Cara Perhitungan :

Volume rata-rata basa NaOH = (vol.percobaan 1 + vol. Percobaan 2) / 2

= (19 + 20) / 2
= 19,5 mL

Va x Ma x val.asam = Vb x Mb x val.basa
25 mL x 0,1 M x 1 = 21 x Mb x val.basa
2,5 = 21 Mb
Mb = 0,11

a. 0,0 mL
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 0,0 x mol NaOH = 0 x 0,11 M = 0 mmol
HCl + NaOH  NaCl + H2O
M 2,5 0 - -
R 00
S 2,5
[H+] = mol asam / total volume HCl dan NaOH = 2,5 / (25+0) = 0,1 =10-1
pH =– log 10-1 = 1

b. 10,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 10,0 x mol NaOH = 10,0 x 0,11 M = 1,1 mmol
HCl + NaOH  NaCl + H2O
M 2,5 1,1 - -
R 1,11.1
S 1,4
[H+] = mol asam / total volume HCl dan NaOH = 1,4 / (25+10) = 0,04= 4 x 10-2
pH = - log 4 x 10-2 = 2 – log 4
= 1,4

c. 15,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 15,0 x mol NaOH = 15,0x 0,11 M = 0,021 mmol
HCl + NaOH  NaCl + H2O
M 2,5 1,65 - -
R 1,65 1,65
S 0,85 0

[H+] = mol asam / total volume HCl dan NaOH = 0,85 / (25+40) = 0,021 = 2,1 x 10-2
pH = - log 2,1 x 10-2 = 2 – log 2,1
= 1,68
d. 20,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 20,0 x mol NaOH = 20,0 x 0,11 M = 2,2 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,2 - -
R 2,2 2,2
S 0,3 0
[H ] = mol asam / total volume HCl dan NaOH = 0,3 / (25+20) = 0,0066 = 6,6 x 10-3
+

pH = - log 6,6 x 10-3 = 3 – log 6,6

= 2,18

e. 21,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 24,9 x mol NaOH = 21,0 x 0,11 M = 2,31 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,31 - -
R 2,312,31
S 0,190
[H+] = mol asam / total volume HCl dan NaOH = 0,19 / (25+21) = 0,0019 = 1,9 x 10-3
pH = - log 1,9 x 10-3 = 3 – log 1,9
= 2,39

f. 22,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 22,0 x mol NaOH = 22,0 x 0,11 M = 2, mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,42 - -
R 2,42 2,42
S 0,08 0
[H+] = mol asam / total volume HCl dan NaOH = 0,08 / (25+22) = 0,008 = 8 x 10-3
pH = - log 8 x 10-3 = 3 – log 8
= 2,77
g. 23,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 23 x mol NaOH = 23,0 x 0,11 M = 2,53 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,53 - -
R 2,5 2,5
S 0 0,03
[OH ] = mol basa/total volume HCl dan NaOH = 0,03/ (25+23) = 0,00625 = 6,25 x 10-3
-

pOH = - log 6,52 x 10-3 = 3 – log 6,25

pH = 14 – (3 – log 6,25) = 11 + log 6,25
= 10,8
h. 24,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 24 x mol NaOH = 24,0 x 0,11 M = 2,53 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,64 - -
R 2,5 2,5
S 0 0,14
[OH ] = mol basa/total volume HCl dan NaOH = 0,14/ (25+24) = 0,00286 = 2,86 x 10-3
-

pOH = - log 2,86 x 10-3 = 3 – log 2,86

pH = 14 – (3 – log 2,86) = 11 + log 2,86
= 11,45
i. 24,5
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 24,5 x mol NaOH = 24,5 x 0,11 M = 2,695 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2, 695 - -
R 2,5 2,5
S 0 0,195
[OH ] = mol basa/total volume HCl dan NaOH=0,03/(25+24,5) = 0,00195 = 1,95 x 10-3
-

pOH = - log 1,95 x 10-3 = 3 – log 1,95

pH = 14 – (3 – log 1,95) = 11 + log 1,95
= 11,6

j. 24,9
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 24,9 x mol NaOH = 24,9 x 0,11 M = 2,739 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,739 - -
R 2,5 2,5
S 0 0,239
[OH-] = mol basa/total volume HCl dan NaOH = 0,03/ (25+24,9) = 0,00479 = 4,79 x
10-3
pOH = - log 4,79 x 10-3 = 3 – log 4,79
pH = 14 – (3 – log 4,79) = 11 + log 4,79
= 11,68
k. 25,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 25,0x mol NaOH = 25,0 x 0,11 M = 2,75 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,75 - -
R 2,5 2,5
S 0 0,25
[OH ] = mol basa/total volume HCl dan NaOH = 0,25/ (25+25) = 0,005 = 5 x 10-3
-
 pOH = - log 5 x 10-3 = 3 – log 5
pH = 14 – (3 – log 5) = 11 + log 5
= 11,7
l. 25,1
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 25,1 x mol NaOH = 25,1 x 0,11 M = 2,761 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,761 - -
R 2,5 2,5
S 0 0,261
-
[OH ] = mol basa/total volume HCl dan NaOH = 0,03/ (25+25,1) = 0,00521 = 5,21 x
10-3
pOH = - log 5,21 x 10-3 = 3 – log 5,21
pH = 14 – (3 – log 5,21) = 11 + log 5,21
= 11,71
m. 25,5
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 25,5 x mol NaOH = 25,5 x 0,11 M = 2,855 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,855 - -
R 2,5 2,5
S 0 0,305
[OH-] = mol basa/total volume HCl dan NaOH = 0,305/ (25+25,5) = 0,00604 = 6,04 x
10-3
pOH = - log 6,04 x 10-3 = 3 – log 6,04
pH = 14 – (3 – log 6,04) = 11 + log 6,04
= 11,79
n. 26,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 26 x mol NaOH = 26,0 x 0,11 M = 2,86 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,86 - -
R 2,5 2,5
S 0 0,36
[OH ] = mol basa/total volume HCl dan NaOH = 0,36/ (25+26) = 0,00706 = 7,06 x 10-3
-

