Jee Mains - 1

SECTION I : PHYSICS
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
1. An ideal gas is at absolute temperature T. Temperature coefficient of volume expansion for an

isobaric process is
2 1 1
(A) (B) (C) 2 (D) None
T T T
2. The potential difference between points A and B is
(A) 0 V (B) 6 V (C) 3 V (D) 9 V
3. Two uniformly charged non-conducting hemispherical shells each having uniform charge density 
and radius R form a complete sphere (not stuck together) and surround a concentric spherical
conducting shell of radius R/2. If hemispherical parts are in equilibrium then minimum surface
charge density of inner conducting shell is
(A) 2 (B) 2 (C)  (D)  / 2
4. An electromagnetic wave going through vacuum is described by

E  E0 sin(kx  t ) ; B  B0 sin(kx  t ) , then
(A) E0 k  B0 (B) E0 B0   k (C) E0  B0 k (D) None
5. A spring-block system undergoes simple harmonic motion on a

smooth horizontal surface. The block is now given some positive
charge, and uniform horizontal electric field to the right is
switched on. As a result,
(A) the time period of oscillation will increase
(B) the time period of oscillation will decrease
(C) the time period of oscillation will remain unaffected
(D) the mean position of simple harmonic motion will shift to the left
6. A point source causes photoelectric effect from a small metal

plate. Which of the curves may represent the saturation
photocurrent as a function of distance between the source and
the metal?
(A) a (B) b (C) c (D) d
7. Two parallel long straight conductors lie on a smooth surface. Two other parallel conductors rest on
them at right angles so as to form a square of side a initially. A uniform magnetic field B exists at
right angles to the plane containing the conductors. Each wire starts moving with a constant velocity
v perpendicular to its length increasing the size of the square uniformly. If r is the resistance per unit
length of the wire, the current in the circuit will be
4Bv 2Bv Bv Bv
(A) (B) (C) (D)
r r 2r r
8. Two stars of mass M and 5M, which are at a distance L apart rotate about their centre of mass due to
mutual gravitational attraction. The time of one rotation is
L
M
5M
L3 L3 3L3
(A) 2 (B) 2 (C) 2 (D) None
3GM 6GM GM
9. In the P-V diagram shown in figure ABC is a semicircle. The work done by the gas in the process
ABC is
 
(A) Zero (B) (atm  l ) (C)  (atm  l ) (D) 4(atm  l )
2 2
10. Two waves having intensities in the ratio 25:4 produce interference. The ratio of maximum to
minimum intensity is
(A) 49 : 9 (B) 5 : 2 (C) 7 : 3 (D) 7 : 4
11. The energy radiated by a black body at 2300K is found to have the maximum at a wavelength 1260
nm, its emissive power being 8000 Wm-2. When the body is cooled to a temperature T K, the
emissive power is found to decrease to 500 Wm-2. Find the temperature T
(A) 1200K (B) 1350K (C) 1050K (D) 1150K
Head Office: ANDHERI : MUMBAI / NASHIK / AKOLA / DELHI / KOLKATA / LUCKNOW/ GOA
12. A body A is thrown vertically upwards with such a velocity that it reaches a maximum height of h.
Simultaneously another body B is dropped from height h. It strikes the ground and does not rebound.
The velocity of A relative to B v/s time graph is best represented by: (upward direction is positive)
13. The current from the battery in circuit diagram shown is

(A) 1 A (B) 2 A
(C) 1.5 A (D) 3 A
14. Two resistances R1   3.0  0.1  and R2   6.0  0.2   are to be joined together.
(A) The maximum resistance obtainable is  9.0  0.2  
(B) The maximum resistance obtainable is  9.0  0.1 
(C) The minimum resistance obtainable is  2.0  0.3 
(D) The minimum resistance obtainable is  2.0  0.07  
15. Two particles are fired from the same point at same time, with speeds 100 m/sec and 100 m/sec, and
firing angles with horizontal = 60o and 120 o respectively. The time after which their velocity vectors
become perpendicular to each other, is [ g =10 m/s2]
(A) 5 sec (B) 5  
3  1 sec (C) 5 3 sec (D) 5 3 / 2 sec
16. Yellow light is used in a single slit diffraction experiment with slit width of 0.6 mm. If yellow light
is replaced by X-rays, then the observed pattern will reveal
(A) that the cental maximum is narrower (B) more number of fringes
(C) less number of fringes (D) no diffraction pattern
17. A plastic circular disc of radius R is placed on a thin oil film, spread over a flat horizontal surface.
The torque required to spin the disc about its central vertical axis with a constant angular velocity is
proportional to
(A) R2 (B) R3 (C) R4 (D) R6
18. A metal ring of radius r = 0.5 m with its plane normal to a uniform magnetic field B of induction 0.2
Tesla carries a current I = 100 A. The tension in newtons developed in the ring is
(A) 100 N (B) 50 N (C) 25 N (D) 10 N
19. In a transistor,
(A) The emitter has the least concentration of impurity
(B) The collector has the least concentration of impurity
(C) The base has the least concentration of impurity
(D) All the three regions have equal concentrations of impurity
20. Statement-1: If a convex lens is placed in liquid, it can behave as diverging lens.
Statement-2: The focal length of a lens is independent of the refractive index of the material of the
lens.
(A) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement 1
(B) Statement1 is True, Statement2 is True; Statement2 is NOT a correct explanation for Statement 1
(C) Statement 1is True, Statement 2 is False,
(D) Statement 1 is False, Statement -2 is True
21. Half-life of a radioactive substance A is two times the half-life of another radioactive substance B.
Initially the number of nuclei of A and B are N A and NB respectively. After three half lives of A
number of nuclei of both are equal. Then the ratio NA/NB is:
(A) 1/4 (B) 1/8 (C) 1/3 (D) 1/6
22. A vessel containing a liquid is heated with its contents. The pressure at the bottom of vessel due to
the liquid (No evaporation and no spilling takes place)
(A) increase (B) decrease
(C) increase if  liq  3 vessel (D)decrease if  liq  3 vessel
23. A particle of mass m moves along a circle of radius R with a normal acceleration varying with time
as an = kt4 where k is a constant. The average value of the power over the first t seconds after the
beginning of the motion will be
mkRt mkRt 3
(A) zero (B) (C) (D) none
2 2
24. A cylinder is pure rolling up an incline plane. It stops momentarily and then rolls back. The force of
friction
(A) on the cylinder is zero throughout the journey
(B) is directed opposite to the velocity of the centre of mass throughout the journey
(C) is directed up the plane throughout the journey
(D) is directed down the plane throughout the journey
25. In an experiment of resonance tube to measure the velocity of sound, first resonance occurs at
l =10cm from the open end of the tube. End correction of the tube is 1.0cm and the frequency of
tuning fork is 700Hz.
(I) Velocity of sound is 308m/s
(II) Next resonance will occur at l = 32cm from the open end of the tube
(III) Radius of resonance tube is 1.67cm
The correct statement is/are
(A) I, II (B) I, III (C) II, III (D) I. II. III
26. The focal length of the objective lens of a compound microscope

