Department of Education

Region VIII
Schools Division of Tacloban City
District Learning Center IV
LEYTE NATIONAL HIGH SCHOOL
Tacloban City

GENERAL CHEMISTRY II
QUIZ 4.2 Answer at least 10 items correctly, all to the best of your ability. Provide your solutions, may it
be numerical or not, on your answer sheets. Enclose your final answer in a box. Failure to follow the
instructions may nullify all your scribbles.
1. Chemical Kinetics. 75% of a first-order reaction was completed in 32 minutes. 50% of the reaction was
completed in how many minutes?
2. Chemical Equilibrium. Given the following reaction and equilibrium constant
3H2(g) + N2(g) 2NH3(g) , Kc = 60. The value of the equilibrium constant for the reaction,
3 1
NH3(g) H2(g) + N2(g) is?
2 2

3. Chemical Equilibrium. The reaction 3A(g) + B(s) 2C(aq) + D(aq) occurs at 25°C in a flask, which has 1.87L
available for a gas. After the reaction attains equilibrium, the concentration (M) of substances or number of
moles is as follows: 2.48 mol A, 2.41 mol B, 1.13 M C, and 2.27 M D. What is the equilibrium constant, Kc, for
this reaction at 25°C?
4. Chemical Equilibrium. NH4HS(s) NH3(g) + H2S(g). Kc = 2.5x10-3 at 35°C. If 2.00 moles of NH4HS is placed
in a 5.00-L vessel, how many moles of NH4HS will be present at equilibrium?
5. Chemical Kinetics. Sulfuryl chloride undergoes first-order decomposition at 320°C with a half-life of 8.75 hr.
SO2Cl2(g) SO2(g) + Cl2(g). What is the value of the rate constant, k, in s-1?
6. Chemical Kinetics. Sulfuryl chloride undergoes first-order decomposition at 320°C with a half-life of 8.75 hr.
SO2Cl2(g) SO2(g) + Cl2(g). If the initial pressure of SO2Cl2 is 791 Torr and the decomposition occurs
in a 1.25-L container, how many molecules of SO2Cl2 remain after 12.5 hr?
7. Chemical Equilibrium. A mixture of 0.236 mol A and 0.570 mol B were put into a 2.00-L flask which was then
closed. A and B react by the following equation: A(g) + 2B(g) 3C(g) + D(g). At equilibrium, the mixture was
found to contain 0.0752 mol D. How many moles of B are in the flask at equilibrium?
8. Chemical Equilibrium. A mixture of 0.236 mol A and 0.570 mol B were put into a 2.00-L flask which was then
closed. A and B react by the following equation: A(g) + 2B(g) 3C(g) + D(g). At equilibrium, the mixture was
found to contain 0.0752 mol D. What is the concentration of D in the flask at equilibrium?
9. Chemical Kinetics. For a certain first-order reaction, it is found that it takes 156 seconds for the
concentration of the reactant to fall from 0.100 M to 0.0500. How much time would it take for the concentration
of the reactant to fall from 0.0500 M to 0.0250 M?
10. Chemical Kinetics. For a certain reaction, it is found that the equation relating the specific rate constant, k
(in M/s), and the absolute temperature, T, is ln k = -4420/T + 12.20. What is the value of the specific rate
constant, k (in M/s) at 500 K?
11. Chemical Equilibrium. The organic matter in a 3.776 g of a mercuric ointment is decomposed with HNO3.
After dilution, the Hg2+ is titrated with 21.30 mL of a 0.1144 M solution of NH4SCN. Calculate the % Hg (200.59
g/mol) in the ointment. This titration involves the formation of a stable neutral complex, Hg(SCN)2.
Reaction: Hg2+ + 2SCN- Hg(SCN)2(aq)
12. Chemical Equilibrium Derive the expression for the equilibrium constant for the reaction:
2A + 4B C + 3D.

I’ll try if you’ll try. I am a failure if you think you are as well. No one is ought to be left behind.
Cheers!
Compiled by: ldddj.rch/2018
Compiled by: ldddj.rch/2018