Beruflich Dokumente
Kultur Dokumente
TITLE:
POLYCHLOROPRENE RUBBER
NOTES:
(A) Reference in this specification to any other document shall be to the latest issue of that
document unless specifically stated otherwise.
(C) For definitions and procedures relating to the use of ABP specifications refer to
AMCD 01 and ABP 0-0001.
(D) This specification does not necessarily detail all the precautions necessary to meet the
requirements of health and safety.
It is the responsibility of the user of this specification to consult and establish appropriate
Health and Safety precautions and the method should be operated only by trained
personnel.
KEY WORDS:
ELASTOMER
POLYCHLOROPRENE
RUBBER
BALLISTIC
1. SCOPE
2. INVOKED DOCUMENTS
3. DEFINITIONS
4. REQUIREMENTS
5. QUALIFICATION
6. RELEASE
7. MATERIAL REQUIREMENTS
M&P FORM 02
1. SCOPE
This specification defines the ordering, supplying requirements and properties for
polychloroprene rubber with a nominal hardness ranges as given below and a service
temperature range as stated in section 7.3. The types of polychloroprene rubber covered by
this document are:
First-tier suppliers may procure elastomers from any sub-tier supplier. Sub-tier suppliers
shall be subject to the first-tier supplier, quality and procurement system requirements.
The first-tier supplier shall ensure that the material property requirements of this
specification are met.
This document previously invoked only general purpose polychloroprene rubber. If not
specified, use this type by default.
Materials qualified to this specification may be used in combination with reinforcing fabrics
qualified to ABR 9-0142 or an equivalent Airbus material specification (AIMS) for seal
designs, which shall be embodied in an Airbus standard (ABS), drawing or ‘J’ section. This
specification does not cover the design requirements of the complete seals.
1.1.2 Miscellaneous
Sundry fittings to prevent general wear, damage or movement, for example grommets, sheet,
snubbers and other un-reinforced rubber items.
1.1.3 Ballistic
Type B material may be used as a binder for ballistic barriers and mats. Where the ballistic
properties are paramount ABR 4-0106 type B classification is to be used. As a necessity this
material has significantly differing material properties from general purpose polychloroprene
rubber type A in order to achieve the ballistic performance.
M&P FORM 02
1.2 Design Responsibility
The designer must establish how the design is affected by the following:
– Fit of seals to the component and assembly (a trial fit is essential to account for seal
profile, and compound stiffness, compressibility and permanent set)
– Fire resistance requirements of the final assembly
– Any non mechanical property requirements, for example electrical conductivity
– The impact protection of ballistic barrier and mat assemblies must be tested when exposed
to all anticipated environmental conditions including fluids and temperatures
Where compatibility is required with any substances not covered in this specification, the
designer shall inform the Materials and Processes Department at Airbus in the UK so that the
suitability of the rubber compound can be established.
To reference materials on drawings use the coding system outlined in section 8.1.
M&P FORM 02
2. INVOKED DOCUMENTS
This Airbus specification incorporates dated or undated reference provisions from other
publications. All normative references cited at the appropriate places in the text are listed
hereafter. For dated references, subsequent amendments to or revisions of any of these
publications apply to this Airbus specification only when incorporated in it by amendment
of revision. For undated references the latest edition of the publication shall be applied.
ABR 9-0142 Knitted and woven fabrics and meshes for use in the manufacture of
elastomeric seals
AMCD 01 THE AIRBUS UK MATERIALS AND PROCESSES SPECIFICATION
SYSTEM MASTER CONTROL DOCUMENT
M&P FORM 02
ISO 2921 Rubber, vulcanized – Determination of low-temperature characteristics –
Temperature-retraction procedure (TR test)
ISO 3302-1 Rubber – Tolerance for products – Part 1: Dimensional tolerances
M&P FORM 02
3. DEFINITIONS
3.1 Manufacturer
Company or organisation manufacturing products.
3.2 Supplier
Company or organisation supplying products, for example a stockist.
Note: The supplier may also be the manufacturer.
3.3 User
Body that procures products used to manufacture aircraft components under relevant
contractual responsibilities.
3.4 Purchaser
Body that purchases the product from the manufacturer or a supplier in accordance with the
requirements of the user.
