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THERMOCHEMISTRY
Specific Curriculum Outcomes
Suggested Time: 30 Hours
THERMOCHEMISTRY
Thermochemistry
Introduction Energy is the essence of our existence as individuals and as a society. An
abundance of fossil fuels has led to a world-wide appetite for energy. There
are pros and cons to using fossil fuels. The relationship between energy and
chemistry needs to be explored to help us find alternative fuels.
Thermochemistry includes energy changes that occur with physical and
chemical processes. The study of energy production and the application of
chemical change related to practical situations has helped society to progress.
Focus and Context Thermochemistry focuses on energy in various systems. Skills involving
planning, recording, analyzing, and evaluating energy changes will be
developed. Fuels for energy provide the context for student research and
projects. These fuels could include energy for industry, energy from foods, or
any other relevant context. This unit will help students to develop an interest
in global energy issues and to appreciate the idea of possible solutions to a
problem. Doing lab work and performing calculations allow students to
discuss their evidence and problem-solving in order to consolidate their
understanding of energy changes.
Science Science 1206 included balancing chemical equations. Heat and temperature
were discussed in the weather unit. Chemistry 2202 outcomes useful for this
Curriculum Links unit include measuring amounts of moles as well as the energy
transformations associated with bond breaking and forming.
Curriculum Outcomes
STSE Skills Knowledge
Nature of Science and Technology Initiating and Planning 308-2 explain temperature using the
concept of kinetic energy and the
114-5 describe the importance of peer 212-3 design an experiment
particle model of matter
review in the development of scientific identifying and controlling major
knowledge variables 324-1 write and balance chemical
equations for combustion reactions of
Relationships Between 212-8 evaluate and select appropriate
alkanes
Science and Technology instruments for collecting evidence and
appropriate processes for problem 324-2 define endothermic reaction,
116-4 analyse and describe examples
solving, inquiring, and decision exothermic reaction, specific heat,
where technologies were developed
making enthalpy, bond energy, heat of
based on scientific understanding
reaction, and molar enthalpy
Performing and Recording
Social and
Environmental Contexts of Science 324-3 calculate and compare the
213-6 use library and electronic research
energy involved in changes of state and
andTechnology tools to collect information on a given
that in chemical reactions
topic
117-6 analyse why scientific and
324-4 calculate the changes in energy
technological activities take place in a 213-7 select and integrate information
of various chemical reactions using
variety of individual and group settings from various print and electronic sources
bond energy, heats of formation and
or from several parts of the same source
117-7 identify and describe science- and Hess’s law
technology-based careers related to the 213-8 select and use apparatus and
324-5 illustrate changes in energy of
science they are studying materials safely
various chemical reactions, using
117-9 analyse the knowledge and skills Analysing and Interpreting potential energy diagrams
acquired in their study of science to
214-3 compile and display evidence 324-6 determine experimentally the
identify areas of further study related to
and information, by hand or changes in energy of various chemical
science and technology
computer, in a variety of formats, reactions
118-2 analyse from a variety of including diagrams, flow charts, tables,
324-7 compare the molar enthalpies of
perspectives the risks and benefits to graphs, and scatter plots
several combustion reactions involving
society and the environment of applying
214-6 apply and assess methods of organic compounds
scientific knowledge or introducing a
predicting heats of reaction
particular technology ACC-8 define, calculate and compare
214-15 propose alternative solutions fuel values
118-8 distinguish between questions
to a given practical problem, identify
that can be answered by science and
the potential strengths and weaknesses
those that cannot, and between
of each, and select one as the basis for a
problems that can be solved by
plan
technology and those that cannot
Communication and Teamwork
118-10 propose courses of action on
social issues related to science and 215-4 identify multiple perspectives
technology, taking into account an array that influence a science-related
of perspectives, including that of decision or issue
sustainability 215-6 work cooperatively with team
members to develop and carry out a plan,
and troubleshoot problems as they
arise
Journal
MGH Chemistry, pp. 628-629
• In their science log, students could respond to the following
questions:
– Explain why, on a hot, summer day at the beach, the sand
can be unbearably hot on bare feet yet the water is very cold. MGH Chemistry, pp. 629-632
– What happens when direct sunlight is blocked by a cloud?
