Beruflich Dokumente
Kultur Dokumente
1007/s12221-009-0221-7
Abstract: The effect of twist level on the mechanical and thermal properties of nylon 66 and polyethylene terephthalate
(PET) tyre cords has been studied. Effects of the twist on some critical cord properties such as tensile properties, shrinkage,
shrink force, adhesion and fatigue have been evaluated. Breaking strength was decreased between 3.1 and 7.3 twist factor val-
ues, whereas breaking elongation was increased, on both nylon 66 and polyester cords. The tensile behaviour of high twist
factor PET is similar to that of low twist factor nylon cords. This is an advantage for the possibility to get closer the properties
of different materials by adjusting theirs twist factors. The shrinkage values increase with increasing twist factor, whereas
shrinks force values decrease for greige nylons and polyester cords. Adhesion and fatigue resistance is increased with increas-
ing twist factors.
Keywords: Tyre, Cord, Mechanical property, Twist factor, Polyester, Nylon 66
Introduction tyre and can be changed according to the customer requests [8].
It is well known that cords in the tyre are continuously
Tyre is a composite matter of reinforcing materials and flexed, extended and compressed tyres while tyre is running.
rubber compounds. The reinforcing materials used are mainly Therefore, the reinforcing materials must withstand to a
textile cords, steel cords and steel bead wire. These materials large number of fatigue cycles keeping the initial properties [9].
carry the major part of the structural load of the automobiles Nkiwane and Mukhopadhyay investigated flex fatigue life
and should exhibit excellent dimensional stability, tensile nylon 66 tyre yarns and cords at different stress levels at
and fatigue properties [1-3]. standard atmospheric conditions [10]. Naskar et al. have
Cord fabric is the basic textile material, which is used to reported the physico-mechanical and fatigue characteristic
reinforce the pneumatic tyre. It consists of parallel warps and of polyester, nylon 6 and nylon 66 cords [1].
rare wefts. It can be produced with different type of yarns. The In this paper PET and Ny 66, mainly used cords types in
most widely offered yarns at the market are Polyamide 6 and the tyre industry, have been studied. Mechanical and thermal
66, Polyester and Rayon. Due to the high cost of the complete properties of nylon and polyester cords at different twist
developing and getting approval of new yarns for use in tyre factors were investigated. Effect of the twist on some critical
application, polyester and nylon yarns are still predominantly cord properties such as on the tensile strength, shrinkage,
used in the tyre industry worldwide [4,5]. The total synthetic shrink force, adhesion and fatigue has been evaluated.
fiber production in 2000 was 51.6 million tones in the world.
Over two-thirds of the synthetic fiber produced was polyester. Experimental
Approximately 4 million tones of nylon were produced in
the world. In terms of production volume, nylon ranked third Material
among the major fibers [6]. The commercial nylon 66 (940 dtex) and polyester (1100
Various efforts have been made to investigate the effects dtex) greige yarns supplied from KORDSA Global (Turkey)
of the twist level on the tyre cord performance. Fristsch had were used for the study. Tyre cords were prepared on an
investigated rayon, PET, and Polyethylene Naphthalate (PEN) industrial ring twister machine by twisting the yarns into
tyre reinforcement materials with different twisting conditions two-ply construction with 200, 350 and 470 turns/m. Then,
[7]. Hockenberger and Koral had investigated the effect of the same twist levels were applied to the single yarns to keep
twist on the cord performance of PEN, dimensionally stable the filaments together. The dipped cords were dried in a
polyester and high tenacity polyester cords [3]. series of oven to obtain the required rubber adhesion and the
For optimum tyre performance, adequate adhesion between tensile properties. The greige cords were then treated with
reinforcing materials and rubber compound is essential. RFL adhesive solutions under controlled tension and
Conventional resorcinol-formaldehyde-latex (RFL) adhesion temperature. Consequently, the excessive tension and the
systems provide required adhesion for nylon cords whereas heat setting on the dipped cords were relaxed. and wound up
polyester cords require the use of reactive chemicals [2]. to the rolls. Standard rubber compounds required for the
RFL formulation depends on to compound type to be used in fatigue and H-adhesion tests were obtained from KORDSA.
221
222 Fibers and Polymers 2009, Vol.10, No.2 Ayse Aytac et al.
Method strips. The samples were vulcanized at 153 C and under the
o
Twist pressure of 3.2 MPa for 25 min. Then the products were cut
The twists (in turns per meter, tpm) of the greige and into H-shaped samples. Static adhesion was evaluated by
dipped cords were measured using a Zweigle twist tester measuring cord pull out force in Instron tester 4502 at 25 C, o
(Germany), according to ASTM D885. Twist level of the (ASTM D4776). An average of 8 test runs has been reported
cords were then transformed in to the twist factor (TF) for each type cord.
values, in order to compare the properties of commercial tire Fatigue Test
cords with different linear densities. The twist factor was Fatigue properties of the cords were measured using Wallace
calculated by using the following equation (1). test equipment. The equipment has five hubs and is capable
= ( /1000) 1/2
(1) of testing up to five specimens at once. The prepared test
TF t LD
specimens are mounted to the hubs. Then the equipment
Where, : twist in turns per meter
t runs up to 100 000 cycles. The number of cycles in each test
LD : linear density in tex is being recorded by a counter affixed to each rocker arm
Tensile Tests (ASTM D 430).
