~~ (CHEMICAL AND PHYSICAL PRINCIPLES 1, The, ion, shat would be igo-electronic with the noble gas Xenon is Qré ae cc. Mgt? ak 2. No-Ewo elements in the same atom can have the same set of quantum is a statement of ‘a. Hund’s Rule of Multiplicity b. Dalton''s Atomic Theory c. Heisenberg’s Uncertainty Principle d. Pauli's Exclusion Principle 3. Defines as acid as a compound that dissolves in water to produce the H+ ions a, Arthenius ce. Lewis b. Bronsted-Lowry d. Lowry 4, The electrons of metals are free to move ina solid. This explains why ‘a. metals are unstable b. metals can easily be melted ¢: metals have high reflectivity a. metals have high conductivity 5. Buffer solution resists changes in acidity. If an acid is added to a buffer solution, the remains the same a. pH b. concentration ©. jonization constant 4. hydrolysis constant 6. In silver plating, the anode is a. copper d. graphite b. the object to be plated e. silver ¢. platinum 7, Brass is an alloy of ‘. aluminum and nickel c. copper and zinc b. lead and tin 4. copper and tin 8. The first step in precipitation is the formulation of ‘a. Nuclei c. Seeds b. supersaturated solution 4. Crystals 9. which will dissolve faster in coffee? a. lump sugar in hot coffee b. granular sugar in hot coffee 1 granular sugar in cold coffee a. lunp sugar in cold coffee 10, the most important cosponent of pitch blend a. Lead ¢. Uranium b. Mercury a. Gold 11, A catalyst is a substance that | increases the rate of reaction b. is independent on the concentration of the reactants ¢. has no effect on the activation energy @. is recovered chemically unchanged at the end of the reaction | 12. Which of the following are most alike? 2. compound and suspension . mixture and compound ce. foam and solution 4. solueson and compound fe, emulsion and colloid 13, an element having three valence of electrons and four main energy levels may belong to ‘a. Family III-A c. Family VII-A | b. Period 3 d. Family I-A. | 14. The mass contribution of an electron in an atom is 2. 1/1,837 that of the proton b. equal to that of a proton c. equal to that of @ neutron @ not known 15. The percentage abundance of Xe in the atmosphere (% Volume) is a. lax 10" ©. 1.32 4 b. 8.0 x 10% J. 93016. ce 18. 20. a 22. 23. 26 25. 26. 20. 28. 29. 30. a. a2. Discovered water by exploding H. + 0; a. Lewis c. Scavendish b. Lavoisier a. Usey A solution of @ weak acid and its salt which resists appreciable changes in pH value is called normal solution colloidal dispersion neutral solution buffer solution molar solution The type in intermolecular force of attraction which exists between molecules of oxygen, nitrogen of methane is 2. dipole-dipole ©. Hebonding b. London d. Interionic Which of the following is insoluble in ,07 a. aluninun sodium silicate b. aluninun sulfate ¢. ammonium oxalate i. ammonium bromide Arrange Ca, Be and Mg according to increasing electron affinity a. Ngccacbe fc. Bectigeca b. cacbecty d. cactigcBe A 620 mg ideal gas occupies 175 cc at STP. What is the molecular weight of the ideal gas? 2.79 b. 80 c. 60 d. 85 Gave the name “oxygen” . a. Priestly c. Lavoisier . Scheele d. Scavendish Mixing 10 ml of a 2M HCL solution with 20m! of a 1M HCl solution will result in @ solution whose molarity is a. 1,33 b. 1.50 1.65 a. 1.75 one of the following is not classified as native elenent ‘2. diamond cc. graphite b. pyrite d. quick silver The basic conclusion drawn from experimental studies with X-rays is that the atomic nunber is equal to the positive charge in the nucleus. These studies are carried out by 3. Rutherford c. Roentgen b. Noseley 4. tendeleev one gnole of a species is that weight of the species equal to the a. molecular weight fc. atomic number b. atomic mass. 4. Isotopic weight Along a row in the periodic table elements have the same ‘a. energy level ce. size b. electronegativity d. ionization energy Saltwater boils at ‘2. slightly higher than 100% ¢. slightly lower than 100% b. 100°C 4. 