Beruflich Dokumente
Kultur Dokumente
O-LEVEL 2006-2010
(May not be taken with 500 General science)
Introduction
This syllabus is designed to meet the needs of those carrying on to “A” level Chemistry
and those leaving school after senior 4 (or UCE). Although a good deal of the content
will be familiar to teachers, the treatment must be based on practical situations whenever
possible. A large portion of the examination questions will demand knowledge and
understanding of practical situations. Candidates will be at a considerable disadvantage if
the teacher has not adopted an approach based on practical work.
The course has been broadly divided into two parts. The first part, Elementary
Chemistry, can be viewed as a complete two-year introductory course in Chemistry. It
should form the basis for UCE Chemistry. The second part for years 3 and 4, constitutes a
deeper, more theoretical treatment of the topics introduced in Elementary Chemistry.
SI units and chemical formulae or names as specified in the ‘UNEB SI’ booklet
and “Chemical Nomenclature’ booklet respectively will be used. Alternative names of
substances will be given wherever ambiguity might otherwise arise. Two areas of subject
matter are worth noting:
Aims:
i. To help students to appreciate the importance and application of Chemistry in
every day life.
ii. To assist a student to learn how to think critically in any given learning situation.
iii. To guide a student to discover knowledge, from known to unknown, using a
practical approach.
iv. To relate and to be able to apply the discovered knowledge in every day life.
Testable objectives:
It should be noted that each section of subject matter is preceded by a statement of the
specific objectives associated with the section. The section objectives should be regarded
as being examinable. They can be conveniently expressed in the more general form
outlined below. The detailed breakdown given under the three main headings is given as
amplification.
There is no suggestion that such clear distinctions can always be made in constructing
examination questions.
1. Knowledge.
a) Knowledge of chemical terminology and conventions.
b) Knowledge of a variety of experimental methods from work in the laboratory,
from demonstration on films, to provide experience of techniques, of equipment
and of observation.
c) Knowledge of the main facts that have been established.
d) Knowledge of the main generalizations that have been made and of the theories
that are widely held.
Note: abilities-‘recall’, ‘state’, ‘recognise’, ‘name’, ‘define’, fall in the above categories.
Note: Abilities- ‘explain’, ‘interpret’, ‘predict’, ‘judge’, ‘classify’, fall in the above
categories.
3. Practical abilities
(a) The ability to apply the above knowledge and abilities to practical situations.
(b) The ability to handle apparatus and perform experiments in given situations.
(c) The ability to make accurate observations.
(d) The ability to devise simple experiments.
(e) The ability to record results accurately and present data in an appropriate
form.
(f) The ability to make correct deductions from observations.
Examination format:
There will be three papers.
Paper 1 (1 ½ hours)
This will consist of 50 compulsory objective type questions covering the whole syllabus.
(50 marks)
Paper 2 (2 hours)
This will consist of two sections, A and B. section A will consist of ten compulsory
structured questions requiring short answers.
Section B will consist of four structured and semi-structured essay questions. Candidates
will be required to answer two. In both sections questions will be set on any part of the
syllabus. (80 marks)
Paper 3 (2 hours)
This will be a practical test designed to test the abilities specified above.
Questions may be set on any section of the syllabus. (30 marks)
Detailed syllabus:
A feature of the syllabus is that the specific objectives of each section are indicated.
These statements are designed to: (i) indicate the depth of treatment to be given by the
teacher and (ii) indicate the level of understanding to be attained by the pupils.
Since some topics may be treated in an elementary manner early in the course and then in
more depth later, teachers must read the section objectives carefully to ascertain the
treatment. For example terms such as ‘recall’, ‘state’, ‘name’, demand low-level abilities,
while ‘explain’, ‘predict’, ‘demonstrate’, ‘analyse’, etc. demand higher-level abilities.
Note: many of the objectives specified for section 1 will be common for other sections of
the Elementary Chemistry Course. Teachers should bear in mind when teaching other
sections’ objectives in Elementary Chemistry.
