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Abstract
A mathematical model to simulate the coupled heat and mass transfer in heated porous media, as well as the
r~~lting stress, is described. A finite element analysis, assuminghomogeneouselastic material, is used to study the
temperature and pore pressure distribution, and the rate of moisture propagation through a concrete containment
wall under different time-dependent temperature boundary conditions. Results are also presented for the internal
stresses caused by the presenceof temperature gradients, pore pressure and the release of chemicailybound water at
high temperatures, Stress analysiscalculationsare superimposedover the calculationsof the moisture propagation.
The temperature,porepressureand volume change resultingfrom the loss of bound water, as derived by the thermal
mass transport calculation, are used as input for rhe stress analysis.
Dayan and Gluekler (Dayan, 1982) studied moisture propagation and induced stressescaused
heat and moisture transport in surface-heated by temperature, pore pressure and shrinkage in a
concrete slabs, in the context of the structural concrete wall subjected to different time-depen-
integrity of nuclear reactor containment struc- dent heating rates.
tures. A heat and mass transfer model, based on
an evaporation and recondensation mechanism
(excluding the release of non-evaporable water), 2. Mathematical model
was solved numerically. Results were presented
for the water release, temperature and pore pres- The state of water in concrete is categorizedas
sure distribution. free or capillary water, adsorbed or chemically
Dhatt et al. presented details on the pore pres- bound water. Fig. l(a) shows a schematicview of
sure and temperature distribution during drying the state of water in the pore system. Water in a
of refractory concrete (Dhatt, 1986), using the chemicallybound form is strongly adhered to the
finite element mode1 of Bazant and Thouguthai, surfaces and is considered to be an integral part
and compared it with experimental results of the of the solid. Adsorbed water covers the pore
temperature distribution. The effects of perme- surface in several monolayers. The amount of
ability and the heat rate also were investigated. adsorbed water (or the number of monolayers of
Schneider and Herbst presented experimental adsorbed water) decreaseswith the decreasedrela-
resul?s for the loss of weight, moisture distribu- tive humidity in the pore system. At the pore wall,
tion and pressure development for heated con- the innermost adsorbed water is considered to be
crete samples subjected to a slow heating rate (up less accessible for motion. The rest of the pore
to 600 “C), for plain and prestressed concrete, space is assumed to be filled by free water, which
using different types of aggegate (Schneider, is removable by heating. Titus+the cqillary water
1987). Witakowski and Pietreyk analyzed the is considered to be part free water and part ad-
thermal stressesinduced by the temperature gradi- sorbed water. A distinction is also made in terms
ents caused during hydration (Witakowski, 198?). of evaporable and non-evaporable water. Part of
Wu and Ouyang presented a finite element tech- the evaporable water is the same as free water,
nique for computation of the shrinkage stress in and the rest of the evaporable part includes the
prestressedconcrete containment (Wu, 1989).Nu- outer layer of adsorbed water.
mao and Mihashi presented experimental results When concrete structures are subjected to high
of drying shrinkage caused by water loss in con- temperatures or heating, as shown in Fig. l(b), a
crete at certain constant temperatures up to 95 “C significant amount of bound water is releasedand
(Numao, 1991). pressure is induced in the pores. This causes the
Takiguchi and Hotta published results on the transport of capillary water through the pores.
thermal and shrinkage stresses of concrete, deal- Therefore, heat and mass transport in the con-
ing with the hydration reaction which occurs at crete structure are coupled, and are described by
low temperatures(Takiguchi, 1991).The degreeof energy and mass conservation equations.
