Beruflich Dokumente
Kultur Dokumente
SOLUTIONS
General Chemistry II
1st Semester AY: 2019 - 2020
DEFINITION AND TYPES OF SOLUTIONS
A solution is a homogenous mixture of 2 or
more substances.
Percent by Mass
mass of solute
% by mass = x 100%
mass of solute + mass of solvent
mass of solute x 100%
=
mass of solution
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
𝑝𝑒𝑟𝑐𝑒𝑛𝑡 𝑏𝑦 𝑣𝑜𝑙𝑢𝑚𝑒 = × 100
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛
• Solution:
34.5 𝑔
% 𝑏𝑦 𝑚𝑎𝑠𝑠 = × 100 = 𝟐𝟏. 𝟔 %
159.5 𝑔
CONCENTRATION UNITS BASED ON
MOLES
1. Mole Fraction
2. Molarity
3. Molality
Mole Fraction (X)
moles of A
XA =
sum of moles of all components
Concentration Units
Molarity (M)
moles of solute
M =
liters of solution
Molality (m)
moles of solute
m =
mass of solvent (kg)
12.3
SAMPLE PROBLEMS
• A solution is prepared by mixing 25.0 g of water, H 2O, and 25.0 g of ethanol, C2H5OH.
Determine the mole fractions of each substance.
moles of each substance
25.0 𝑔
𝑚𝑜𝑙 𝐻20 = = 1.39 𝑚𝑜𝑙
18.02 𝑔/𝑚𝑜𝑙
25.0 𝑔
𝑚𝑜𝑙 𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = = 0.543 𝑚𝑜𝑙
46.08 𝑔/𝑚𝑜𝑙
Mole fractions
1.39 𝑚𝑜𝑙
𝑋𝐻2𝑂 = = 𝟎. 𝟕𝟏𝟗
1.39 𝑚𝑜𝑙 + 0.543 𝑚𝑜𝑙
0.543
𝑋𝑒𝑡ℎ𝑎𝑛𝑜𝑙 = = 𝟎. 𝟐𝟖𝟏
1.39 𝑚𝑜𝑙 + 0.543 𝑚𝑜𝑙
What is the molarity of a solution containing 28.0 grams of NaCl per 1.00 L of
solution?
28.0 𝑔
𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑁𝑎𝐶𝑙 = 𝑔 = 0.479 𝑚𝑜𝑙
58.44
𝑚𝑜𝑙
0.479 𝑚𝑜𝑙
𝑚𝑜𝑙𝑎𝑟𝑖𝑡𝑦 = = 𝟎. 𝟒𝟕𝟗 𝑴
1.00 𝐿
Calculate the molality of a sulfuric acid solution containing 24.4 g of sulfuric
acid in 198 g of water. The molar mass of sulfuric acid is 98.09 g.
0.249 𝑚𝑜𝑙
𝑚𝑜𝑙𝑎𝑙𝑖𝑡𝑦 = = 𝟏. 𝟐𝟔 𝒎
0.198 𝑘𝑔
DILUTE CONCENTRATION UNITS
• Parts per million, and parts per billion are often used in expressing very low
concentrations of liquid and gaseous solutions.
What is the concentration in ppm of calcium if 250 grams of the solution
contains 9.75 X 10-4 grams Ca?
9.75 × 10−4 𝑔
𝐶𝑎 𝑝𝑝𝑚 = × 106 = 𝟑. 𝟗𝟎 𝒑𝒑𝒎
250 𝑔
SAMPLE EXERCISES
1. Calculate the amount of water (in grams) that must be added to 5.00 g of
urea in the preparation of a 16.2 percent by mass solution.
2. Calculate the mole fraction of H2O2 in a 20.0 % by mass aqueous solution.
Assume that the solution is 100. grams.
3. How many grams of KMnO4 are needed to make 100.0 mL of 0.250 M
solution?
4. What is the mass of NaOH needed to produce 250. mL of 0.100 M solution?
5. What is the mass of water (in kg) that is needed to be added to 14.3 grams
of sugar (C12H22O11) to produce a 0.0621 molal solution?