Practice

Questions
Atomic Structure
Topics Covered:

1. Introduction
2. Shape Of Orbitals
3. Calculation Of No. Of Nodes
4. Electronic Configuration
5. Schrodinger Wave Equation
 6. Probability Distribution Curves

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Question Number: 1

Wave function of an orbital is plotted against the distance

from nucleus. The graphical representation is of :

(A) 1s

(B) 2s

(C) 3s

(D) 2p

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 Question Number: 2

Among the following represetations of excited states of

atoms which is impossible?

(A) 1s1 2s1

2 3 1
(B) [Ne]3s 3p 4s
2 2 4 2
(C) 1s 2s 2p 3s
2 6 3 2
(D) [Ne]3s 3p 4s 3d
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 Question Number: 3

Which of the following d orbitals has diagonal nodal planes?

(A) dx2 − y2

(B) dxz

(C) dxy

(D) dyz

CORRECT ANSWER: A

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 Question Number: 4

Which orbital has only positive value of wave function at all

distances from the nucleus :

(A) 1s

(B) 2s

(C) 3p

(D) 3d

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Question Number: 5

Maximum number of nodes are present in :

(A) 5s

(B) 5p

(C) 5d

(D) All have same number of nodes

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 Question Number: 6

The variation of radial probability density R2 (r) as a function

of distance r of the electron from the nucleus for 3p orbital:

(A)

(B)

(C)

(D)

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 Question Number: 7

The subshell that rises after f subshell is called g subshell

What is the total number of orbitals in the shell in which the g
subshell first occur?

(A) 9

(B) 16

(C) 25

(D) 36

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 Question Number: 8

Consider the following six electronic configurations

(remaining inner orbitals are completely filled) and mark the
incorrect option.

(A) Stability order : II gt I gt IV gt III

(B) Order of spin multiplicity : IV gt III = I gtII

(C) V does not violate all the three rule of electronic

configuration

(D) If IV represents A than A + when kept near a maget,

actsas paramagnetic substance.

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 Question Number: 9

For an electron, with n=3 has only one radial node.

The orbital angular momentum of the electron will be :

(A) 0
h
(B) √6
2π
h
(C) √2
2π
3
(D) 3( )
2π

CORRECT ANSWER: C

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 Question Number: 10

Which orbital is represented by the complete wave function ,

Ψ420 ?

(A) 4s

(B) 4p

(C) 4d

(D) 4f

CORRECT ANSWER: C

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