hydration was formulated experimentallyand the
stress analysis method dealing with the hydration 2.1. Heat and mass transfer analysis
reaction was formulated numerically. Results for
the normal stress distribution caused by drying The mathematical mode1 used for the coupled
were presented. heat and mass transport is based on the model of
Majumdar et al. used the finite element formu- Bazant and Tbonguthar (Bazant, 1978). The
lation to estimate the stress resulting from the model is based on the foIlowingassumptions:
thermal and pore pressure loadings during mois- (1) the Dufour flux is negligible;
ture migration, occurring on heating of concrete (2) the material is homogeneous and isotropic,
walls (Majumdar, 1993).The present study is an and all the physical properties can be expressedas
extension of that work, to investigatethe heat and effective properties;
P. Majumdpr el 01.1 Nuclear Engineering and Design 156 (1995) 147-158 149
MoIstweflow
f--
_--- _c--
_----- bound water
-----
---c-__
-- ---
- - - -\ water
* . . , ’a. Ft-~e
’* . * .
i------- 03
3
*
4 t
z
L
w2
t
GIL 2
I . u2
INSlOE SURfACE OUTSIDE SuRrACE'
1 r_ i
w (4
Fig. I. (a) State of water in pore system. (b) Physical model of a concrete slab. (c) Discretization of the analytical model.
(d) Quadrilateral element used in stress analysis.
where
expansion, pore pressure and shrinkage resulting Fig. l(c). The material is assumed to be homoge-
from the release of bound water, the stresses neous and elastic. Four-node quadrilateral ele-
resulting from these three effects are computed ments (as shown in Fig. l(d)) are used, with a
together, and the total elF:t is observed. displacement vector given as (UjT = [u, wl uz w2
Stress analysis formulations are superimposed u3 w3 u, w4j. The displacements u and w are re-
over existing heat and mass transfer solutions, so lated to the nodal displacements U, and wi by
that the nodal temperatures and pore pressure
values calculated are used as input to perform u= c NiUi
stress analysis. It is assumed that the structure i=l
0 1
Relative vapor pressure P/Ps (Torrl The total strain {e} is related to the nodal
Fig. 2. Sorption isotherms. displacement {I/) by matrix [B], using
id = WC W (14) where the individual component terms of the
force vector {F) correspond to the changes in
On combining Eqs. (13) and (14), we obtain
temperature, moisture content, body force and
A= ; ( U)T[B]T[D][B]{U) dV pressure force respectively. For axisymmetric ge-
IY ometry, the stress and strain components are
(o}T= [ar a, a,, ere] and {.c}~= [E,E,qz ~1. The
remaining symbols in the force vector of Eq. (21)
are the r and z components of the body force
(R, Z), and those of the surface force (P,, P_)
respectively.
& is the potential energy of the body forces The nodal pressure calculations are used to
formulate the volumetric pressure loading equiva-
and is given by
lent to the body forces, which results in the calcu-
%= -IvWWIT{;]d~- (16)
lation of the equivalent force components R and
2. The surface force components (P,, P, ) result
Also, f& is the potential energy of the pressure from imposed pressures at the boundaries of the
analytical model.
forces and is given by
The volumetric strain components of .5r corre-
spond to the effect of the temperature change,
(17)
and ew corresponds to the effect of the change
in moisture. The thermal strain vector {sr}T =
On combining Eqs, (lo), (15)-(17), the potential
energy (II) of each element of the structure can be CIAT[l 1 0 l] and the change in nodaf tempera-
expressed as ture values (AT) are utilized to formulate ihe
element volumetric thermal strain components.
UllllllQlly,
~L’L’-- ihe strain vector resulting from the
change in volume because of moisture loss is
(&$Jr=CJl 1 0 11.
The strain resulting from dehydration (aw)is esti-
mated as the change in the volume of concrete per
unit volume of concrete. The change in the vol-
ume of concrete is assumed to be equal to the
volume of water released by dehydration. It is
expressed as
Using the principle of minimum potential en-
ergy, we have the global system of equations (22)
Table !
input parameters for rmwoR2
--_ --
Number of elements 100
Age of concrete 40 days
Initial humidity of concrete 0.95
Humidity of environment 0.70
Initial temperature 20 “C
Thickness of cOncrete 0.35 m
Saturation water content IOOkgm-
Mass of cement per unit concrete
volume 300kgm13
Density of concrete M10kgm-3
Waterxernent ratio 0.5
Volume of specimen 210m
Inner radius IOOOm
Thermal conductivity 1.674 J m-’ s-’ OC-’
Permeability IO-” m s-’
3. Numericalillustration
0.11p
Fig. 4. Temperature input at the inside surface.
