Beruflich Dokumente
Kultur Dokumente
CDI 413B
2018
Chapter 1
This chapter will focus on the discussion of definition of fire, nature and origin
of fire, types of combustion and physical properties of matter related to fire. This
chapter will provide the students of knowledge on how fire starts and the things that
takes place before and after it ignites.
I. Definition of terms
b. Backdraft. A fire phenomenon caused when heat and heavy smoke (unburned
fuel particles) accumulate inside a compartment, depleting the available air,
and then oxygen/air is re-introduced, completing the fire triangle and causing
rapid combustion.
h. Exothermic reaction. Chemical reaction giving off heat in the process, such
as combustion.
n. Flame over. Also known as rollover. The ignition of heated fire gasses at the
ceiling level only. While dangerous to firefighters, this is not as deadly
as Flashover.
r. High-rise building. Any building taller than three or four stories, depending
upon local usage, requiring firefighters to climb stairs or aerial ladders for
access to upper floors.
w. Thermal balance. The hot area over the fire (often termed the fire plume or
thermal column) causes the circulation that feeds air to the fire.
However, when the ceiling and upper parts of the wall linings become
super-heated, circulation slows down until the entire room develops a kind of
thermal balance with temperatures distributed uniformly horizontally throughout
the compartment.
All matters exist of one of the three states – solid, liquid and gas (vapor). The
atoms or molecules of a solid are packed closely together, and that of a liquid is
packed loosely, the molecules of a vapor are not packed together at all, they are
free to move about. In order for a substance to oxidize, its molecules must be
pretty well surrounded by oxygen molecules. The molecules of solids or liquids are
too tightly packed to be surrounded. Thus, only vapors can burn.
When a solid or a liquid is heated, its molecules move about rapidly. If enough
heat is applied, some molecules break away from the surface to form a vapor just
above the substance (This vapor can now mixed with oxygen). If there is enough
heat to raise the vapor to its ignition temperature (temperature needed to burn),
and if there is enough oxygen present, the vapor will oxidize rapidly – it will start to
burn.
The start of burning is the start of a Chain Reaction (the burning process).
Vapor from heated fuel rises, mixes with air and burns, It produces enough heat to
release more vapor and to draw in air to burn that vapor. As more vapor burns,
flame production increases. More heat is produced, more vapor released, more air
drawn into the flames and more vapor burns, the chain reaction keeps increasing
the size of the fire increases until fuel is consumed.
A. Combustion
B. Types of Combustion
Oxygen Heat
Fuel
The figure show that if any side of the fire triangle is missing, a fire cannot
start or if any side of the fire triangle is removed, the fire will go off. With the
presence of the elements of fire, combustion may take place. Before a fuel will
burn, it must be changed to its vapor state. In a fire situation, this change usually
results from the initial application of heat (The process is known as PYROLYSIS).
The combustion process is better represented by the fire tetrahedron. The fire
tetrahedron is useful in illustrating and remembering the combustion process
because it has room for the chain reaction and because each face touches the
other three faces.
The basic difference between the fire triangle and the fire tetrahedron is that:
The tetrahedron illustrates how flaming combustion is supported and sustained
through the chain reaction. In this sense, the chain reaction face keeps the other
three faces from falling apart.
The fire tetrahedron also explains the flaming mode of combustion. The
modes of combustion are either Flaming mode or Surface mode (Glowing–
represented by the fire triangle)
a. Specific Gravity – the ratio of the weight of a solid or liquid substance to the
weight of an equal volume of water.
b. Vapor density – the weight of a volume of pure gas composed to the volume
of dry air at the same temperature and pressure.
c. Vapor Pressure – the force exerted by the molecules on the surface of a
liquid at equilibrium.
e. Boiling Point – the constant temperature at which the vapor pressure of the
liquid is equal to the atmospheric pressure.
a. The fuel is heated until its temperature reaches its fire point,
b. Decomposition takes place – moisture in the fuel is converted to vapor,
c. Decomposition produces combustible vapors that rise to the surface of the
fuel (free radicals)
d. Free radicals undergo combustion
Chapter II
This chapter will focus on the process of pyrolysis, combustion and oxidation
reaction. Also this chapter will provide knowledge to the students with regard to
different heat energy sources, heat transfer, production of heat and how it is
measured and the chemical properties of fire.
