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Part Test - 1 Physics (Main)

PART (A) : PHYSICS


SOLUTION

1. (B)

l l l
4F  3F  2F 
e1  4, e  2, e  4
2 3
AY AY AY
FL 3FL FL 3FL
e  e1  e2  e3    
AY 2 AY 2 AY AY

2. (C)
Vdv
a
dS
1 V 2 270
   22.5 m s 2
2 S 26

3. (C)
Initial velocity and acceleration are in the same direction and acceleration is positive through out the
motion. Hence velocity always increases.

4. (D)
Gmx
ER  3/2
; x  3R
 R2  x2 
3GMm
F  MER 
8R2

5. (A)
 mR 2   3 2 2
I  2   4  mR   7 mR
 2  2 

6. (A)
Energy conservation : K i  U i  K f  U f
2
1 2 1 2 V 
mgh  mV  mK  2 
2 2 R 
R
K  Solid cylinder
2

7. (C)
mV  MV
MV
V
m
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V 2  2gS
V2 M 2V 2
S 
2g 2m 2 g

8. (D)
FB  mg  T
m
FB  Vb  g   g
b
 mg   b 
 T     1 mg

9. (C)
1 2
mgh  mv
2
v  2 gL 1  cos   ... 1
v  2 g  L   1  cos   ...  2 
From (1) and (2)
L 1  cos     L   1  cos  
L cos   
cos  
 L  

10. (A)
I11  I 2 2
MR 2    MR 2  4mR 2  
M
 
 M  4m 

11. (A)
RP  2 Re
M P  8M e
2GM e
Ve 
Re
2GM P 2G  8 M e 
VP  
RP 2 Re
 VP  2Ve

12. (C)
V
 0.001, P  gh
V

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P 103 10  200


B   2 109 Pa
 V  0.001
 
 V 

13. (C)
R1 2 P F A R2 1
  1  1 1  22 
R2 1 P2 F2 A2 R1 4

14. (C)
  U ˆ U ˆ U  20 y ˆ 20 x 20 xy
F   i j kˆ   i  2
 x y x  z z z

15. (C)
 
F  ma (No thrust in horizontal direction)

 dV
F   m0  t 
dt

16. (A)
a  A cos t
V  fa  dt   A sin t
V  V0 sin t KE
1
 K .E.  mV 2 (Positive curve of sin 2 t )
2 t
T

17. (B)
Applying bernaulies theorem
1
Patm   2gh    2gh    2 V 2  Patm
2
2
4gh  V
V  2 gh

18. (B)
P  Kt 2
d
 kt 2  W   Kt 2  dt
dt
1 t3
 mV 2  K
2 3
3/ 2
V t

19. (D)
Vx  3 m s , Vy  u y  a y t  4 m s

V  Vx2  Vy2  5m s

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V  1  4 
  tan 1  y   tan  
 Vx  3

20. (A)

1 P
P and V  t  r  t1/3
r
1
 P  1/3
t
t

21. (1.00)

T  2
g
 mg  FB   1  7
g eff .     1   g  g
 m   8 8
8
 T   2
7g
m  8, n  7
m n 1

22. (2.00)
F   3x2  2 x 
a  3x2  2 x 
0 0
 V .dv    3x  2 x  dx
2
v 4

v2 0
   x3  x 2 
2 4

V  96
P
 96  P  2592
27
P
Then,  1.99
1300

23. (8.00)
 mg  f  r   3mr 2  mr 2   ..... 1
mg  f  4ma .....  2 

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 8ma  mg
g g
 a  
8 8r

24. (7.91 to 8.00)


1 2 1
mg 1  x   Kx  0  mV 2
2 2
 Kx  mg
 mg  0.2  2  10
x   0.4
 K  10
1 1
0.2  2  10 1.4    10  0.16   2  V02
2 2
2
5.6  0.8  V0
8
V0  6.4   P8
10

25. (0.00)
S Px   5  10  t
1
STx  10t   10  t 2
2
24 y
t  1s
g
S Px  STx
S PT  0

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PART (B) : CHEMISTRY


SOLUTION

26. (D)
Suppose the mol. Wt. of enzyme =x
Given 100 g of enzyme wt of Se = 0.5 gm
0.5
 In x g of enzyme wt. of Se  x
100
0.5  x
Hence 78.4 
100
 x  15680  1.568  104

27. (A)
 n  l  rule: the higher the value of  n  l  ,the higher is the energy. When  n  l  value is the same
see value of n.

 IV  II  III  I

28. (C)
Not more than two electrons can be present in same atomic orbital. This is Paulis exclusion principle.

29. (D)
For a gas, maximum deviation from ideal gas behaviour is observed at lower temperature & high
pressure.

