Crosslinker CX100 Msds

Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United
Kingdom (UK)
SAFETY DATA SHEET
CROSSLINKER CX-100
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : CROSSLINKER CX-100
Internal code : 030119WW53246 - EU - TR
Chemical product name : Reaction mass of 2-ethyl-2-[[3-(2-methylaziridin-1-yl)propionyl]methyl]propane-1,3-diyl bis
(2-methylaziridine-1-propionate) and 2,2-bis({[3-(2-methylaziridin-1-yl)propanoyl]oxy}methyl)butyl
3-2,2-bis({[3-(2-methylaziridin-1-yl)propanoyl]oxy}methyl)butoxy] propanoate
EC number : 939-180-9
REACH Registration number
Registration number
01-2119963929-15
CAS number : Not available.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Industrial use : monomer
Formulation for Adhesives
Industrial use : Adhesives
Professional use : Adhesives
Formulation of Coatings
Industrial use of Coatings
Professional use of Coatings, Indoor use
Professional use of Coatings , Outdoor
1.3 Details of the supplier of the safety data sheet

Supplier : DSM Coating Resins B.V. Tel: +31 416 752222
PO Box 123 www.dsmcoatingresins.com
5140 AC Waalwijk
Netherlands
e-mail address of person : DSMRESINS.SDS@dsm.com (Communication in English only please)
responsible for this SDS
1.4 Emergency telephone number

Emergency telephone : Belgium: +32 3 575 5555
number
National advisory body/ : UK: Tel: + 44 844 892 0111
Poison Centre Ireland: Tel: +353 1 837 9964
Only for the purpose of informing medical personnel in cases of acute intoxications
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Substance
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Acute Tox. 4, H302
Eye Dam. 1, H318
Skin Sens. 1A, H317
Muta. 2, H341
STOT RE 2, H373 (kidneys) (oral)
Aquatic Chronic 2, H411
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 16 for the full text of the H statements declared above.
2.2 Label elements
Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 1/59

Safety Data Sheet CROSSLINKER CX-100
Hazard pictograms :
Signal word : Danger

Hazard statements : H302 - Harmful if swallowed.
H318 - Causes serious eye damage.
H317 - May cause an allergic skin reaction.
H341 - Suspected of causing genetic defects.
H373 - May cause damage to organs through prolonged or repeated exposure if swallowed.
(kidneys)
H411 - Toxic to aquatic life with long lasting effects.
Supplemental label : Not applicable.
elements
Precautionary statements
General : Not applicable.
Prevention : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves: < 1 hour (breakthrough time): butyl rubber (0.5 mm). Wear
protective clothing. Wear eye or face protection.
P273 - Avoid release to the environment.
P260 - Do not breathe vapour.
P270 - Do not eat, drink or smoke when using this product.
P264 - Wash hands thoroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
Response : P391 - Collect spillage.
P314 - Get medical attention if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical attention.
P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel
unwell. Rinse mouth.
P302 + P352 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse.
P333 + P313 - If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or physician.
Storage : P405 - Store locked up.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and
international regulations.
2.3 Other hazards

Substance meets the : Not listed
criteria for PBT according PBT: Specified
to Regulation (EC) No.
1907/2006, Annex XIII
Substance meets the : Not listed
criteria for vPvB according vPvB: Specified
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification
SECTION 3: Composition/information on ingredients

3.1 Substances / 3.2 Mixtures : Substance Yes. No.
Product/ingredient name Identifiers % Classification

Regulation (EC) No. 1272/2008
[CLP]
Reaction mass of 2-ethyl-2-[[3- REACH #: 100 Acute Tox. 4, H302

(2-methylaziridin-1-yl)propionyl]methyl] 01-2119963929-15 Eye Dam. 1, H318
propane-1,3-diyl bis(2-methylaziridine- EC: 939-180-9 Skin Sens. 1A, H317
1-propionate) and 2,2-bis({[3- Muta. 2, H341
(2-methylaziridin-1-yl)propanoyl] STOT RE 2, H373 (kidneys)
oxy}methyl)butyl 3-2,2-bis({[3- (oral)
(2-methylaziridin-1-yl)propanoyl] Aquatic Chronic 2, H411

oxy}methyl)butoxy] propanoate
2-methylaziridine EC: 200-878-7 0 - 0.0009802 Flam. Liq. 2, H225