Content:
1.1 Mixtures and pure substances: separation of mixtures. Miscible and immiscible
liquids, distillation, crystallisation, paper chromatography. Methods of gas
collection, drying of solids, liquids and gases. Simple criteria of purity, melting-
point and boiling-point.
1.2 Heating substances:
States of matter, melting and boiling, simple kinetic (particle) theory (see 9.1);
atoms and molecules; definitions of element and compound; permanent and non-
permanent changes (using iodine, wax, copper (II) sulphate crystals, sand, copper
(II) nitrate, potassium manganate (VII), and zinc oxide). Test for water of
crystallisation.
2.2 Oxygen
Laboratory preparation (prepared by hydrogen peroxide with manganese (IV) oxide or
sodium peroxide with water); combustion of elements in oxygen; uses.
Competition for oxygen: reactivity series K, Na, Ca, Mg, Al, C, Zn illustrate with CO2
/Mg, PbO/Mg. Experiments carried out on a ‘bottle top’. Take care.
Content
Flower extracts as simple indicators. Universal indicator, pH scale. Acidic, neutral and
basic/alkaline solutions. Simple properties of mineral acids. Test solutions: NH4CI,
(NH4 ) 2 SO4, NH3 (aq), NaCI, NaOH, CO2 (aq), SO2 (aq), H2 SO4 (aq), HNO3 (aq),CH3
COONa, NaHCO3, Ca(OH)2, MgO.
Section 4: Water and Hydrogen
Objective
At the end of this topic students should be able to:
1. Explain the experiments showing that water contains hydrogen.
2. State the products of the reaction of water and steam with different metals.
3. List the reactivity series obtained from metal/water reactions.
4. Recall the preparation and test for hydrogen.
5. Define oxidation and reduction as gain/removal of oxygen.
6. Explain metal oxide/hydrogen reaction in terms of this definition.
Content
Burning of organic matter (energy source). Water as oxide of hydrogen. Reactions of
metals with water/steam. Burning hydrogen in air. (Burn candle in air, test for CO2 and
H2O vapour, Na, Ca, Mg with water and Mg, Zn, Fe with steam).
Metals and dilute acids:
Preparation and test for hydrogen, oxidation and reduction (oxygen gain/removal
only). Metal oxide (use copper (II) oxide, hydrogen reduction (see 16.3)
Melts: PbBr2.
Electrolytes contain ions, non-electrolytes contain molecules. Avoid solutions where
water could interfere: use CuCl2, HCl, PbBr2.
Content
Evidence of existence of atoms, molecules, ions and electrons; effect of heat and
electricity on elements and compounds; Brownian movement; diffusion experiments;
qualitative relationship between diffusion rate and density.
Use bromine, copper (II) sulphate crystals/water as illustrations. Effect of density on
ammonia and hydrogen chloride diffusion.
Use of kinetic theory to explain nature of solids, liquids and gases. Diffusion of gases,
evaporation of liquids, dissolving solute in solvent. Qualitative explanation of Boyle’s
law and Charles’ law for gases (no calculations to be set).
The mole as a basic unit (see revised UNEB ‘SI Units” booklet). Relative atomic mass.
The mole as a number of particles can be illustrated by ‘counting by weighing’
experiments.
Determination of formulae; ionic compounds, empirical and molecular formulae.
Quantitative determination of magnesium oxide (Mg/air) and copper (II) oxide (reduction
of copper (II) oxide with butane) should be carried out.
Molar gas volume (22.4 dm3 at S.T.P.); atomicity of gases; mass volume relationship for
gases. Molar solutions.
Stoichiometry of chemical reactions; quantitative work must be emphasised.
Reactions to be considered:
i. Ba2+ (aq) + CO
ii. Pb2+ (aq) + 2I‾ (aq) → PbI2 (s)
iii. Cu2+ (aq) + Fe (s) → Cu (s) + Fe 2+ (aq)
iv. CO2 evolution from Na2CO3 + HCl.
v. Titration of NaOH with HCl and H2SO4 recommended.
Use of ionic equations and full formulae equations (latter recommended) in the
calculation of reacting masses. (See 16.1).