How does this affect the temperature of the sand versus that
of the water ? (308-2, 117-7, 324-7)
• Students could be told they can use a balance to find the mass of their
substance only when it is at room temperature. They should explain
this statement. (116-4, 308-2)
• Students could be asked, “Why is it helpful to fill your thermos
bottle with hot water before filling it with a hot beverage?” (114-5,
215-4, 308-2)
• A Scottish chemist, Joseph Black (1728–1799), differentiated
between temperature and thermal energy. Students could discuss how
these are different. They should give an example of an experiment to
show when two objects at the same temperature do not necessarily
have the same thermal energy. (308-2, 324-2, 212-3)
Calculating Heat
Calculating Heat
Performance
• Students could calculate which has more heat: 250.0 mL of water at
90°C or 20 000.0 mL of water at 30°C? They should qualitatively
and quantitatively explain their result. (324-3) MGH Chemistry, pp. 632-633,
pp. 831-832
Paper and Pencil
• Heat lost equals heat gained. Students could explain this
assumption. (324-3)
Presentation
MGH Chemistry, pp. 633-637
• For a selected reaction, students could make the case that the Law
of Conservation of Energy has been “upheld.” (324-5, 214-3)
• Students could investigate industrial applications of heat capacity. MGH Chemistry, pp. 627-628
For example; refrigerator, household heating systems and cookware
design. (324-3)
o
−(mc∆T )water −(200.0 g )(4.18 J g o C )(5.0 C )
Cx = =
(m∆T ) x (10.0g )(−255.0 oC )
Cx = 1.6 J g o C
Simple temperature versus time graphs are often useful in solving such
problems.
X
280.0 Water
(mc)T)X
T(oC)
25.0
20.0 (mc)T)water
Time
Students should perform problems involving solutions for any of the 6
variables m,c, ∆T of X, or m, c, ∆T of water. Heat capacities can also be
incorporated into such problems.
Journal
• The calorimeter is a basic instrument for measuring heat transfer.
Students could explain what a calorimeter is, how it measures heat
transfer, and how it works. (324-3) MGH Chemistry, pp. 661-663
Paper and Pencil
• Students could explain what is meant by the following terms: specific
heat, heat of reaction, and molar enthalpy. (324-2, 324-3)
• As students plan one of their labs for this unit, they should list the
MGH Chemistry, pp. 664-665,
skills and knowledge needed to perform the lab properly. (324-3,
p. 832
117-9)
• Students could calculate the heat gained or lost from the following
system:
– A piece of metal having a mass of 100.0 g, originally at
-30.0°C, was dropped in 300.0 g of water at 35°C. The
temperature of the water went down to 32.0°C. Students
could calculate the specific heat of that metal. (324-2,
324-3)
• HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)
When 50.0 mL of 1.00 mol/L HCl(aq) and 50.0 mL of 1.00 mol/L
NaOH(aq) are mixed in a Styrofoam cup calorimeter, the temperature
of the resulting solution increases from 21.0°C to 27.5°C. Students
could calculate the heat of this reaction (measured in kilojoules per
mole of HCl(aq)). (324-2, 324-3)
Enthalpy Change
H2O(l)
Reaction Coordinate
Enthalpy Change
Presentation
• Students could explain the difference in the energies of reactants
and products with reference to a given thermochemical equation.
(324-2)
Journal
• Students could analyze the following: “As a living person, my energy
exchange position is exothermic.” Discuss this statement. (324-3,
324-5, 214-3)
• Fire in a fireplace is started by lighting crumpled paper under logs MGH Chemistry, pp. 639-641
with a match. Students could explain the energy transfers using
the terms potential energy, kinetic energy, kindling temperature,
system surroundings, endothermic, and exothermic. (324-3, 213-6,
213-7)
Presentation
• Students could explain the energy changes in situations such as:
(i) when a frozen pond melts, the surrounding air
temperature drops
(ii) a layer of ice may form on a propane cylinder while it is
being used
(iii) why vineyards in Ontario spray their crops with water if a
frost warning is issued. (324-3)
Thermochemical Equations
– calculate the ∆H for a ∆H values can be determined experimentally using calorimetry similar to
system, given the mass of a the method and calculations used previously to determine specific heat. The
reactant (or vice versa) energy lost or gained by the chemical reaction or phase change (qsystem) is
now calculated using the formula qsystem = n∆H . This energy normally
warms or cools some substance in the calorimeter, usually water or the
calorimeter and its contents. See CORE LAB #6.