CAS: 75-55-8 Acute Tox. 2, H300
Index: 613-033-00-6 Acute Tox. 1, H310
Acute Tox. 2, H330
Eye Dam. 1, H318
Carc. 1B, H350
allylamine EC: 203-463-9 0 - 0.0000099 Flam. Liq. 2, H225

CAS: 107-11-9 Acute Tox. 3, H301
Index: 612-046-00-4 Acute Tox. 1, H310
Acute Tox. 3, H331
Skin Corr. 1B, H314
xylene, mixture of isomers REACH #: 0 - 0.0000099 Flam. Liq. 3, H226

01-2119488216-32 Acute Tox. 4, H312
EC: 215-535-7 Acute Tox. 4, H332
CAS: 1330-20-7 Skin Irrit. 2, H315
Index: 601-022-00-9 Eye Irrit. 2, H319
STOT SE 3, H335
STOT RE 2, H373
Asp. Tox. 1, H304
See Section 16 for the full text
of the H statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable,
are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplace exposure limit
and hence require reporting in this section.
Remarks : Main component : 2-ethyl-2-[[3-(2-methylaziridin-1-yl)propionyl]methyl]propane-1,3-diyl bis
(2-methylaziridine-1-propionate) ; CAS no. 64265-57-2 ; Concentration Range (%) : 60 - 70 .
SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes
with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any
contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated
promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still
present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration
or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-
to-mouth resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap
and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician. In the event of any complaints or
symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before
reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with
water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Stop if the exposed person feels sick as vomiting may be dangerous.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the
head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately. Maintain an
open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected
that fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.

4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have
been ingested or inhaled.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
5.2 Special hazards arising from the substance or mixture

Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst. This material is
substance or mixture toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
(dense) black smoke
aldehydes
organic acids
nitrogen oxides (NO, NO₂ etc.)
ammonia (NH3)
amines
5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a
for fire-fighters fire. No action shall be taken involving any personal risk or without suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-
fighters (including helmets, protective boots and gloves) conforming to European standard EN
469 will provide a basic level of protection for chemical incidents.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training. Evacuate
personnel surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or
walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency : If specialised clothing is required to deal with the spillage, take note of any information in Section
responders 8 on suitable and unsuitable materials. See also the information in "For non-emergency
personnel".
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
precautions Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air). Water polluting material. May be harmful to the environment if released
in large quantities. Collect spillage.
6.3 Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-
soluble. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind.
Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for
disposal according to local regulations (see Section 13). Dispose of via a licensed waste
disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt
product. Note: see Section 1 for emergency contact information and Section 13 for waste
disposal.
6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted
for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling No.
Protective measures : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking
should be prohibited in areas where this material is handled, stored and processed. Workers
should wash hands and face before eating, drinking and smoking. Remove contaminated
clothing and protective equipment before entering eating areas. Persons with a history of skin
sensitization problems should not be employed in any process in which this product is used.
Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour
or mist. Do not ingest. Avoid release to the environment. If during normal use the material
presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator.
Keep in the original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be hazardous.
Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored
occupational hygiene and processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.
7.2 Conditions for safe : Store between the following temperatures: 5 to 40°C (41 to 104°F). Store in accordance with
storage, including any local regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10). Store locked up. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination. Store in original container, protected from direct sunlight.
7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions
Remarks : Formation of aerosols should be avoided when handling the product.
SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses of
the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker
exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
xylene, mixture of isomers EH40/2005 WELs (United Kingdom (UK), 12/2011). Absorbed through
skin.
STEL: 441 mg/m³ 15 minutes.
TWA: 50 ppm 8 hours.
TWA: 220 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere or
procedures biological monitoring may be required to determine the effectiveness of the ventilation or other
control measures and/or the necessity to use respiratory protective equipment. Reference
should be made to monitoring standards, such as the following: European Standard EN 689
(Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical
agents for comparison with limit values and measurement strategy) European Standard EN
14042 (Workplace atmospheres - Guide for the application and use of procedures for the
assessment of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance documents for methods for
the determination of hazardous substances will also be required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
Reaction mass of 2-ethyl-2-[[3- DNEL Long term Inhalation 1.62 mg/m³ Workers Systemic
(2-methylaziridin-1-yl)propionyl]methyl]
propane-1,3-diyl bis(2-methylaziridine-
1-propionate) and 2,2-bis({[3-
(2-methylaziridin-1-yl)propanoyl]
oxy}methyl)butyl 3-2,2-bis({[3-
DNEL Short term Inhalation 8.4 mg/m³ Workers Systemic
DNEL Short term Inhalation 11.1 mg/m³ Workers Local
DNEL Long term Dermal 0.023 mg/ Workers Systemic
kg bw/day
DNEL Short term Dermal 0.417 mg/ Workers Local
cm²
DNEL Long term Inhalation 0.972 mg/m³ Human via the Systemic
environment
DNEL Long term Oral 0.278 mg/ Human via the Systemic
kg bw/day environment
allylamine DNEL Long term Inhalation 0.23 mg/m³ Workers Systemic
DNEL Long term Dermal 0.13 mg/kg Workers Systemic
bw/day
xylene, mixture of isomers DNEL Long term Inhalation 221 mg/m³ Workers Systemic
DNEL Short term Inhalation 442 mg/m³ Workers Systemic
DNEL Long term Inhalation 221 mg/m³ Workers Local
DNEL Short term Inhalation 442 mg/m³ Workers Local
DNEL Long term Dermal 212 mg/kg Workers Systemic
bw/day
DNEL Long term Inhalation 65.3 mg/m³ Consumers Systemic
DNEL Short term Inhalation 260 mg/m³ Consumers Systemic
DNEL Long term Inhalation 65.3 mg/m³ Consumers Local
DNEL Short term Inhalation 260 mg/m³ Consumers Local
DNEL Long term Dermal 125 mg/kg Consumers Systemic
bw/day
DNEL Long term Oral 12.5 mg/kg Consumers Systemic
bw/day
PNECs
Product/ingredient name Compartment Detail Value Method Detail
Reaction mass of 2-ethyl-2-[[3-(2-methylaziridin- Fresh water 5.5 μg/l -
1-yl)propionyl]methyl]propane-1,3-diyl bis
(2-methylaziridine-1-propionate) and 2,2-bis({[3-
(2-methylaziridin-1-yl)propanoyl]oxy}methyl)butyl
3-2,2-bis({[3-(2-methylaziridin-1-yl)propanoyl]
Marine water 0.55 μg/l -
Intermittent releases. 55 μg/l -
Sewage Treatment Plant 10 mg/l -
Fresh water sediment 0.066 mg/kg -
dwt
Marine water sediment 0.003 mg/kg -
dwt
Soil 3.315 μg/kg -
wwt
allylamine Fresh water 7.65 μg/l Assessment Factors
Marine water 0.77 μg/l Assessment Factors
Intermittent releases. 76.5 μg/l Assessment Factors
Sewage Treatment Plant 7.7 mg/l Assessment Factors
xylene, mixture of isomers Fresh water 0.327 mg/l Assessment Factors
Marine water 0.327 mg/l Assessment Factors
Sewage Treatment Plant 6.58 mg/l Assessment Factors

Fresh water sediment 12.46 mg/kg Assessment Factors

dwt
Marine water sediment 12.46 mg/kg Assessment Factors
dwt
Soil 2.31 mg/kg Assessment Factors
dwt
8.2 Exposure controls

Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local
controls exhaust ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits.
Individual protection measures No.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Contaminated work clothing should
not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Safety glasses with side shields.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all
times when handling chemical products if a risk assessment indicates this is necessary. < 1 hour
(breakthrough time): butyl rubber (0.5 mm)
Skin and body : Chemical-resistant protective suit.
Respiratory protection : Face shield.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure they comply
controls with the requirements of environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.
Advice on personal protection is applicable for high exposure levels. Select proper personal protection based on a risk
assessment of the actual exposure situation.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid.
Colour : Light yellow.
Odour : Amine-like.
Odour threshold : Not available.
pH : Not available.
Melting point/freezing point : -58 °C
Initial boiling point and : Decomposes. >175 °C
boiling range
Softening range : Not available.
Flash point : 253 °C Setaflash. Closed cup
Flammability (solid, gas) : Not available.
Evaporation rate : Not available.
Upper/lower flammability or : Not available.
explosive limits
Vapour pressure : <0.01 kPa
Vapour density : Not available.
Relative density : 1.07 to 1.08 (Water = 1)
Density ( g/cm³ ) : 1.07 to 1.08 g/cm³ (20°C)
Bulk density : Not available.
Solubility : Partially soluble in the following materials: cold water and hot water.
Solubility in water : Not available.
Solubility at room : 34.9 g/l
temperature
Partition coefficient: n- : 1.4
octanol/water
Auto-ignition temperature : 345 °C
Decomposition temperature : >175°C
Viscosity : Dynamic (room temperature): 200 mPa·s (200 cP)
Kinematic (room temperature): 1.85 cm2/s (185 cSt)
Kinematic (40°C): >0.205 cm2/s (>20.5 cSt)

Explosive properties : Not available.

Oxidising properties : Not available.
9.2 Other information
SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : No specific data.
10.5 Incompatible materials : Acids , Strong oxidising materials .
10.6 Hazardous : No specific data.

decomposition products
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Reaction mass of 2-ethyl-2-[[3- LD50 Oral Rat - Female 2000 mg/kg -
1-propionate) and 2,2-bis({[3-(2-methylaziridin-
1-yl)propanoyl]oxy}methyl)butyl 3-2,2-bis({[3-
(2-methylaziridin-1-yl)propanoyl]oxy}methyl)
butoxy] propanoate
2-methylaziridine LD50 Oral Rat 19 mg/kg -
allylamine LD50 Dermal Rabbit 35 mg/kg -
LD50 Oral Rat 102 mg/kg -
xylene, mixture of isomers LC50 Inhalation Rat - Male, Female 6247 ppm 4 hours
Vapour
LD50 Dermal Rabbit 12126 mg/kg -
LD50 Oral Rat - Male 3523 mg/kg -
Conclusion/Summary : Formation of aerosols should be avoided when handling the product.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Reaction mass of 2-ethyl-2-[[3- Skin - Erythema/ Rabbit 0.7 4 hours 0.5 g 24 to 72 hours
(2-methylaziridin-1-yl)propionyl]methyl] Eschar
butoxy] propanoate
Eyes - Cornea Rabbit 3.4 0.1 ml 24 to 72 hours
opacity
Eyes - Iris lesion Rabbit 1.1 0.1 ml 24 to 72 hours
Eyes - Redness of Rabbit 2.8 0.1 ml 24 to 72 hours
the conjunctivae
Eyes - Oedema of Rabbit 4 0.1 ml 24 to 72 hours
the conjunctivae
allylamine Eyes - Severe irritant Rabbit - 0.333333333 -
minutes 50
milligrams
Skin - Severe irritant Rabbit - 24 hours 500 -
milligrams
Skin - Visible Human - 1 hours 1 hours
necrosis
xylene, mixture of isomers Skin - Irritant Rat - - -
Eyes - Moderate Rabbit - - -