500
-40min
------~min ------E3;&,
. . . . . . . .. .._..... - 40 mifl ..__. .._._.-..-... 80 min
.-+-.-.- 50 min .-.-.--- 1w min
-__--__--_.--‘a min W-t -..-._-..- 120mj”
\
0 0.05 0.10 0.15 0.201 Q 0.05 0.10 0.15 0.20 0.05 0.10 0.15 0.20
Fig. 5. Temperature distributions in the slab for different temperature conditions at the inside surface: (a) type I; (b) type II; (c) type
III.
The pore pressure in the type III case is lower than i.e. that the loss of all bound water causes
that in the type II case in most of the heating a decreasein the total change in volume. While the
periods. However, the peak value of the pore relationship between these two variables (water
pressure at 120min in the type III case is higher content and /I) is not fully known, this is consid-
than that in the type II case. This is because of the ered to be a good first approximation, from e
iqid increase in iiX im:aringrate in the iatter hait conservative point of view. More accurate estima-
of the heating period for the type III case. tion of these values would need to be determined
Fig. 7 shows the variations of the free water experimentally. Since only tensile stress can cause
content in the slab. The results show that, as the cracking, representative caszs of tensile stressesfor
heating progresses,moisture migrates towards the locations at 0.175, 0,875, 1.575 and 2.275cm,
outer surface, increasing the free water content in corresponding to the centroid of the first, third,
the region near the heated region. The peak values fifth and seventh elements, are shown in Figs.
of free water content in this region also increase, 8- 10.
as a result of the releaseof bound water. The shape It should be mentioned here that the magnitudes
of the plot and appearance of the peak are affected of the stresses resuttingfrom shrinkage are consid-
by the release of bound water with an increase in erably higher than those caused by pore pressure
temperature above a threshold of 100*C; this or the temperaturechange. The total stress that is
corresponds to the temperature variation shown in presented here is almost of the same magnitude as
Fig. 5, and the amount of bound water content that given by the shrinkage stress component. Fig.
shown in Fig. 3. Also, it can be noticed that, as the 8 shows stress plots for the type I case and shows
heating continues, the region near the heating very high peaks soon after dehydration starts, near
surface dries up and the peaks move toward the the element at r = 0.175cm. For the remaining
outer surface, from which moisture is lost to the elements, multiple peaks appeared, starting with
environment. smaller peaks. Similar trends are also noticed for
Figs. 8-10 show the variations in total tensile the type II and type III cases, as shown in Figs. 9
stress for differentheating conditions subject to the and 10 respectively.
input data given in Table 2. This total stress However, peaks started appearing at a later
includes contributions from the thermal stress, time when dehydration started based on the heat-
pore pressure loading and the contribution from ing rate shown in Fig. 4. Also, the magnitudes of
dehydration. It was assumed in this illustrative the induced tensile stresses are lower in cases II
examplethat the coefficientof shrinkage was /3 = 1, and III, as a result of the lower rate of heating,
P. Majutndar el al. I Nudeor
Engineering and Design 156 (19951 147-158 155
v-!r-
-6Clmin
_____-mmjn
. . .. . .. .. . . .. . .. . . 100 mi”
.-.-.-_- 110 min
G
3ow ‘1
\\ _..-..__.._
120min
B \
i
0 0.05 0.10 0.15 0.20 0 0.05 0.10 0.15 0.20 0 0.05 0.10 0.15
Distance (ml Distance (m) (c)%w 111 Distance (ml ??