(A) Equal to the focal length of its eye piece
(B) Greater than the focal length of eye piece
(C) Less than the focal length of eye piece
(D) Any of the above three
27. A nucleus with mass number 220 initially at rest emits an α -particle. If the Q-value of the reaction is
5.5MeV, the kinetic energy of the α -particle is
(A) 4.4MeV (B) 5.4MeV (C) 5.6MeV (D) 6.5MeV
28. Two full turns of the circular scale of a screw gauge cover a distance of 1 mm on its main scale. The
total number of divisions on the circular scale is 50. Further, it is found that the screw gauge has a
zero error of − 0.03 mm while measuring the diameter of a thin wire, a student notes the main scale
reading of 3 mm and the number of circular scale divisions in line with the main scale as 35. The
diameter of the wire is
(A) 3.38 mm (B) 3.73 mm (C) 3.67 mm (D) 3.32 mm

29. The electric field intensity in a region is given by E   ( yiˆ  xjˆ ) V/m where x, y are in metres. The
shape of equipotential curves on X-Y plane is
(A) parallel lines making 45°with the positive X and Y axes.
(B) concurrent lines passing through the origin.
(C) concentric circles with origin as centre
(D) rectangular hyperbola
30. Statement 1: A charged particle cannot be accelerated by magnetic field.

Statement 2: Work done by magnetic field force on the moving charge particle is always zero.
(A) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement 1
(B) Statement 1 is True, Statement 2 isTrue; Statement 2 is NOT a correct explanation for Statement 1
(C) Statement 1is True, Statement 2 is False,
(D) Statement 1 is False, Statement -2 is True
SECTIONII : CHEMISTRY
This section contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONLY ONE is correct.
31.
S SO O
H H H
(1) (2) (3)
The correct order of acidity of the hydrogen’s represented above is

(A) (3) < (1) < (2) (B) (1) < (3) < (2) (C) (3) < (2) < (1) (D) (2) < (3) < (1)
32. How many stereoisomers can be formed by catalytic hydrogenation of both the double bonds in the
following compound?
H2
Ni
(A) (1) only (B) (2) only (C)(3) only (D) (4) only
R
N–NO2 Conc. H2SO4
33. ?Product of this reaction is?

NH2 NHR NHNO2
(A) (B) (C) (D) No reaction
NO2 NO2 R
34. A mixture of immiscible liquids (an organic liquid compound plus water) boils at 90ºC temperature.
The distillate contains 73% by weight of organic liquid. The molar mass of organic liquid (the vapor
pressure of water at 90ºC is 526 mm and organic liquid is 732 mm) is :
(A) 34.9 g (B) 134 g (C) 114 g (D) 104 g
35. 25 mL of a solution of Na2CO3 having a specific gravity of 1.25 g mL–1 required 32.9 mL of a
solution of HCl containing 109.5 g of the acid per litre for complete neutralization. Find the volume
of 0.84 N H2SO4 that will be completely neutralized by 125 g of Na2CO3 solution.
(A) 470 mL (B) 370 mL (C) 530 mL (D) 280 mL
36. Point out the false statement :

(A) Brownian movement and Tyndall effect is shown by colloidal systems.
(B) Gold number is a measure of the protective power of a lyophilic colloid.
(C) The colloidal solution of liquid in liquid is called gel.
(D) Hardy-Schulze rule is related with coagulation.
37. For the reactions,

(i) H 2 (g)  Cl 2 (g)  2HCl (g)  x kJ (ii) 2HCl (g)  H 2 (g)  Cl 2 (g)  y kJ
which one of the following statements is correct ?
(A) x  y  0 (B) x  y  0 (C) x  y  0 (D) None of these
38. Which of the following ions is responsible for the brown colour in the ring test for a nitrate?
(A) [Fe(H2O)5NO]2+ (B) [Fe(CN)5NO]2–
(C) [Fe(NO2)6]4– (D) [Fe(H2O)5NO2]+
39. When a nitrate is warmed with zinc powder and anNaOH solution, a gas is evolved. Which of the
following reagents will be turned brown by the gas?
(A) Sodium nitroprusside (B) Sodium cobaltinitrite
(C) Nessler’s reagent (D) Barium chloride
40. Pyridine is mixed with aqueous solution of NiSO4. NaNO2 solution is then added to mixture to get
dark blue precipitate ‘A’. Analysis show that A does not contain any SO 24 ion but produce three
ions per molecule A is
(A) Ni ( Py ) 2 ( NO 2 ) 2  (B) Ni (Py) 4   NO 2 2
(C) Ni (Py) 3 NO 2 2 SO 4 (D) Ni (Py) 4  SO 4
41. The following compounds have been arranged in order of their increasing thermal stabilities. Identify
the correct order :
I. K2CO3 II. MgCO3 III. CaCO3 IV. BeCO3
(A) I < II < III < IV (B) IV < II < III < I (C) IV < II < I < III (D) II < IV < III < I
42. CH3CHO + NH2OH   CH3CH = N – OH