Note: The purchaser may also be the user.
3.5 Qualification
Process of demonstrating that the manufacturer and the product supplied are capable of
fulfilling the specified requirements as laid down in this specification. The proof is given by
the qualification testing.
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3.10 Inspection Schedule
The inspection schedule defines the specific semi-finished product related requirements
(inspection and test) deviating from those of the relevant specification.
3.11 Batch
A batch shall consist of material of the same type made in a single continuous operation.
3.12 Lot
A lot shall consist of the entire product from one batch received in one delivery. The size of
the lot refers to the total number of units in any one lot.
3.13 Unit
A unit is one sealed container of a component or material.
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3.15 Full description of a sample
At least the following information is required:
3.18 Formulation
The make up of the mix including ingredients, mixing proportions, mixing sequence and
curing schedule.
3.19 Reversion
Condition where polymerisation of the material breaks down.
Example
Reference number – ISO 1629: 1995 (E)
3.21 Accuracy
The closeness of agreement between a test result and the accepted reference value, as per
ISO/TR 9272, section 3.2.3.
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4. REQUIREMENTS
4.1 Requirements
The product shall be manufactured to reproducible quality and shall fulfil the requirements of
this specification. The manufacturer shall define the raw materials, processes and inspections in
a manufacturing schedule and present this to the Qualification Body or user upon request on
qualification or audit. The Qualification Body or user shall treat any information contained in
the schedule as confidential. Changes of the manufacturing schedule which may affect the
quality of the product must be stated by the manufacturer and shall be subject to written
approval of the Qualification Body before production starts. If necessary, the Qualification
Body may define a re-qualification programme before approval. The release test certificate for
the first delivery to each purchaser made after the approved changed manufacturing schedule
shall contain a reference to the change.
4.1.2 Traceability
Each individual product shall be traceable to individual component level at all stages of
manufacture and delivery.
All products shall be free from irregularities not complying with the requirements of this
specification or the order. Further irregularities prejudicial to the subsequent manufacture or
use of products shall be cause for rejection of the specific delivery.
4.1.4 Workmanship
The product specified herein shall be processed as required in order to obtain the specified
quality. Any defects attributed to bad workmanship shall be cause for rejection of the specific
delivery.
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4.1.5 Hazardous Constituents
For qualification the product shall fulfil the requirements, defined in this specification. For
release the product shall fulfil the local requirements of the current health and safety and
environmental protection laws of the country of the purchaser or user.
The manufacturer or supplier shall inform the purchaser in writing about the safe handling
conditions of the product for first delivery to every new user and shall inform the user about
any modification to these recommendations.
For every delivery the manufacturer or supplier shall provide a material safety data sheet
appropriate to the country of purchase and use.
4.2.1 General
4.2.2 Specific
None applicable.
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5. QUALIFICATION
5.1 Introduction
To use a certain product in airframe structure shop trials and product qualification may not be
sufficient. The eventual use of the product within the airframe structure is normally dependent
on the successful completion of several stages for example:
– Unless otherwise agreed, screening tests to verify basic properties according to the
requirements of this specification and process routes
– Health and Safety and environmental analysis
– Shop trials carried out by the user for certain materials to verify processability
– Product qualification to the requirements of this specification
– Specific component tests when required separately specified as part of the certification
process
Work sharing for qualification shall be agreed between the qualification body and the
manufacturer.
The manufacturer shall be responsible for the development and manufacture of any product
submitted in accordance with this specification.
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5.3 Product Qualification
The product tested in the qualification shall be manufactured in accordance with the same
specification and manufacturing schedule as the serial products that will be delivered
afterwards. The qualification is directly related to the raw Material Specifications and sources,
the equipment and the processes that have been identified in the manufacturing schedule.
As part of the qualification or monitoring, the Qualification Body reserves the right to carry
out manufacturing or shop trials and additional tests in house or at an independent facility.
All results of the qualification tests, including the manufacturing schedule and approval of the
raw materials, the manufacturing of specimens and the test procedures carried out, shall be
recorded by the manufacturer in a qualification test report.
The properties specified in this specification are obtained from standard test specimens.
Therefore, the suitability of the material for a specific application may have to be determined
by complimentary tests carried out on the finished product.