I. Pyrolysis
A. What is Pyrolysis?
C. Oxidation Reaction
A. What is Combustion?
Is one of the kinds of oxidation (the same as the actual burning). The rapid
oxidation accompanied by heat and light.
Oxidation
Production of
Combustible (Combustible
Combustible
Materials (fuels) is Vapors are mixed
Vapors (Free
being heated with the oxidizing
Radiclas)
agent)
Combustible
Material
Combustion
Oxidizing Ignition
Agent Source
a. Chemical
b. Electrical
c. Mechanical
d. Nuclear
Sources of Heat
a. Heat of Combustion
b. Spontaneous Heating
c. Heat of Decomposition
d. Heat of Solution
Sources of Heat
a. Resistant Heating
It is produced when the rate of heat generation is proportional to the
resistance and square of the current.
Lighting passing the cloud and the ground can develop very high
temperature in any material of high resistance in its path, such as wood
or masonry.
c. Inductive Heating
Sources of Heat
a. Frictional Heat
It resulted when mechanical energy is used in overcoming the
resistance to motion when two solids are rubbed together. Any friction
generates heat. The danger depends on:
b. Overheating of Machinery
c. Heat of Compression
Sources of Heat
a. Nuclear Fission
a. Conduction
b. Radiation
c. Convection
Methods of Transfer
a. Conduction
Thermal Conductivity
Cross – sectional area
Thermal Conductivity
The measure of the rate of flow of heat through unit area of the
material with unit temperature gradiant. Unit temperature gradiant means
that the direction of heat flow.
Means normal to the flow path and length of the flow path, the solution
to heat conduction problems takes into consideration the. Thickness of the
material subjected to temperature with the time constant.
b. Radiation
c. Convection
V. Heat Production
Chemical
Mechanical
Electrical
Compressed gas
Nuclear
No. Source of Heat Production of Heat
1. Chemical Heat is the result of rapid oxidation
2. Mechanical Heat is the product of friction
3. Electrical Heat is the product of arcing, shorting or other
electrical malfunction (Poor wire connections,
too much resistance, a loose ground, and too
much current flowing through an improperly
sized wire are other sources of electrical heat)
4. Compressed gas When a gas is compressed, its molecular
activity is greatly increased producing heat
5. Nuclear The product of the splitting or fusing of atomic
particles (Fission or fusion respectively)
Temperature Units:
Degree Celsius
Degree Fahrenheit
Kelvin or Absolute
b. Latent Heat
c. Condensation
The heat that is absorbed without changing the temperature of the water is
the latent heat. It is not lost but expended in changing the water to steam and
is then stored as energy in the steam. It is again released when the steam is
condensed to form water (Condensation).
2. Exothermic Reactions – those that release or give off energy (heat) thus
they produce substances with less energy than the reactants.
Types of Flames:
c. Based on Smoothness
Classification of Fuels
1. Class A Fuels – they are ordinary combustible materials that are usually made of
organic substances such as wood and wood-based products. It includes some
synthetic or inorganic materials like rubber, leather, and plastic products.
2. Class B Fuels – materials that are in the form of flammable liquids such as
alcohol, acidic solutions, oil, liquid petroleum products, etc.
3. Class C Fuels – they are normally fire resistant materials such as materials used
on electrical wiring and other electrical appliances.
The most obvious solid fuels are wood, paper and cloth. Its burning rate depends
on its configuration. For example, solid fuels in the form of dust will burn faster than
bulky materials.
b. Non-pyrolyzable solid fuels – solid fuels that are difficult to ignite. A common
example is charcoal. Chemical decomposition does not occur because there are no
pyrolyzable elements present. No vapors are released. The glowing combustion that results
is an example of a gas-to-solid reaction.
