II

INSTITUT PERTANIAN BOGOR Name

PROGRAM PENDIDIKAN NIM
KOMPETENSI UMUM Group

CHEMISTRY MIDTERM Signature

ODD SEMESTER, 2OI8I2O19
Date: Friday,26 October 2018
Time: 120 minutes

..STUDENTS INVOLVED IN CHEATING

WILL RECEIVE A FAILING GRADE FOR THIS TEST"

T-F-S: Cross T if the statement is true, F if it isfalse, or S if the statement is not always true orfalse.
1. T-F - S A hypothesis is a consistent explanation ofa set ofobservations.
2. T-F - S A limiting reagent is an agentthat is completely consumed in areaction.
3. T-F- S A covalentbond is abond formed fromthe same atoms.

4. T - F - S Gas condensation is an example of a deviation from an ideal gas.

5. T - F - S A change from one phase to another phase results in the release ofenergy.

! _ 6. T - F - S 1M of NaOH is the same as the concentration of 1m of NaOH.

7. T- F- S The freezing point of salt water is lower than that of pure water.
8. T * F - S Thermal energy is the energy available by virtue of an object's position.
9. T-F-S A reaction will proceed spontaneously when AH, AS, and AG all have negative
values.

10. T - F - S The reaction CH3COOH @q1+ H2Oq? CH:COO @dt H:O+(,q) is a homogeneous
equilibrium.
Multiple Choice 15. The correct coefficients to balance the
Put an x for the correct answer on the provided followingequationconsecutivelyis.......
answer sheet! Cu + HNO: ) Cu(l.tO3)2 + NO + H2O
11. Whichofthefollowingsubstancesisnotapure A. 1,2,4,3,7 D.3,6,3,3,3
substance? 8.2,4,5,2,1 E.2,6,2,3,3
A. Felsy C.H2O6; E. NaOHluqy C. 3, 8,3,2,4
B. He 1g1 D. NaCl1,;
16. For the following reaction:
12. A piece of iron with mass of 0.6 g with volume CH3OH + 02 ) COz + HzO
of 0.12 mL will have density of . .... glmL When this reaction is balanced 1 mol of COz
A. 0.5 8.2 C.4 D. 5 E. 6 formed will correspond with....
A. 2 mol of CH:OH
13. The following process is considered as a B. 3molof 02
physical change.... C. 1 mol of CH3OH
A. Exploding firework D. water electrolysis D. 0.5 mol of 02
B. Rusting iron E. Electroplating E,. 1.5 mol of Oz
C. Melting iron
17. As much as 29 g of an organic compound
14. The ratio between neutrons and protons in zllU (C*Hy) was burned to give 88 g of COz and 45
is.... g of H2O. The empirical formula of this
A. 0.39 C. 1.59 8.2.59 compound is...
8.0.63 D. 1.63 A. CH+ C. CzHe E. C+Hro
B. CzHs D. C:Hro
18. 5g CaCO3 is reacted with 1 L HCI 1 M 1A The compound which is in a gas phase at a
according to the following equation: temperature of 25 oC and a pressure of 1 atm
CaCO3lpy + 2HCl ) CaClz (uq) * HzO(uq) * 1S...
COr,", A. HzOz C. CH+ E. HNO:
The limiting reagent is .. .. B. NH+ D. LiF
A. CaCOr C. CaClz E. COz
B. HCI D. HzO 25. A factor that causes a molecule to have high
viscosity is.. .
19. Fluoride acid is made through the following A. A high boiling point
reaction: B. A high melting point
CaF2+HzSO+)CaSO++2HF C. A strong dispersion force
In an experiment where sulfuric acid is in D. A weak dispersion force
excess, 97.5 g of CaFz produces 47 g of HF. E. A strong intermolecular force
The percent yield of this experiment is...
A.98% c.96% 8.94% 26. If a light bulb filled with argon at 1.20 atm and
8.97% D.95% 18 'C is heated to 85 oC at constant volume,
then the final pressure of argon inside the light
20. The correct Lewis svmbol for elements in bulb is ...
group VA is: A. 1.48 atm C.0.25 atm E.7.08 atm
ACE B. 0.98 atm D.5.77 atm