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5.3.2 Qualification Testing
Full qualification testing shall consist of the tests given in section 7 of this specification. The
test results shall demonstrate compliance with the technical requirements of this specification.
For products manufactured from new materials or for manufacturers without experience of
supplying for aerospace applications, full qualification testing shall be required.
A re-test may be required when one or more test results do not meet the requirements. A
re-test shall be performed on products from the same batch or batches agreed with the
Qualification Body. All individual test and re-test results shall be reported. Unsatisfactory
test results shall be cause for refusal of the qualification of the product.
The qualification test report shall be written in English language and shall contain at least
the following information:
– Manufacturer’s name and the address of the site where the product is manufactured
– Manufacturing schedule with release date
– Delivery condition
– Batch numbers
– The name of the test facilities used and their accreditation for each test performed
– All information as specified in the referenced test standards
– The critical dimensions of test pieces, when a test specification states limits for
comparative purposes
– The maximum and minimum test result/value for each set of tests
– This specification number
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5.3.5 Health, Safety and Environment
Re-qualification may be necessary if changes to the manufacturing schedule occur which may
adversely affect the quality of the product. The specific programme shall be defined by the
Qualification Body and carried out by the manufacturer.
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6. RELEASE
6.1 General
Full release testing shall consist of the tests given in section 7.5, indicated by an asterisk (*).
The test results shall demonstrate compliance with the technical requirements of this
specification. Release testing shall be the responsibility of the manufacturer. The test samples
extracted should be representative of the whole batch delivered in accordance with this
specification. The purchaser reserves the right to perform any of the inspections and tests
required by this specification during acceptance testing, for example First Article Inspections
(FAI).
When required, the manufacturer shall inform the purchaser or his chosen agent of the
planned dates for the extraction of samples and release testing, in order that these operations
may be witnessed.
Reductions in test frequency may also be negotiated with the Qualification Body in favour of
statistical process control.
For proof of the required properties, the manufacturer shall prepare and sign a release test
certificate and forward at least two copies thereof to the purchaser. It shall the following
information as a minimum:
– Manufacturer’s name and the address of the site where the product is manufactured
– Order number
– IPS number
– Material and delivery condition
– Trade name, if appropriate
– Quantity
– Batch number
– Results of mandatory tests and re-tests
– The name of the test facilities used and their accreditation for each test performed
– All information as specified in the referenced test standards
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6.4 Capability Clause
If a manufacturer can demonstrate proven capability, using statistically based data, then the
requirement to test against an individual specification may be reduced with agreement of the
Qualification Body.
Such an action shall not reduce the obligation of the manufacturer to comply with all the
specification requirements.
6.5.1 Re-testing
If the test procedure or test piece preparation is faulty, testing shall be re-applied at the
original frequency after rectification of the original cause of failure.
When failure cannot be attributed to faulty testing, or test piece preparation, further test
samples shall be selected at twice the original frequency from products on which the incorrect
results were obtained unless already withdrawn by the manufacturer after suitable
identification of the cause of failure. If all re-test results are satisfactory, the batch shall be
accepted. If one or more re-test results are unsatisfactory, the batch shall be:
- Rejected, or
- 100 % re-test and the conforming products accepted
6.5.2 Rejection
Any failure of the product to meet the requirements of the relevant specification shall be cause
for rejection of the product. Any defect not detected during acceptance testing, but which
becomes apparent during the subsequent use of the product shall be cause for rejection of the
unused portion of the batch, provided such a defect is cause for rejection under the
requirements of the relevant specification.
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6.5.3 Warranty
Each production batch or shipment, whichever is smaller, of the qualified product submitted
to this specification shall be warranted through a release test certificate by the manufacturer or
supplier to meet the requirements of this specification.
The manufacturer or supplier shall also warrant that the raw materials and processes used in
manufacture of the subsequent production batches or shipment are the same in type, form and
quality as those used for the qualification products and agreed revisions.
6.5.4 Audit
Airbus retains the right to periodically audit the manufacturing process of a qualified product.
Audit will be performed against this specification. The manufacturer shall make available all
necessary documents, records etc. for inspection by the representatives of Airbus. If required
the audit can be carried out in the frame of a non-disclosure agreement for specific activities.
