BIOMOLECULES, POLYMERS, POC

Single answer type questions:

POLYMERES
1. In a polymer sample, 30% molecules have a molecular mass of 20,000, 40%
have 30,000 and rest have 60000. The number average  Mn  and weight
average  Mw molecular weights are respectively
(A) 1, 10, 000 and 10, 538 (B) 36,000 and 43,333
(C) 1,40,000 and 1,56,000 (D) 228,000 and 56,000
2. Which of the following is not a natural polymer?
(A) Wool (B) Silk
(C) Cotton (D)Teflon
3. The product of addition polymerization reaction is
(A) PVC (B) nylon
(C) terylene (D) polyamid
4. Polymer consists of large molecules
(A) Called macromolecules which are made by linking together repeated units
of small molecules, called monomer
(B) Called capolymer
(C) Called  - caprolactum
(D) all of the above
5. On the basis of intermolecular forces, polymers are classified as
(a) rubbers (b) fibres
(c) elastomers, fibres, thermoplastics and thermosetting
(d) amino acids
6. Which of the following is not a natural polymer?
(a) Wool (b) Silk
(c) Cotton (d) Teflon
7. Isoprene on polymerization, produce
(a) synthetic rubber (b) gutta – percha
(c) nepprene (d) cis – poly (2-methyl – 1,3 – butadiene)
8. Natural rubber is obtained from latex, which is a
(a) mixture of wood, plants and gums
(b) colloidal dispersion of rubber in water
(c) mixture of chloroprene and carbohydrates
(d) none of these
9. Natural silk is
(a) Polyester (b) Polyamide
(c) Epoxide (d) Polyurethane
10. Natural rubber is polymer, derived from
a) 1, 3 – butadiene b) isoprene
c) Protein d) DNA
11. Step – growth polymers are formed by
a) The reactions of a single monomer that possesses two different functional
groups A and B

Page No - 1 -
 b) The reaction of two different bifunctional monomers and concentrated
HNO3
c) The intermolecular reaction of bifunctional molecules
d) All of these
12. A polyurethane is the product of
a) toluene – 2, 6 – diisocyanate and ethylene glycol in presence of a blowing
agent
b) - caprolactum and ethylene glycol
c) terephthalic acid and ethylene glycol
d) an isocyanate and an alcohol
13. Which of the following is not a copolymer?
a) Cross copolymer b) block copolymer
c) Random copolymer d) Graft copolymer
14. Polymeric molecules are held by
a) interatomic forces b) coulombic forces
c) intermolecular forces d) gravitational forces
15. The polymers such as polyethylene are
a) held together by Vander Waals forces
b) held together with the forces which operate at long distance
c) closely packed with coluombic forces
d) none of these
16. Example of thermosetting plastic is/are
a) Bakelite b)PVC
C) polyurethane d) Mylar
17. Terylene is a condensation polymer of ethylene glycol and
a) benzoic acid b) acetic acid
c) terephthalic acid d) salicylic acid
18. The fibre obtained by the condensation of hexamethylene diamine and adipic
acid is
a) Dacron b) nylon 6,6
c) Rayon d) Teflon
19. A raw material used in making nylon is
a) adipic acid b) 1,3 – butadiene
c) ethyne d) cyclohexanone
20. –caprolactum is the starting material for the manufacture of nylon 6 and is
obtained by Beckmann rearrangement of
O OH O

NOH

a) O b) c) OH d) O
21. The repeating units of PCTFE is
a) CF2 = CF2 b) CH2 = CH2
c) CF3 – CF3 d) FClC = CF2
22. The repeating units of PTEF are
a) CH  CH b) CF3 – CF3

Page No - 2 -
 c) CH2 = CHCN d) CF2 = CF2
23. Glyptal is the polymer of ethylene glycol and
a) terephthalic acid b) adipic acid
c) benzoic acid d) picric acid
24. A polymer which is used for making ropes and carpet fibres is
a) polyacetylene b) polypropylene
c) polyacrylonitrile d) PVC
25. Hard plastic covers of telephone are made of polymer of
a) metyl methacrylate b) venyl acetate
c) neoprene d) phenol and formaldehyde
26. The polymer which contains nitrogen is
a) PVC b) Teflon
c) butyl rubber d) nylon
27. The product of addition polymerization reaction is
a) PVC b) nylon
c) terylene d) polyamide
28. Cellulose is a condensation polymer of
a) maltose b)  -glucose
c)  –glucose d)  –fructose
29. Which of the following is a “polyamide”?
a) Rayon b) Terylene
c) nylon d) Orlon
30. Teflon, polystyrene and neoprene are all
a) copolymers b) condensation polymer
c) homopolymers d) monomers
31. Teflon
a)(– CF2 – CF2 –)n b) – (CCl2 – CCl2)n
c) – (CBr2 – CBr2)n d) CF2Cl2
32. The product of addition polymerization reaction is
a) PVC b) nylon
c) Terylene d) polyamide
33. Isoprene is used in making
a) petrol b) nylon
c) rubber d) liquid fuel
34. Which of the following is an inert polymer used in coating, particulary in
nonstick cookware?
a) Teflong b) Cellulose
c) Bakelite d) Orlon
35. Cellulose trinitrate, also called “gun cotton” is used in
a) Cellophane paper b) dyes
c) explosives d) making rayon
36. Cellulose contains glucose units joinind by  -1, 4-glycosidic linkages. These
molecules are held by
a) ionic bond b) intramolecular hydrogen bonds
c) weak vander Waals forces d) all of these
37. Which of the following cannot serve as a food source for human?