27. The fusion curve in the following picture is

shown by...
2r. The bond that is formed between Ca and Cl in P, *i
CaClz is....
A. An ionic bond because there is a shared
electron
B. A covalent bond because there is a shared
electron
C. An ionic bond because the Ca atom donates A. Line l-4 D. Point 3
its electron to the Cl atom B. Line24 E. Point 4
D. A covalent bond because the Ca C. Line 3-4
donates its electron to the Cl atom
E. A polar covalent bond because Ca is an 28. The solute in a solder solution is ...
electropositive atom and Cl is an A. Sn C. Pb E. Cr
electronegative atom B. Ag D. Zn

22. The group of three compounds with covalent 29. The solubility of compound X in water at 25
bonds is... oC and at a pressure of 1 atm is 35 glL. When
A. HCl, SClz, BaClz D. HzO, SOz, OFz 175 g of compound X is dissolved in 5 L of
B. HBr, NaF, LiI E. CaO, Li2O, MgO water at the same temperature and pressure,
C. H2SOa, KOH, KzSO+ then the obtained solution is a . . .. solution.
A. Diluted D. Unsaturated
23. The moment dipoles of NH3, HzO, SOz, HCI B. Supersaturated E. Concentrated
are 1.46;1.87; 1.60; 1.08, consecutively. The
C. Saturated
correct order for polarity is ....
A. NH: > HzO > SOz > HCI 30' The molality of a 6.58 M of ethanol
(cH3cH2oH) solution with density of 0.927
B. NH: < HzO < SOz < HCI g/ml- is .. ..
C. HzO > SOz > NH: > HCI A.0.001 m D.0.1 m
D. HzO < SOz < NHr < HCI B. 10.54 m E. 7.10 m
E. HzO > SOz > HCl > NHr C. 0.0892 m
 Cause and Effect Multiple Choice.
The following problems consist of three parts, the STATEMENT, the word BECAUSE, and the REASON,
which ore written consecutively.
Answer criteria:
A. If the statement is coruect, the reason is correct, and both statement and reason have a cause and ffict
relationship
B. If the statement is conect, the reason is correct, but both the statement and reason DO NOT have a
cause and ffict relationship
C. If the statement is correct, and the reason is wrong
D. If the statement is wrong, but the reason is correct
E. If both the statement and the reason are wrong

41. Mol is an intensive property 46. The size of cells in an isotonic solution will
BECAUSE remain relatively unchanged
Two substances with the same number of BECAUSE
moles contain the same number of atoms or An isotonic solution has a balanced amount
molecules of solute and solvent inside and outside of the
cells
42. The reaction coefficient of reactants and
products of a chemical equation must be 47. The melting process of ice has a positive
balanced entropy value
nr^ a rrdr
BECAUSE BECAUSE
Chemical equations must obey the law of The melting of ice follows the first law of
mass conservation thermodynamics

43. NH3is anexample ofapolar compound 48. The reactionofABz ---+ A* 28 has LH <0
BECAUSE BECAUSE
The arrangement of the electron pairs of NH, In this reaction, energy is absorbed
is tetrahedral
49. The reaction of CaCO31,; +
=: CaO1,y CO2G.;

44. Solid COz will not melt when it is heated at a has the value of Kp: Pcoz
temperature of 80 "C and a pressure of 1 atm BECAUSE
BECAUSE The Kp value is not influenced by solids
Liquid CO2 only forms when the pressure is
more than 5.2 atm 50. An equilibrium reaction of COlry + C12G; *
COCl2lgy will have a Kc value equal to the Kp
\!- 45. The boiling point of water is lower than the value
boiling point of H2S RECAIISE
BECAUSE The An* of that reaction is equal to 0
HzS has a molecular mass bigger than that of
water.
r
31. Based on the pictures below, the solution with 36. At an equilibnum process the following is
the lowest freezing point is... true. . ..
./--'\. ,---\
F-:n A. AG<O D.AG>O
B. AG:0 E.AH<O

ffi I ilm
ffiffi ffi
o: mol of solute particles
c. AH>0

)t_ For the following reaction:

Note: Ca(HCO:)21,; P CaOl'1 + 2 COzG; + H2O1g;.
o : mol of solvent pafiicles The equilibrium equation is ....