50% Measurement of the wave lengths of emitter radiation is involved in ‘3. ultraviolet spectrophotometry b. spectroscopy ¢. infrared spectrophotonetry 4. Nuclear Magnetic Resonance ‘the strongest attong the chemical bond is + lonic bond "covalent bond | coordinate covalent bond | metallic bond + hydrogen bond Waxes are {Fatty acids alcohol esters d. Salts of fatty acids ‘The Lucas test is used to determine the types of + alcohols. d. amino acids 2 amines fe. phenols > ‘a. Triglyceride ¢. Alkyl sulfonates >. Ch » ce. acids33. Natural rubber is a polymer of a. ethylene ‘ « chloroprene B! propene @: isoprene c. isobutene 34. No carbonyl group $s found in: a. ether c. ketone BI aldehyde @! Carboxylic acta 35. Nylon is a copolymer of ‘a. urea formaldehyde b. phenal formaldehyde c. hexamethylene and adipic acid 4d. styrene and adipic acid 36. Which of the following is not an aliphatic hydrocarbon? a. n-octane c. propylene b. n-tridecane d. toluene 37. An unsaturated fatty acid with one double bond in the chain: a. Stearic c. linoleic b. linolenic d. oleic 38. Following Markownikoff’s Rule, when 1-butene is reacted with HOCL, the main product is: ‘a. n-butane c. 2-butanol b. 1-chloro-2-butanel d. 2-chloro-3-butano 39. The strongest acid among the following is a. p-nitro phenol J, pechlerophenol b, menitro phenol fe. m-chlorophenol 1 o-nitrophenol 40, 2.24 g of alkene A add 3.2g of bromine. The molecular formula of A is: a. Chale b. Coil c. Cals de Cathe 42. Conversion of poly-unsaturated vegetable oils to solid fats can be achieved by a. hydrooxylation b. catalytic hydrogenation cc. hydrohalogenation ‘d. halogenation 42, This one is classified as an aromatic compound: fa. acetic acid fe. eltric acid b. carbolic acid 4d. lactic acid 43. when CahcH,CH, is oxidized by excess Kmn0, in acid, the main product is a. CelleCH,COOH d. Phtalic acid b. ehenol ©. Benzolc acid 44, R0S0,0na is a general formula for: a. soap c. synthetic detergent b. wax a. fatty acid salt 45, Which of the following compounds is incorrectly named: ‘a. p-chloroaniline di. ethyl benzene b. S-methy) pentane fe. 2-ethyl butane c. methyl benzene 46. The chemical formula of pyruvic acid {9 ‘a. OHC COOH d. cHscococt, bs cHscooH fe. OHCCHO 1 CH,cOCooH 47, the following aze polymers, except: ‘a. natural rubber a. Nylon b. protein fe. Dynanite fc. Pvc ‘carbonyl compound is 40. n carpeny’ pon and one oxygen bounded by a double bond g: one caxbon ong one oxygen bounded by a single Bond B. One carpon and one O7/Gen pounded by one single and one double bond Fe cP Gnd two onyoen Bounded by two, double bonds Cee ate ae ee a crigiyceride is 200. The average WW of the eriglyceride Le: 2. 200 b. 280 e. 600 4. 940———— LrUr—r—“—OO———.._C—Cs=sia iszisCUCristizsés#itCCN Properties of Teflon are due to 7 4. the strength of the carbon-carbon bond b. the strength of the carbon-hydrogen bond €. the strong carbon-fluorine bond d. high cost A 0-1 M Ca(OH)2 solution can also be labeled as: 2. 0.1 molal c. O.1N b. 0.2 N d. ow ote raemmams Of AL ace added to one Liter of 3N CuSO, the number of grans OF Gu Shat will be displaced is (atomic weights : Cu= 64; Al-27), a. 32 d. 128 b. 64 2. 96 ©. 132 $2. The determination of lead ions by reduction to metallic lead and weighing 2. an electronetric method b. an electrodeposition method €. a precipitation method d. @ potentimetric method 53. What is the color of nickel chloride? a. white c. yellow bl red 7 4. green 54. Ksp values are valid ®. for all sates B. only'for slightly soluble compounds G1 when deternines tinder supersaturated conditions d. only when measured at 25°C 55. the ph value at the equivalence point when titrating strong base 13 a. at exactly 7 ! greater than 7 ©. fess than 7 4. neutral 56. nad, ia oxidized by kan0,. ‘a Fedicing agent is: a 0.0508 . 0.01978 3! of03987 & oloaaie 57, Im'a general analysis wi is tested advance because ®. Ny cannot be present in acid mediun BI Several ammondun containing rengents are added during analysis @. ie is the standard procedure @. Tt wiii'nane the solution basis 58. rerrie ferrocyanide is a. Indigo blve b! prossian blue @) Rurnbull’s blue a. Cobalt blue 59. which Teagent ili dissolve 2n(Oll), but not Ni (0M) :2 eich e. Bekos Bo a, Rao 60. A golution of cation gives a crinson red ‘flame. This flane test is a Contkimtory test fort a b. K? d. ca’ 61. which of the following should be considered in the choice of an indicator: 2. ph range BL Bh at equivalence pe. olor of indicator 62. wining tom ‘of #24 HEL solution with 20 ml of aH HCL solution vill result “its peas e. 1.65 a. 1.75 @ weak acid against a ‘The millequivalent weight Of As:03 {MW=197.84) as63. 6a 65. 66. 67. Which of these gravimetric factor is not correct? a. Ca0/Cac.o, bl 4Fe0/Fe.0, cc. 28g0/tg:>.0, d. Fes,/28a50, What weight in grams of Ca(OH); is chemically equivalent to 0.59 of Ca0? 2. 