The tensile tests were performed by using Instron tester Optical Microscopy Studies
4502, with cross head speed of 300 mm/min and gauge Olympus SZ6045 Model, Automatic Trinoculer Stereo
length of 254 mm according to ASTM D885. Averages of 5 Zoom Microscope, was used for optical microscopic analysis.
test runs have been reported for each type cord.
Shrinkage and Shrink Force Results and Discussion
The hot shrinkage of the greige cords was measured using
Testrite shrinkage tester at 177 C for 2 min. The pretension
o
Tensile Properties
used for the thermal and free shrinkages measurements was The optical microscope pictures of two ply nylon and
0.05 g/denier. An average of 3 test runs has been reported for polyester cords with three different twist levels are shown in
each type cord. the Figures 1-2 respectively. The number of turns per unit
H-adhesion Test length increases with increasing twist factor. Therefore the
The rubber strips were placed in the channels of a stainless amount of yarn per unit length increases. The filaments are
steel die. Then dipped cords were placed on rubber strips. tightened and the contact area of the plies in unit length
The ends of cords were stretched by 50 g weights. The cords increases as the number of twist increases. Since, the changes
were then covered completely by the second layer of rubber on the surfaces and the direction of the plies depend very
Figure 1. Polyester cords with different twist levels (a) 200 tpm (b) 350 tpm, and (c) 470 tpm.
Figure 2. Nylon cords with different twist levels (a) 200 tpm (b) 350 tpm, and (c) 470 tpm.
Effect of Twist Level on Tyre Cord Performance Fibers and Polymers 2009, Vol.10, No.2 223
cords.
for better adhesion to rubber.
Low shrinkage value of polyester is an advantageous for the
Shrinkage and Shrink Force tyre production process.
A comparison of shrinkage-shrink force values of greige It is known that shrinkage force is a combination of
and dipped cords are shown in Table 3. It was observed that pretension force and the force that is developed in the
nylon 66 tyre cords have higher shrinkage than that of the specimen as a result of heating. Shrinkage force increases
polyester tyre cords. As the twist increases, linear density, with total shrinkage for single fiber or untwisted yarn. But
i.e. the weight of material in unit length increases (Table 3). this relationship becomes invalid with the increasing twist
Therefore, shrinkage values of nylon and polyester cords are factor due to the increase in the helix angle. In this study, it
increased with increasing twist factors. It has also been was observed that shrinkage force values were decreased with
observed that shrinkage values of dipped cords are lower increasing twist factors for all greige cords and dipped nylon
than those of greige cords for both nylon and polyester cords, but was increased slightly for dipped polyester cords.
(Figure 4). However, if different dipping conditions are
applied, these values can be changed as shrinkage and shrink Fatigue Resistance
force values are controlled by different dipping conditions. The flex fatigue resistance test results for dipped nylon
Shrinkage and shrink force test results
Table 3.
Table 4.At different twist factor fatigue resistance for nylon and polyester cords
Adhesion (N) Breaking strength (N)
Cord type Twist factor Unflexed sample Flexed sample (N) %Residual adhesion
%Residual
strength
(N) (100 000 cycle ) Unflexed sample Flexed sample
2.9 205 181 88 141 67 48
Polyester 5.0 307 256 83 147 92 63
6.7 299 248 83 137 110 80
3.1 376 300 80 117 113 97
Nylon 66 5.4 363 358 97 145 144 99
7.3 370 328 89 140 137 98
Effect of Twist Level on Tyre Cord Performance Fibers and Polymers 2009, Vol.10, No.2 225
nylon 66 tyre cords to obtain deteriorations. Industry”, Tyre Technology International, 1995.
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recorded for fatigue resistance. The fibers with lower twist Polyolefin”, CRC Press, England, 2005.
factors are subjected to the destructive interactions during 7. J. F. Frisch, “Technical and Cost Optimization of Textile
the fatigue testing due to their low extensibility. When the Constructions for Advanced Reinforcement of Passenger
twist factor is increased, the fiber extensibility increases as and Van Tyres”, IRC 2000 Rubber Conference, Helsinki-
well, as a function of increased helix angle of yarns. This Finland, 2000.
results in, the protection of fibers from any kind of deformation. 8. Y. Ayyildiz, “Cord Fabric Production, Kordsa Training
Additionally, tyre cords act like a spring at the higher twist Notes”, Turkey, 2005.
factor and consequently can flex. Therefore the fatigue resistance 9. H. H. Cho, K. H. Lee, and Y. H. Bang, J. Appl. Polym. Sci.,
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10. L. Nkiwane and S. K. Mukhopadhyay, J. Appl. Polym. Sci.,
Conclusion 75, 1045 (2000).