A. I B. II C.il D. IV E.V
lruro]lcorl'lr,ol
A'
a-^ -
32. Which of the following is an example of a lrarrqtrl
system that allows the movement of energy and
mass?
u
^ = EiHCoiJ
lcorl'lcool
A. A capped bottle D. Battery B.
B. A refrigerator E. A thermos w _
" - Fiaea;;
lcoo)
C. A swimming pool
c.
33. 2.04 mol of aluminum metal with a specific D. y =lco,1'[tt,o]
oC
heat of 0.903 Jig
oC.
has an initial temperature t = lcorl'
of 2l .5 If the aluminum metal receives 725
E.
^ Enuaan
J of heat, the final temperature of the metal will
be....
A.41.8 0C
D. 41.1
0C 38. If the known equilibrium constant for the
oC reaction of H2 + 12 + 2HI is 50 at 600 K, then
B. 42.t 8.42r.50C
0C the equilibrium constant for HI + Yz Hz + Yz Iz
c.315
15....

34. The known data is as follows:

A. 50 c.25 8.0.282
S(s) + 312 Oz(et + SOr (, AH : -395.2 kJ B. 100 D.0.141
2SO21g1 + Oz er ---- 2SOr t,t AH : -198.2 kJ
Determine the AH of the following reaction: 39. At a temperature of 923 oC, the reaction of
S15; + O21gy --. SOz(et 2NOz (st + Oz 1gy ? 2NO3 1ry has a K, value of
A. 1.2 kJ D. 390 kJ 56,1. The K. value of that reaction at the same
B.-197 kJ E. -296.1kJ temperature is...
c.-s93.4 kJ A. -21.25 C. 0.1s E. 5501
8.1.32 D.0.57
35. If 207 g of ethanol(C2H6O) is evaporated at its
normal boiling point, at 61.3 oC, and the molar 40. The formation reaction of HF from hydrogen
enthalpy of evaporation at this temperature is and fluorine has a K" value of 0.43 at a certain
28.5 kJ/mol, then the entropy for this process temperature. If 3 mol of each species are put in
is... .
a 1.5 L container, then the reaction will ...
A. 223.58 JtK D.399.67 JIK A. Have Q> K"
B. 383.64 J/K E. t57.93 llK B. Be at equilibrium
C. Not shift
c.287.17 IIK
D. Shift toward HF
E. Shift toward Hz and Fz
t-
Complex Multiple Choice
Read carefully the choices numbered (l) through 55. The pair(s) of molecules with their correct
(4). Cross: molecular geometry is/are. . .
(1) BF3 and NH3 - trigonal planar
A. If (l),
(2), and (3) are correct
(2) BeCl2 and COz - linear
B If (1) and (3) are cotect
(3) SO2 and HzO - linear
C If (2) and (4) are correct
(4) NH3 and PCl: - trigonal pyramid
D. If only (4) is correct
E. If ALL are corcect
s6. The correct statement(s) about "the Kinetics
51. Chemical and physical changes can occur in Molecular Theory of Gases" is/are ....
our daily life. The following processes that (1) Gas molecules always move in a certain
can be said to be chemical changes is/are... direction
(1) A (2) Gas molecules exert an attraction or
stone building becoming brittle when
exposed to air, water, or acid. repulsive force on one another
(2) The melting process of ice to water.
(3) The kinetic energy of gas molecules is
(3) The burning process of wood to become inversely proportional with temperature
charcoal.
(4) A gas is made up of molecules that are
(4) Moth balls (naphthalene balls) that separated from each other by distances
sublimate when exposed to open air. smaller than their own dimensions