irritant
Respiratory - Irritant Mammal - - - -
species
unspecified
Conclusion/Summary
Eyes : Causes serious eye damage.
Skin : Non-corrosive to skin. Non-irritating to the skin.
Respiratory : No study available .
Sensitisation
Product/ingredient name Route of exposure Species Result
Reaction mass of 2-ethyl-2-[[3- skin Mouse Sensitising
butoxy] propanoate
xylene, mixture of isomers skin Mouse Not sensitizing
Conclusion/Summary
Skin : Sensitising - Category 1A
Respiratory : No study available .
Mutagenicity
Product/ingredient name Test Experiment Result
Reaction mass of 2-ethyl-2-[[3- OECD 471 Bacterial Experiment: In vitro Positive
(2-methylaziridin-1-yl)propionyl]methyl] Reverse Mutation Test Subject: Bacteria
butoxy] propanoate
OECD 473 In vitro Experiment: In vitro Positive
Mammalian Chromosomal Subject: Mammalian-
Aberration Test Animal
Cell: Somatic
OECD 474 Mammalian Experiment: In vivo Positive
Erythrocyte Micronucleus Subject: Mammalian-
Test Animal
Cell: Somatic
Conclusion/Summary : Not available.

Carcinogenicity

Reproductive toxicity

Teratogenicity
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
Reaction mass of 2-ethyl-2-[[3-(2-methylaziridin-1-yl)propionyl] Category 2 Oral kidneys
methyl]propane-1,3-diyl bis(2-methylaziridine-1-propionate) and
2,2-bis({[3-(2-methylaziridin-1-yl)propanoyl]oxy}methyl)butyl 3-2,
2-bis({[3-(2-methylaziridin-1-yl)propanoyl]oxy}methyl)butoxy]
propanoate
Aspiration hazard
Not available.
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : May give off gas, vapour or dust that is very irritating or corrosive to the respiratory system.

Skin contact : May cause an allergic skin reaction.

Ingestion : Harmful if swallowed.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
Potential chronic health effects
Product/ingredient name Result Species Dose Exposure
Reaction mass of 2-ethyl-2-[[3- Sub-acute LOAEL Rat - Male, Female 100 mg/kg day -
(2-methylaziridin-1-yl)propionyl]methyl] Oral
butoxy] propanoate
General : May cause damage to organs through prolonged or repeated exposure if swallowed. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : Suspected of causing genetic defects.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure Effects
Reaction mass of 2-ethyl-2-[[3- Acute EC50 3.8 mg/l Fresh Algae 72 hours (biomass)
(2-methylaziridin-1-yl)propionyl] water
methyl]propane-1,3-diyl bis
(2-methylaziridine-1-propionate)
and 2,2-bis({[3-
oxy}methyl)butyl 3-2,2-bis({[3-
Acute EC50 5.5 mg/l Fresh Algae 72 hours (growth rate)
water
Acute EC50 81 mg/l Fresh Daphnia - Daphnia Magna 48 hours Mobility (
water Including
mortality )
Acute EC50 >1000 mg/l Fresh Micro-organism 3 hours Respiration
water rate
Acute LC50 >100 mg/l Fresh Fish - Cyprinus carpio 96 hours Mortality :
water None
Acute NOEC 0.92 mg/l Fresh Algae 72 hours (growth rate)
water
Acute NOEC 0.92 mg/l Fresh Algae 72 hours (biomass)
water
Acute NOEC 22 mg/l Fresh Daphnia - Daphnia Magna 48 hours -
water
Acute NOEC 100 mg/l Fresh Fish - Cyprinus carpio 96 hours -
water
allylamine Acute EC50 23000 μg/l Fresh Algae - Selenastrum sp. 96 hours -
water
Acute LC50 100000 μg/l Fresh Crustaceans - Asellus aquaticus 48 hours Mortality
water
Acute LC50 28000 μg/l Fresh Daphnia - Daphnia cucullata 48 hours Mortality
water