1. Biomass – it is the name given to such replaceable organic matters like wood,
garbage and animal manure that can be use to produce energy. For example, heat produced
by burning nutshells, rice and oat hulls, and other by-products of food processing. They are
often used to operate plant equipment.
a. Physical form – the smaller the piece of wood, the easier it is to burn.
b. Moisture content (water content) – the freshly cut wood is more difficult to
ignite and burn than dry wood.
c. Heat conductivity - a poor conductor of heat takes a longer time to ignite than
those materials that are good conductors of heat.
d. Rate and period of heating – less flammable materials don’t easily ignite and
needs direct contact with flame than highly combustible materials.
f. Ignition temperature – the higher the temperature, the faster it reaches ignition
point and it varies depending on the other factors above.
2. Fabrics and Textiles – almost all fibers and textiles are combustible. A fiber is a
very fine thin strand or thread like object. Fabrics are twisted or woven fibers. And textiles
are machine woven or knitted fabric.
Classification of Fibers
a. Natural Fibers – they come from plants (Coir – coconut fiber, Cotton – seed
fiber, pulp – wood fiber) , from animals (wool, silk, protein fibers – leather), from
minerals (asbestos)
b. Fiber finish or coating – fiber coating combined with organic fibers are
supportive to continued burning of fabric.
c. Fabric weight – the heavier the fabric, the greater its resistance to ignition, thus
delaying its ignition.
d. Tightness of weave – the closer the fiber are woven, the smaller the space it
contains, thus it takes a longer period to ignite it.
e. Flame retardant treatment – fabric treated with flame retardant have higher
resistance to ignition.
Fabric Ignition
3. Plastics – plastics are included as ordinary fuels under class A except those
materials of or containing cellulose nitrate. Cellulose Nitrate is a chemical powder used in
bombs, they are also called pyroxylin.
4. Coal – a black, combustible, mineral solid resulting from the partial decomposition
of matter under varying degrees of temperature. They are used as fuels in the production of
coal gas, water gas, and many coal compounds. They are also used to heat buildings and to
provide energy for industrial machinery.
The forms of coal are lignite or brown coal, sub-bituminous coal, bituminous coal,
anthracite. Bituminous coal is the most plentiful and important coal used by industry. It
contains more carbon and produces more heat than either lignite or sub-bituminous coal. It
is also the coal best suited for making coke. Antracite is the least plentiful and hardest coal.
It contains more carbon and produces more heat than other coals. However,
antracite is difficult to ignite and burns slowly.
5. Peat – It is partially decayed plant matter found in swamps called bags and used
as a fuel chiefly in areas where coal and oil are scarce. In Ireland and Scotland, for example,
peat is cut formed in blocks, and dried; the dried bloks are then burned to heat homes.
Liquid fuels are mainly made from Petroleum, but some synthetic liquids are also
produced. Petroleum is also called crude oil. They may be refined to produce gasoline,
diesel oil, and kerosene.
Other fuel oils obtained by refining petroleum to distillate oil and residual oils.
Distillate oils are light oils, which are used chiefly to heat homes and small buildings.
Residual oils are heavy, and used to provide energy to power utilities, factories and large
ships.
In the process of vaporization, flammable liquids release vapor in much the same
way as solid fuels. The rate of vapor is greater for liquids than solids, since liquids have less
closely packed molecules. In addition, liquids can release vapor over a wide range, example,
gasoline starts to give vapor at –40C (-45 F).
This makes gasoline a continuous fire hazard; it produces flammable vapor at normal
temperature.
General Characteristics of Liquids
1. Flammable liquids – they are liquids having a flash point of 37.8 C (100F) and a
vapor pressure not exceeding 40 psia (2068.6 um) at 37.8 C.
2. Combustible Liquids – these liquids have flash point at or above 37.8 C (100F).
Since it is the vapors from the flammable liquid which burn, the case of ignition as
well as the rate of burning can be related to the physical properties such as vapor pressure,
flash point, boiling point, and evaporation rate.
1. Liquids having vapors in the flammable range above the liquid surface at the
stored temperature have rapid rate of flame propagation.
2. Liquids having flash points above stored temperature have slower rate of flame
propagation. The chemical explanation is, it is necessary for the fire to heat
sufficiently the liquid surface to form flammable vapor-air moisture before the
flame will spread through the vapor.