Ww 1 (W Type 11
Fig. 6. Pore pressure distributions in the slab for different temperature conditions at the inside surface: (a) type I; (b) type II; (c)
type111.
which eventually gives lower rates of release of neous concrete wall subjected to temperature and
dehydration water. It may be noticed that the moisture prnpag+?iorr The rrra~lt~!ol of ?!K ten-
induced tensile stresses in all three cases are above sile stress can be monitored to seek indications of
the tensile limit of around 3 MI% for concrete. crack openings. The example illustrated showed
Also, the stresses mused by the release of mois- stress primarily dominated by shrinkage, and
ture are by far the largest, and are several orders showed stress values above the tensile stress limits.
of magnitude greater than the contributions from However, the magnitude and appearance of the
thermal stress and pore pressure. It appears that, stress peak with respect to space and time were
even if the strains and stresses or coefficient were significantly affected by the heating rate or time-
to decrease by a factor of 10, they still would be dependent temperarare boundary conditions at the
large enough to cause cracking. Then, only the heated surface. The numerical values of the stress
time of cracking would change, as depicted in shown illustrate the qualitative variation with time
Figs. 8- 10. Because the stresses resulting from the and space. More meaningful results could he ob-
change in moisture are so large, the coefficientof taineJ when accurate values of the modulus of
shrinkage /? and other factors that affect this elasticity, Poisson’s ratio, coefficient of thermal
volume strain must he evaluated by preciseexper- expansion, coefficientof shrinkage and other prop
iments. The present analysis is limited to ideal erties are utilized in the calculation. The accuracy
elastic materials without cracking, and the stress also should reflectthe variation of these properties
distribution is not limited by the shortest peak with the temperature and moisture content.
that reaches the tensile limit, i.e, weakening of The present analysis is limited to ideal elastic
cracked elements is not accounted for, since materials without cracking, and the stress distri-
cracking is not modelled in the stress program. bution is not limited by the shortest peak that
reachesthe tensile limit. Also, if it is assumed that
cracks exist in the original material, then any
4. Conclusions tensile stress would tend to open those cracks.
Then, the formulation for temperature and mois-
The comp’dter simulation provides a convenient ture propagation would need to be altered. A
tool to calculate the state of stress in a homoge- further improvement of the computational model
Free water content
2 - 3’5’=5s
33333
1 P
a ,g
Free water content
g g g g
P. Mqjumdnr et 01.1Nuclear
Engineering wrd De& 156 (1995) 147-158 157
Appendix G: Nomenclnme
- r = 0.175 cm a permeability
------ r P 0.875 cm
_....-. __.++
. . . . . . r 3 I.575 cm strain displacement matrix
PI
.-----_- r = 2.275 cm c specificisobaric heat capacity of concrete
-.A-.--+-- r -2.975 cm
ca heai of sorption of free water
heat capacity of isobaric water
ii material matrix
E modulus of elasticity
iF1 force vector
g acceleration resulting from gravity
h convective heat transfer coefficient
J moisture flux
k thermal conductivity
mass transfer c&Ecient
Ei
n
stiffness matrix
porosity
N shape function
P pressure
PO pressure in environment *
Y heat flux
: ---rrl;n*t-
Y”“.U...ti*l &I
. . . rwGo1
.““.W. Air4;nn
W.-I--.-C.
0 10 20 30 40 so 50 70 90 90 100 110 120
lime (min) R body force in r direction
Fig. IO. Variation of total tensile stress in the slab for type III
s surface
temperature conditions at the inside surface. i :imc
T temperature
TO temperature in environment
U displacement in r direction
Table 2 V VOhW
Input parameters for stress analysis
W displacement in z direction
Thermal moisture flux 0.0 W all free water
Modulus of elasticity 36 MPa Wd dehydration water
Poisson’s ratio 0.2 WWchange in dehydration water
Coefficient of thermal expansion 9.5 x lo-"*Cm' Z coordinate in axial direction
Cross-sectional area l.0m2
Caefficient of shrinkage I.o z body force in z direction
Greek letters