficiency vs HTF inlet temperature
different values of mass flow. I ¼ 750 W/m2. with and without vacuum, for natural and forced convection. I ¼ 250 W/m2.
R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586 585

Fig. 8. Collector efficiency and collector exergy efficiency vs HTF inlet temperature _ ¼ 7 kg=s;
Fig. 10. Dimensionless exergy losses vs Inlet temperature. Conditions: m
with and without vacuum, for natural and forced convection. I ¼ 750 W/m2. Vair ¼ 5 m=s (forced convection); without vacuum.

of solar irradiance, HTF mass flow rate, HTF inlet temperature, with  Solar Irradiance has a significant effect on the performance of
and without vacuum in annulus, and with presence and absence of the parabolic trough solar receiver. High solar irradiances allows
wind. Based on the results obtained, the following conclusions are to work at higher HTF inlet temperatures, which leads to high
proposed: values of Collector Exergy Efficiency with a negligible reduction
of the Collector Efficiency.
 Current results are useful to improve the design of PTCs and  The optimal performance of PTC is independent from the mass
compare performances between PTCs options. However oper- flow rate, since exergy destruction due to friction of the heat
ating conditions are also determined by others factors beyond transfer fluid and heat transfer between the absorber and the
exergy analysis of the collector like collector area, which impacts HTF depends on mass flow rate, but their contribution to the
capital costs as the fuel (sunlight is free), and pumping power at total exergy wasted is less than 0.5%.
increasing mass flow rates.  The performance of the solar receiver is strongly dependent on
 HTF inlet temperature has a significant effect on Collector Effi- vacuum in annulus. Vacuum in annulus mitigates the effect of
ciency and Collector Exergy Efficiency. HTF inlet temperature wind speed, but its absence increases the thermal losses to the
affects the exergy leakage due to thermal losses, and exergy surroundings, which leads to a reduction of both Collector Ef-
destruction due to heat transfer from the sun to the absorber. ficiency and Collector Exergy Efficiency.

_ ¼ 7 kg=s;
Fig. 9. Dimensionless exergy losses vs inlet temperature. Conditions: m Fig. 11. Dimensionless exergy losses vs mass flow rate. Conditions: I ¼ 750 W/m2;
Vair ¼ 0 m/s (natural convection); without vacuum. Vair ¼ 0 m/s (natural convection); without vacuum in annulus.
586 R.V. Padilla et al. / Applied Thermal Engineering 67 (2014) 579e586

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