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7. MATERIAL REQUIREMENTS
Unless otherwise stated on the drawing the tolerances on the dimensions shall be as follows:
The dimensions of moulded parts and extruded sections shall conform to the requirements of
the drawing or the order. Methods of measurement of dimensions and tolerances shall be in
accordance with ISO 3302-1.
Tolerances on thickness and cut lengths shall be in accordance with ISO 3302-1 ‘Good
Quality’ classification. Width tolerances shall be as follows:
The properties specified are obtained from standard test specimens. Therefore, the suitability
of the material for a specific application may have to be determined by complimentary tests
carried out on the finished product.
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7.3 Temperature Range
Temperature ( °C )
Section Duration Type A Type B
Minimum Maximum Minimum Maximum
7.3.1 Operating Temperature Range
7.3.1.1 Continuous service - 40 100 - 55 80
7.3.1.2 Intermittent service - 55 150 - 55 100
A general rating for the compatibility of the standard reference rubber polymer,
polychloroprene ( CR ), with a range of chemicals is given in ISO/TR 7620.
These polychloroprene rubber compounds are intended for dry areas and are not suitable for
exposure to hydraulic fluids. Occasional splash exposure to greases, oils and fuel may be
permitted provided that exposure is short term. Splashing with the fluids listed in
section 7.5.13 may be permitted provided that exposure is short term.
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PAGE 21
Test Temperature ( °C )
Requirements
Type A Type B
Section
Property Unit ( General Purpose ) ( Ballistic ) Test Method
45 55 65 75 85 65
Airbus Operations Ltd 1993 - 2013 All Rights Reserved
7.5 All test results for rubber compounds approved to ABR 4-0106 shall after accounting for accuracy meet the material property requirements of this
specification when in the vulcanised condition. The time interval between vulcanisation and testing shall be in accordance with ISO 23529. The
materials shall be classified in accordance to ISO 1629.
7.5.1* ρ 23 Mg/m3 Within + 0,05 of agreed value – See Appendix A ISO 2781
7.5.2*
H ( Standard Hardness ) 23 IRHD 41 - 50 51 - 60 61 - 70 71 - 80 81 - 90 61 – 70
ISO 48
Monolithic test block Method N
ISO 37 Type 2
7.5.3* TS 23 MPa ≥ 10,3 ≥ 13,7 ≥ 11,0
( 5 samples )
ISO 37 Type 2
7.5.4* Eb 23 % ≥ 500 ≥ 500 ≥ 300 ≥ 175 ≥ 150 ≥ 500
( 5 Samples )
Compression set, 24 hours
70 ≤ 20 ≤ 20
test piece type A ISO 815-1
7.5.5* %
Compression set, 72 hours Method A
100 Record Record
test piece type A
ISO 34-1
7.5.6 Ts 23 kN/m ≥ 25 ≥ 30 ≥ 20
ABR 4-0106
Method C
7.5.6.1 Small ( Delft ) test piece - - - - - - - -
Tendency to adhere to and a) Complete separation from both metal surfaces. No indication of any adhesion.
corrode metals, 24 hours b) Surfaces stained or discolouration present, but no corrosion as evidenced by pitting or
7.5.7 100 - ISO 6505
(Test both standard test erosion of one or both metal surfaces.
