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Relative atomic mass Relative atomic mass of an element is the ratio of the weighted
1
average mass of an atom of the element to 12 the mass of an
atom of carbon-12 isotope.
Relative molecular mass Relative molecular mass of a molecular substance is the ratio
1
of the weighted average mass of the molecules to 12 the mass
of an atom of carbon-12 isotope.
Relative formula mass Relative formula mass of a chemical formula is the ratio of the
weighted average mass of one formula unit of the compound
1
to 12 the mass of an atom of carbon-12 isotope.
Molecular formula Chemical formula that displays the actual number of atoms of
each element present in one molecule of a compound.
Empirical formula Chemical formula that displays the smallest ratio of atoms of
each element in a compound.
Aufbau principle Electrons will always fill into the orbital with the lowest
energy available.
Pauli exclusion principle Electrons in the same orbital must have opposite spins.
Hund’s rule In the event of filling electrons into degenerate orbitals,
electrons will always fill separately into the vacant orbitals
and have equal spins.
First ionization energy Energy required to remove one electron from each atom in one
mole of atoms in its gaseous state to form one mole of gaseous
+1 ion.
Bond energy Energy required to break one mole of a covalent bond between
two atoms in the gaseous state.
Bond length Distance between nuclei of the two atoms joined by a covalent
bond.
Dative bond A covalent bond formed with the electrons contributed by one
of the two atoms only.
Metallic bond The net attraction that exist between the cation and the
delocalised electrons.
Bond polarity Bonding electrons are unequally shared // the molecule has a
dipole/δ+ and δ- ends to molecule.
Charles’ law For a fixed amount of gas at constant pressure, the volume of
the gas is directly proportional to the thermodynamic
temperature of the gas.
Avogadro’s law For a gas at constant pressure and temperature, the volume of
a gas is directly proportional to the amount of particles
contained in the gas.
Real gases Real gases are actual, realistic gases in contrast to the
hypothetical ideal gas.
Surrounding The remainder of the universe that is not part of our system.
Endothermic reaction Reactions where heat is absorbed by the system from the
surrounding.
Specific heat capacity of a Heat required to change the temperature of a unit mass of the
substance substance by 1K / 1°C
Standard enthalpy change Enthalpy change produced when one mole of a compound is
of formation, ▲Hfθ formed (product) from its elements in their standard states
under standard conditions.
Standard enthalpy change Enthalpy change produced when one mole of free gaseous
of atomisation, ▲Hatθ atom is formed (product) from its element under standard
conditions.
Standard enthalpy change Enthalpy change produced when one mole of substance
of solution, ▲Hsolθ (reactant) dissolves in such a large volume of solvent that
addition of more solvent produces no more further heat change
under standard conditions.
Standard enthalpy change Enthalpy change produced when one mole of a substance
of combustion, ▲Hcθ of a (reactant) is completely burnt in excess oxygen under standard
substance conditions.
Standard enthalpy change Enthalpy change produced when one mole of the gaseous ions
of hydration, ▲Hhydθ of an (reactant) is dissolved in a large amount of water under
ion standard conditions.
Standard enthalpy change Enthalpy change produced when one mole of an anhydrous
of hydration, ▲Hhydθ of an salt (reactant) forms one mole of a hydrated salt (product)
anhydrous salt under standard conditions.
Standard enthalpy change Enthalpy change when the amount of reactants shown in the
of reaction, ▲Hrθ equation reacts to give the products under standard conditions.
CHAPTER 6: ELECTROCHEMISTRY
Oxidation A process that losses electron / increase in oxidation number.
Acid (Arrhenius’ theory) A substance that ionises in water to form hydrogen ions.
Alkali (Arrhenius’ theory) A substance that dissociates in water to form hydroxide ions.
Collision theory States that when reactant particles collide with one another,
the effective collisions are produced if the total energy of the
reactants is equal or greater than the activation energy and the
reactants must collide at the correct orientation.
Homogeneous catalysts Catalysts that are in the same physical state as the reactants.
Heterogeneous catalysts Catalysts that are in a different physical state from the
reactants.