Page No - 3 -
 a) Proteins b) Starch
c) Enzymes d) Cellulose
38. Natural rubber is a cis-1, 4-polyisoprene. During vulcanization, natural
rubber is heated with sulphur. As result, a reaction takes place
a) that produces cross-links between the cis-polyisoprene chains
b) and makes the rubber much harder
c) and sulphur reacts both at the double bonds and at allylic hydrogen atoms
d) all of these
39. Nylon-6,9 is so named because it is a polyamide, formed from a
a) six – carbon dibase and a six-carbon diamine
b) six – carbon diacid and a sis-carbon diamine
c) six – carbon -caprolactum and a six-carbon diamine
40. Rubber is a
a) conducting polymer b) oriented polymer
c) elastomer d) strong commercially available fabric

POC
41. Sulphur present in an organic compound is detected by treating the ‘sodium
extract’ with
a) potassium ferricyanide b) postassium ferrocyanide
c) sodium nitroprusside d) ammonium thiocyanate
42. Which of the following nitrogenous compounds does not give blue colour in
the usual Lassaigne’s test for the detection of nitrogen?
a) Glycine b) Urea
c) Aniline d) Hydrazine
43. For the detection of sulphur in an organic compound, sodium nitroprusside
is added to the sodium extract of the compound. If sulphur is present, an
intense pink to purple colour is obtained due to the formation of
a) Fe(CN)2 b) K3[Fe(CN)5NS]
c) Na4[Fe(CN)5NO.S] d) Na4[Fe(CN)6]
44. Lassaigne’s test is performed to detect the presence of the elements N,S,X & P
in an organic compound. In this test the organic substance is at first fused
with
a) NaCl b) metallic sodium
c) metallic copper d) NaOH
45. In Lassaigne’s test, the sulphur present in the organic compound, on fusion
with sodium, is converted into
a) Na2S b) C4H4S
c) Na2S2O3 d) CH3SH
46. Halogens present in organic compounds may be detected by heating the
compound on a copper foil in a Bunsen nonluminous flame whereby it
imparts green colour to the flame. This test is known as
a) Marsh’s test b) Lassaigne’s test
c) Gutzeit test d) Beilstein test
47. The sodium extract prepared from sulphanilic acid, contains SCN-. It gives
blood-red colouration with

Page No - 4 -
 a) FeCl3 b) Na2CS3
c) FeSO4 d) a mixture of Na2S and CS2
48. An organic compound contains C, H, N, S and Cl. For detection of chlorine in
the compound, the sodium extract of the compound is at first heated with a
few drops of concentrated HNO3 and then silver nitrate solution is added to
get a precipitate of AgCl. This digestion with HNO3, prior to addition of AgNO3,
is required
a) to prevenet the formation NO2
b) to convert the CN- and S2- ions to volatile HCN and H2S, otherwise, they
will interfere with the test by forming AgCN and Ag2S.
c) to prevent the hydrolysis of NaCN and Na2S
d) to form S4N4 which prevent formation of AgCl with AgNO3
49. In Lassaigne’s test, when ‘sodium extract’ of an organic compound containing
both N and S is heated with sodium nitroprusside solution, a blood-red
colouration is developed. This is due to the formation of
a) sodium nitroprusside b) sodium thiosulphate
c) ferric sulphocyanide d) thiourea
50. When a nitrogenous organic compound is fused with sodium, the nitrogen
present in the compound is converted into
a) sodium nitrate b) sodium nitrite
c) sodamide d) sodium cyanide
51. To detect iodine in presence of bromine, the sodium fussion filtrate is treated
with NaNO2+ glacial acetic acid + CCl4. Iodine is detected by the appearance
of
a) purple colour in the organic layer of CCl4
b) brown colour in the organic layer of CCl4
c) deep blue colour in CCl4 layer
d) yellow colour in CCl4 layer
52. A mixture of acetone and carbon tetrachloride can be separated by
a) fractional crystallization b) fractional distillation
c) steam distillation d) vacuum distillation
53. Benzoic acid can be separated from a mixture of phenol and benzoic acid by
treatment with
a) NaHCO3 solution b) NaOH solution
c) Na2S2O3 solution d) FeCl3 solution
54. Orthonitrophenol can be separated from paranitrophenol by
a) chromatography b) solvent extraction
c) steam distillation d) sublimation
55. Anthracene can be purified by
a) sublimation b) crystallization
c) distillation d) filtration
56. Rectified spirit contains
a) 95.6% ethanol and 4.4% water b) 100% ethanol
c) 95.6% ethanol and 4.4% water c) 95.6% ethanol and 4.4% benzene
57. A liquid organic compound decomposes at its boiling point. It can be purified
by

Page No - 5 -
 a) simple distillation
b) sublimation
c) distillation under reduced pressure
d) all of these
58. Aniline can be separated from phenol using
a) NaHCO3 b) dilute HCl
c) NaCl d) conc. HNO3
59. KOH can be used as drying agent for
a) amines b) acids
c) phenols d) esters
60. Which of the following compounds are purified by steam distillation?
a) Nitrobenzene b) Chlorobenzene
c)Orthonitrophenol d) All of these
61. Quick time can only be used for drying
a) ethanol b) phenols
c) esters d) carboxylic acid
62. Silver salt method is used for the determination of molecular weight of
a) organic bases b) organic acids
c) aliphatic amines d) esters
63. The molecular weight of aniline is determined by
a) converting it into its chloroplatinate salt and then estimating platinum
obtained by ignition of the salt.
b) converting it into its acetate
c) making aniline into its tribromo derivative
d) all of these
64. Which of the following methods is used for the estimation of nitrogen in
organic compounds?
a) Hypobromite method b) Rast method
c) Dumas’ method d) Carius method
65. Which of the following methods is used for the estimation of sulphur in
organic compounds?
a) Carius method b) Victor Meyer’s method
c) Kjeldahl method d) Dumas’ method
66. An organic compound has carbon and hydrogen percentages in the ratio 6 : 1
and carbon and oxygen percentages in the ratio 3 : 4. The compound has the
empirical formula
a) CH2O b) CH4O
c) C2H6O d) CHO2
67. 0.0833 mole of a carbohydrate of empirical formula CH2O contains 1.00g of
hydrogen. The molecular formula of the carbohydrate is
a) C5H10O5 b) C3H4O3
c) C12H22O11 d) C6H12O6
68. Which of the following aliphatic aldehydes on heating with concentrated
NaOH solution gives an yellow resinous precipitate?
a) CH3CHO b) CCl3.CHO.H2O/CCl3CH(OH)2
c) HCHO d) All of these