The above reaction occurs satisfactorily at
(A) pH = 1 (B) pH = 4.5 (C) pH = 12 (D)any value of pH
43. The set with correct order of acidity is :

(A) HClO< HClO2< HClO3< HClO4 (B) HClO4< HClO3< HClO2<HClO
(C) HClO< HClO4< HClO3< HClO2 (D) HClO4< HClO2< HClO3<HClO
44. Of the following species, one which is non-existent :

(A) XeF6 (B) XeF5 (C) XeF4 (D) XeF2
45. Potassium hexachloroplatinateK2[PtCl6] adopts antifluorite crystal structure. Which of the following
ions adopts fcc arrangement?
(A) Cl– ions (B) K+ ions (C) Pt4+ ions (D) [PtCl6]2– ions
46. When an ideal diatomic gas is heated at constant pressure the fraction of the heat energy supplied
which increases the internal energy of the gas is:
(A) 2/5 (B) 3/5 (C) 3/7 (D) 5/7
47. Naturally occurring potassium consists of 0.01% K40, which has a half life of
1.28  10 9 yr. The activity of 1.0 g sample of KCl would be
(A) 8  10 17 yr1 (B) 4.37  108 yr1 (C) 5.42  1010 yr1 (D) 7.81  109 yr1
48. Two moles of an equimolar mixture of two alcohols, R1—OH and R2—OH are esterified with one
mole of acetic acid. If 80% of the acid is consumed and the quantities of ester formed under
equilibrium are in the ratio of 3:2, the value of the equilibrium constant for the esterification of R1—
OH with acetic acid is
(A) 3.3 (B) 3.7 (C) 3.5 (D) 3.9
49. Two systems PCl5(g) PCl3(g) + Cl2(g) and COCl2(g) CO(g) + Cl2(g) are
simultaneously in equilibrium in a vessel at constant volume. If some CO is introduced into the
vessel, then at the new equilibrium the concentration of
(A) PCl5 is greater (B) PCl3 remains unchanged
(C) PCl5 is less (D) Cl2 is greater
50. A real gas at a very high pressure occupies
(A) more volume than that of an ideal gas under identical conditions.
(B) less volume than that of an ideal gas under identical conditions.
(C) same volume than that of an ideal gas under identical conditions.
(D) can’t predict
51. A flask filled with CCl4 vapour was weighed at a temperature and pressure. The flask was then filled
with oxygen at the same temperature and pressure. The mass of CCl4 vapour would be about
(A) the same as that of the oxygen (B)onefifth as heavy as oxygen
(C) five times as heavy as oxygen (D) twice as heavy as oxygen
52. The frequency  of certain line of the Lyman series of the atomic spectrum of hydrogen satisfies the
following conditions:
(i) It is the sum of the frequencies of another Lyman line and a Balmer line.
(ii) It is the sum of the frequencies of a certain line, a Balmer line and a Paschen line.
(iii) It is the sum of the frequencies of a Lyman and a Paschen line but no Bracket line.
To what transition does corresponds?
(A)n2 = 3 to n1 = 1 (B) n2 = 3 to n1 = 2 (C) n2 = 2 to n1 = 1 (D) n2 = 4 to n1 = 1
53. A solution contains Na+, Sn2+, NO 3 , Cl and SO24  ions, all at unit concentration, is electrolyzed
between a silver anode and a platinum cathode. Which of the following change does not occur when
current is passed through the cell?
(A) Sn2+ will be oxidized to Sn4+ first, at the anode.
(B) Sn2+ will be reduced to Sn first, at the cathode.
(C) Cl will be oxidized to Cl2 first, at the anode.
(D) Ag will be oxidized to Ag+ next, at the anode.
54. Consider the following sequence of reactions.

O
HOCH2 .CH2OH 1. LiAlH4, Et2O

A B
H+ 2. H3O+
COOCH3
The products (A) and (B) are, respectively,
O OH
O O O
(A) and (B) and

O
CH3OC COOCH3
O COOCH3 CHO
O O O HO OCH2CH2OH OCH=CH2
(C) and (D) and
COOCH3 CH2OH COOCH3 CH2OH
55. In the reaction
BrCH2COOC2H5 H2O
N
the main product obtained at the final stage is
+ +
N Br– N
(A) CH2COOC2H5 (B) Br–
CH2COOC2H5
O CH2COOC2H5
HO
CH2COOC2H5
(C) (D)
56. Ge(II) compounds are powerful reducing agents, whereas Pb(IV) compounds are strong oxidants. It
can be due to
(A) lead is more electropositive than germanium.
(B) the ionization potential of lead is less than that of germanium.
(C) the ionic radii of Pb 2+ and Pb4+ are larger than those of Ge2+ and Ge4+.
(D) in lead the inert pair effect in more pronounced than in germanium.
57. Nitrogen (I) oxide is produced by

(A) thermal decomposition of ammonium nitrate.
(B) disproportionation of N2O4.
(C) thermal decomposition of ammonium nitrite.
(D) interaction of hydroxylamine and nitrous acid.
58. P4O10 has short and long PO bonds. The number of short P=O bonds present in P4O10 are
(A) 1 (B) 2 (C) 3 (D) 4
59. In the nitrogen family, the HMH bond angle in the hybrides (MH3) gradually becomes closer to
90° on going from N to Sb. This shows that gradually
(A) the basic strength of hydrides increases.
(B) almost pure porbitals are used for MH bonding.
(C) the bond energies of MH bond increases.
(D) the bond pair of electrons become nearer to the central atom.
60. The conversion

O O
O
can be effected by using the reagent

(A) H2O2 (B) O3
Cl CO2H Cl CO3H
(C) (D)
SECTIONIII :MATHEMATICS
This section contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONLY ONE is correct.
z1  z 2
61. A relation R on the set of complex numbers is defined by z1Rz 2  is real, then the relation R
z1  z 2
“is real” is
(A)equivalence (B) only reflexive (C) only transitive (D) none of these
62. If n  U   60, n  A   35, n  B   24 and n  A  B  '  10 then n  A  B  is