Thermochemical Equations
Performance
• With a partner, students could design a lab to calculate the molar
heat of solution of NH4Cl and of NaOH. They should include
safety issues that should be addressed. After their plan is
approved, they should carry out their procedure and collect
evidence (data) and report their findings. (212-3, 215-6, 212-8, MGH Chemistry, pp. 671-672,
324-2, 324-3) p. 832
• Students could select and use appropriate equipment to make an
inexpensive hand warmer. (Hint: Use these substances: powdered
iron; H2O; NaCl; and vermiculite.) They should design their
experiment and consider safety precautions. If approval is
obtained, they could do this experiment. A teacher or student could
test the results. (212-3, 215-6, 212-8, 324-2)
– use heating and cooling Re-emphasize here that changes of temperature always involve a change in
curves to represent and EK whereas changes of state always involve a change in EP . Changes in EP are
explain changes in often more difficult for students to understand than changes in EK. One
potential energy and way to demonstrate this change in EP is to make a saturated solution of
kinetic energy of a system sodium thiosulfate (10 mL); let it cool to room temperature to form a
supersaturated solution; then add a crystal of sodium thiosulfate. The
resulting rapid crystallization of the excess sodium thiosulfate releases a large
amount of energy (an obvious conversion of potential energy to kinetic
energy). Ask students to feel the test tube before and after. Another way to
emphasize this concept is to generate discussion around issues such as the
following:
1. Why does steam at 100oC give you a much more severe burn than
water at 100oC ?
2. If you are lost in the woods in winter and you are thirsty, why should you
drink water from a stream rather than eating snow or ice to help prevent
hypothermia ?
– calculate the total heat for a In solving these problems, the energy units involving temperature
multi-step process that change ( mc∆T ) are generally in joules whereas the units for phase
includes a temperature and change ( n∆H ) are generally in kilojoules. Students often forget to convert
phase change to one common unit before adding to get the total energy.
Presentation
• Students could present their project using multimedia,
audiovisual, or other suitable format. They should present their
scenario to the class. The following questions might be helpful
with their thinking:
MGH Chemistry, pp. 692, 694,
– What are the characteristics of a good chemical fuel? 695, 699, 701
– What makes your fuel a good choice?
– What is the most common method of producing your fuel?
– What are some advantages of your fuel? Some disadvantages? MGH Chemistry, pp. 692-693
– Outline the process of your fuel’s development.
– What energy efficiency does your fuel have according to industry?
– What impact will the fuel have on the local environment?
(117-6, 118-2, 118-8, 118-10, 324-7, 117-9)
Hess’s Law
Hess’s Law
Performance
• Students could demonstrate correct use of chemical disposal while
doing a Hess’s Law lab. (324-4, 214-6, 116-4)
MGH Chemistry, pp. 677-678
Paper and Pencil
• Given the following reactions and ∆H values:
2NH3(g) + 3N2O(g) → 4N2(g) + 3H2O(l) ∆H = –1012kJ
2N2O(g) → 2N2(g) + O2(g) ∆H =–164kJ
Students could calculate ∆H , using Hess’s Law for
4NH3(g) + 3O2(g) → 2N2(g) + 6H2O(l) (324-4) MGH Chemistry, pp. 678-681,
• From their knowledge of standard states and from an enthalpy of p. 832
formation chart, students could list the standard enthalpy of
formation of each of the following substances: (324-4)
a) Cl2(g) c) C3H6(g) e) H2O(g)
b) H2O(l) d) Na(s) f ) P4(g) MGH Chemistry, pp. 648-687,
• Students could calculate ∆H for the following reaction: p. 832
2C3H6(g) +9O2(g) → 6CO2(g) + 6H2O(l) (324-4)
• Students could calculate the heat of formation, ∆Hf , of NO2.
N2(g) + 2O2(g) → 2NO2(g) ∆H =+16.2kJ (324-4)
• Hydrazine, N2H4(g), is used as a fuel in liquid-fuelled rockets. It
can react with O2(g) or N2O4(g) both producing N2(g) and H2O(g).
Students could write balanced chemical equations for the two
reactions. They should calculate ∆H for each reaction, using MGH Chemistry, p. 686
information from an enthalpy table and compare the values. Students
could then determine which is the more efficient rocket fuel. (324-4)
Bond Energy
Bond Energy