Beruflich Dokumente
Kultur Dokumente
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use
SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
· Product category PC9a Coatings and paints, thinners, paint removers
· Process category
PROC10 Roller application or brushing
PROC11 Non industrial spraying
· Environmental release category
ERC8e Wide dispersive outdoor use of reactive substances in open systems
ERC8f Wide dispersive outdoor use resulting in inclusion into or onto a matrix
· Application of the substance / the mixture Epoxy curing agent
· Uses advised against -
· Contact details:
· Further information obtainable from: Occupational product safety department of Seal For Life Industries
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Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Repr. 2 H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
STOT SE 1 H370-H371 Causes damage to the skin, the respiratory system, the digestive system and the
stomach. Route of exposure: Oral, Inhalative, Dermal. May cause damage to the
central nervous system and the lung.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS05 corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
C; Corrosive
R35: Causes severe burns.
Xn; Harmful
R21/22-48/20/21/22-62: Harmful in contact with skin and if swallowed. Harmful: danger of serious damage to
health by prolonged exposure through inhalation, in contact with skin and if swallowed.
Possible risk of impaired fertility.
(Contd. on page 3)
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Xn; Sensitising
R42/43: May cause sensitisation by inhalation and skin contact.
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P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see on this label).
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Additional information:
Restricted to professional users.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not available.
· vPvB: Not available.
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Aliphatic amine (Proprietary) 5,0-10,0%
T+ R26; T R39/23; C R35; Xn R21/22-48/20/21/22;
Xn R42/43; Xi R41
Acute Tox. 2, H330; Resp. Sens. 1, H334; STOT SE 1, H370-H371-
H335-H336; STOT RE 2, H373; Skin Corr. 1A, H314; Eye Dam. 1,
H318; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317
CAS: 1761-71-3 4,4'-methylenebis(cyclohexylamine) 5,0-10,0%
EINECS: 217-168-8 C R35; Xn R22-48/22; Xi R43; N R51/53
STOT RE 2, H373; Skin Corr. 1A, H314; Aquatic Chronic 2,
H411; Acute Tox. 4, H302; Skin Sens. 1, H317
CAS: 111-40-0 2,2'-iminodiethylamine 2,5-5,0%
EINECS: 203-865-4 C R34; Xn R21/22; Xi R43
Index number: 612-058-00-X Acute Tox. 2, H330; Skin Corr. 1B, H314; Acute Tox. 4, H302;
Acute Tox. 4, H312; Skin Sens. 1, H317; STOT SE 3, H335
CAS: 84852-15-3 4-nonylphenol, branched 2,5-5,0%
EINECS: 284-325-5 C R34; Xn R22-62-63; N R50/53
Index number: 601-053-00-8 Repr. Cat. 3
Repr. 2, H361fd; Skin Corr. 1B, H314; Aquatic Acute 1, H400;
Aquatic Chronic 1, H410; Acute Tox. 4, H302
Alkyl amine (Proprietary) 2,5-5,0%
T+ R39/26/27; C R35; Xn R20/21/22-48/20/21/22;
Xn R42/43; Xi R41
Resp. Sens. 1, H334; STOT SE 1, H370-H371-H335-H336; STOT RE
2, H373; Skin Corr. 1A, H314; Eye Dam. 1, H318; Acute Tox. 4,
H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Sens. 1, H317
CAS: 100-51-6 Benzyl alcohol 2,5-5,0%
EINECS: 202-859-9 Xn R20/22
Index number: 603-057-00-5 Acute Tox. 4, H302; Acute Tox. 4, H332
· Additional information: For the wording of the listed risk phrases refer to section 16.
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Do not induce vomiting; call for medical help immediately.
Rinse out mouth and then drink plenty of water.
· 4.2 Most important symptoms and effects, both acute and delayed
Headache
Disziness
Disziness
Unconsciousness
Coughing
Breathing difficulty
Asthma attacks
Nausea
Gastric or intestinal disorders
Cramp
· 4.3 Indication of any immediate medical attention and special treatment needed
If swallowed or in case of vomiting, danger of entering the lungs.