(A) 9 (B) 8 (C) 6 (D) none of these
63. The entire domain of the function f  x   1  1  1  x 2 is

(A)  ,1 (B)  1,   (C)  0,1 (D)  1,1
1 1
64. If 3f  x   5f     3, x   0   R , then f  x  
x x
1 3  1 3  1 3 
(A)   5x  6  (B)    5x  6  (C)    5x  6  (D) none of these
16  x  16  x  16  x 
65. The inequality z  4  z  2 represents the region given by (z is a complex number)

(A) Re  z   0 (B) Re  z   0 (C) Re  z   3 (D) none of these
66. The complex number z satisfying the equations z  4  z  i  z  5i  0 is

(A) 3  i (B) 2 3  2i (C) 2 3  2i (D) 0
67. The equation 125x  45x  2.27 x has, x  R

(A)no solution (B) one solution (C) two solution (D) more than two solution
3x
68. The roots of the equation 2x  2.3 x 1  9 are given by
2 log 3
(A) log   , 2 (B) 3, 3 (C) 2,1  (D) 1  log 2 3, 2
3 log 2
 1 2 1
69. If A   1 1 2  , the det  adj  adjA   is
 2 1 1 
4 3 2 1
(A) 14  (B) 14  (C) 14  (D) 14 
70.  
If two events A and B are such that P A  0.3, P  B  0.5 and P  A  B  0.3 , then P B A  B is  
equal to
5 7 3
(A) (B) (C) (D) none of these
8 8 8
 2sin   1 sin  cos 
 
71. The value of  in  0, 2 such that the matrix  sin      2 cos   3 tan   is skew-symmetric,
cos      tan      0 

is
(A)  2 (B)  3 (C)  4 (D)  6
15
72. C8 15 C9 15 C 6 15 C 7 
(A) 2 (B) 3 (C) 4 (D) none of these
73. There are 10 lamps in a hall. Each one them can be switched on independently. The number of ways
in which the hall can be illuminated is
(A) 10 2 (B) 18 (C) 210 (D) 1023
74. For natural number n, 2n  n  1!  n n , if

(A) n  2 (B) n  2 (C) n  2 (D) for no n
2n
 1
75. The greatest coefficient in the expansion of  x   is
 x
1.3.5...  2n  1 2n !
(A) (B) (C) 2n C n (D) None of these
n!  
n !
4 1
76. The sum of positive terms of the series 10  9  9  ... is
7 7
352 437 852
7 7 7
3 n 1 3
77. For any odd integer n  1 , n 3   n  1  ...   1 1 
1 2 1 2 1 2 1 2
(A)  n  1  2n  1 (B)  n  1  2n  1 (C)  n  1  2n  1 (D)  n  1  2n  1
2 4 2 4
1
78. If f  x   , then the points of discontinuity of the function f 3n  x  in the domain of f(x),
1 x
where f n  fof ... of (n times), are
(A) x  2 (B) x  0 (C) x  1 (D)none of these
d  3 d2 y 
79. If y2  P  x  , a polynomial of degree n  3 , then 2 y 
dx  dx 2 
(A) P  x  .P"'  x  (B) P  x  .P"'  x  (C) P  x  .P ''  x  (D) none of these
80. The tangent to the curve x  y  4 is equally inclined to the axes at the point
(A) 1, 2  (B)  4, 4  (C)  4, 4  (D)  4, 4 

81. If 0      then
2
tan   tan   tan  
(A)  (B)  (C)  (D)None of these
tan   tan   tan  
2
1 101  1
82.  x cos ec
12
 x   dx 
 x
(A) ¼ (B) 1 (C) 0 (D) 101/2
 
1 1 1 1
83. The value of the lim     ...   is
n   2 
n2 n2 1 n 2  22 2
n   n  1 

  
4 3 2
2 3
 dy  1  dy  1  dy 
84. The degree of differential equation x  1           ….is
 dx  2!  dx  3!  dx 
(A)three (B) one (C) not defined (D) none of these
 a3 a 2  3 
85. If the points Pi  i , i  ,i  1, 2,3 are collinear and a1 ,a 2 and a3 are distinct real numbers, then
 a i 1 a i  1 
(A) a1a 2a 3   a1a 2  3 a1  0 (B) a1a 2a 3   a1a 2  3 a1  0
(C) a1a 2a 3   a1a 2  3 a1  0 (D) a1a 2a 3   a1a 2  2 a1  0
86. If       0 , the line 3x   y  2   0 passes through the fixed point

 2 2   2
(A)  2,  (B)  , 2  (C)  2,  (D) none of these
 3 3   3
 1 
87. If  mi ,  ,i  1, 2, 3, 4 are four con-cyclic points, then the value of m1.m 2 .m3.m4 is
 mi 
(A) 1 (B) – 1 (C) 0 (D) none of these
88. If the parabola x 2  ay  a  0  makes an intercept of length 40 on the line y  2x  1, then a is

equal to
(A) 1 (B) 2 (C) 3 (D)4
2 2
x y
89. If bx  3ay  2ab touches the ellipse 2  2  1 , then the eccentric angle of the point of contact is
a b
  
6 4 3
a a2 1  a3
90.      
If b b 2 1  b3  0 and the vectors A  1, a, a 2 , B  1, b, b 2 , C  1, c, c2 are non-coplanar then
c c 2 1  c3
the product abc 
(A)  1 (B) 1 (C) 0 (D) none of these
PHYSICS SOLUTION
1. (B)
1 dV
 forisobaric process
V dT
PV  nRT ___(1)
 PdV  nRdT ___(2) [ P is constant]
dV dT
 
V T
1 dV 1 1
   
V dT T T
2. (C)
Ceff  4F 6F 3F
Charge in each branch = 18 C A
 6  9  v A   18 (1)
3  9  VB   18 (2) 0
9
By equation (1) B
VA  6 3F 6F
VB  3
 VA  VB  3 Volt
3. (A)
Force on each hemispherical shell due to other is
2
 R 2 (By electrostatic pressure)
2 0
Let surface charge density of inner shell is 1
Field at the surface of hemispherical shell is 