0.3303 a. 0.7569 b. 0.3785 fe. 1.514 2 0.6505 A colorless solution was treated with HCl with no change in appearance. Addition of NH) formed a permanent white is present a. Zn" b. Bit a * tgs” In the systematic cation analysis, after the separation of the acid sulfide Group, the PO" if found present must be eliminated because: a. it will be destroyed in the latter part of the analysis b. it reacts with a number of remaining cations in @ basic med c. it changes the acidity of the solution d. it destroys the effect of the buffered solution Analytical methods taking 1-10 mg. Size samples for analysis maybe referred to as 2. semi-micro methods b. micro methods c. macro methods a. ultra micro methods 68. Which of the following should not be used for high temperature ignition? 6 ne 2. 73. m, 15. 16. a. porcelain crucible b. Munroe crucible ©. Gooch crucible d. Sintered glass crucible e. Platinum crucible The “Hanging Drop Test” is used to identity a. Mad, b. 005” NO; a. C057 The Cv of polyatomic substance Like NO;, Clk, and Ni a. 4-8 cal/moltc b. slightly greater than 6 c. less than ® d. about & A soap bubble of a 15 cm radius is formed by blowing through a 2.5 cm diameter wire loop. Assume that all soap film goes into making bubbles. The Surface tension of the film is 0.02N/m. Find the total work require to make a bubble. 14x10 Nem 2 2125x107 wom 1132x107 Nom 2 2lLox1a? wom Which law is the basis for the manufacture of thermoneter? a. Boyle's law b. Zeroth law of thermodynanics c. Raoult’s Law 4d. Carnot’s principle ‘The amount of heat absorbed when CO? gas reacts with a solid cao to form solid CaCO3 is measured in a bomb calorimeter the data obtained gives direct measure of a. aU ©. AH b. vaP a. cp When the system is in equilibrium , the change in the free energy is b. greater than zero eo1 d. less than zero A Carnot cycle heat engine operating between 1540°F and 440° has an efficiency of approximately a. 35% b. 82% c. 558 a. 258net energy available to a system is given by a. entropy ©. enthalpy D. free energy . none of these Liquid water at ODC and atmospheric pressure has a density of 1.0q/cc. ‘AT the sane conditions, ice has a density of 0.817 g/cc. How much work is done in KJ at these conditions by 1.0 kq of ice as it melts to liquid water ‘a. 0.00917 ©. -0.00917 b. 0.0912 4. -0.0912 ‘The turbine in a hydraulic plant is fed by water falling from a height of 30 m. Assuming 95t efficiency of converting potential energy to electrical eneray and 10% loss of resulting power in transmission, how many MT of water per hr are needed to keep a 100W light bulb burning? a. 1.43 b. 1.29 c. 1.63 4. 1.75 Calculate the change in entropy when 100 grans of ice at 0°C is converted to steam a. 645.23 eu fe. 205.28 eu b. 302.34 eu 4d. 342.25 eu 81. Calculate the change in molar Gibb’s energy of liquid H.0 treated as incompressible fluid when pressure is increased from 1.0 bar to 2.0 bar at 238K. a. 41.82 9 ce. H1.e2x10" J b. 1.82 J d. -Lle2x10" 5 82. Heat values of entropy are associated with a. high possibility of a state b. high randomness of the state ¢. both a and b 4. none of these 83. The heat content of the system is called 78 79. 20. a. a sensible heat c. heat capacity b. specific heat d. enthalpy 84. ‘The study of the interrelation of the various forms of energy in a ‘system is called a. physical chemistry c. physics b. chemistry d. thermodynamics 8s. ‘A measure of the total energy not available for useful work is the a. entropy c. enthalpy b. free energy d. none of these 86 [A 70% NaOH Liquor at 160°F with a heat content of 325 Btu/Ib is diluted with 208 NaOH Liquor at 80°F with a heat content of 40 Btu/1b to give a final solution containing 40% NaOH ( heat content is 94 Dtu/Ib ). For every 100 1b Of product, how much heat must be removed to maintain a final product temperature of 100°F? ‘a. 6000 Btu ce. -11700 atu bl 20100 Btu 4. -7500 Btu 87. The densities of liquid and solid mercury are 13.7 and 14.19 g/cc respectively at a melting point of ~38.87°C. The heat of fusion of Hig is 566 Gal/g-atom. The change in melting point per atmosphere change in pressure is a. 0.505 K ¢. 0.013 K b. 0.0051 K a. 0.231 « 88. The difference hetween the heat of combustion of methane at constant pressure and at constant volume at 27° when liquid water forms is ‘a. 1192.2 cal e. 1257.44 cal b. -2314.5 cal 1257.44 cal 88. The more stable aystem with regard to AS are systems that have miniman AS zero AS maximum SS none of these 90, A newly designed refrigerator has a capacity of 3140 watt and an input rating to 735 watts. The coefficient of performance of the refrigerator is a. 5.67 bl a.27 ©. 3.26 as aady 91. The normal boiling point of chloroform, CHCl), is 334K, pressure is 0.824 atm, What is the temperature range? 3. 