metals) ( Include photographs of all samples )
Resistance to ozone ISO 1431-1
7.5.8 30 - No cracking
cracking under load Procedure A
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PAGE 22
Test Temperature ( °C )
Requirements
Type A Type B
Section
( General Purpose ) ( Ballistic ) Test
Property Unit
Method
Nominal Hardness ( IRHD )
45 55 65 75 85 65
Airbus Operations Ltd 1993 - 2013 All Rights Reserved
7.5.9 Resistance to heat ageing – ISO 188 Method B ( 168 hours at 100 °C )
ISSUE 14
7.5.9.2
ΔH 23 IRHD - 5 to + 5 - 5 to + 5 ISO 1817
ISO 48, Method N
7.5.9.3 ΔTS100 23 % - 12 to + 5 - 12 to + 5 ISO 1817
7.5.9.4 ΔΕb100 23 % - 15 to + 5 - 15 to + 5 ISO 1817
7.5.10 Resistance to heat ageing – ISO 188 Method B
7.5.10.1 ΔV100 - - - - - - - - -
7.5.10.2 ΔH - - - - - - - - -
7.5.10.3 ΔTS100 - - - - - - - - -
7.5.10.4 ΔΕb100 - - - - - - - - -
7.5.11 Resistance to low temperature
7.5.11.1 t when G = 70 MPa Record °C ≤ - 40 ≤ - 40 ISO 1432
ABR 4-0106
≤ - 35 ISO 2921
7.5.11.2 TR 10 Record °C Record
Procedure A
7.5.12 Resistance to crystallization by hardness measurement
Initial
- 10 ≤ 10 -
IRHD
ΔH1 0 - Record ISO 3387
7.5.12.1 ( Standard thickness monolithic
168 hours ( Graph A, H1 )
test piece, 5 readings )
- 10 ≤ 15 -
IRHD
0 - Record
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t1 ISO 3387
7.5.12.2 ( Standard thickness monolithic - 55 Hours Record Record
( Graph B, t1 )
test piece, 5 readings )
PAGE 23
Test Temperature ( °C )
Requirements
Type A Type B
Section
( General Purpose ) ( Ballistic ) Test
Property Unit
Method
Nominal Hardness ( IRHD )
Airbus Operations Ltd 1993 - 2013 All Rights Reserved
45 55 65 75 85 65
ISSUE 14
7.5.13.2.2
ΔH 23 IRHD Record ≥ - 30 ISO 1817
ISO 48, method N
7.5.13.2.3 ΔTS100 23 % Record ≥ - 25 ISO 1817
7.5.13.2.4 ΔΕb100 23 % Record ≥ - 30 ISO 1817
ABR 4-0106
M&P FORM 11
PAGE 24
Test Temperature ( °C )
Requirements
Type A Type B
Section
( General Purpose ) ( Ballistic ) Test
Property Unit
Method
Nominal Hardness ( IRHD )
Airbus Operations Ltd 1993 - 2013 All Rights Reserved
45 55 65 75 85 65
ISSUE 14
7.5.13.3 Resistance to liquid 103 – ISO 1817 Annex A.3.3 ( 168 hours at 70 °C )
7.5.13.3.1 ΔV100 23 % ≤ 100 ≤ 210 ISO 1817
7.5.13.3.2
ΔH 23 IRHD Record ≥ - 40 ISO 1817
ISO 48, method N
7.5.13.3.3 ΔTS100 23 % Record ≥ - 100 ISO 1817
7.5.13.3.4 ΔΕb100 23 % Record ≥ - 80 ISO 1817
7.5.13.4 Resistance to liquid 101 – ISO 1817 Annex A.3.1 ( 24 hours at 70 °C )
7.5.13.4.1 ΔV100 23 % ≤ 110 ≤ 90 ≤ 50 ISO 1817
7.5.13.4.2
ΔH 23 IRHD ≥ - 20 ≥ - 35 ISO 1817
ISO 48, method N
7.5.13.4.3 ΔTS100 23 % ≥ - 80 ≥ - 90 ISO 1817
7.5.13.4.4 ΔΕb100 23 % ≥ - 70 ≥ - 80 ISO 1817
7.5.13.5 Resistance to liquid B – ISO 1817 Table A.1 ( 168 hours at 70 °C )
ABR 4-0106
7.5.13.5.2
ΔH 23 IRHD ≥ - 25 Record ≥ - 30 ISO 1817
ISO 48, method N
7.5.13.5.3 ΔTS100 23 % ≥ - 75 Record ≥ - 90 ISO 1817
7.5.13.5.4 ΔΕb100 23 % ≥ - 60 Record ≥ - 50 ISO 1817
7.5.14 Fire resistance
7.5.14.1 Burn length - - - - - -
7.5.14.2 After flame + after glow time - - - - - -
M&P FORM 11
Materials and unassembled components shall be inspected, packaged and stored in accordance
with ISO 2230.
The storage period of raw (green) material shall be in accordance with ISO 7664.
A general purpose silicone rubber of nominal hardness of 50 IRHD can be selected from the
qualified products list.