Latent heat is the quantity of heat absorbed by a substance from a solid to a liquid
and from a liquid to gas. Conversely, heat is released during conversion of a gas to liquid or
liquid to a solid.
Gaseous fuels are those in which molecules are in rapid movement and random
motion. They have no definite shape or volume, and assume the shape and volume of their
container.
There are both natural and manufactured flammable gases. Gas fuels flow easily
through pipes and are used to provide energy for homes, businesses, and industries.
Examples of gas fuels are acetylene, propane, and butanes.
Classification of Gases:
1. Based on Source
a. Natural Gas – the gas used to heat buildings, cook food, and provides
energy for industries. It consists chiefly of methane, a colorless and odorless
gas. Natural gas is usually mixed with compounds of foul-smelling elements
like sulfur so gas leaks can be detected.
b. Manufactured Gas – this gas like synthetic liquid fuels is used chiefly where
certain fuels are abundant and others are scarce. Coal, petroleum, and
biomass can all be converted to gas through heating and various chemical
procedures.
b. Liquefied Gas – gas, which, at normal temperature inside its container, exist
partly in the liquid state and partly in gaseous state and under pressure as
long as any liquid remains in the container. The pressure basically depends
on the temperature of the liquid although the amount of liquid also affects the
pressure under some condition. A liquefied gas exhibits a more complicated
behavior as the result of heating.
3. According to Usage
a. Fuel Gases – flammable gases usually used for burning with air to produce
heat, utilize as power, light, comfort, and process. Most commonly used
gases are natural gas and the LPG (butane and propane).
b. Industrial Gases - This group includes a large number of gases used for
industrial processes as those in welding and cutting (oxygen, acetylene);
refrigeration (freon, ammonia, sulfur dioxide); chemical processing (hydrogen,
nitrogen, ammonia, chlorine); water treatment (chlorine, fluorine).
Medical Gases – those used for treatment such as anesthesia (chloroform, nitrous oxide);
respiratory therapy (oxygen).
Chapter IV
This chapter will focus on the dangerous behavior of fire, the three stages of
fire, classification of fire, classification of fire according to fuel, combustion products
and their effects and the color of smoke.
Thermal Balance refers to the rising movement or the pattern of fire, the
normal behavior when the pattern is undisturbed. Thermal imbalance, on the
other hand is the abnormal movement of fire due to the interference of foreign
matter. Thermal imbalance often confuses the fire investigator in determining the
exact point where the fire originated.
3. Biteback - a fatal condition that takes place when the fire resists
extinguishment operations and become stronger and bigger instead.
4. Flash Fire – better known as dust explosion. This may happen when the
metal post that is completely covered with dust is going to be hit by
lightning. The dust particles covering the metal burn simultaneously thus
creating a violent chemical reaction that produces a very bright flash
followed by an explosion.
Based on Cause
1. Class A Fire – Ordinary fires; they are the types of fire resulting from the
burning wood, paper, textiles, rubber and other carbonaceous materials. In
short, this is the type of fire caused by ordinary combustible materials.
2. Class B Fire – Liquid fires; they are caused by flammable and or
combustible liquids such as kerosene, gasoline, benzene, oil products,
alcohol and other hydrocarbon deviations.
3. Class C Fire – Electrical fires; they are fires that starts in live electrical
wires, equipment, motors, electrical appliances and telephone
switchboards.
4. Class D Fire – Metallic fires; fires that result from the combustion of
certain metals in finely divided forms. These combustible metals include
magnesium, potassium, powdered calcium, zinc, sodium, and titanium.
A. Products of Combustion
1. Smoke – matter made up of very fine solid particles and condensed vapor
as a consequence of combustion. Frequently, smoke provides warning of
fire and contributes to panic because of its irritating effects. Combustion of
common combustibles (as wood) brings both fire gases that contain water
vapor, carbon dioxide, and carbon monoxide.
