Q.

63 The mass of P4O10 produced if 440 gm of P4S3 is mixed with 384 gm of O2 is

P4S3 + O2 → P4O10 + SO2
(A) 568 gm (B) 426 gm (C) 284 gm (D) 396 gm

Q.64 Calculate percentage change in Mavg of the mixture, if PCl5 undergo 50% decomposition.
PCl5 → PCl3 + Cl2
(A) 50% (B) 66.66 % (C) 33.33 % (D) Zero

Q.65 The mass of Mg3N2 produced if 48 gm of Mg metal is reacted with 34 gm NH3 gas is
Mg + NH3 → Mg3N2 + H2
200 100 400 150
(A) (B) (C) (D)
3 3 3 3

Q.66 The number of carbon atoms present in a signature, if a signature written by carbon pencil weights
1.2 × 10–3 g is
(A) 12.04 × 1020 (B) 6.02 × 1019 (C) 3.01 × 1019 (D) 6.02 × 1020

Q.67 The average atomic mass of a mixture containing 79 mole % of 24Mg and remaining 21 mole % of 25Mg
and 26Mg , is 24.31. % mole of 26Mg is
(A) 5 (B) 20 (C) 10 (D) 15

Assertion Reason:
Q.68 Statement -1 : 2A + 3B → C
4/3 moles of 'C' are always produced when 3 moles of 'A' & 4 moles of 'B' are
added.
Statement -2 : 'B' is the liming reactant for the given data.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
Q.1 Number of atoms in 558.5 g Fe (at. wt. 55.85) is : [AIEEE-2002]
(A) Twice that in 60 g carbon (B) 6.023 × 1022
(C) Half in 8 g He (D) 558.5 × 6.023 × 1023

Q.2 Which of the following changes with increase in temperature : [AIEEE-2002]

(A) Molality (B) Weight fraction of solute
(C) Fraction of solute present in water (D) Mole fraction

Q.3 In a compound C, H, N atoms are present in 9 : 1 : 3.5 by weight. Molecular weight of compound is
108. Its molecular formula is : [AIEEE-2002]
(A) C2H6N2 (B) C3H4N (C) C6H8N2 (D) C9H12N3

Q.4 What volume of hydrogen gas at 273 K and 1 atm pressure will be consumed in obtaining 21.6 g of
elemental boron (at. mass = 10.8) from the reduction of boron trichloride with hydrogen:
(A) 44.8 L (B) 22.4 L (C) 89.6 L (D) 67.2 L [AIEEE-2003]

Q.5 25 mL of a solution of barium hydroxide on titration with 0.1 molar solution of hydrochloric acid gave a
titre value of 35 mL. The molarity of barium hydroxide is : [AIEEE-2004]
(A) 0.28 (B) 0.35 (C) 0.07 (D) 0.14

Q.6 6.02 × 1020 molecules of urea are present in 100 mL solution. The concentration of urea solution is :
[AIEEE-2004]
(A) 0.1 M (B) 0.01 M (C) 0.02 M (D) 0.001 M

Q.7 To neutralize completely 20 mL of 0.1 M aqueous solution of phosphorus (H3PO3) acid the volume of
0.1 M aqueous KOH solution required is : [AIEEE-2004]
(A) 60 mL (B) 20 mL (C) 40 mL (D) 10 mL

Q.8 Two solutions of a substance (non-electrolyte) are mixed in the following manner ; 480 mL of 1.5 M of
first solution with 520 mL of 1.2 M of second solution. The molarity of final solution is :
(A) 1.20 M (B) 1.50 M (C) 1.344 M (D) 2.70 M [AIEEE-2005]

Q.9 If 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the mass of one
mole of a substance will : [AIEEE-2005]
(A) Decrease twice (B) Increase two folds
(C) Remains unchanges (D) Be a function of the molecular mass of element

Q.10 How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atom :
[AIEEE-2006]
(A) 2.5 × 10 –2 (B) 0.02 (C) 3.125 × 10 –2 (D) 1.25 × 10–2

Q.11 How many EDTA (ethylenediaminetetraacetic acid) molecules are required to make an octa-hedral
complex with a Ca2+ ion : [AIEEE-2006]
(A) Two (B) Six (C) Three (D) One

Q.12 Density of a 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of the solution is :
(A) 0.44 mol kg–1 (B) 1.14 mol kg–1 (C) 3.28 mol kg–1 (D) 2.28 mol kg–1
[AIEEE-2006]
Q.13 In the reaction :
2Al(s) + 6HCl(aq.) → 2Al3+ –
(aq.) + 6Cl (aq.) + 3H2(g) [AIEEE-2007]
(A) 6 litre HCl(aq) is consumed for every 3L H2(g) produced
(B) 33.6 litre H2(g) is produced regardless of temperature and pressure for every mole Al that reacts
(C) 67.2 litre H2(g) at STP is produced for every mole Al that reacts
(D) 11.2 litre H2(g) at STP is produced for every mole HCl(aq) consumed

Q.14 The density (in g mL –1 ) of a 3.60 M sulphuric acid solution that is 29% H 2 SO 4
(Molar mass = 98 g mol–1) by mass will be : [AIEEE-2007]
(A) 1.64 (B) 1.88 (C) 1.22 (D) 1.45