Medical supervision for at least 48 hours.
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Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Additional information about design of technical facilities: No further data; see item 7.
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· Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
Butyl rubber, BR
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· Eye protection:
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· Explosion limits:
· Lower: Not determined.
· Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1,03 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
· water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
· Dynamic: Not determined.
· Kinematic: Not determined.
· Solvent content:
· Organic solvents: 3,1 %
· VOC (EC) 3,15 %
· 9.2 Other information No further relevant information available.
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions
Reacts with acids.
Reacts with oxidising agents.
Corrosive action on metals.
Reacts with various metals.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials:
Reacts with strong acids.
Reacts with oxidising agents.
· 10.6 Hazardous decomposition products:
Poisonous gases/vapours
Flammable gases/vapours
Nitrogen oxides
Ammonia
Aldehyde
EU
(Contd. on page 10)
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· 12.1 Toxicity
· Aquatic toxicity:
Alkyl phenol (Proprietary)
LC50/96h 5 mg/l (Fish - Pimephales promelas)
98-54-4 4-tert-butylphenol
EC50 2 mg/l (Daphnia magna) (OECD 211 - 21 days)
EC50/48h 4,8 mg/l (Daphnia magna) (OECD 202)
ErC50/72h - Inhibition of average growth rate 14 mg/l (Algae - Pseudokirchneriella subcapitata) (OECD 201)
LC50/96h > 1 mg/l (Fish - Oncorhynchus mykiss) (OECD 203)
NOEC/21days 0,73 mg/l (Daphnia magna) (OECD 202)
NOEC/72h 0,32 mg/l (Algae - Pseudokirchneriella subcapitata) (OECD 201)
1761-71-3 4,4'-methylenebis(cyclohexylamine)
EC50/48h 9,24 mg/l (Daphnia magna)
EC50/72h 140 mg/l (Algae)
LC50/96h 46 mg/l (Fish - Leuciscus idus)
111-40-0 2,2'-iminodiethylamine
EC50/48h 16 mg/l (Daphnia magna) (DIN 38412, part 11)
LC50/96h 430 mg/l (fish)
84852-15-3 4-nonylphenol, branched
EC50/48h 0,14 mg/l (Daphnia magna) (EU Method C.2)
EC50/72h 1,3 mg/l (Algae - Desmodesmus subspicatus) (other guideline)
LC50/96h 0,23 mg/l (Fish - Oncorhynchus mykiss) (ASTM 1991 E729-88a)
0,128 mg/l (Fish - Pimephales promelas) (ASTM 1991 E729-88a)
NOEC/21days 0,024 mg/l (Daphnia magna) (OECD 202 (reproduction))
NOEC/91d 0,006 mg/l (Fish - Oncorhynchus mykiss) (Study report acc. ASTM
guideline)
100-51-6 Benzyl alcohol
EC50/24h 55 mg/l (Daphnia magna)
IC50/72h 700 mg/l (Algae)
LC50/96h 10 mg/l (Fish - Lepomis macrochirus)
460 mg/l (Fish - Pimephales promelas)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
(Contd. on page 12)
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· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· ADR, IMDG
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· IATA
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code E
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· UN "Model Regulation": UN2735, POLYAMINES, LIQUID, CORROSIVE, N.O.S.
(DIETHYLENETRIAMINE, Alkyl amine (Proprietary)),
ENVIRONMENTALLY HAZARDOUS, 8, II
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· National regulations:
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· Relevant phrases
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361f Suspected of damaging fertility.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H370 Causes damage to the skin, the respiratory system, the digestive system and the stomach.
Route of exposure: Oral, Inhalative, Dermal.
H371 May cause damage to the central nervous system and the lung.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
· Department issuing MSDS: Occupational product safety department of Seal For Life Industries
(Contd. on page 15)
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