1. A container is divided into two equal compartments (Fig. 5.8). One contains 3.

0 mol
H2(g) at 25°C; the other contains 1.0 mol N2(g) at 25°C. Calculate the Gibbs energy
of mixing when the partition is removed. Assume perfect behaviour.

A.) 7.9 KJ
B.) -7.9 KJ
C.) 6.9 KJ
D.) -6.9 KJ

2. The vapour pressure of 0.500 M KNO3(aq) at 100°C is 99.95 kPa, so the activity of
water in the solution at this temperature is

A.) 0.9864 kPa

B.) 1.0635 kPa
C.) 0.0975 kPa
D.) 1.9864 kPa
3. The addition of 5.00 g of a compound to 250 g of naphthalene lowered the freezing
point of the solvent by 0.780 K. Calculate the molar mass of the compound.

A.) 158 g mol-1

B.) 168 g mol-1
C.) 178 g mol-1
D.) 180 g mol-1

4. The partial molar volumes of two liquids A and B in a mixture in which the mole
fraction of A is 0.3713 are 188.2 cm3 mol−1 and 176.14 cm3 mol−1, respectively.
The molar masses of A and B are 241.1 g mol−1 and 198.2 g mol−1. What is the
volume of a solution of mass 1.000 kg?

A.) 843.5 cm-3

B.) 833.0 cm-3
C.) 830.5 cm-3
D.) 828.8 cm-3

5. The osmotic pressure of an aqueous solution at 288 K is 99.0 kPa. Calculate the
freezing point of the solution.

A.) -0.097 °C
B.) -0.077 °C
C.) -0.055 °C
D.) 0 °C
6. Calculate the Gibbs energy of mixing when 1.00 mol C6H14 (hexane) is mixed with
1.00 mol C7H16 (heptane) at 298 K; treat the solution as ideal.

A.) 3.57 kJ
B.) -4.07 kJ
C.) -3.43 kJ
D.) 5.05 kJ