29.4 KJ/mol b. 27.5 Ku/mol its vapor enthalpy of chloroform fro this c. 19.65 Ku/nol d. 30.61 KI/nol When the potential of 110 volts de is applied to the terminals of an electric lamp, a current of 2 amperes is found to flow. What is the resistance of the lanp? ‘a. 62 ohms b. 55 ohns 92 c. 32 ohms d. 58 ohms How long would it take a current 1 ampere to reduce completely 80 cc of 0.1 molal Fe;(S0), to FeSO? a. 25.73 min b. 22.65 min 93. ce. 31.26 min di 19.69 min 94. A constant direct current flows through an iodine coulometer for a period of 2 hours. At the end of this time, it is found that the couloneter contains 0.0020 equivalent of liberated 1,. what was the current passing thorough the coulometer? a. 0.048 ampere c. 0.027 ampere b. 0.058 ampere d. 0.034 ampere 98. As a solid changes to a liquid, all of the following occur except a. molecules becone more disordered b. kinetic energy of molecules decreases c. intermolecular forces become separated d. molecules becone further separated 96. Absolute zero maybe regarded as that T at which a gas cease a. all gases become Liquids b. all substances are solids ©. molecular motion increases d. water freezes 97. Ethyl alcohol is to be used in an autonobile carburetor that is adjusted to give a2 9 to 10 air-fuel ratio ( mass ratio}. If the temperature in the Manifold is 0dF and the pressure is atmospheric, what percentage of the alcohol will be evaporated assuming the equilibrium between vapor and liquid is reached? a. 558 4. 908 b. 158 c. 658 98. At what temperature will the velocity of CO: molecules equel the velocity of oxygen molecules at 0°C a. 102°C e. 132" b. 632°C gd. 125% 99, Suppose you are given a gaseous compound for which the formula is C2 at ‘the same tenperature and pressure at which oxygen weighs 4.8 grams per liter, the unknown gas weighs 8.10 g/L. What is the formula of the compound? a. Cally c. Calle bi Colle «Caio 100.a gas tends to expand indefinitely into a vacuum or into another gas. This ability is referred as ‘a. viscosity c. compressibility b. turbulence 4d. diffusion 101. If a given gas nas a compressibility factor, 2>1, this means that a. attractive forces b. repulsive forces €. no force of attraction Gi. exist between the molecules of gases 102. The vapor pressure of a liquid ‘a. always increases with temperature b. always decreases with temperature €. is independent of temperature @! increases only up to boiling point 103-As the atmospheric pressure decreases, the boiling point of a liquid ‘@. cannot be determined b. is not affectedggg ae 4 c. increases d. decreases 104. The direction of electron flow is from a. from anode to cathode b. from cathode to anode c. either way 105.PC1, (g) dissociates to PCL, (g) and Cl: (g) when heated at 250°C and 1 atm If the density of the gas mixture at equilibrium is 4.4 g/L, the fraction of PCL, (g) dissociated is a. 0.103 b. 0.328 c. 0.725 . 0.209 106. An ideal gas is made up of molecules that have these properties except a. Are points in space in tine b. have mass and velocity ©. attract or repel each other on the wall of the container d. collide with the walls of the container without loss of energy 107.Which of these 0.1M solution will give the highest boiling at 1 atm 2. table salt solution ‘c. barium chloride b. sugar solution a. potassiun chloride 108.What term is used to define the phenomena of emission of light in a ‘chemical reaction 1. photosensitisation ! chemical luninescence ©! photosensitisation and chemical luminescence @. hone of these 109.thE vapor pressure of all the Liquids a. is the sane at 100% Bi is the sane at their frezzing pint ©! increases with the volume of Liquid separated 4: increases with tenperature 110,2f ethanol are mixed 50/50 by eight at 60%, and the solution assumed deat, the composition of the vapor above the solution is 3.268 ethanoi, 72" methane? BI 728 ethanol, 268 methanol €! 59 ethanol, 418 methanot 4. 418 ethanol, 598 methanol 111.all of the following conclusion of the kinetic theory of gases except a. 2 derivation of the Van der Waele equation Bi derivation of Boyle's and Charlie's Law C1 relation of average kinetic energy Of gases to temperature a! Graham's law of diffusion 112.the freezing point of a substance is always loser than its a melting posne ‘specific heat Br Bolling posne 4! heat of vaporization 113. one ‘colligative property of solutions is its “freezing point depression. Which observation will show that the solute 1s an electrolyte? at/m ‘ar is aoe constant Gr fs ese than KE Bis not Ke a0 43 "Geeater chan Kr 114.coliigative properties depend upon @. the chemical properties of the solute Bi the physical properties of the solute C1 