52. The correct statement about the Rutherford 57. Strong electrolyte compound(s) is/are. ..

experiment is/are... (1) HCI

(1) It used alpha rays (2) CH3OH
(2) Lots of alpha rays were deflected (3) NaoH
(3) It used a gold plate (4) CoHrzOo
(4) It is the basis of the plum pudding
atomic model 58. The correct statement(s) about the solubility
of a solid compound in a solvent is/are....
53. The organic compound propanoic acid has
the formula of CHTCHzCOzH (1) The solubility of a solid compound
(1) The element with the smallest percent increases at lower temperature
mass is O
(2) The solubility of a gas in liquid is
(2) its molar mass is 88 g/mol inversely proportional with the gas
(3) 1g of propanoic acid contains more C pressure above the liquid
atoms than H and O atoms,
(3) A saturated solution contains the amount
(4) Its empirical formula is the same as its of solid compound higher than its
molecular formula solubility value
(4) The solubility of a gas will increase at
54. Based on the VSEPR theory, the compound(s) lower temperature
or ion(s) with linear geometry is/are...
(1) SO2 59. The First Law of Thermodynamics is
(2)rF2- associated with. ...
(3) H2O (1) Degree of disorder
(4) BeCl2 (2) The orderliness of pure crystal
(3) Direction of a spontaneous change
(4) The law of conservation of energy

60. For the reaction NzO+tet * 2NO21gy with AH :

56.9 kJ, the amount of NzO+ can be increased
by.. ..
(1) Increasing the pressure
(2) Increasing the volume
(3) Lowering the temperature
(4) increasing the concentration of N2Oa
Short Fill in the Blanks
Fill the questions below with the correct short answers!
61 .
Elements of A and B form 4 binary compounds K, L, M, and N. The mass ratio of A combined with
1.0000 g of B in compounds K, L, M, and N is 1:3:4:5. If the molecular formula of compound M is
AzBr, then the molecular formula of compound N is... ....
62. The average atomic mass of Lithium is 6.941 amu. Lithium has two isotopes: 6Li and'Li. Th" atomic
6Li 7Li isotope
mass of isotope is 6.015 amu with a natural abundance of 7.42o/o. The atomic mass of
is.......
63. Hydrogen (H) and Sulphur (S) atoms have electronegativity values of 2.I and2.5, respectively. The
type of bonding they will form is. .. ... ..

64, The intermolecular forces that occur when CCl+ is mixed with CH3(CHz)+CH: is. ......
65, The deeper someone dives, the higher the solubility of gas inside the blood, which is the application
of which law?
66. Measurement of energy using a bomb calory meter is done at constant ..... ..

67. 1 mol of gas A and 1 mol of gas B are addedto aclosed containerwith avolume of 1 L,. Those gases
then react according to the following reaction: 2A + 3B * AzB:. When the equilibrium condition is
reached, there is still 0.25 mol of gas B left unreacted. The value of Kc for this reaction is . .. . . ..

,A
 C
6= 6)r
ttF
(l}o( {)f. El c'
ts
LI

c{
lrr : ^zz
=.. =<; HgT *XF ,odf;
&
&

r- r-C 't,e -O i,r;

lt-
ru; ;F.
r.r
lr..\c
e'
-{r
0(,
-l-{f
r,..
8 '..1
v\d On
o0\c ()\{ r(}€
v,
&
^9
\J; \o
a4 q.f'
o0F
m
*hF <, l-(
* a' .,h$
r* 8zI
4
l. ro6 -I HV
t{}
r-
ZC rrc ..{I * [n: n
oo
,Y\ ol
e{
o.F'{
\o
52"
i$ ()€ Lrr
7*1 F Hu
-
6 r{r Ae c *UF
m
oC Y ct-(c
mG
t oo l-l v Ekc
r,
in aA
a
gt $s do( *a
ht:
*HI
u7n
H(
*a! -()g r+ ta
f,ri <
a.
r.- *(
\o
V
o\

(rl HS tO !{ Ci0\c >tq

oNu *U!
.d.
I'(€
ol-tC
ooe
\OH\ €\./c
Ot

sso(
o<
{c sE
nuu *{E
'(t
^<b
F'
-h$
\o "-&I
dr\

TiF
*c /h r
Orf
nxI .oE! €
r\ 'olJ'
o\

q).^ -<
53 L6
e.