30. (C)
According to question:
For initial stage of a gas,
P1  1atm, V1  24.6 litres ,
T1  273  27  300K
For final stage of a gas,
P2  10atm, V2  ?
T2  327  273  600K
By gas equation,
P1V1 P2 V2

T1 T2
1 24.6 10  V2

300 600
24.6  600
 V2 
300  10

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 4.92 litres

31. (D)
G  H  TS; G is positive for a reaction to be non-spontaneous when H is positive and S is
negative

32. (C)
1
SO 2  O 2   SO 3
2
H  H f  SO3   H f  SO2 
 98.2  298.2  200kJ / Mole

33. (B)
B  OH 3 does not provide H  ions in water instead it accepts OH  ion and hence it is Lewis acid.

  B  OH    H 
B  OH 3  H 2 O   4

34. (C)
Weak acid + its conjugate base   acid buffer
Weak base + its conjugate acid   basic buffer
A buffer solution resist the change in pH on adding a drop of acid or a base

35. (B)
AgBr has the highest solubility in 103 M NH 4OH . All other solvents will dissolve AgBr poorly,
Moreover bromides of Ag  , Hg 22 and Cu 22 are water insoluble.

36. (A)
Given  H 3O    1 1010 M
At 25  H3 O   OH    1014
1014
  OH    10
 10 4
10
OH OH
Now,  OH    10 P  104  10 P
 POH  4

37. (B)
Dissociation of CH 3COOH is suppressed by the addition of sodium acetate  CH 3COONa  due to
common ion  CH 3COO   effect. The  H   decreases raising the pH of the acid solution.
Note: After the addition of CH 3COONa to CH 3COOH , a buffer solution is formed which has
reserved pH value.

38. (A)

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39. (A)
3
For bcc structure, atomic radius, r  a
4
3
  4.3  1.86
4
Since, r = half the distance between two nearest neighbouring atoms.
 Shortest inter ionic distance  2 1.86  3.72

40. (D)
C 2 H 5 I and C2 H 5 OH form non-ideal solution.

41. (A)
Tf  i  K f  m
Van’t Hoff factor, i  2 for NaCl
Hence Tf  0.02 K f which is maximum in the present case.
Hence Tf is maximum or freezing point is minimum

42. (B)
Density= 1.17 gm/cc (Given)
Mass
As d 
Volume
Volume  1cc  mass  d  1.17g
No.of moles 1.17 1000
Now molarity  
Volumein litre 36.5 1
1170
  32.05 M
36.5

43. (B)
Given ESn4 /Sn2  0.15 V
ECr3 /Cr  0.74 V
Ecell  E cathode  Eanode
 0.15   0.74 
 0.89 V

44. (B)
Given current (i) =0.5 amp
Time (t)= 100 minutes 60  6000 sec
Equivalent weight of silver nitrate (E) =108. According to Faraday’s first law of electrolysis
Eit 108  0.5  6000
W   3.3575g
96500 96500

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45. (B)
Given specific conductance of the solution  k   0.012 ohm 1cm 1 and resistance  R   55ohm . We
know that cell constant = Specific conductance  Observed resistance  0.012  55  0.66 cm 1

46. (4.00)
K b  1010 ; K a  104 or pK a  4
For the buffer solution containing equal concentration of B and HB
pH  pK a  log1
pH  pK a  4

47. (8.00)
IO3  5I   6H  
 3I 2  3H 2 O
a = 5 and b = 6 and c = 3
ac8

48. (3.00)
Overall order= sum of orders w.r.t each reactant
Let the order be x and y for G and H respectively
Exp. No. [G] mole [H] mole Rate
litre 1
litre1  mole litre1 time1 
1 a B r
2 2a 2b 8r
3 2a B 2r
 y
Applying r  k  G   H  we get,
x  1, y  2
 For(1) and (3), the rate is doubled when conc. of G is doubled keeping that of H constant i.e. ,
rate   G   x=1
From (2) and (3), y=2
 Overall order is 3.

49. (2.00)
 NOBr2  g 
(i) NO  g   Br2  g  
(ii) NOBr2  g   NO  g  
 2NOBr  g 
Rate law equation  k  NOBr2  NO 
But NOBr2 is intermediate and must not appear in the rate law equation

From Ist step K C 


 NOBr2 
 NO  Br2 
 NOBr2   K C  NO Br2 
2
 Rate law equation  k.K C  NO  Br2  hence order by reaction is 2 w.r.t. NO

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50. (4.00)
(ii) 2Px
(iii) 3d xy
(iv) 4d xz
(vi) 3d yz

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PART (C) : MATHEMATICS


SOLUTION

51. (B)
Now according to condition a  1
b 2  10b  25  a  1
 b 2  10b  24  0
  b  4  b  6  0 i.e. b  4 or b  6

52. (A)
Equation of tangent in the slope form is y  mx  a 2 m 2  b 2
1
Slope of the tangent require is 
2

53. (C)
tan 1 2  tan 1 3
 23 
   tan 1  
 1 23 
 3
  
4 4

54. (A)

