P Z w Tc Pc Zc Vc T Pr Tr

10 0.985 0.224 304.2 73.83 0.274 94 423.15 0.135446 1.391026

20 0.97 0.224 304.2 73.83 0.274 94 423.15 0.270893 1.391026
40 0.942 0.224 304.2 73.83 0.274 94 423.15 0.541785 1.391026
60 0.913 0.224 304.2 73.83 0.274 94 423.15 0.812678 1.391026
80 0.885 0.224 304.2 73.83 0.274 94 423.15 1.08357 1.391026
300
100 0.869 0.224 304.2 73.83 0.274 94 423.15 1.354463 1.391026
1.1
200 0.765 0.224 304.2 73.83 0.274 94 423.15 2.708926 1.391026
250
300 1 0.762 0.224 304.2 73.83 0.274 94 423.15 4.063389 1.391026
400 0.824 0.224 304.2 73.83 0.274 94 423.15 5.417852 1.391026
200
500 0.9 0.91 0.224 304.2 73.83 0.274 94 423.15 6.772315 1.391026

f ( Bar )
0.8 150
Փ

0.7
P O 100

0.6 10 0.986041
20 0.972277 50
0.5 40 0.945322
60 0.919114 0
0.4 80 0.893633 0 100 200 300 400
0 100 100 0.868859
200 300 400 500 600
P ( Bar )
200 0.754916P ( Bar )
300 0.655915
400 0.569898
500 0.495161

a)
ij T w ij Tc ij Vcij Zcij Pcij Trij B0 B1
11 423.15 0.087 282.3 131 0.281 50.4 1.498937 -0.13783 0.107578
22 423.15 0.14 365.6 188.4 0.289 46.65 1.157412 -0.25099 0.045915
12 423.15 0.1135 321.2614 157.9661 0.285 48.18917 1.317152 -0.18858 0.084917

q12 20.81488

g1 0.957416
g2 0.874844
f1 10.05287
f2 17.05946

b)
P Pcij Pr Trij B0 B1 w ij g f
30 50.4 0.595238 1.498937 -0.13783 0.107578 0.087 0.950263 9.977759
30 46.65 0.643087 1.157412 -0.25099 0.045915 0.14 0.872944 17.02241

140
³/mol )

120
 140
x2
0 70

V ( cm³/mol )
120
1 85
x1
100
0 12
1 4
80

x1 x2 V V1 V2 x1 V V1 V
0 60
1 70 12 70 0 70 V1 12
0.1 0.9 75.783 11.614 70.024 0.1 75.783 11.614
V2
0.2 0.8
40 81.504 10.912 70.152 0.2 81.504 10.912
0.3 0.7 87.121 9.978 70.468 0.3 87.121 9.978
0.4 0.6
20 92.592 8.896 71.056 0.4 92.592 8.896
0.5 0.5 97.875 7.75 72 0.5 97.875 7.75
0.6 0.40 102.928 6.624 73.384 0.6 102.928 6.624
0.7 0.3 0107.709
0.1 5.6020.3
0.2 75.292
0.4 0.5 0.6 0.7 0.8 0.7
0.9 107.709
1 5.602
0.8 0.2 112.176 4.768 77.808 x1 0.8 112.176 4.768
0.9 0.1 116.287 4.206 81.016 0.9 116.287 4.206
1 0 120 4 85 1 120 4

TC B
50
75
100
 B0 B1 O f
-0.16587 0.095995 0.986041 9.860409
-0.16587 0.095995 0.972277 19.44553
-0.16587 0.095995 0.945322 37.81287
-0.16587 0.095995 0.919114 55.14686
-0.16587 0.095995 0.893633 71.49067
-0.16587 0.095995 0.868859 86.88589
-0.16587 0.095995 0.754916 150.9831
-0.16587 0.095995 0.655915 196.7746
-0.16587 0.095995 0.569898 227.9591
-0.16587 0.095995 0.495161 247.5804

P f
10 9.860409
20 19.44553
40 37.81287
60 55.14686
200 300 400 500 600 80 71.49067
P ( Bar ) 100 86.88589
200 150.9831
300 196.7746
400 227.9591
500 247.5804

Bij
-59.8268
-159.349
-99.1807
V2
70
70.024
70.152
70.468
71.056
72
73.384
75.292
77.808
81.016
85