-U Iil
(r\ '*$ L \C' },,
.,{i
".Qr "'&*
c.l
.-H9
r-
=;)*
o\

Yn .
6 $X J(: lra \O =c
.^ [I. 'r $F(;
tvt 2 - Fa a^l c.rU)i o*I
a{ !f 'oW9 = \o (},

tto ()^ q) a.. 2a Er. Q.r

r.,
*2$
('.1
H
f-( 6
tr"
Alrc \"iK
vp -0,(- nZi
\c r
\o L: o(
.^ tr.o po
'*Us *,}S
o.l !f,
oFI
a-
XH!N oZX
\o 6l
(},

a
\o .a6 (c? to
A. ,It c
ln v?<x H: e
cn;
-l -Z* -3fi
r-
61 H'

r-i * trf
r{i
a'l-+
Frr oNa
tc
H6
ctHr-
a"
AF\C *U{ otsF

rrl
(,O
y'*
t qs 9r (
U)'{ 0,d
rJ o(
r..'*'(' -#F
6 &
sl
(}:C bot (!E ,.{
rc
at; 4 /t!{ r'
d(v
,*s
n'
+.rl,t
TET
Ira
oUs
e{
*oE
6
\olq('
V1
*C(E
&

,d
\; (gq r.rl !i q) 6, Ld
*t(
*,( E td v;
^zi 6nxo udr -US "..hF
0c
I
INSTITUT PERTANIAN BOGOR Name
DIREKTORAT PROGRAM NIM
PENDIDIKAN KOMPETENSI UMUM (PPKU) CIass

PPKU CEMISTRY MIDTERM Signature

ODD SEMESTER 2018/2019
DATE: Friday, 26 OCTOBER 2018
Time: 120 minutes

Directions:
1. Put an X on your answer choice on the answer sheet. If you want to change the answer, put a double
line on your old answer (X), and cross your new answer.
2. Use a black/blue ballpoint to answer. It is not allowed to use pencil nor to making lots of corrections
using tip-x.

PUT AN X FOR THE CORRECT ANSWER

T_F_S
1. T F S 6. T F S

2.TF S 7. T F S

3.TF S 8. T F S

4.TF S 9. T F S

5.TF S 10. T F S

Multiple Choice
11. A B CD E 26 A B C D E
12.AB CD E 27 A B C D E
13.AB CD E 28 A B C D E
14.AB CD E 29 A B C D E
15.AB CD E 30 A B C D E
T6.AB CD E 31 A B C D E

_17. A B CD E 32 A B C D E

^8.AB CD E JJ A B C D E
19.AB CD E 34 A B C D E
20,AB CD E 35 A B C D E
21,AB CD E 36 A B C D E
22.AB CD E JI A B C D E
23, A B CD E 38 A B C D E
24.AB CD E 39 A B C D E
25,A8 CD E 40 A B C D E
Additional Data:
R: 0,0821 L atmlmol K: 8,314 J/mol K

PJU PJU 2 Coordinator

E
1

)&^-
 Cause and Effect Multiple Choice
41. A B C D E 46A B C D E
42.ABCDE 47A B C D E
43, A B C D E 48A B C D E
44.ABCDE 49A B C D E

45. A B C D E 50A B C D E

Complex Multiple Choice

51.ABCD E s6. A B C D E
52,ABCD E s7. A B C D E

53.ABCD E 58. A B C D E
54.ABCD E 59. A B C D E
55.ABCD E 60. A B C D E

- Shorf Fill in the Blanks

61

62.

63.

64.

65.

66.

67.

j-\

Best Wishes for u Successful Exum

PJU 1 PJU 2 Coordinator