pOH = - log 7,06 x 10-3 = 3 – log 7,06

pH = 14 – (3 – log 7,06) = 11 + log 7,06
= 11,85
o. 27,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 27 x mol NaOH = 27,0 x 0,11 M = 2,97 mmol
HCl + NaOH  NaCl + H2O
M 2,5 2,97 - -
 R 2,5 2,5
S 0 0,47
[OH ] = mol basa/total volume HCl dan NaOH = 0,47/ (25+27) = 0,00904 = 9,04 x 10-3
-

pOH = - log 9,04 x 10-3 = 3 – log 9,04

pH = 14 – (3 – log 9,04) = 11 + log 9,04
= 11,95
p. 28,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 28 x mol NaOH = 28,0 x 0,11 M = 3,08 mmol
HCl + NaOH  NaCl + H2O
M 2,5 3,09 - -
R 2,5 2,5
S 0 0,58
[OH ] = mol basa/total volume HCl dan NaOH = 0,58/ (25+28) = 0,011 = 1,1 x 10-2
-

pOH = - log 1,1 x 10-2 = 2 – log 1,1

pH = 14 – (2 – log 1,1) = 12 + log 1,1
= 12,04
q. 29,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 29 x mol NaOH = 29,0 x 0,11 M = 3,19 mmol
HCl + NaOH  NaCl + H2O
M 2,5 3,19 - -
R 2,5 2,5
S 0 0,69
[OH ] = mol basa/total volume HCl dan NaOH = 0,69/ (25+29) = 0,013 = 1,3 x 10-2
-

pOH = - log 1,3 x 10-2 = 2 – log 1,3

pH = 14 – (2 – log 1,3) = 12 + log 1,3
= 12,11
r. 30,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 30 x mol NaOH = 30,0 x 0,11 M = 3,3 mmol
HCl + NaOH  NaCl + H2O
M 2,5 3,3 - -
R 2,5 2,5
S 0 0,8
[OH ] = mol basa/total volume HCl dan NaOH = 0,8/ (25+30) = 0,014 = 1,4 x 10 -2
-

pOH = - log 1,4 x 10-2 = 2 – log 1,4

pH = 14 – (2 – log 1,4) = 12 + log 1,4
= 12,14
s. 35,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 35 x mol NaOH = 35,0 x 0,11 M = 3,85 mmol
HCl + NaOH  NaCl + H2O
 M 2,5 3,85 - -
R 2,5 2,5
S 0 1,35
[OH-] = mol basa/total volume HCl dan NaOH = 1,35/ (25+35) = 0,0135 = 1,35 x 10 -2
pOH = - log 1,35 x 10-2 = 2 – log 1,35
pH = 14 – (2 – log 1,35) = 12 + log 1,35
= 12,38
t. 40,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 40 x mol NaOH = 40,0 x 0,11 M = 4,4 mmol
HCl + NaOH  NaCl + H2O
M 2,5 4,4 - -
R 2,5 2,5
S 0 1,9
[OH-] = mol basa/total volume HCl dan NaOH = 1,9/ (25+40) = 0,03 = 3 x 10-2
pOH = - log 3 x 10-2 = 2 – log 3
pH = 14 – (2 – log 1,35) = 12 + log 3
= 12,5
u. 45,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 45 x mol NaOH = 45,0 x 0,11 M = 3,85 mmol
HCl + NaOH  NaCl + H2O
M 2,5 4,95 - -
R 2,5 2,5
S 0 2,45
[OH-] = mol basa/total volume HCl dan NaOH = 2,45/ (25+45) = 0,035 = 3,5 x 10-2
pOH = - log 3,5 x 10-2 = 2 – log 3,5
pH = 14 – (2 – log 3,5) = 12 + log 3,5
= 12,54
v. 50,0
n HCl = vol HCL x mol HCl = 25 mL x 0,1 M = 2,5 mmol
n NaOH = vol NaOH x mol HCl
= 50 x mol NaOH = 50,0 x 0,11 M = 5,5 mmol
HCl + NaOH  NaCl + H2O
M 2,5 5,5 - -
R 2,5 2,5
S 0 3
[OH-] = mol basa/total volume HCl dan NaOH = 3/ (25+50) = 0,04 = 4 x 10-2
pOH = - log 4 x 10-2 = 2 – log 4
pH = 14 – (2 – log 4) = 12 + log 4
= 12,6