K 1  4  R / 2 
2

2
R
1

4 0
Force due to inner shell

 1  R 2
4 0
 Net force on hemisphere= 0
2 2 1R
2
R  0
2 0 4 0
 1  2
4. (A)
E 0 k  Bo   E 0  cB0
Also,   k 
 c 
5. (C)
Mean position will shift but time period will remain same.
6. (A)
7. (D)
A  x2 v
d d
induced  
dt dt
Bx 2  
dx x x x x x
 2Bx v a
dt x x x x x
dx v
 2v
dt a
 induced  2Bx  2v 
v
 4 Bva
 4Bva
Induced current = ind   Bv / r
4ra 4ra
8. (B)
5L 1 r1 r2
r1  r2  L CM
6 6
m2 r1  5M 2 r2 M 5M

G 5M 2
 L
L2
5GM
 2 r1  2
L
6GM
2  3
L
6GM

L3
L3
Time period = 2
6GM
9. (B)
Work done = + (Area of semi circle)
 1 litre  2 / 2 
    atm  l 
2 2
[Area under the curve is greater during expansion hence work done is +ve]
10. (A)
2
Imax

 I1  I2  I1 25

Imin 2 I2 4
 I1  I2 
I1 5

I2 2
2 2

 5 2  1   7 2 
2 2
 5 2  1  3 2 
 49 : 9
11. (D)
Emissive power  T 4
4
8000  2300  2300
   T 1
500  T  16  4
 1150 K
12. (C)
 a rel  0
Hence VAB  constant.
  
Once B strikes the Ground a rel  a AB  a A  a B
= g downward
Slope of VAB vs tgraph is –ve
13. (A)
18  6
Req  2  0.5  5 
18  6
 2  0.5  8  4.5
= 15
 i 1 A
14. (D)
For maximum For minimum
RR 18
  R  R 2 R 1 2   2
R1  R 2 3  6
1 1 1
 0.1  0.2  0.3  
R R1 R 2
1 1 1
R  R1  R 2  9 =  2 dR   2 dR1  2 dR 2
R R1 R2
dR 0.1 0.2
 R max  9  0.03   
4 9 36
0.2
  0.06
3
 R min  2  0.0666
 R min  2  0.07
15. (B)

 
v1  100 cos 60o   100 sin 60o  gt ˆj
100 100


v 2  100 cos 60o   100 sin 60o  gt ˆj 
60o 60o
 
v1.v2  0
2 2
 
 100 cos 60o  100 sin 60  gt   0
o
2
 2500   50 3   g 2 t 2  100 gt 3  0
 25  75  t 2  10 3t  0
 t 2  10 3t  50  0
10 3  300  200 10 3  10
 
2 2
 5 3 5
16. (D)
Diffraction is obtained when the slit width is of the order of wavelength of light (or any
electromagnetic wave) used.
Here, wavelength of x- rays (1- 100A o ) << slit width (0.6 mm).
Therefore, no diffraction pattern will be observed.
17. (C)
dv
Viscous force = A
dy
   Fv r
R   2r dr  r r
  R4 (h – thickness of oil film)
0 h
18. (D) i(2R)B

FBD of half part
2T  100    2  0.5  0.2
T  10 N
T T
19. (C)
20. (C)
21. (B)
1 half life of A = 2 half lives of B
3half lives of A = 6half lives of B
 NA  NB (after 3 half lives of A)

N A NB

23 26
N 1 1
 A  3
NB 2 8
22. (B)
Since weight of liquid will remain same but area of base increases on increasing temperature.
Hence pressure will decrease at the bottom of vessel. (In case of no spilling)
23. (C)
a n  kt 4
v2
  kt 4  v 2  kRt 4
R
1
mv 2
total work k 2
Avg. power =  
time time t
1
= m

KRt 4 1 
 mkRt 3
2 t 2
24. (C) v
 During rolling up f
v  , Hence  to ensure pure rolling  f

so torque of friction must oppose  . v
 During rolling up
v   mustincreaseso torque of friction  
must be increasing  .
Hence frictionalforce must be up the inclined the plane
25. (D)

 L1  e (end correction) for first resonance
4
3
 L 2  e for second resonance
4
v  f  andendcorrection 'e '  0.6 r
   44  L2  e  33
 L 2  32
26. (C)
The objective has smaller aperture and smaller focal length than those of eyepiece.
27. (B)
Let and K1 and K 2 : P1 and P2 are K.E. and momentum of  particle and remaining nucleus, then
K1  K 2  5.5 Mev (1)
P1  P2 (2)
2K1  4m  2K 2  216m
 K1  54K 2
 by equation (1)
5.5  54
K1   5.4 MeV
55
28. (A)
Diameter =M.S.R. +  C.S.R.  LC  – zero error
 0.5 
 3m m  35     0.03
 50 
 3.38 m m
29. (D)
 V
E  yiˆ  xjˆ   y  V  xy  constant
x
V
  x  V  xy  constant
y
For equipotential the equation is xy = constant.
represents rectangular hyperbola.
30. (D)
Magnetic field can change direction of particle hence velocity changes and hence acceleration.
CHEMISTRY SOLUTIONS
31. (C)
32. (C)
CH3 CH3 CH3 H H CH3

