D.T.E.A.

Senior Secondary School, Pusa Road New Delhi

Chemistry Holiday Homework Class XII
Solve the following Questions
Chapter 1 Solutions
Q 1 Calculate the Mole Fraction of the solute in an aqueous solution containing 18.0g of
Glucose in 100g of water. (Molar Mass of Glucose=180g)
(Ans: 0.018 )
Q 2 Calculate the Molality and Mole Fraction of the solute in an aqueous solution containing
23.4g of NaCl in 90g of Water. (Na=23, Cl=35.5)
(Ans:4.44 m& 0.074)
Q 3 Calculate the Molarity and Molality of 20% aqueous Ethanol solution (C2H5OH) by Volume.
(Density of the solution=0.960g/cm3)
Q 4 A 10 cm3 sample of Human Urine was found to have 5mgs of Urea on analysis. Calculate the
Molarity of the Given sample w.r.t. Urea (Molar Mass of Urea=60g)
(Ans:0.008 mole/litre)
Q 5 If 4g of NaOH are dissolved in 100cm3of the solution, what shall be the difference in its
Normality and Molarity?
(Ans: No Difference)
Q 6 A Solution contains 2.80 moles of Acetone and 8.20 moles of chlorofoam (CHCl 3) Calculate
the Mole Fraction of Acetone.
(Ans: 0.255)
Q 7 Calculate the Molality of a solution obtained by dissolving 15.87g of Ethyl Alcohol in 168g of
H2O
(Ans:
2.05m)
Q 8 Determine the Molality of a solution formed by dissolving 0.850g of NH3 in 100g of H2O
(Ans: 0.5m)
Solve the Questions Using Henry’s law
Q 9 The Mole Fraction of He in a saturated solution at 0®Celsius is 1.2×10-6 Find the Pressure of
He above the solution.Given Henry’s Constant=6.8×10-6atm-1
(Ans0.176 atm)
Q 10 N2 is bubbled through H2O at 293K Thw partial of N2 is found to be 0.987bar. Calculate the
amount of N2 in miilimoles that would dissolve in 1 litre of H2O Given Henry’s constant for N2 in
H2O at 293K is 76.8 Kbar
(Ans: 0.716 millimoles)
Solve the Questions using Roult’s Law
Q 11 Benzene and Toulene(C6H5CH3)form nearly Ideal solution at a certauin temperature,the
vapour pressure of the pure toulene is 50mm Hg For this temperature Calculate the vapour
pressure of solution containing equal weights of two substances.
(Ans 104.1mm of Hg)
Q 12 The Mole Fraction of C2H5OH in its solution with Methyl Alcohol is 0.80.The Vapour
Pressure of C2H5OH at the temperature of the solution is 40mm of Hg. What is its Vapour
Pressure in the solution if the solution is ideal ?
(Ans :32mm)

Relative Lowering Of Vapour Pressure

Q 13 Vapour Pressure of H2O at 293K is 17.51mm Lowering of Vapour Pressure of a sugar
solution is 0.0614mm Calculate
i. Relative Lowering of Vapour Pressure (Ans: 0.00351)
ii. Vapour Pressure of the solution (Ans:17.4468mm)
iii. Mole fraction of H2O (Ans:0.99649)

Hint
i. P1=17.51mm
P1-Ps=0.00614mm , (P1-Ps)/P1=?
ii. Ps=?
Iii(.P-Ps)P=N2/(N1+N2)
Q 14 The Vapour Pressure of water at 293K is 17mm. Calculate the Vapour Pressure of a
solution containing 2g of Urea(Molar Mass =60) in 50g of H2O.Assume that the solution is not
dilute.(Ans 16.799mm)
Q 15 The Vapour Pressure of2.1% of an aqueous solution of a non electrolyte at 373Kis 755mm
Calculate the ;:/degree/mole) (Ans:18.68 atm)
Q 16 Calculate the concentration of that solution of Sugar which has osmotic pressure of
2.46atm at 300K.
(Hint: p=2.46 atm
T=300K
R=0.0821 Latm/kmol
Apply, P=CRT ) (Ans:3429 mol_1)
Q 17 Calculate the molal elevation constant of H2O, it being given that 0.1 molal aqueous
solution of a substance boiled at 373.052K
Hint:
m=0.1
B.P. of solution=373.052K
ϫTb=KBM
Kb= ϫTb/m (Ans:0.52 C/m
Q 18 10g of a Non Volatile solute when dissolvred in 100g of Benzene raises its boiling point by
1K. What is the molecular mass of the solute? (Kb for C6H6 =2.53K/m)
(Ans:253g/mol)
Q 19 Calculate the Boiling point of a solution containing 0.456g of Camphor(molar mass
=152)dissolved in 31.4g of acetone (B.p.=56.30C) If the Molecular elevation constan per 100g of
Acetone is 17.2C
Hint:
Kb=17.2C/100g
ϫTb=0.16C
B.P. of solution =56.30+0.16
=? (Ans:56.46C)
Q 20 A solution containing 34.2g of canesugar(C12H22O11) dissolved in 500cm3 of water form at -
0.374C Calculate the freezing point depression of constant of water.
(Ans:1.87K/m)
Q 21 A solution of urea in water has a boiling point of 100.128C. Calculate the freezing point of
the same solution Molal Constant for water Kf and Kb are 1.86C and 0.512C respectively.
Hint:
ϫTf=100.128-100=0.128C
ϫTf=KTb*m
To calculate the depression in freezing point
Kf=1.86C
Let m=x
ϫTf=Kf*m
Freezing point of the solution :
Ts=T0- ϫTf (Ans:0.465C)
Q 22 The Freezing point depression of 0.1 molal solution of CH3COOH in C6H6 is 0.256K Kf for
C6H6 is 5.12K kg/mol what conclusioncan youb draw about the molecular state of CH3COOH in
C6H6?(Ans:Molar mass is diuble of the theoritical value Hence CH3COOH exist as doubly
associated)
Q 23 The Freezing point odf 0.1m NaCl solution is 0.372C What conclusion would you draw
about its molecular state? Kf of H2O is 1.86K kg/mol (Ans:NaCl is
dissociated completely)
Q 24 Which of the following solution will have the highest and which will have the lowest
freezing point?
i. 0.1M NaCl Solution
ii.0.1 M Glucose solution
iii 0.1 M BaCl2 solution (Ans:Gluicose is higher and BaCl 2
is lower )

Chapter 3(Electro Chemistry)

Q 1 How much charg is required for e following?
i. 1mol of Al3+ to Al (Ans: 289500C
ii.1 mol of Cu2+ to Cu 193000C
iii. 1 mol of MnO4- to Mn2+ 482500C)
Q 2 How many columb of Electricity are required for
i. Complete Qxidation of 90g of water (Ans:965000C
ii Complete reduction of 100ml of 0.1M KMNO4 solution 4825C
Q 3 If specific conductivity of N/50 KCl solution at 298K is 0.002765 mho/cm and resistance of a
cell containing this solution is 100 ohms Calculate the Cell Constant. (Ans:0.2765cm -1)