Maximum value of 4sin 2 x  3cos 2 x  sin 2 x  3 is 4 hold at x  and maximum value of
2
 x 
sin  cos is 2 at x 
2 2 2
 x
So combining above two results maximum value of 4sin 2 x  3cos 2 x  sin  cos is 4  2
2 2

[ Both hold at x  ]
2

55. (A)

3 3 7
CP  CQ   OC  2  
2 2 2
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Equation of OC
x0 y0 7
 
1 1 2
2 2
7 7
x y
2 2 2 2

56. (A)
x y
Let equation of line  1
a b
a  b  1 ..... 1
and passing through (4,3)
4 3
 1 .....  2 
a b
Solve get, a  2, b  3, 1
x y x
Equation of line   1 and  y 1.
2 3 2

57. (D)
 
2a  n 2b
a
 n
b
a2  b2 b2
 e  1 
a2 a2
1 n2  1
1 
n2 n

58. (C)
Use condition of orthogonality  2 gg   2 ff   c  c 

59. (B)
This given equation can be written as
3 4 sin 
5 
cos  cos 
 4sin   5 cos   3, cos   0
4 5 3
 sin   cos  
41 41 41
5 4
Let  cos  , then  sin 
41 41
3
cos        cos 
41
3
     2n   , where cos  
41

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Or   2n     or   2n     in total in  0, 4


We have, 2  2  4 solutions

60. (A)
a
R
2sin A
1
x2  y 2  R 2 
4
AM  GM
1
 x2  y 2  2 x2 y 2
4
1
xy 
8

61. (A)
4
Putting y  in the equation of the circle, we get x 4  2ax 3  16ax  16  0
x
x x x x a
So, 1 2 3 4 
4 2
y  y  y3  y4
Similarly 1 2  a
4
a
 h  , k  a
2
k
 h    y  2x  0
2

62. (A)
q
 tan  , so p cos 2  q sin 2
p
 q2  q
p 1  2  2
p  p
  2
 q p
q q2
1 2 1 2
p p

63. (Bonus)
Let R is  ,   , then
 1  1
 1
 1
3  1
 (   0 as R is on segment PQ)
 1
A point is inside parabola y 2  4 x if y 2  4 x  0
2
 3  1 
   4 1  0
  1 

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 3  1  3  1 
  2   2  0
  1    1 
 5  3   1  0
3
    1 (but   0 )
5
So 0    1

64. (A)
Multiply and dividing with 2
   n
 2 sin   n  
4 2  2
   n
 sin   n  
4 2  2 2
1 n
  1  4  n  8
2 2 2

65. (A)
  3    1
sin   sin 1   
  sin   
2 2 2 3 2
  

66. (A)
a cos  tan   a sin   c
Distance  2
 c cos 
tan 2    1

67. (C)
 AB  ab C  AB  3 1
Using Napier’s analogy, tan   cot  tan  
 2  ab 2  2  3 1
o
 A  B  30
 A  75o , B  45o
sin 45o 2 2 3 2
Now, o
  c  6
sin 60 c 2 1

68. (A)
Squaring and adding gives the required locus.

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Part Test - 1 Mathematics (Main)

69. (A)

 
Combined equation of OP and OQ is

 POQ 
2
4al  n  0

70. (B)
25cos 2   20 cos   15 cos   12  0
5cos   5cos   4   3  5cos   4   0
3
cos   (rejected)
5
4 3
cos    , sin  
5 5
4 3 24
sin 2  2 sin  cos   2     
5 5 25

71. (5.00)
On putting cos 2x  t we get 2t 2  1  6  7t
5 5
 t  1, t  (Impossible)
2 2
 t  1  cos 2 x  1  2 x  2n
 x  n, n  I
The roots over [0, 314] are , 2, 3, .......99 .
 100  314
 Sum of roots    2  3  ....  99  4950
   4950

72. (7.00)
Let coordinates of R  ,  
1
If R divides PQ internally then    ,   2
3
If R divides PQ externally   7,   14

73. (7.00)
2
x  4cos 3   3cos    y cos4   9 cos 2   16 cos6 
 9 x cos2    y  24 x  cos 4   16 x cos6   9cos 2   16cos6  being an identify

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI # 5
Part Test - 1 Mathematics (Main)

 9 x  9, y  24 x
 x  1, y  24

74. (4.00)
y  0  3  x  2  it intersect y  x
2 3
 x
3 1
 2 3 2 3 
So P is  , 
 3 1 3  1 
So required line is
2 3 1  2 3 
y   x  
3 1 3 3  1 
It intersect y-axis at x = 0
  42 3

75. (8.00)
2cos x  sin x
cos x  0  sin x  1
sin x  1
 3
x ,
2 2

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA /NASHIK / PUNE / GHAZIABAD / BOKARO / DUBAI # 6

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