Three isomers
H H H CH3 CH3 H
meso enantiomers
33. (B)
34. (A)
Number of moles  vapour pressure
w1
M1 VP1 P10
 
w 2 VP2 P 0
2
M2
w1 P10 M1 27 526  18
 0  
w 2 P2 M 2 73 (732)  M
 M = 34.9 g/mole
35. (A)
109.5
N HCl  3
36.5  1
Since Na2 CO3 is completely neutralized by HCl
 Meq.of Na2CO3 = Meq. of HCl
N × 25 = 32.9 × 3
 N Na 2CO3  3.948
Now Na2CO3 fresh solution reacts with H2SO4
Wt. of Na2CO3 solution = 125 g
125
 Volume of Na2CO3 solution =  100 mL
1.25
 Meq.of H2SO4 = Meq. of Na2CO3
0.84 × V = 100 × 3.948
 Volume of H2SO4 required = 470 mL
36. (C)
37. (C)
H2(g) + Cl2(g)  2HCl(g) H1 = – x KJ
2HCl(g)  H2(g) + Cl2(g) H2 = y KJ
 –x=–y
 y–x=0 or x– y= 0
40. (B)
The chemical reaction involved is
NiSO 4  4Py  2NaNO 2 
 Na 2SO 4  [Ni (Py) 4 ](NO 2 ) 2
41. (B)
Carbonate being a bigger anion is stabilised by bigger cation.
46. (D)
For an isobaric process,
Q  nC p T
U  n Cv T
U C v 5
 required fraction =  
Q Cp 7
47. (B)
0.693
= 9
= 5.41  10 10 yr1
1.28  10
1. 0 0.01
Activity, A = N = 5.41  10 10  6.023  1023
75 .5 100
A = 4.37  108 yr1
48. (B)
R1OH + CH3CO2 H CH3CO2R1 + H2O
(1 x) (1 x y) x (x + y)
R2OH + CH3CO2H CH3CO2R2 + H2O
(1  y) (1xy) y (x + y)
Since, the amount of acid consumed is 80% in complete esterification process, therefore
x + y = 0.8
x 3
Also, =
y 2
 x = 0.48 and y = 0.32
x ( x  y)
Thus, equilibrium constant for first esterification process =
(1  x) (1  x  y )
0.48  0.8
K C1 
0.52  0.2
K C1  3.7
49. (C)
PCl5(g) PCl3(g) + Cl2(g) …(i)
COCl2(g) CO(g) + Cl2(g) …(ii)
If some amount of CO has been introduced into the vessel at constant volume then the second
equilibrium will move for the backward direction. As a result the equilibrium concentration of Cl2
will be less. So the equilibrium constant of the first reaction will also be disturbed and the reaction
quotient will be less than the equilibrium constant. Therefore to attain the new equilibrium the first
reaction will move for the forward direction and the concentration of PCl5 present at new equilibrium
will be less.
50. (A)
When the pressure is high, volume would be small. So, excluded volume ‘b’ cannot be ignored. But
a
as the pressure is high, the quantity 2 may be neglected in comparison with P. So the van der
V
Waal’s equation reduces to
P(Vb) = RT
PV Pb = RT
 RT 
V=   b i.e. Vreal = Videal + b
 P 
 Vreal>Videal
51. (C)
As the pressure, temperature and volume remain constant therefore the number of moles of CCl4 and
O2 will be same. But the molar mass of CCl4 is nearly 5 times than that of O2.
52. (D)
n=4
From the above figure, it is evident that the
n=3
frequency  of certain line of Lyman series
 corresponds to n = 4 to n =2 transition.
n=2
n=1
53. (C)
The standard oxidation potentials are in the order Sn2+> Ag >Cl–> NO3 > SO 24  . So Sn2+ would be
first oxidized to Sn4+ and then Ag will get oxidized to Ag+. At cathode, first Sn2+ will be reduced to
Sn and then Na+ is reduced to Na.
54. (C)
O O O O
OH
OH (i) LiAlH4, H2O
H+ (2) H3O+
COOCH3 COOCH3 CH2OH

(A) (B)
55. (C)

N N N
CH2–COOEt H2O O–H
CH2COOEt CH2COOEt
Br
O
CH2COOEt
+
N
H
56. (D) As we go down the group inert pair effect will be more predominant.
Therefore, inert pair effect is more pronounced in lead than germanium.
57. (A) Nitrogen(I) oxide is produced by thermal decomposition of ammonium nitrate


NH4NO3  N2O + 2H2O
58. (D)
O
143 pm
P 102°
O O
O 123° 160 pm
P P
O O
O
O P O
O
P4O10 has four short P = O bonds
59. (B)
In nitrogen family H – M – H bond angle in the hydrides (NH3) gradually decreases and becomes 90°
on going from N to Sb. This is due to p–orbital is used for formation of
M–H bonding.
60. (D)
O O
MCPBA O (Bayer villiger oxidation)
MATHS SOLUTION
61. (d)
z1  z1
Since  0 , which is real z1  C , therefore R is reflexive.
z1  z1
z z
For z1 , z 2  C, z1Rz 2  1 2 is real
z1  z 2
 z z  z z 
   1 2  is real   2 1  is real
 z1  z 2   z 2  z1 
For z1 , z 2 , z3  C , let z1  a1  ib1 , z 2  a 2  ib 2 and z 3  a 3  ib3
z z
Now, 1 Rz 2  1 2 is real
z1  z 2
 a1  a 2   i  b1  b 2  is real