Page No - 6 -
69. Which fot he following compounds will give chloroform on warming with
NaOH solution?
a) CCl3CH(OH)2 b) H.CHO
c) CH3CONH2 d) C6H5NHCOCH3
70. Which of the following organic compounds will not yield CO2 when treated
with Na2CO3 solution?
a) Benzoic acid b) Phenol
c) Sulphanilic acid d) Orthonitrophenol
71. Phenol and carboxylic acid can be distinguished from each other using
a) NaOH solution b) NaCl solution
c) NaHCO3 solution d) None of these
72. HCHO and CH3CHO can be distinguished from each other by the use of
a) Fehling’s solution b) ammoniacal silver nitrate solution
c) evaporation by heating d) alkaline KMnO4 solution
73. Acetaldehyde on treatment with alkaline solution of sodium nitroprusside will
produce
a) black colouration b) yellow colouration
c) blue colouration d) red colouration
74. Acetaldehyde and acetone can be distinguished by
a) iodoform test b) nigroprusside test
c) Fehling’s solution test d) NaHSO3 test
75. Which of the following compounds will not give iodoform test?
a) CH3COCH3 b) CH3CO.C6H5
c) CH3CH2COCH2CH3 d) CH3CH2OH
76. Methanol and ethanol can be distinguished by
a) iodoform reaction b) esterification
c) oxidation with acidified K2Cr2O7 solution
d) acrolein test
77. Which of the following observations is correct and is useful in identifying
carboxylic acids?
a) Carboxylic acids liberate CO2 gas from NaHCO3 solution.
b) They produce fruity smell of esters when heated with alcohol in presence of
concentrated H2SO4.
c) Acids liberate I2 from a mixture of KIO3and KI.
d) All of these
78. Which of the following carboxylic acids will give “silver-mirror test”?
a) CH3CO2H b) H.CO2H
c) (COOH)2 d) CH3CO.CO2H
79. Which of the following compounds will give orange-yellow precipitate with
2,4-dinitrophenylhydrazine reagent?
a) CH3CH2.CO2.H b) CH3COOC2H5
c) CH3COCH3 d) C6H5OH
80. Which of the following organic compounds will give foul odour of isocyanide
on heating with chloroform and alcoholic KOH?
a) para-toluidine b) Glycine
c) Anthranilic acid d) Sulphanilic acid

Page No - 7 -
81. An organic compound is treated with NaNO2 and dilute HCl at 0oC and then
the resulting solution is added to an alkaline solution of  -naphthol whereby
a brilliant red dye is produced. This observation indicates that the compound
processes
a) – NO2 group b) – CONH2 group
c) aromatic – NH2 group d) aliphatic – NH2group
82. Which of the following aromatic amines will undergo Liebermann’s reaction?
a) C6H5NHCH3 b) C6H5N(cH3)2
c) (C2H5)3N d) C5H5N
83. Nitrobenzene on heating with a mixture of conc. HNO3 and conc. H2SO4 at
1000C produces
a) p-dinitrobenzene b) m-dinitrobenzene
c) o-diritrobenzene d) benzene sulphonic acid

84. Lysine exists as a Zwitter ion

+ Ka1 +
H3N-(CH2)4-CH-COOH  
 H3N-(CH2)4-CH-COO
+NH3 +NH3
Mono cationic form
Dicationic form
Pka2 = 8.95
pKa1 = 2.18
Ka2
Ka3 +

H2N-(CH2)4-CH-COO-  
 H3N-(CH2)4-CH-COO-

NH2 NH2
Anionic form Dipolar ion
Pka3 = 10.53

Then isoelectric point (PI) of Lysine is

a) 5.56 b) 9.74 c) 6.25 d) 0
85. Choose correct answer
I) Sucrose on hydrolysis gives   D  glu cos e
II) Sucrose on hydrolysis gives   D  glucose
III) Sucrose on hydrolysis gives   D  fructose
IV) Sucrose on hydrolysis gives   D  fructose
A) I, II, IV only B) I, IV only C) I, II & III only D) I, II , III & IV
86. Which of the following will not show fermentation?

Page No - 8 -
 CHO
CHO
CHO H OH
H OH
CHO
H OH H OH
A) HO H B) C) H OH D)
H OH H OH
CH2OH H OH
CH2OH H OH
CH2OH
CH2OH

87. Compound (A), C5 H10O4 is oxidized by Br2  H 2O to the acid, C5 H10O5 which readily
forms a lactone. (A) forms a triacetate with Ac2O and a hydrazone with
PhNHNH 2 . ‘A’ is oxidized by HIO4 , only one molecule of which is consumed. The
structure of ‘A’ is
A) B) CH 2OH
CHO
CO
(CHOH)3
 CHOH 2
CH2OH
CHO
C) CHO D)
H C OH
CH 2 OH
C O
HOH 2C  CH  CH  OH   CHO
H C OH
CH 2OH

88. Which one of the following statements concerning the given

equilibrium is true?
H HOH C H HOH C
2 O 2 O
H H
HO HO
H H H
OH
OH H OH
H OH H
OH OH

A) The two structures are enantiomers of each other and their

inter conversion is mutarotation.
B) The two structures are diastereomers of each other and their
interconversion is mutarotation
C) The two structures are diastereomers of each other one is
furanose form and the other is pyranose form

Page No - 9 -
 D) The two structures are enantiomers of each other one is
furanose form and the other is pyranose form.
89. Which one of the following is not an aldohexose ?
(A) Mannose (B) Galactose (C) Talose (D) Tagatose
90. Epimers are represented by:

CH2OH CHO CHO CHO CHO

O H OH HO H H OH HO H
HO H HO H HO H H OH HO H
H OH H OH H OH HO H HO H
H OH H OH H OH HO H HO H
CH2OH CH2OH CH2 OH CH2OH CH2OH

I II III IV V
a) I, II, and III b) II and III c) III and IV d) I, II, and V
91. Which of these compounds, I, II, III, IV, is a reducing disaccharide?

CH2OH CH2OH CH2 OH CH2OH

O H H O O H H O
H H H H
H H H H
OH H OH H OH H OH H
OH O OH OH O OH

H OH H OH H OH H OH
I II

CH2OH CH2OH CH2 OH

OH
O H H O O O
H H H H H
H H H
OH H OH H OH H OH H
OH O OCH3 OH O CH2OH

H OH H OH H OH H OH
III IV

a) I alone b) II alone c) III alone d) IV alone

92. Reaction of the following substance with nitric acid would yield:
CHO
HO H
HNO3
HO H ?
H OH
H OH
CH2OH

CO2H CO2H CH2OH CHO CO2H

HO H HO H HO H HO H HO H
HO H HO H HO H HO H HO H
H OH H OH H OH H OH H OH
H OH H OH H OH H OH H OH
CH2OH CO2H CH2OH CO2H CHO

I II III IV V
a) III b) IV & V c) II d) I

Page No - 10 -
93. Predict the nature of the products Z and Z in the following series of reactions
CHO