Note: The use of full formulae equations and ionic equations should be emphasised
henceforth.
Section 10: Atomic and Molecular Structure: Chemical Bonding.
Objectives
At the end of this topic students should be able to:
1. Recognise the importance of the outer electrons in chemical bonding.
2. Explain in a qualitative way the energetics of covalent and ionic formation.
3. Represent the covalent and ionic bonds in simple compounds by electron
sharing and transfer respectively.
4. Differentiate between different bond types on the basis of their chemical and
physical properties.
5. Demonstrate the changes in bond type within the groups and periods of the
Periodic Table
Content
10.1 The significance of the outer electrons in chemical bonding. Qualitative treatment
of the energetics of chemical bonding. Consider the molecules in terms of a
position of balance between p-p, e-e repulsions, and p-e attraction (the ionic bond
as an extreme example).
10.2 Significance of the noble gas configuration; covalent bond as electrons sharing;
ionic bond as electron-transfer. Consideration of C-C and C=C (see 11.5)
10.3 Influence of bond type on physical and chemical properties (melting point,
solubility and electrical conductivity).
Molecular, giant atomic and giant ionic structures (iodine, carbon (diamond), and
sodium chloride respectively.
10.4 Metallic bond related to electrical conductivity only.
10.5 Periodic of bond type.
Elements Na, Mg, Al, Si,S,Cl, Ar: their electronic structures, their ions (valency),
mode of combination in oxide and chloride; inertness of noble gases; chemical
and physical properties of metals and non-metals (across a period).
Elements: fluorine, chlorine, bromine and iodine (down group). Electronic
configuration, graduation in size of atom and ion, reactions, (see 8.3).
Elements: Li, Na, K (as above including ease of oxidation, reaction with water,
chlorine). (See 8.1)
Section 11: Carbon Chemistry
Objectives
At the end of this topic students should be able to:
1. Explain the physical properties of the carbon allotropes in terms of the
bonding.
2. Recall the preparation and properties of carbon dioxide.
3. State the chemical reactions of carbonates and hydrogen carbonates.
4. Recognise the importance of carbon compounds in the natural
environment and industry.
Content
11.1 Diamond and graphite (note charcoals)
Structure and physical properties.
11.2 Carbon monoxide
Combustion, reducing action, poisonous fumes (car exhausts, coke fire “sigiri”).
Laboratory preparation not required (see 19.1).
Reducing action illustrated with copper (II) oxide + blast furnace. (See extraction
of ion 19.4).
11.3 Carbon dioxide
Preparation, reaction with water, limewater.
Weathering, boiler ‘scale’; no detailed treatment of hard water.
11.4 Carbonate and hydrocarbonates
Action of heat, dilute acids.
Production of soda ash (Lake Magadi). (See 19.4d)
Carbon and carbon dioxide cycles. (See equilibration of atmosphere 19.1)
11.5 Alkanes (methane to butane)
Formulae and combustion only.
Natural gas.
Paraffin wax.
Ethane: formulae and combustion. (See combustion of fuels, 19.1).
Preparation of ethane by dehydration of ethanol: reaction with bromine (see 10.2)
Note: a detailed study of the organic chemistry of alkanes, alkenes, alkanols etc. is not
required.
Section 12: Nitrogen
Objectives
At the end of this topic students should be able to:
1. Recognise the unreactive nature of nitrogen in comparison with oxygen.
2. Recall the laboratory preparation of ammonia and list its properties.
3. Recognise the difference in chemical reactions of ammonia gas and its aqueous
solution.
4. Recall the reactions of both dilute and concentrated nitric acid and recognise the
difference between their chemical action.
5. Name the products when different metal nitrates are heated.
Content
12.1 Nitrogen
Inert character. Compare combustion of Na, Ca, P, S, in N2 andO2.
(See 19.1 Industrial solution of component of air).
12.2 Ammonia
Laboratory preparation, solubility in water, reaction with air/oxygen (catalysed
and uncatalysed), copper (II) oxide and chlorine. Reactions of aqueous solution:
metal ions, dilute acids.