 a1  a 2   i  b1  b 2 
 a1  a 2   i  b1  b2   a1  a 2   i  b1  b2  is real
 
 a1  a 2   i  b1  b2   a1  a 2   i  b1  b2 
 a1  a 2  a1  a 2    b1  b2  b1  b2   i  b1  b2  a1  a 2    b1  b 2  a1  a 2 
2 2
is real
 a1  a 2    b1  b2 
  a1  a 2  b1  b 2    a1  a 2  b1  b 2   0
 2a 2 b1  2b2 a1  0
a1 b1 a1 a 2 a 2 a 3
  or  or 
a 2 b2 b1 b2 b2 b3
a 2 a3
Similarly, z 2 Rz 3  
b 2 b3
a1 a 2 a a
Therefore, z1Rz 2 and z 2 Rz3   and 2  3
b1 b 2 b 2 b3
a1 a 3
   z1Rz3
b1 b3
 R is transitive
Hence R is equivalence relation.
U
62. (A)  A  B '
We have, n  A  B   n  U   n  A  B  '  60  10  50 A B
Now, n  A  B   n  A   n  B   n  A  B 
 50  35  24  n  A  B   n  A  B   59  50  9
A B
63. (D)
f  x  is defined if
2
1  1  1  x 2  0,1 1  x 2  0 and 1  x  0
1  x 2  0   x  1 x  1  0  01  x  1
Clearly for these values, the other two inequalities hold.
Thus domain of f   1,1
64. (B)
We have,
1 1
3f  x   5f     3, x   0   R (1)
x x
1
 3f    5f  x   x  3 (2)
x
1
[Replacing x by
]
x
Multiplying (1) by (3) and (2) by 5 and subtracting, we get
3 
9f  x   25f  x     9    5x  15 
x 
3
 16f  x    5x  6
x
1 3 
 f  x      5x  6  , x   0   R
16  x 
65. (C)
2 2
Given z  4  z  2
2 2
  x  4   iy   x  2   iy
2 2
  x  4   y2   x  2   y2
 4x  12  4x  12; x  3  Re  z   3
66. (B)
We have two equations
z  4  0 and z  i  x  5i  0
Putting z  x  iy , these equations becomes
x  iy  4 i.e., x 2  y 2  16 (1)
and x  iy  i  x  iy  5i
2 2
or x 2   y  1  x 2   y  5  (2)
i.e. y  2
putting y  2 in (1), x 2  4  16 or x  2 3
hence the complex numbers z satisfying the given equations are
z1  2 3  2i , and z 2  2 3  2i
67. (B)
3x x
The given equation can be written as  5 3   5 3  2
x
5
Putting    t , the equation becomes
3
t 3  t  2  0  t 3  1   t  1  0
 
  t  1 t 2  t  1  t  1  0
  t  1  t 2
 t  2  0
 t  1 or t 2  t  2  0
68. (C)
We have, 2x  2.33x  x 1  9  32
3x
  x  2 log 2  log3  2log 3
x 1
1
  x  2   log 2  
log 3   0
 x 1 
log 3
 x  2 or x  1 
log 2
69. (A)
n 2
We know that adj(adj A)  A A if A  0 , provided orders of A is n.
 adj (adj A)  A A  as n  3 
3 4
 det (adj(adj A)  A det A  A
1 2 1
But A  1 1 2  14
2 1 1
4
 det (adj (adj A))  14 
70. (C)
 
We have, P A  B  P  A   P B  P A  B    
  
 1  P A  1  P  B    P  A   P  A  B 
 
P B A B 
 
P B AB   P AB  


P B  A  B  B  

P AB 
P  A  B 0.3 3
  

P AB  0.8 8
71. (D)
The matrix can be written as
 2sin   1 sin  cos 
 
  sin  2 cos   3 tan  
  cos   tan  0 
 
The above matrix is skew symmetric if
2sin   1  0 and 2cos   3  0

The simultaneously equations hold in  0, 2  if  
6
72. (D)
We have,
15
C8 15 C9 15 C 6 15 C7   15 C8 15 C9    15 C6 15 C7 
16 C9 16 C 7
 n
C r  n C r 1  n 1 C r 1 
16
 C9  C9 16
 n
Cr  n C n r 
0
73. (D)
Each bulb has two choices, either switched on or off
 Required number of ways
 210 1  1024  1  1023
[since in one way when all are switched off, the hall will not be illuminated].
74. (B)
Check the options. The condition is satisfied for n  2
75. (C)
Since the middle room term has greatest coefficient,
 greatest coefficient  coefficient of the middle term
 2n C n 
 2n !
n!n!
2n  2n  1 2n  2  2n  3 ...4.3.2.1

n!n!
 2n  1 2n  3 ...3.1  2n  2n  2  2n  4  ...4.2 

n!n!
n
1.3.5...  2n  1 2  n  n  1 n  2  ...2.1 
 
n!n!
1.3.5...  2n  1 2 n! 1.3.5...  2n  1 2n
n
 
n!n! n!
76. (C)
3
Here, a  10, d  
7
 3
Then, t n  10   n  1     0 ;
 7
1
or 70  3  n  1  0 or 73  3n; or 24 n
3
 First 24 terms are positive
 Sum of the positive terms
24  3 
 S24   2 10  23  
2  7
 69  852
 12  20   
 7 7
77. (D)
n 1
Since n is an odd integer  1  1 and n  1 , n  3, n  5 etc., are even integers. We have
3 3 3 n 1 3
n 3   n  1   n  2    n  3  ...   1 1
3 3 3 3
 n3   n  1   n  2   ...13  2  n  1   n  3  ...  23 
 
3 3 3 3
  n  1  3  n  3 3
3

 n   n  1   n  2   ...  1  2  2      ...  13 
 2   2  
[ n  1, n  3 are even integers]
2 2
 n  n  1   1  n  1  n  1  
   16     1 
 2   2  2  2 
2 2
1 2
 n 2  n  1  16
 n 1  n  1
4 16  4
1 2 2 1 2
 n  1  n 2   n  1    n  1  2n  1
4 4
78. (B)
1
Clearly, x  1 is a point of discontinuity of the function f  x  
1 x
 1  x 1
If x  1 , then  fof  x   f  f  x    f   ,
 1 x  x
Which is discontinuous at x  0
If x  0 and x  1 , then
x 1 
 fofof  x   f  fof  x   f  x,
 x 
which is continuous everywhere.
n
Hence, f 3n  x    fofof   x   x , which is continuous everywhere.
So, the only point of discontinuity is x  0 .
79. (B)
We have,
y2  P  x  (1)
dy
 2y  P ' x  (2)
dx
dy dy d2y
2 .  2y. 2  P"  x 
dx dx dx
2
 dy  d2y
 2y 2    2y 3. 2  y 2 P"  x 
 dx  dx
2
d2y 3  dy 
 2y 2
 y 2 P"  x   2y 2  
dx  dx 
1 2
 y 2 P "  x    P '  x   [form (2)]
2
d  d2y 
 2  y3 2 
dx  dx 
dy 1
 2y P "  x   y 2 P "'  x   2P '  x  .P "  x 
dx 2
2
 P '  x  P"  x   y P"'  x   P '  x  P"  x 
 dy 
 2y dx  P '  x  
 y 2  P  x  
 y 2 P"'  x   P  x  P '''  x 
80. (B)
We have, x  y 4
1
1 dy dy y
   0 or 
2 x 2 y dx dx x
Since the tangent is equally inclined to the axes,
dy y
 tan 45o or tan 135 o i.e., 1 or – 1. Thus   1. This gives y  x
dx x
From (1), x  x  4  x  4 . Also y  x  4
The point is (4, 4)
81. (B)
Let f  x   x tan x
 