CHOH NaCN/HCN H3O+ HI/P

[X] [Y] [Z]
(CHOH)3

CH2OH

CH2OH

CO NaCN/HCN H3O+ HI/P

[X] [Y] [Z]
(CHOH)3

CH2OH
(A) both are n–heptane
(B) both are n–heptanoic acid
(C) both are 7–iodoheptanoic acid
(D) Z is n–heptanoic acid and Z is a substituted hexanoic acid
94. Ring structure of glucose is due to formation of hemiacetal and ring formation
between
(A) C1 and C5 (B) C1 and C4
(C) C1 and C3 (D)C3 and C4
95. In the given reaction:
H /
Glucose + 3C6H5NH – NH2   Osazone + A + B
(A) and (B) are
(A) C6H5NH2 and NH3 (B) C6H5NH2 and NH2OH
(C) C6H5NH – NHOH and NH3 (D) NH2OH and HOH

96. The reaction, sucrose  glucose +fructose, takes place at certain
H

temperature while volume of solution is maintained at 1 lt. At time zero, the

initial rotation of the mixture is 340. After 30 minutes the total rotation of
solution is 190 and after a very long time, the total rotation is -110C. Find the
time when the solution would be optically inactive?
(A) 135 min (B) 103.7min
(C) 38.7 min (D) 45min

Page No - 11 -
97. H OH
C
C OH
HO H
H OH
H OH
CH2OH
The Fischer projection formula shown above is the enolic form of
(A) D-fructose (B) D-mannose
(C) D-glucose (D) All
98. Give the correct order of initials T or F for following statements. Use T if
statement is true and F if it is false. X (molecular formula, C7H6O2) is and
aromatic white solid which liberates colourless, odourless gas on rescting
with NaHCO3.
S1 : Only three of th3e five functional isomers of X (including 'X' itself) will
give positive 2, 4-DNP test.
S2 : The liberated colourles, odourless gas will contaning radioactive 14C.
S3 : Except 'X', no other functional isomer will liberate colourless odourless
gas with NaHCO3.
S4 : The DU of higher homolog of 'X' will be four.
(A) TTTF (B) FTTF (C) FTTT (D) TTFF
99. Which one of the following will not give white precipitate with ammonical
silver nitrate solution
(A) CH3 – C C – CH3 (B) CH3 – CH– C C – CH3

CH3
(C) CH3 – CH2– CH = CH2 (D) All of these

100.
(i) Na metal
No H2 gas evolved
(ii) Cl 2/h 3-monochloro
Compound C4H10O
products
(iii) Lucas reagent
–Ve test
Compound is
O
(A) (B) (C) O (D)
O O
101. An aromatic compound A (C8H10O) gives following tests with the given
reagents.
Na metal
Positive

FeCl3 (neutral)
A(C 8H10O) Negative

Lucas reagent
Positive
Anhydrous ZnCl2/HCl

Identify 'A'

Page No - 12 -
 OH OH
CH2 – CH2 – OH OCH3
CH3 CH2–CH3
(A) (B) (C) (D)
CH3
CH3
Br2/H2O

Bayer's reagent
C4H6
(X) Na metal
102.
(A) H3C – C C – CH3 (B) CH2 = CH – CH = CH2
C CH
(C) CH3 –CH2 – C CH (D)

103. The following two compounds I and II can be distinguished by using reagent
OH HO

COOH COOH
(1) aq. NaHCO3 (2) Neutral FeCI3 (aq.) (FfeCI3 + NH4OH + H2O)
(3) Blue litmus solution (4) Na metal (5) HCI (ZnCI2
anhydrous)
(A) 1 or 3 (B) 2 or 5 (C) 4 or 5 (D) 3 or 4
104. Tollen's regent (AgNO3 + NH4OH) can be distinguished between
O O O
O
(A) H–C–H and Ph–C–H (B) H and H H
O O
D O Me
C C=O

(C) and (D) Ph–C–Ph and Me–C–Me

O O
C=O
Me
105. Observe the4 following compound and select +Ve & –Ve tests respectively
(i) Na metal

HO C CH (ii) NaHCO3
(iii) 2,4-DNP
OHC COOH
(iv) Lucas reagent
(A) + + + – (B) + + + +
(C) + – + – (D) + – – +
106. Consider following compounds and decide as to which of the following
statements are true ?
CH3 CH3 CH3

CH2 = CH – C – COOH CH3 – C – OCH3 CH3O–C C–H CH3 – C – CH2OCH3

H CH3 OH
(I) (II) (III) (IV)
(A) (II) gives no reaction with Na metal, however, 1 mole of (IV) on reaction
with Na metal willliberate 22.4 litres of H2 gas at STP
(B) (I) will give brisk effervescence on addeition of NaHCO3 but will not bring
any change in the colour of Br2 water

Page No - 13 -
 (C) (III) Iiberates H2 gas with Na metal, gives white precipitate with Tollen's
reagent but does not respond towards lucas reagent or 2, 4-DNP test.
(D) (IV) gives turbidity with anhydrous ZnCI2
107. An aromatic compound 'X' (C9H8O3) turns blue litmus to red.It gives yellow
precipitate with I2/NaOH and forms Y (C8H6O4).Y forms three mononitro
isomeric products. Identify X.
COCH3 COCH3 COCH3
COOH
(A) (B) (C) (D) none of these
COOH
COOH
108. Which will not give iodoform reaction with I2/OH–?
(A) CH3COCH2CH3 (B) CH3CONH2
(C) C6H5COCH3 (D) CH3CHO
109. Compound Y1C7H8O is insoluble in water, dil HCI and aqueous NaHCO3.It
dissolves in dilute NaOH. When Y is treated with bromine water it is
converted rapidly into a compound of formula C7H5OBr3.Identfy the
structure of Y
OH OH O–H O – CH3
CH3
(A) (B) (C) (D)
CH3
CH3
110. Compounds I and II can be distinguished by using reagent
(I) (II)
4-Amino-2-methlbut-3-en-2-ol 4–Amino–2, 2-dimethylbut-3-yn-1-ol.
(A) NaNO2/HCI (B) Br2/H2O
(C) HCI/ZnCI2 (anhydrous) (D) Cu2CI2 + NH4OH
111. Compound P(C6H10) does not have any geometrical isomer. ON ozonolysis,
two products R(C3H4O) and Q(C3H6O) are formed. R gives negative iodoform
test while Q responds positively towards I2/NaOH solution. S, another isomer
of P is an unsyumetrical alkene and on ozonolysis produces T(C6H10O2)
which also gives a yellow precipitate with I2/NaOH solution and also gives
positive test with Tollen's reagent. Which of the following does not represent
any of the molecules amongst P,Q,R,S&T.
H OO H H OO H
(A) O (B) (C) (D)