the chemical properties of solvent SI the number of solute particles present in the solution Lis. adi’ ofthe ellowing factor increases the strengeh of Van der Waals forces between molecules except By an Soi decane in the molecular weight of the molecules 2: ingrease In the nunber of atone in the molecules 8: ineresse in tne number of electrons in the molecules 4G. increase in the onic strength of the molecule tierce ‘2 "themtcet veaction ina state of equilibriua, a decrease in Cenperature will =. favor reaction that is exothermic favors reaction that is endothernic have no effect on the system Merease the equslibrium constant of che systemwhich law governs the behavior of liguids in Liquids? a. Henry's Law b. Le-Chatelier’s principle c. Raoult’s Law 4. Nernst Distribution coefficient A substance above its critical T fa. is gas at any P b. is boiling ¢. can be liquefied only by application of P a. is ready to explode 119.8 0.2 mol aqueous solution of KCI freezes at -0.690°C, The osmotic F at OC a. 9.8 atm c. 8.2 atm b. 16.3 atm @. 10.8 atm 120-All of the following are characteristics of ideal gases except ‘a, absence of intermolecular forces Bl non ideal gases may exhibit ideal gases at high pressure and low temperature ¢. the molecules occupy no space d. all of the above are correct What volume of water should be added to 300 ml of a 0.6 M solution to a2. ‘make the molarity to 0.200? Assume that the volume is additives. ‘a. 300 ml . 300 ml b. 100 mi d. 600 mt 122.Hiydrocarbons that contain one or more carbon triple bonds. a. alkynes c. alkenes >. alkyl a. alkanes 123.All these about redox are correct except 2. The total number of the electon lost by the element reduced is equal to the total number of electrons gained by the element oxidized b. The reducing agent is oxidized . Reduction is loss is in positive valence 4, Oxidation is loss of electrons 124.1F the infrared radiation has @ wavelength of 3.5 microns, wave number in om"? what will be the a. 3,000 cn cc. 2900 en b. 2,500 cn 4. 2700 em 125. The compressibility factor for every gas as its pressure approaches zero is a. 0 c.2 b. -1 al 126.Choose the correct statement about a family of elements in the periodic table a, The atoms of al elenents in a family have the same nuaber of shells of electrons 'p. All elements in a family have the same physical state @, all elements ina family have the sane chemical reactivity GL fhe atoms of all elements in a family have the sane number of valence electrons, 127; All of the following are colligative properties except ‘a. solubility BL vapor pressure lowering ¢. freezing point depression @. boiling point elevation system undergoes an irreversible cycle. The entropy of the universe remains the sane bl decreases cannot be defined 129.n solution used principally to contzol the pi value of a solution to a point where selective precipitation can be nade 2. acid solution €. basic solution bl neutral solution 4. buffered solution 128.130.Doubling the concentration of the substances taking part in a chemical reaction will: a. double the rate of the reaction bl have no effect on the rate of the reaction €. have an effect which must be determined by experiments a. quadruples y experiment 13i.Mothyl Chloride is represented by a. CCl, aie bl cach, a: cel, 132. he pil of an aqueous solution which has an aialytical concentration of 1 x ho” Mis a. 6.00 ©. 6.79 b._ 7.00 a) 6169 193," solution containing 1gnol of salt per cuble decineter of solution at °C or Teeé216 g of potassiun chloride in 10009 of water both weighed in a. a strong electrolyte ©. an aqueous solution Dla supersaturated solution @! a'demal solution 134.Which of the following statement is incorrect? a. The mole fraction is equal to the weight fraction b. None of these €. The mole fraction is equal to the volume fraction d. The mole fraction is equal to the pressure fraction 135. What weight of ice could be melted at Odeg C by the heat liberated by condensing 100g steam at 100 deg C to liquid? Heat of vaporization = $40 cal/g Heat of fusion - 80 cal/g a. -675g c. 660 9 b. 6759 d. -660 5 136,Caleulate the enthalpy of decomposition of calcium carbonate into calcium oxide and carbon dioxide a. 40.1 keal cc. -42.6 keal 242.6 keal d. 43.6 keal 137. The nunber that express the oxidation state of atom of an element or groups ‘of atom is called the a. indicator c. displacement factor b. valence 4. electrolyte 138 All fats are a. acids cc. ketones b. unsaturated a. esters 139.aluminun chloride is found to exist as a ‘a. monomer fc. trimet b. drier a. tetramer 