 f '  x   tan x.1  x sec 2 x  0 , for x   0, 
 2
 
So, f  x  is increasing for x   0, 
 2

Since, 0       f b  f 
2
tan  
  tan    tan  i.e., 
tan  
82. (C)
2
1 
101 1
I  x cos ec  x  x  dx
12  
1 1 1 1
Let  t,  2 dx  dt   dx  dt
x x x t
2
1  1
 I    cos ec101  t   dt  I  I
12
t  t
 2I  0  I  0
83. (C)
 
 1 1 1 1 
lim    ... 
n   2 
n2 n2 1 n 2  22 2
n   n  1 

 
 1 1 1 1 
 lim    ... 
n   2 2 2 2 2 
n n 1 n 2 2
n   n  1 

n 1 n 1
1 1 1
lim   lim  .
r 0 n
2 2
n 
r 0 n r n 
1 r 2 n2
1
dx 1 
  sin 1 x  
0 1 x2 0 2
84. (B)
 dy 
  dy
x  e  dx    ln x
dx
 order  1 and degree  1
85. (C)
Let the given points lie on the line lx + my = n = 0
 a3   a2  3 
 l i   m i n 0
 ai 1   ai 1 
 la 3i  ma i2  na i  3m  n  0
m n 3m  n
  a1   l ,  a1a 2  l and a1a 2a 3  l
 a1a 2a 3  3 a1   a1a 2  0
86. (B)
The given line is 3 x   y  2   0
 3x  y  2      0        0 
   3x  2     y  2   0
 the given line passes through the point intersection of the line 3x  2  0 and y  2  0 i.e.,
2 
 , 2  , for all values of  and  .
3 
87. (A)
Let the equation of circle be x 2  y2  2gx  2fy  c  0
 1
If  m,  lies on this circle, then
 m
1 1
m2   2gm  2f  c  0
m2 m
Or m 4  2gm3  2fm  cm 2  1  0
This is a fourth degree equation in m having m1 , m2 , m3 , m 4 as its roots.
1
Therefore, m1m 2 m3m4  product of roots   1
1
88. (A)
Solving the two equation x 2  ay and y  2x  1 , we get
x 2  a  2x  1 or x 2  2ax  a  0
 x1  x 2  2a and x1x 2  a
So, the given line cuts the parabola at two points  x1 , y1  and  x 2 , y 2  .
2
Now,  40  2
  x1  x 2    y1  y 2 
2
[Given]
2
2  x 2 x2 
 40   x1  x 2    1  2 
 a a 
2
  x1  x 2  2 
  x 2  x 2  1  
 a2 
2  4a 2 
  x1  x 2   4x1x 2   2  1  5  4a 2  4a 
  a 
 a 2  a  2  0 or  a  2  a  1  0
 a 1
89. (C)
Equation of tangent is
x 1 y 3
.  . 1 (1)
a 2 b 2
Also, equation of tangent at the point  a cos , b sin   is
x y
cos   sin   1 (2)
a b
Since (q) and (2) are identical, we get
1 3 
cos   and sin   
2 2 3
90. (A)
The given determinant can be written as
a a2 1 a a 2 a3
b b2 1  b b 2 b3  0
c c2 1 c c2 c3
1 a a2 1 a a2
 1 b b 2   abc  1 b b 2  0
1 c c3 1 c c2
1 a a2
 1  abc  1 b b2  0
1 c c2
1 a a2
 1  abc  0  1 b b 2  0  abc  1
1 c c2

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SECTION I : PHYSICS

1. An ideal gas is at absolute temperature T. Temperature coefficient of volume expansion for an

2. The potential difference between points A and B is

(A) 0 V (B) 6 V (C) 3 V (D) 9 V

4. An electromagnetic wave going through vacuum is described by

5. A spring-block system undergoes simple harmonic motion on a

6. A point source causes photoelectric effect from a small metal

13. The current from the battery in circuit diagram shown is

26. The focal length of the objective lens of a compound microscope

30. Statement 1: A charged particle cannot be accelerated by magnetic field.

The correct order of acidity of the hydrogen’s represented above is

36. Point out the false statement :

37. For the reactions,

42. CH3CHO + NH2OH   CH3CH = N – OH

43. The set with correct order of acidity is :

44. Of the following species, one which is non-existent :

54. Consider the following sequence of reactions.

HOCH2 .CH2OH 1. LiAlH4, Et2O

(A) and (B) and

(C) and (D) and

COOCH3 CH2OH COOCH3 CH2OH

the main product obtained at the final stage is

57. Nitrogen (I) oxide is produced by

60. The conversion

can be effected by using the reagent

62. If n  U   60, n  A   35, n  B   24 and n  A  B  '  10 then n  A  B  is

63. The entire domain of the function f  x   1  1  1  x 2 is

65. The inequality z  4  z  2 represents the region given by (z is a complex number)

66. The complex number z satisfying the equations z  4  z  i  z  5i  0 is

67. The equation 125x  45x  2.27 x has, x  R

74. For natural number n, 2n  n  1!  n n , if

86. If       0 , the line 3x   y  2   0 passes through the fixed point

88. If the parabola x 2  ay  a  0  makes an intercept of length 40 on the line y  2x  1, then a is

Field at the surface of hemispherical shell is 

18. (D) i(2R)B

 NA  NB (after 3 half lives of A)

Hence frictionalforce must be up the inclined the plane

CH3 CH3 CH3 H H CH3

COOCH3 COOCH3 CH2OH

57. (A) Nitrogen(I) oxide is produced by thermal decomposition of ammonium nitrate

MCPBA O (Bayer villiger oxidation)

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