112. A set of reagents (1 to 8) are successively reacted with the followit compound
O

OH
OH

1. NaHCO3 2.2, 4, DNP 3.Na metal 4. AgNO3 +OH

5. Fehling's solution 6.Cu2CI2 + NH4OH 7. Br2/H2O
8. NaNO2 + HCI
The reagents which give positive test with the given compound are :

Page No - 14 -
 (A) 1, 2, 3, 4, 5 (B) 3, 4, 5, 6, 8
(C) 1, 2, 3, 4, 8 (D) All reagents except 1 and 8
113. Compounds (C8H8O) X will give following laboratory tests.
Isomers FeCl3 AgNO3 / NH4OH Na metal
X Coloured solution Negative 1/2 H2
X can be :
H3C O
OCH3 CH2OH OH
O

(A) (B) (C) (D)

CH = O CHO CH = CH2
OH
114. Which of the following alcohol will show positive iodoform test ?
OH OH
(A) CH3 – CH – CH2 – NO2 (B) CH3 – CH– CH2 – COOH

OH
(C) ICH2 – CH – CH2 – CH3 (D) none of these

115. The compound A gives following reactions.

Na metal
H2 gas

2, 4-DNP
A(C6H8O2) yellow orange ppt

O3
B(C6H8O4)

Its structure can be

(A) CH2=CH–(CH2)2–C– CH2OH (B) OHC–(H2C)2–HC = HC – COOH
O
OH OH
(C) (D)

O CHO
116. In compound A (C30H60O) following tests are observed negatively, A can be :

Br2 / H2O
-Ve
2, 4 DNP
C30H60O -Ve
(A) Na metal
-Ve

(A) an unsaturated ether (B) an epoxide

(C) a cyclic ketone (D) a cycloalkanol
117. A mixture of two orgnaic compound gives red coloured precipitate with
cuprous chloride (ammonical) and silver mirror on heating with Zn dust and
NH4CI followed by AgNO3 + NH4OH solution. The mixture contains
O COOH COOH
NH2
(A) CH3–(CH2)8–CHO and (B) and

NO2 NH2
CHO CHO CHO
(C) and (D) and
NO2
118.

Page No - 15 -
 The above process in which a and b form remain in equilibrium with acyclic
form and a change in optical rotation is observed which is called as-
(A) Mutarotation (B) Epimerisation (C) Condensation (D) Inversion
119. How many moles of HIO4 is required to brak down the following molecule?

(A) 1 (B) 2 (C) 3 (D) 4

120. List - I List - II
VITAMIN DEFICIENCY RESULT
1) Ascorbicacid a) Beri - beri
2) Retinol b) Cracked lips
3) Riboflavin c) Scurvy
4) Thiamin d) Night - blindness
Selected the correct answers using the codes.
Codes :
a) 1 - B ; 2 - A ; 3 - C ; 4 - D b) 1 - A ; 2 - B ; 3 - C ; 4 - D
c) 1 - D ; 2 - C ; 3 - B ; 4 - A d) 1 - C ; 2 - D ; 3 - B ; 4 – A
121. Which of the following chemical units is certainly to be found in an enzyme?
OH
O
O
N

HO HO O
a) b) N

Page No - 16 -
 O

O R
O

O R
O
H O
N C O R
c) d)
122.The functional groups present in Cortione are
HOH2C
CH3
O OCH3

Cortisone
O
a) Ether, alkene, alcohol b) Alcohol, ketone, Alkene, ether
c) Alcohol, ketone, amine d) Ether, amine, ketone
123. Pick out the wrong statement
A) Methyl salicylate gives violet colour with neutral FeCl3
B) Aspirin gives effervescence with a saturated solution of NaHCO3 .
C) Benzamide and urea gives ammonia when heated with NaOH solution.
D) Acetanilide answers the azodye test.
124. The term anomers of glucose refers to
(A) isomer of glucose that differ in configuration at carbon one and four (C – 1
and C – 4)
(B) a mixture of (D)-glucose and (L)-glucose
(C) Enantiomers of glucose
(D) isomer of glucose that differ in configuration at carbon one (C – 1)

125. Terylene is a condensation polymer of ethylene glycol and

(A) benzoic acid (B) acetic acid
(C) terephthalic acid (D) salicylic acid
126. When glucose is heated with nitric acid, the product is
(A)gluconic acid (B) glucaric acid
(C) glycolic acid (D) oxalic acid
127. In a polymer sample, 30% molecules have a molecular mass of 20,000, 40%
have 30,000 and rest have 60000. The number average  Mn  and weight
average  Mw molecular weights are respectively
(A) 1, 10, 000 and 10, 538 (B) 36,000 and 43,333
(C) 1,40,000 and 1,56,000 (D) 228,000 and 56,000

Page No - 17 -
128. Which one of the following is not an aldohexose ?
(A) Mannose (B) Galactose (C) Talose (D) Tagatose
129. The correct statement is
(A) Glucose and mannose are C – 3 epimers
B) Glucose and galactose are C – 4 epimers
(C) Glucose and fructose are anomers
(D)   D - glucose and   D - glucose are enantiomers

130. Histidine can exist in following four structures depending on pH of the

medium
O O O O
O OH O O

+ + +
NH3 NH3 NH2 NH3

+ NH + NH NH NH
HN HN N N
(I) (II) (III) (IV)
Which of the following option is correct description?
pH = 0 pH = 4 pH = 8 pH = 12
(A) III I IV II
(B) II I IV III
(C) II IV I III
(D) II III IV I

131. Which of the following reagents would convert an aldose to saccharic acid?
(A) Tollen’s reagent (B) Fehling’s solution
(C) HNO3 (D) Red P + Hl.

132. In the given reaction:


H /
Glucose + C6H5NH—NH2   Osazone + A + B + H2O
(A) and (B) are
(A) C6 H 5 NH 2 and NH3 (B) NH2OH and NH3
(C) C6H5NH—NH2 and NH3 (D) C6H5NH—NHOH and NH2OH.