2. Fire Gases – gases that remain when the products of combustion are
cooled to normal temperature. Gases formed by a fire depends on many
variables among which are:
2.3. Hydrogen Sulfide – when materials like rubber, skin, hides, wool,
hair, silk and meat are burned one of the products formed is
hydrogen sulfide. This colorless highly toxic gas smells like rotten
eggs.
2.4. Sulfur Dioxide – this colorless gas with irritating, suffocating odor
is formed when sulfur containing organic substances like wood,
rubber, wool and silk are burned. Sulfur dioxide causes the eyes to
be watery and is irritating to the respiratory tract.
I. Definition of terms
b. Damper – A normally open device installed inside an air duct system which
automatically closes to restrict the passage of smoke or fire
e. Fire Lane – The portion of a roadway or public way that should be kept opened
and unobstructed at all times for the expedient operation of fire fighting units.
f. Fire Protective And Fire Safety Device – Any device intended for the
protection of buildings or persons to include but not limited to built-in protection
system such as sprinklers and other automatic extinguishing system, detectors
for heat, smoke and combustion products and other warning system
components, personal protective equipment such as fire blankets, helmets, fire
suits, gloves and other garments that may be put on or worn by persons to
protect themselves during fire.
h. Fire Door – A fire resistive door prescribed for openings in fire separation walls
or partitions.
i. Hose Box – A box or cabinet where fire hoses, valves and other equipment are
stored and arranged for fire fighting.
j. Hose Reel – A cylindrical device turning on an axis around which a fire hose is
wound and connected.
n. Vestibule – A passage hall or antechamber between the outer doors and the
interior parts of a house or building.
Fire resistive floors and walls extending up to the next floor slab or roof,
curtain boards and other fire containing or stopping components.
A fire exit plan for each floor of the building showing the routes from each
other room to appropriate exits, displayed prominently on the door of such
room.
Properly marked and lighted exits with provision for emergency lights to
adequately illuminate exit ways in case of power failure.
Emergency Stairs
Extinguisher
Sign Symbol Description
Evacuation Means Emergency stairs to the
lower floor
b. FOAM-EXTINGUISHING SYSTEM
a. Cooling
b. Smothering or Extinguishing
It is the method which consists in isolating the combustible element or
oxygen, or reduces their concentration within the environment.
This method modifies the chemical reaction, altering the release of free
radicals produced in the combustion and therefore delaying its development.
V. Overhauling
The Late stage in fire-suppression process during which the burned area is
carefully examined for remaining sources of heat that may re-kindle the fire. Often
coincides with salvage operations to prevent further loss to structure or its contents,
as well as fire-cause determination and preservation of evidence.
Blasting Agent – Any material or mixture consisting of a fuel and oxidizer used to
set off explosives.
Combustible Liquid – Any liquid having a flash point at or above 37.8_C (100_F).
Corrosive Liquid – Any liquid which causes fire when in contact with organic matter
or with certain chemicals.
Dust – A finely powdered substance which, when mixed with air in the proper
proportion and ignited will cause an explosion.
Ember – A hot piece or lump that remains after a material has partially burned, and
is still oxidizing without the manifestation of flames.
Fire Trap – A building unsafe in case of fire because it will burn easily or because it
lacks adequate exits or fire escapes.
Overloading – The use of one or more electrical appliances or devices which draw
or consume electrical current beyond the designed capacity of the existing electrical
system.
Pressurized Or Forced Draft Burning Equipment – Type or burner where the fuel
is subjected to pressure prior to discharge into the combustion chamber and/or
which includes fans or other provisions for the introduction of air at above normal
atmosphere pressure into the same combustion chamber.
VIII. Acts and Conditions that increases or may cause an increase in the
probability of the occurrence of fire.
Obstructing or blocking the exit ways or across to buildings clearly marked for
fire safety purposes. Constructing gates, entrances and walkways to buildings
components and yards which obstruct the orderly and easy passage of fire
fighting vehicles and equipment
Locking fire exits during period when people are inside the building.
Prevention or obstruction of the automatic closure of fire doors or smoke
partitions or dampers. Use of fire protective of firefighting equipment of the fire
service other than for firefighting except in other emergencies where their use are
justified.