Manufacture of ammonia (Haber process). (See 19.4 (a))
Ammonium salts as fertilizers. (See 19.2).
12.3 Nitric Acid
Dilute: reaction with metals, carbonates, hydroxides, oxides.
Concentrated: oxidizing action; Fe (II) solution, sulphur, copper metal.
Nitrates: action of heat (Na, K, Cu, Pb, Ag).
Acidic nature of nitrogen (IV) oxide. (See 19.4)
Manufacture of nitric acid (see 19.4(b))
Section 13: Sulphur
Objectives
At the end of this topic students should be able to:
1. Recall the preparation of sulphur dioxide and state its properties and uses.
2. Recall the preparation and properties of dilute sulphuric acid.
3. Illustrate the difference in chemical action between dilute and concentrated
sulphuric acid.
4. Recognise the atmospheric pollution caused by sulphur containing compounds.
Content
13.1 Sulphur dioxide
Preparation (Sulphite +Acid), acid character, bleaching action, test with potassium
dichromate (IV)
Reducing action is not required.
Combination with oxygen (laboratory demonstration, Pt. Catalyst).
13.2 Sulphuric acid
Dilute: reaction with metals carbonates and bases.
Concentrated: dilution with water, copper (II) sulphate crystals, ethanol, sucrose.
Test for sulphate: barium nitrate solution.
Manufacture of sulphuric acid (Contact process). (See 19.4(c)).
13.3 Hydrogen sulphide (iron (II) sulphide and acid).
‘Bad eggs’ smell.
Pollution by S, SO2, H2S. (See 19.1 The atmosphere.)
Section 15: Acids and Bases (Acidity and Alkalinity) (See section 3)
Objectives
At the end of this topic students should be able to:
1. Define acids as proton donors and bases as proton acceptors.
2. Recognise the difference between weak and strong acids and bases.
3. Explain the role of the solvent in the acidity of hydrogen chloride.
4. Write ionic and formula equations for specified acid-base reactions.
Content
15.1 Weak and strong acids.
PH, electrical conductivity, rate of reaction with marble chips, magnesium, for
acids and bases. (Use hydrochloric/ethanoic and sodium hydroxide, aqueous
ammonia as illustration.).
Note: other examples are tartaric and citric acids instead of HCI.
15.3 Acids (proton donors), bases (proton acceptors). Use of ionic equations.
15.4 Amphoteric oxides (Al2O3, PbO, ZnO): react with acid and alkali (no equations
for reaction with alkali).
Content
16.1 Precipitation reactions involving the following ions:
Mg2+ (aq), Ca2+ (aq), Fe3+ (aq), Al3+ (aq), Zn2+ (aq), Cu2+ (aq), Fe2+(aq),
with Cl–(aq), OH–(aq), CO
(See 9.7)
16.2 Complex ions: limited to dissolving of specific metal hydroxides in excess
ammonia solution or sodium hydroxides. Formula of the following required:
Cu (NH3)2+ Pb(OH)2–, Al(OH).
Note: No instructions on equations required.
16.3 Redox reactions.
Electron transfer.
Useful illustrations Fe2+, Fe3+ (with 2 – (aq) H2O2/ H+ )
3
Content
17.1 Molar heat of vaporization and boiling-point (latent heats). As evidence for
interparticle forces.
Enthalpy notation (ΔH) for exo and endo-thermic reactions.
17.2 Enthalpy chemical reactions
Students should carry out simple quantitative work (See 15.1), e.g. enthalpy of
combustion (methanol, ethanol), enthalpy of displacement (Cu2+ (aq) + Fe (s))
(see 16.3); enthalpy of solution (NH4NO3, NaOH, and conc. H2SO4) (see the
combustion of fuel and the internal combustion engine 19.1).
17.3 Electrochemical cell
Qualitative look at the electrochemical series.
Students can use copper reference, sodium chloride electrolyte and metal strip
electrodes.
Zn-Cu cell: teacher demonstration and measurement of potential difference.
The potential E is not required (see 19.1).
17.4 Simple treatment of solar energy as energy from atoms.