133. Aspartame, an artificial sweetener is a peptide and has the following

structure. Which of the following is correct about the molecule?
O
C6 H5
OH
NH O
O
H 2N CH3
O
(A) It has four functional groups and on hydrolysis produces only one amino
acid
(B) It has three functional groups and on hydrolysis produces only one amino
acid

Page No - 18 -
 (C) It has four functional group and on hydrolysis it produces a mixture of
amino acids
(D) It has five functional groups and on hydrolysis it produces a mixture of
amino acids.

134. Which of the following separate benzamide and benzyl amine from their
mixture dissolved in CH2Cl2?
(A) aqu NaHCO3 (B) aqu NaOH
(C) aqu HCl (D) H2O.

135. Select the reagent/s needed to perform the following transformation

CH2OH CH2OH
O O
OH 
 ?
OCH3
HO HO
OH OH OH OH
(A) CH3OH, KOH (B) (CH3CO)2O
(C) (CH3)2 SO4, OH (D) CH3OH, HCl.

136. Probable structure of P would be

H3C
+
OH C O, H
CH2OH
O 2 mols H3C
P,
HO
HO HO
O
CH2 OH
O O O
H2 C
(A) O
(B) O
O O O
O OH

O O
O CH 2OH
H2C
O
O
(C) (D) O
HO
O
O O O

137. C6H5O3N (A) is insoluble in aq. NaHCO3 and soluble in aqueous NaOH. It is
not steam volatile. On treatment with Br2/H2O it produces C6H3O3Br2N(B).
Probable structure of A would be

Page No - 19 -
 OH OH
NO2
(A) (B)

NO2
OH
OH
ONO
(C) (D)

NO2
138 In a Kjeldahl’s nitrogen estimation, ammonia liberated by 0.7 gm
. of an organic compound is absorbed into 160 ml of 0.25 N
solution. The excess of acid requires 64 ml of 0.5 N NaOH
solution for neutralization. The given compound is likely to be
A) B) C) D)
H2N CH CO2H

139. The isoelectric point of the amino acid R is 6. In a solution of

pH  1 , which of the following species will predominate ?

(A) + (B)
H3N CH CO 2H H2N CH CO 2H

R R

(C) + - (D) -
H3N CH CO 2 H2N CH CO2

R R

140. Which of the following compound is unlikely to react with sodium metal?
CH3
O OH Br NH2

A) B) C) D)

141. Which of the following is a glucoside?

OH
OH
H
O OH OH
H H O H H O
H H
A) OH H B) OH H H H H
HO H HO O OH
H OMe H OH OH OH

Page No - 20 -
 OH
H
HO OH
H H OH H O
O H
C) OH HO D) OH OH H H H
H OMe HO O OH
H H H H OH OH

142. The optical rotation of the   form of a pyranose is +150.70, that of the
  form is +52.80. In solution an equilibrium mixture of the anomers has an

optical rotation of +80.20. The percentage of the   form at equilibrium is

(A) 28 % (B) 32 % (C) 68 % (D) 72 %

143. Which of the following is formed by condensation polymerisation?

(A) Teflon (B) Polystyrene
(C) PVC (D) Dacron
144. Histidine can exist following four structures depending on pH of the medium
O O O O
– – –
O OH O O

+ + +
+ NH3 + NH3 NH2 NH3
HN NH HN NH N NH N NH

(I) ( II ) ( III ) ( IV )
Which of the following option is correct description ?
pH = 0 pH = 4 pH = 8 pH = 12
(a) III I IV II
(b) II I IV III
(c) II IV I III
(d) II III IV I
145. Which amino acid does not contain chiral centre ?
a) Valine b) Leucine
c) Glycine d) Isoleucine
146. Which of the following pair give same phenyl osazone ?
a) D – glucose and D – allose b) D – glucose & D - altrose
c) D – glucose and D – mannose d) D – glucose & D - talose

N H 3Cl 
NO2
Cl

147 (P) and (Q)

Above compounds (P) and (Q) can be differenciated by
a) ammonical. AgNO3 b) NaOH
b) c) FeCl3 d) Both (a) and (b)

Page No - 21 -
148. Acetaldehyde and Benzaldehyde can be differentiated by
a) Fehling test b) Iodoform test
c) Tollen’s reagent d) both (a) & (b)

149. The Prussian blue colour obtained during the test of nitrogen by Lassaigne’s
test is due to the formation of
a) Fe4[ Fe(CN )6 ]3 b) Na3[ Fe(CN )6 ]
c) Fe(CN )3 d) Na4[ Fe(CN )5 NOS ]
HgSO (1) NH 3  HCN
150. H  C  C  H 
H SO ( A) 
4
(2)H3O ( B) Pr oduct ( B )is
2 4
a) Glycine b) Alanine
c) Valine d) leucine
151. Bakelite is
a) addition polymer of HCHO + C6H5COOH
b) Condensation polymer of 1,3,5 trimethyl Benzenene + 1,3-butadiene
c) Addition polymer of 2-methyl, -1,3-butadiene and ethylene
d) Condensation polymer of HCHO + PhOH
152. Orlan is a polymer of
a) Styrene b) CF2  CF2 c) Vinyl chloride d) Acrylonitrile
153. In lactose, the reducing part is
a) Galactose b) Glucose c) Fruclose d) Mannose

154. Which of the following compounds gives blood red colour in Lassaigne’s test ?

(A) CN (B) H2N COOH

O
(C) (D)
H2N C NH2 H2N SO3Na

155. 5 ml of a gaseous hydrocarbon was subjected to combustion with 30 ml of

O 2 . The resulting gaseous mixture on cooling is found to measure 25 ml.
When the gaseous mixture was passed through NaOH solution, 10 ml of the
gas is absorbed and the remaining gas is absorbed by pyrogallol. All
measurements are made at constant pressure and temperature. The
molecular formula of the hydrocarbon is.
(A) C 2H 2 (B) C3H 8
(C) C 2H 4 (D) C 2H 6
156. What is water soluble fraction in starch?
A) Amylopectin B) Amylose C) Lactose D) Maltose

157.

Page No - 22 -
 CHO
CHO
CHO H OH
H OH
CHO
H OH H OH
A) HO H B) C) H OH D)
H OH H OH
CH2OH H OH
CH2OH H OH
CH2OH
CH2OH

158. Which one of the following statements concerning the given equilibrium is
true?
H HOH C H HOH C
2 O 2 O
H H
HO HO
H H H
OH
OH H OH
H OH H
OH OH

A) The two structures are enantiomers of each other and their inter conversion
is mutarotation.
B) The two structures are diastereomers of each other and their interconversion
is mutarotation
C) The two structures are diastereomers of each other one is furanose form and
the other is pyranose form
D) The two structures are enantiomers of each other one is furanose form and
the other is pyranose form.

