UNIVERSIDAD NACIONAL DE TRUJILLO

FACULTAD DE INGENIERÍA QUÍMICA

ESCUELA DE INGENIERÍA QUÍMICA
DEPARTAMENTO DE INGENIERÍA QUÍMICA
Curso: Modelamiento y Simulación de Procesos
Docente: Dr. Ing. Guillermo D. Evangelista Benites

S1 10970 kg/h
M2
MIX
macid = 6527 kg/h
magua = 4443 kg/h

S16 Ts16 = 24
h1o = -0.04 kJ/mol m1 = 0.0193 kg NH3/h
h2o = 1.81 kJ/mol m2 = 4457.1 kg H2O/h
h3o = -0.13 kJ/mol m3 = 1932.9 kg NH4NO3/h
hacido = -0.11 kJ/mol macid = 6527.2 kg HNO3/h nacid = 103573

H1
Qh = 1160 kW
HEAT
S17
h1 = 4.68 kJ/mol m1 = 0.0193 kg NH3/hTs17= 149 °C
h2 = 11.32 kJ/mol m2 = 4457.1 kg H2O/h
h3 = 16.50 kJ/mol m3 = 1932.9 kg NH4NO3/h
hacid = 13.64 kJ/mol macid = 6527.2 kg HNO3/h
S2
M3
Ps2 = Ps17 = Ps18 = 4.5 bar
MIX
m0 = 1852
S18 Ts2 = 108
n0 = 30.2 mol/s m0 = 1852.0 kg NH3/h h0 = 3.08
n1 = 3.15E-04 mol/s m1 = 0.0193 kg NH3/h h1 = 4.68
n2 = 68.71 mol/s m2 = 4457.1 kg H2O/h h2 = 11.32
n3 = 6.71 mol/s m3 = 1932.9 kg NH4NO3/h h3 = 16.50
nacid = 28.77 mol/s macid = 6527.2 kgHNO3/h hacid = 13.64
Ts18 = 149 °C
epsilon = 28.8 mol/s S5A
R1
NH3 c = 1764 kg NHNO3/h REACT
NH4NO3 g = 8290 kg NHNO3/h m4c = 88.19
Qr = -745 kW m5c = 10223
m6c = 4457
Capacidades caloríficas promedio Ts5 = 238
Especie MM, g/g-mol Cp, kJ/mol. Cp, kJ/kg.°C Hf, kJ/mol n4 = 1.44
NH3(g) 17.03 0.041 2.408 -46.19 n5 = 35.48
HNO3(l) 63.02 0.110 1.745 -206.57 n6 = 68.71
NH4NO3(v) 80.04 0.126 1.574 -399.36 h4 = 8.33
H2O(v) 18.02 0.035 1.942 h5 = 33.74
Air(g) 28.97 0.030 1.036 h6 = 52.94

Constantes de Antoine
A B C
 H2O 7.96681 1668.21 228
NH3 7.55466 1002.711 247.885

dHrx (25°C) -146.6 kJ/mol

dCp -0.025 kJ/mol.°C

Capacidades caloríficas: constantes (kJ/mol.°C)

Especie Estado a b c d Hf, kJ/mol
NH3 g 3.515E-02 2.95E-05 4.22E-09 -6.69E-12
HNO3 l 1.100E-01
NH4NO3 s 1.331E-01 5.4
H2O l 7.540E-02
v 3.346E-02 6.88E-06 7.60E-09 -3.59E-12
Air g 2.894E-02 4.15E-06 3.19E-09 -1.97E-12
 AMMONIUM NITRATE PLANT
S14

m12 = 1626 kg NH4NO3/h

S10

m10 = 306.69 kg NH4NO3/h

m14 = 0.02 kg NH3/h
m15 = 14.26 kg H2O/h
°C
xw = 0.171 Presiones de vapor
CD1
xa = 0.0002 Pvw = 17703 mmHg
CONDNS
Pva = 259600 mmHg
mol/h

Kw = 5.25
Ka = 76.92

C1
CALC1
S8

PS8 = 3375 mmHg

kg NH3/h
°C S4
E1
kJ/mol
HEAT EXCHANGER
kJ/mol m7 = 664.6 kg air/h
kJ/mol Table B.6. = 623.2 kJ/kg Ts4 = 205 °C
kJ/mol
kJ/mol
mS5Bs = 14768 kg/h
S5B S6
CN1
M1 MIX
CNVG
kg NH3/h m4s = 88.19 kg NH3/h m4 = 88.19
kg NH4NO3/h m5s = 10223 kg NH4NO3/h m5 = 10223
kg H2O/h m6s = 4457.1 kg H2O/h m6 = 4457.1
°C m7 = 664.6
mol/s
mol/s
mol/s C2 CALC2 S3
kJ/mol m7 = 664.6
kJ/mol Ts3 = 24
kJ/mol
m4s = 88.1921331 kg NH3/h
m5s = 10222.9035 kg NH4NO3/h
m6s = 4457.10938 kg H2O/h
 m16s = 4442.85 kg H2O/h
m17s = 88.1728345 kg NH3/h

fo1 = 1.4645E-11
fo2 = 4.7611E-07
fo3 = 0
fo4 = 0
fo5 = 0
Hv, kJ/mol

40.656
ATE PLANT

m7 = 664.6 kg air/h
m16s = 4442.9 kg H2O/h S11
m17s = 88.17 kg NH3/h
yw = 0.898 m7 = 664.6
ya = 0.0188

S9
SP3
SEPR

S12

m16 = 4443
m7 = 664.6 kg air/h m17 = 88.17
m8 = 88.19 kh NH3/h
m9 = 4457.1 kg H2O/h
m10 = 306.7 kg NH4NO3/h

Ta =Ts8 = 221 °C

S7

m7 = 664.6 kg air/h
m8 = 88.19 kh NH3/h
m9 = 4457.1 kg H2O/h
m10 = 306.7 kg NH4NO3/h
Ts7 = 233 °C
S13 S15
SP1 SP2
SEPR SEPR
kg NH3/h m11 = 9916.2 kg NH4NO3/ m13 = 8290.0
kg NH4NO3/h
kg H2O/h
kg air/h

kg air/h
°C
kg air/h

kg H2O/h
kg NH3/h

kg NH4NO3/h