140-Al1 these about solutions are correct except: 2. the quantity of solute is not dissolved in saturated solution Bl the uantity of solute dissolved in a saturated solution give its solubility of the solute as a certain temperature ©. an ionic solute dissolves in water through salvation brought about by columbic attraction between the ions and water So the boiling of solution in water rise by 1.86 deg C molal increase in the concentration of the solution La1-an uneven sharing of electrons between two atoms indicate a. bonding €. electronegativity b. coupling a. polarity L2.bagasse is a by-product in the manufacture of raw sugar. This product however can still be valuably used as suitable aubstitute for bunker fuel all of these Taw material for the manufacture of plywood substitute Faw material for paper substitute making 143:k chemical engineer wants to make chlorine from molten sodiun chloride. If he uses a current of one ampere for 5 min, how many grams could be roduced? aol g c. 0.09 9 b 015 g d. 0.14 3Vee SS 144. NMR (proton) spectum of ethanol contain groups of a 2 c.4 b. 5 3 145.Calculate the neutralization equivalent for a 0.2 9 of an organic acid required 100 ml of 0.12 NaOH for neutralization a. prbenzoic acid c. penitrobenzene acid bl benzoic acia d. prtoluic acid 146.The radiation that produces the greatest number of ions as it passes through matter is a. omega, c. beta b. alpha d. ganna 147.Which of the following is an extensive property? ‘a. molar volume c. beta b. enthalpy d. ganna 148.Carboxylic organic compounds contains rings made up solely of atoms known a. carbon c. oxygen b. nitrogen 4d. hydrogen 149. Assume the following, the ionization potential of C3 = 3.09 eV, h = 6.63 x 10-34/sec and C3 metal is sensitive to real light of 700 nm, What number of electrons that can be removed from metallic cesium with the energy required to remove one electron from an isolated cesium atom a 2 amas) b. 13 a4 150.Which solute is expected to be the most stable in water? a. ammonia c. dodine b. hydrogen sulfide di methane 151.A chemical process used in manufacturing caustic soda a. Le Blanc Method c. Haber-Bosh Method b. Electrolysis d. Solvary process 152.Hypochlorite are strong agents in alkaline solution ‘a. catalyzing c. reducing bl neutralizing a. oxidizing 153. The enthropy change for any closed system which undergoes a cycling process a. must be negative may be positive or negative but bl must be zero not 2er0 d. must be positive 154.The process of dissolving hydrogen sulfide gas in water is known as a. endothermic c. exothermic b. hydrogenation 4. sulfonation 155.Which of the enumerated solvent is aprotic ‘a. dimethyl formanide ce. citric acid b. ethylene alcohol d. hydrochloric acid 1s6.the temperature of the calorimeter and contents is raised to 5.00 deg ¢ when 10000 kJ of electric energy is added to a calorimeter containing 400 g of Water. what is the water equivalent of the calorimeter? a. 2.39 keal cc. 2.39 kcal b. 2.01 kcal 4. 2.01 keal 157, The Lonic strength of 0.1 solution of ferric sulfate is a. 0.75 ce. 0.50 bl 1.00 4. 0.25 158.Styrene is 3. benzoyl chloride c. vinyl benzene b. mesitylene 4. benzoyl benzene 159,The ‘phosphorus in a sample of phosphate rock weighing 0.5428 g is precipitated as MgNH:P0,.61,0 and ignited to Mg.P:0;. If the ignited precipitate Reighs 0.2234 9 calculate the percentage of P:0: in the sanple a. 25.95% c. 27.118 bl 26.918 d. 26.25% 160,Choose ‘the organic compound that will not react with an aqueous solution of the ammonia silver nitrate: a. acetylene ce. 1-butyne b. 2-butyne d. none of these 1e1.what is the law that governs ideal gas-liquid solutions a. Raoult’s Law bl Henry’s Lawc. Nerrist Distribution Law a. law of Hess 162.In alcohol fermentation by yeast, this microorganism furnishes an organic catalyst or enzyme which affects this hydrolysis ‘a. bacterease c. lactase b. 2ymase Gd. invertase 163.At standard temperature and pressure, a gas occupies 0.213 liters. How many moles are there in this sample of gas? a. 0.0089 mole ce. none of these b. 0.0890 mole d. 0.0095 mole 164.1£ common salt NaCl is dissolved in water, which of the following statements is true about the behavior of the solution relative to the behavior of pure water? a. boiling point is lowered c. freezing point is decreased b. melting point increases d. none of these is true 165. The osterified product of n-propanone acid and methane is: a. none of these ¢. methy propanoate b. n-propanoxy methane d. ethyl acetate 166.Complete the following equation CH,CHBr + 2Li a. CHCHLE + Libr c. CHCHBreLi + Li b. CHCHLIS, + Li d. CHCHALi: + Be 167.L is a non-volatile, non-electrolytic liquid. A solid S, is added to L to form a solution that just boils at 1 atmospheric pressure. The vapor pressure Of pure L is 850 torr. What is the mole fraction of liquid L in the solution? a. 85.78 b. 95.30 c. 89.48 d. 79.4% 168.The behavior of the plastics that can be simulated using physical models such as Maxwell and Kelvin Models 2. elasticity c. deformation b. wear resistance d. viscoelastic 169.The following 5 expressions describe general energy equation for an open system ‘a. Transfer of energy out of mass flow by Accumulation of energy €: Transfer of energy is by mass flow 4. Net energy transfer by work (std Sign concentration) e. Net energy transfer by heat (std Sign concentration) 170.Which combination would represent the general energy equation representing the first law of themodynanics? a.b-=dteteta eb=c-e-c-a bib=d-e-cta db-d+tetreta 171.7he study of the interrelation of the various forms of energy in a system is called ‘a.physical chenistry b. chemistry cc. physics a. thermodynanics 172. The standard for mass measurement ic a. wavelength of kr = 86 b. invariant property of Cs - 133 c. earth's pull 4. a cylinder of platinum-iridium alloy 173. The heat content of the system is called a. sensible heat b. specific heat heat capacity a or b 174.The quantity of heat required to raise the temperature of a unit weight of ‘@ substance 1 degree temperature is called: a. specific heat b. heat capacity a acre 175. During the adiabatic expansion of an ideal gas, work is done ‘and change in internal energy 2. decreases b. increases c. does not change c. sensible heat by the system 176. Which law is the basis for the manufacture of thermoneters? a. Boyle's law ce. Raoule’s baw B. aaroch Law ot a. Carnot's ‘sinciple Thermodynamics '177.8 homogeneously physically dis Uz honesencously physically distinct and mechanically separable portion of a. phase . d. mixture solid ¢. true solution 178. During the adiabatic reversible expansion o 172, uring the saianetio covers f an ideal gas, the amount of than zero d. au be one 0 179." hen a certain gea expands, work is said to be ae done by the gas on’ sts S. done on the ges by the surroundings surrounding b. lost. by the surrounding Erte 189. When the system io in equilibrium, the change in the free eneray S a. zero b. greater than zero eo. d. less than zero 181.The network accomplished by an engine undergoing adiabatic compression is equal to a. au b. a0 ce. -au a. -a9 182. A sample of an ideal gas is allowed to escape reversibly and isothermally into a vacuum. Which statement is correct? a. We0 AUSQ= a positive number biW=pav a "av and is a negative number e.WePaV + OP d.W=9=a0=0 183. ‘The amount of heat absorbed when CO; gas reacts with a solid CaO to form ‘solid Caco, is measured in a bomb calorimeter (at constant volume) the data obtained give a direct measure of a. av b. VAP c. aH d. c 184. Which of the following statements is correct? ‘a. The standard heat of formation of an element is negative b. Since s=aU + PV and can never be equal to aU ©. Q and W are state functions d. Q-W is @ state function 185. ‘Amore stable system with regard to OH are systems that have a. Zero alt ce Maximum Ait b. Minimum oF 4d. None of these 186. A measure of the total energy not available for useful work is the a. entropy D. free eneray cc. enthalpy a._none of these 167. “the more stable system with regard to OS are systems that have a. minimum as b. zero 43 ‘c. maximum 4S d. none of these 188. The net energy available to a system is given by a. entropy b. free energy cc. enthalpy a none of these 189. If acco, then a. the reaction is at equilibrium Bb. a spontaneous reaction is possible €. no reaction is possible G. none of the above 190. ‘High values of entropy are associated with a. high possibility of a state b. high randomness of the state fe. both a and b 4, none of these igi. °A newly designed refrigerator has a capacity of 3140 watt and an input rating of 735 watts. The coefficient of performance of the refrigerator is: a, 5-67 b. 4.27 cc. 3.26 a. aa 192. A carnot cycle heat engine operating between 1540 °F and 440 °F has an efficiency of approximately a. 358 b. 628 d. 258 so193. A heat engine absorbs The “gasoline “hae “OSCINS Neat fron the combustion of gasoline at 2200 *c 11, 200¢a1/gean, she ic gravity of 0.8 and a heat combustion of Calories (at carte (agiNe felects heat at 1200 *C. The maximin work in a. 3.62 n Lak Ue°beained from the combustion