159. Which is NOT TRUE about polymers?

(A) Polymers do not carry any net charge
(B) Polymers have high viscosity
(C) Polymers scatter light
(D) Polymers have low molecular weight

160. Which of the following is a copolymer?

(A) Buna-S (B) PAN
(C) Polythene (D) PTFE
161.

Page No - 23 -
162. Compound ‘X’, C7 H 8O , is insoluble in H 2O , dil HCl and aq. NaHCO3 but
dissolves in dil NaOH . When ‘X’ is treated with Br2 / H 2O , it is converted rapidly
in to a compound of formula C7 H 5OBr3 . Then compound ‘X’ is

A) o  Cresol B) p  Cresol C) m  Cresol D) anisole

163. Choose correct answer

I) Sucrose on hydrolysis gives   D  glu cos e
II) Sucrose on hydrolysis gives   D  glucose
III) Sucrose on hydrolysis gives   D  fructose
IV) Sucrose on hydrolysis gives   D  fructose
A) I, II, IV only B) I, IV only
C) I, II & III only D) I, II , III & IV

164. A nitro alkane reacts with nitrous acid to yield a product which is blue and is
insoluble in alkali. The nitroalkane is
(A) CH3CH2NO2 (B) (CH3)2CHNO2
(C) (CH3)3CNO2 (D) (CH3)2CHCH2NO2

Page No - 24 -
BIOMOLECULES, POLYMERS, POC– KEY SHEET
Single Answers :

1 B 2 D 3 A 4 A 5 C 6 D
7 D B B 9 B 10 B 11 A 12 A
13 A 14 C 15 A 16 A 17 C 18 B
19 A 20 B 21 D 22 D 23 A 24 B
25 D 26 D 27 A 28 B 29 C 30 C
31 A 32 A 33 C 34 A 35 C 36 B
37 D 38 D 39 B 40 C 41 C 42 D
43 C 44 B 45 A 46 D 47 A 48 B
49 C 50 D 51 A 52 B 53 A 54 C
55 A 56 C 57 C 58 B 59 A 60 D
61 A 62 B 63 A 64 C 65 A 66 A
67 D 68 A 69 A 70 B 71 C 72 C
73 D 74 C 75 C 76 A 77 D 78 B
79 C 80 A 81 C 82 A 83 B 84 B
85 D 86 C 87 D 88 B 89 D 90 B
91 B 92 C 93 D 94 A 95 A 96 B
97 D 98 B 99 D 100 B 101 A 102 C
103 B 104 C 105 A 106 C 107 A 108 B
109 B 110 C 111 B 112 D 113 C 114 C
115 C 116 B 117 B 118 A 119 A 120 D
121 122 B 123 C 124 D 125 C 126 B
127 B 128 D 129 B 130 B 131 C 132 A
133 C 134 C 135 D 136 B 137 D 138 B
139 A 140 A 141 B 142 A 143 D 144 B
145 C 146 C 147 A 148 D 149 A 150 B
151 D 152 D 153 B 154 D 155 C 156 A
157 C 158 B 159 D 160 A 161 A 162 C
163 D 164 B

BIOMOLECULES, POLYMERS, POC– SOLUTIONS

Single solutions
30  20, 000  40  30, 000  30  60000
1. Mn  Number average    36,000
 30  40  30 

Page No - 25 -
 30   20, 000   40   30000   30   60000
2 2 2

Mw  weight average    43,333

30  20000  40  30000  30  60000
2. Teflon is artificially made as (… CF2—CF2 …)n
3. CH2 = CHCl
4. A
5. C
6. Teflon is artificially made as (….CF2 – CF2) n
7. D
8. B
9. B
10. B
11. A
12. A
13. A
14. C
15. A
16. A
O O
|| ||
H +
HO.CH 2CH 2.OH  HO  C C  OH 
Δ

17.
Poly (ethylene terephthalate terylene) + H2O
18. B
19. A
20. B
21. D
22. D
23. A
24. B
25. D
26. D
27. A
CH2 = CHCl
28. B
29. C
30. C
31. A
32. A
33. C
CH 3
|
Isoprene is CH 2  C  CH  CH 2
34. A
35. C
36. B
37. D
38. D
39. B

Page No - 26 -
40. C
A polymer, that can stretch and then revert back to its original shape is
called elastomer.
41. C
42. It does not produce NaCN, because N2H4 does not contain carbon.
43. c
44. b
45. a
46. d
47. Sulphanilic acid contain N,S and C which give NaSCN. With FeCl3 it gives
blood-red precipitate of Fe(SCN)3
48. b
49. c
50. d
51. 2Nal + 2NaNO2 + 4HAc  I2 + 2NO + 4NaAc + 2H2O
52. b
53. a
54. c
55. a
56. c
57. c
58. Aniline forms C6H5 NH 3Cl  (solid salt)
59. Amines and KOH are both bases
60. d
61. Rest will react with Ca(OH)2 produced by the absorption of water by CaO.
62. b
63. a
64. c
65. a
66. C : H : O = 6 : 1 : 8, % C : H : O
= 6/15 x 10 : 1/15 x 10 : 8/15 x 100
= 40 : 6.67 : 53.3
= 40/12 : 6.67/1 : 53.3/16
= 1 : 2 : 1 i.e. CH2O
67. d
68. a
69. a
70. Phenol is least acidic among all.
71. c
72. c
73. d
74. c
75. Does not have CH3CO – C group and CH3CH(OH) group.
76. a
77. d
78. b

Page No - 27 -
79. c
80. No odour is detected due to the non-volatility of the acidic isocyanide in the
alkaline solution.
81. c
82. Secondary amine undergo Liebermann’s reaction.
83. b
84. Conceptual
85. Conceptual
86. Aldopentoses do not undergo fermentation.
87. A should have 3 hydroxyl groups and an aldehyde and forms lactone with
only one oxidisable group CHO by Br2 water /HIO4
88. Fact
89. Tagalose is an aldoketose
90. At C2 the configuration is changed in II & III remaining carbon having the
same configuration.
91. Only II is having anomeric OH i.e., in the hemiacetal form which can be
isomerised to free CHO in presence of alkaline medium
92. Nitric acid is strong oxidizing agent hence CHO as well as terminal CH 2OH is
oxidized to COOH groups
93.
CHO OH OH COOH
HC
CN CH
CH OH COOH CH2
CH OH
CH OH
NaCN / HCN
(CHOH)3   H 3O 