Q.15 A solution containing 2.675 g of CoCl3.6 NH3 (molar mass = 267.5 g mol–1) is passed through a cation
exchanger. The chloride ions obtained in solution were treated with excess of AgNO3 to give 4.78 g of
AgCl (molar mass = 143.5 g mol–1). The formula of the complex is
(At. mass of Ag = 108 u) [AIEEE-2010]
(A) [CoCl3 (NH3)3] (B) [CoCl(NH3)5]Cl2 (C) [Co(NH3]6Cl3 (D) [CoCl2(NH3)4]Cl

Q.16 29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl's method and
the evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid required 15
mL of 0.1 M NaOH solution for complete neutralization. The percentage of nitrogen in the compound is:
(A) 23.7 (B) 29.5 (C) 59.0 (D) 47.4 [AIEEE-2011]

Q.17 A 5.2 molal aqueous solution of methyl alcohol, CH3OH, is supplied. What is the mole fraction of methyl
alcohol in the solution ? [AIEEE-2011]
(A) 0.100 (B) 0.190 (C) 0.086 (D) 0.050

SECTION : B

Q.18 The weight of 1 × 1022 molecules of CuSO4.5H2O is - [IIT-1991]

(A) 41.59 g (B) 415.9 g (C) 4.159 g (D) none of the three

Q.19 Rearrange the following (I to IV) in the order of increasing masses and choose the correct Answer from
(A), (B), (C) and (D)
(At. mass : N = 14, O = 16, Cu = 63) [IIT-1993]
(I) 1 molecule of O (II) 1 atom of nitrogen
–10
(III) 1 × 10 g molecular mass of oxygen (IV) 1 × 10–7 g atomic mass of copper
(A) II < I < III < IV (B) IV < III < II < I (C) II < III < I < IV (D) III < IV < I < II
Q.20 One mole of calcium phosphide on reaction with excess of water gives [IIT-1999]
Ca3P2 + H2O (excess) → Ca(OH)2 + 2PH3
(A) One mole of phosphine (B) Two mole of Phosphoric acid
(C) Two moles of phosphine (D) One mole of phosphorus pentoxide
Q.21 At 100ºC and 1 atm, if the density of liquid water is 1.0 g cm–3 and that of water vapour is
0.0006 g cm–3 , then the volume occupied by water molecules in 1 litre of steam at that temperature is
(A) 6 cm3 (B) 60 cm3 (C) 0.6 cm3 (D) 0.06 cm3 [IIT-2000]
 ANSWER KEY

EXERCISE # I
Q.1 D Q.2 B Q.3 B Q.4 B Q.5 A Q.6 C Q.7 B
Q.8 A Q.9 B Q.10 B Q.11 A Q.12 D Q.13 C Q.14 A
Q.15 D Q.16 A Q.17 A Q.18 B Q.19 B Q.20 D Q.21 A
Q.22 C Q.23 A Q.24 B Q.25 B Q.26 D Q.27 B Q.28 C
Q.29 B Q.30 A Q.31 B Q.32 B Q.33 B Q.34 A Q.35 A
Q.36 C Q.37 C Q.38 B Q.39 D Q.40 C Q.41 A Q.42 C
Q.43 D Q.44 D Q.45 D Q.46 C Q.47 C Q.48 C Q.49 D
Q.50 B Q.51 A Q.52 B Q.53 A Q.54 A Q.55 B Q.56 B
Q.57 B Q.58 C Q.59 B Q.60 A Q.61 A Q.62 B Q.63 C
Q.64 A Q.65 B Q.66 C Q.67 A Q.68 A Q.69 B Q.70 C

EXERCISE # II

Q.1 A Q.2 B Q.3 A Q.4 A Q.5 D Q.6 A Q.7 D

Q.8 C Q.9 A Q.10 C Q.11 A Q.12 D Q.13 B Q.14 A
Q.15 B Q.16 C Q.17 C Q.18 C Q.19 B Q.20 A Q.21 C
Q.22 C Q.23 D Q.24 D Q.25 B Q.26 D Q.27 A Q.28 B
Q.29 D Q.30 B Q.31 A Q.32 C Q.33 D Q.34 B Q.35 A
Q.36 C Q.37 C Q.38 A Q.39 C Q.40 C Q.41 A Q.42 B
Q.43 B Q.44 A Q.45 D Q.46 B Q.47 C Q.48 C Q.49 D
Q.50 B Q.51 A Q.52 C Q.53 A Q.54 B Q.55 B Q.56 B
Q.57 A Q.58 A Q.59 C Q.60 C Q.61 C Q.62 A Q.63 B
Q.64 C Q.65 A Q.66 B Q.67 C Q.68 C

EXERCISE # III
Q.1 A Q.2 C Q.3 C Q.4 D Q.5 C Q.6 B Q.7 C
Q.8 C Q.9 C Q.10 C Q.11 D Q.12 D Q.13 D Q.14 C
Q.15 A Q.16 A Q.17 C Q.18 C Q.19 A Q.20 C Q.21 C