of 1 Liter of gasoline is a. tap EE 0" cn 3.78 x 10" 194. A 70% NaOH Liquor ae x 10 ith 200 Met, IGUEE at 160 F with a neat content of 325 Btu/ib is diluted Final soineen, LAguOr at 80 °F with a heat content of 40 BTU/Ib co give a Toone eopution eontaining 40% NaOH {heat content is 94 Btu/ib). For every Product, how much heat must be renoved to maintain a final product temperature of 100 °F? a. 6,000 atu b. 20,100 atu -11,700 Btu Ror ~1, 500 Btu ‘in process requires cooling of a brine solution continuously fron F to 30 °F. The atmospheric tenperature is 80 "F. There is an available Tefrigerator with a power requirement of 40 kW. Can this refrigerator be used if 100 gallons of brine is to be cooled per minute? a. Yes b. no c. can not be determined 196. Superheated steam flows at a steady state through an insulated nozzle with an inlet diameter of 5 cm. At the nozzle entrance, steam P is 700 kPa and T is 300 *C, and the velocity is 30 m/s. At the nozzle exit, the steam temperature and pressure are 233 °C and 350 kPa respectively, the exit diameter of the nozzle is b. 3.26 cm b. 1.62 om ce. 0.38 om d. 2.92 cm 197.1t 1s proposed to warm a collector plate with solar energy. The collected energy is then transferred as heat to a fluid in a heat engine which in ture rejects heat to the atmosphere. If 200 BTU/nr-ft* of energy can be collected nen the plate is operating at 190 °F, estimate the minimum collector area Fequired for a plant producing 1 kW of Useful shaft power. Assume atmospheric temperature of 10 °F. : 2.86.2 ft? b. 92.4 ft? ec. 97.8 ft? a 01.6 fe 198. Eight grams of oxygen gas at 27 °C and 10 atm expands adiabatically and reversible to. final P of 1.0 atm, The work done in the process is a. 82 J) b. 445.7 a. 7523 199, an inventor claimed that he has devised an engine that absorbs 1000 kW of heat from the heat source and discards 700 kW of heat to the heat sink. If the engine operates between 500 K and 200 X, is the inventors claim valid? 195, 198 5 a. Yes b. no c. can not be determined 200. The turbine in a hydroelectric plant is fed by water falling down from a height of 30 m.. Assuming 95 ¥ efficiency of converting potential energy to Bfedtrical energy and 105 loss of resulting power in transmission, how many MT Si water per hour are needed to keep a 100W light bulb burning? 2.1.43 b. 1.29 ec. 1.63 a. 1.75, 201. Liguid water at 0 °C and atmospheric pressure ahs a density of 1.0 g/cc. Ay ihe same conditions, ice has a density of 0.917 g/cc. How much work is done fn ko at these conditions by 1.0 kg of ice as it melts to liquid water? 2.0.0097 b. 0.0812 c. -0.00817 a= 010312 202, 3.0 g-mole of an idle gas at 1.0 atm and 20 °C are heated at constant pressure until the temperature is 80 °C. (Cv = 7.50 + 3.2 x 10°, cal/mol-K). The change in internal energy of the process is 2.5629.16 cal -b. 3425.27 cal © = 3210.50 cal d. 4590.42 cal 203.the difference between the heat of combustion of methane at constant pressure and at constant volume at 27 °C when liquid water is formed is ‘2.11922 cal b. -2314.5 cal e. 1257.44 cal 4. -1257.44 cal204.The minimum work required £: fOr the manufacture of 5 bs of ice cubes from water initially at 32 °F ts facture of 5 lbs of ice cubes f aca76 a B. 73.0 Btu c. 90.2 peu a. 70.0 205.1f the surxc 243.4 Btu/ib Calculate the change in converted to steam at 100 °C an a. 645.23 eu re 206. The main concern in the study of thermodynamics is change in enthalpy the time elenent in transformation the initial and final state of the system . the change in entropy 207. At 90 °C, the vapor pressure of acetic acid 293 mmlig and its vapor [Pressure at 2 100 °C is 417 mig. Calculate the normal boiling point of acetic acid. a.271.4 K b. 391.3 K c. 298.2 K a 313.0 K ee 208.Calculate the change in molar Gibb’s energy of liquid H,0 treated as incompressible fluid when pressure is increased from 1.0 bar to 2.0 bar at 298 Sunding air is 80 "r and the latent heat of fusion of water is entropy when 100 grams of ice at 0 °C is b. 302.34 eu c. 205.28 eu a. 342.25 ant 1.929 b. = 182 3 e. + 1.02 x10" 3 tied co a Z 209.0n€ ol of NOs forms 2.0 mol of NO; ig) under standard conditions. xf a8 4.6 dik, the reaction 13, wipe B! non-spontaneous &. can'nae be determined 210. ‘Tne densieies of Ligald and aotid neroury are 19.7 and 14.29 g/cc respectively at a melting point of 20.07 °C. The heat of fusion of Hg is Cel/gcaton,” The change in melting point per atmospheric change in pressure {3 a. 0130s wb. 0.0051 c. 0-013 K a ola3i kANSWER KEY: 23. 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