HI / P
  CH2
(CHOH)3
(CHOH)3
CH2OH (CH2)3
CH2OH
CH2OH
CH3
CH2OH CH2OH CH2OH CH3
CN OH
CO C C CHCOOH
OH H 3O  COOH 
HI / P
NaCN / HCN
   
(CHOH)3 (CHOH)3 (CHOH)3 (CH2)3

CH2OH CH2OH CH2OH CH3

94. A
95. A
2.303  r r
 2.303  11  34  2
96. k  ;
log   0  log    1.35 10
t  r  rf 30   11  19 
 
1  45 
When rt  0 t  ln    103.7
k  11 
97. The keto forms could be either of

Page No - 28 -
 CHO CHO CH2OH
H OH HO H O
HO H HO H HO H
H OH H OH H OH
H OH H OH H OH
CH2OH CH2OH CH2OH
98. (B)

Other Functional isomers of ‘X’ are None of these will

14
give +ve test with NaH CO3

Higher homolog of ‘X’: 4 isomeric form

99. (D)

100. (B)

101. (A)

Page No - 29 -
102. (C)
103. (B)
104. (C)
105. (A)
106. (C)

107. (A)
108. (B)
109. (B)

110. (C)

(I) gives immediately turbidity by Lucas reagent and (II) does not give turbidity
Appriciably
111. (B)

112. (D)
There is no COOH group or NH2 group.
 Regents 1 and 8 will fall to give test.
113. (C)
114. (C)

Page No - 30 -
115. (C)
OH

The compound O
gives positive test with Na metal, 2, 4-DNP and it

gives single product with O3

116. (B)
The compound C30H60 O has one degree of unsaturation since it gives
negative test with Br2/H2O, 2, 4 [MP and Na metal it must be an
epoxide.
117. (B)
- NO2 group gives +ve test with Zn/NH4CI followed by AgNO3 + NH4OH
solution
118. The above phenomenon is called as mutarotation.
119. Only 1 mole H104 is needed.
120.Ascorbicc - deficiency result is - scurvy
Retionl - night - blindness
Riboflvin - cracked lips
thiamine - Beri – beri
H O
| ||
121. Many enzymes are found to possess - N - C -; since they are polypeptides
122. B
123. C6 H 5 NHCOCH 3 does not answer azodye test as that of C6 H 5 NH 2
124. Conceptual
125. Conceptual
126. CHO(CHOH)4CH2OH  HNO
[O]
 COOH(CHOH)4COOH
3

30  20, 000  40  30, 000  30  60000

127. Mn  Number average  
 30  40  30 
 36,000
30   20, 000   40   30000   30   60000
2 2 2

Mw  weight average    43,333

30  20000  40  30000  30  60000
128. Tagalose is an aldoketose.
129. Conceptual
130. pKa of -COOH = 1.82

Page No - 31 -
 pKa of  – NH 3 = 9.17
pKa side chain = 6.04.
131. Conceptual
132.
CHO HC N NHC6H5

H C OH 
C6 H 5 NHNH 2
 H 2O
 H C OH

(CHOH)3 (CHOH)3

CH2OH CH2OH
D-Glucose D-Glucose
phenylhydrazone

CH N NHC6H5
2C6 H 5 NH  NH 2
H C OH  CH N NHC6H5
(CHOH)3 C N NH C6H5
CH2OH (CHOH)3 C6H5NH2 NH3

D-Glucose CH2OH
phenylhydrazone
D-Glucosezone

O
||
133. It has four functional groups, — NH 2 , —CO2 H, — C— NH—, and — C— O — CH3 .
||
O
On hydrolysis it produces.
O
C 6 H5
H2N OH H2N

O OH O OH
134. Benzyl amine dissolves in dil HCl at room temp.

C6H5CH2NH2 + HCl  25ºC
 C6H5CH2 N H3Cl
135. Conceptual
136. If the 1, 2 diol is attached to a ring, formation of the cyclic acetals occurs only
when the vicinal hydroxyl groups are cis to each other.
137. Conceptual
138. Amount of taken =

Amount of neutralised by NaOH =

Amount of neutralised by ammonia = 40 32 = 8 meq

1000 meq of

Page No - 32 -
 8 meq of

% by wt of nitrogen = =
139. In the acidic medium the Zwitter ion converts into
+
NH3 CH CO2H

+
NH3 CH - + +
COO + H NH3 CH COOH
R
R
140 Conceptual
141. Conceptual
142. x 150.7 0   100  x   52.80   100  80.2
 x  28%
143. Teflon, polystyrene and PVC are formed by addition polymerization
144. SOL:

145. solution : c
NH 2  CH 2  COOH
146. solution : c
Conceptual
147. solution: a
AgNO2
P   AgCl  ( ppt )

148. solution : d
NaOI
+ve iodoform
CH 3  CHO
+ve test
Fehling solution

Page No - 33 -
 NaOI
-ve iodoform
Ph  CHO
-ve test
Fehling solution
149 SOLUTION : a
Conceptual
150. SOLUTION : c
NH2
HgSO NH 3  HCN
HC  CH 
H SO  CH 3  CH 
4
H O
 CH 3  CH  COOH
2 4 3

151. SOLUTION : d
Conceptual
152. SOLUTION : d
CH 2  CH  CN is undergo polymerization to form Orlan
153 SOLUTION : d
In Lactose, Glucose have hemiacetal group

154. Compounds containing C,S & N gives blood red colour in Lassaigne’s test
 y
155. C x Hy(g )   x   O2  xCO2g   y /2 H2O   
 4  g 
Initial volume 5 30 0 0
 y
Final volume 0 30   x   5 5x 0
 4
Volume of CO 2 absorbed = 10 ml
Volume of O 2 absorbed = 15 ml
5x  10 , x  2
 y
30   x   5  15, y  4 formula  C2 H 4
 4
156. Conceptual
157. Aldopentoses do not under go fermentation.
158. Fact
159. D
160. (A)
Buna-S is a copolymer of butadiene and styrene while all the other are
homopolymers.
161. (a) Explain :
Let the fraction of -form
Fraction of form

Page No - 34 -
 form
form
162. conceptual
163. conceptual
164. Test of nitroalkane having 2 0 carbon

Page No - 35 -