Acute LC50 6000 μg/l Fresh Fish - Carassius auratus 96 hours Mortality
water
Acute NOEC 1.09 mg/l Fresh Fish - Oncorhynchus mykiss 96 hours -
water
xylene, mixture of isomers Acute EC50 2.2 mg/l Fresh Algae 72 hours -
water
Acute EC50 1 mg/l Daphnia 24 hours -
Acute IC50 96 mg/l Micro-organism 24 hours -
Acute LC50 2.6 mg/l Fish 96 hours -
Chronic NOEC 0.96 mg/l Daphnia 7 days -
Chronic NOEC 1.3 mg/l Fish 56 days -
Chronic NOEC 16 mg/l Micro-organism 28 days -
12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
Reaction mass of 2-ethyl-2-[[3-(2-methylaziridin- OECD 301B 1 % - 29 days - -
1-yl)propionyl]methyl]propane-1,3-diyl bis Ready
(2-methylaziridine-1-propionate) and 2,2-bis({[3- Biodegradability -
(2-methylaziridin-1-yl)propanoyl]oxy}methyl) CO2 Evolution
butyl 3-2,2-bis({[3-(2-methylaziridin-1-yl) Test
propanoyl]oxy}methyl)butoxy] propanoate
Conclusion/Summary : Not readily biodegradable.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
allylamine - - Readily
xylene, mixture of isomers - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
Reaction mass of 2-ethyl-2-[[3- 1.4 - low
(2-methylaziridin-1-yl)propionyl]
and 2,2-bis({[3-(2-methylaziridin-
1-yl)propanoyl]oxy}methyl)butyl
3-2,2-bis({[3-(2-methylaziridin-
1-yl)propanoyl]oxy}methyl)
butoxy] propanoate
allylamine 0.03 - low
xylene, mixture of isomers 3.12 8.1 to 25.9 low
12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
12.5 Results of PBT and vPvB assessment

PBT : Not listed
PBT: Specified
vPvB : Not listed
vPvB: Specified
12.6 Other adverse effects : No known significant effects or critical hazards.
SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. Reference number: 2008/98/EC.
13.1 Waste treatment methods

Product

Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not
feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact
with soil, waterways, drains and sewers.
SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN3082 UN3082 UN3082 UN3082
14.2 UN proper ENVIRONMENTALLY ENVIRONMENTALLY ENVIRONMENTALLY Environmentally

shipping name HAZARDOUS HAZARDOUS HAZARDOUS hazardous substance,
SUBSTANCE, LIQUID, N. SUBSTANCE, LIQUID, N. SUBSTANCE, LIQUID, N. liquid, n.o.s. (Reaction
O.S. (Reaction mass of O.S. (Reaction mass of O.S. (Reaction mass of mass of 2-ethyl-2-[[3-
2-ethyl-2-[[3- 2-ethyl-2-[[3- 2-ethyl-2-[[3- (2-methylaziridin-1-yl)
(2-methylaziridin-1-yl) (2-methylaziridin-1-yl) (2-methylaziridin-1-yl) propionyl]methyl]propane-
propionyl]methyl]propane- propionyl]methyl]propane- propionyl]methyl]propane- 1,3-diyl bis
1,3-diyl bis 1,3-diyl bis 1,3-diyl bis (2-methylaziridine-
(2-methylaziridine- (2-methylaziridine- (2-methylaziridine- 1-propionate) and 2,2-bis({
1-propionate) and 2,2-bis({ 1-propionate) and 2,2-bis({ 1-propionate) and 2,2-bis({ [3-(2-methylaziridin-1-yl)
[3-(2-methylaziridin-1-yl) [3-(2-methylaziridin-1-yl) [3-(2-methylaziridin-1-yl) propanoyl]oxy}methyl)
propanoyl]oxy}methyl) propanoyl]oxy}methyl) propanoyl]oxy}methyl) butyl 3-2,2-bis({[3-
butyl 3-2,2-bis({[3- butyl 3-2,2-bis({[3- butyl 3-2,2-bis({[3- (2-methylaziridin-1-yl)
(2-methylaziridin-1-yl) (2-methylaziridin-1-yl) (2-methylaziridin-1-yl) propanoyl]oxy}methyl)
propanoyl]oxy}methyl) propanoyl]oxy}methyl) propanoyl]oxy}methyl) butoxy] propanoate)
butoxy] propanoate) butoxy] propanoate) butoxy] propanoate)
14.3 Transport 9 9 9 9
hazard class(es)
14.4 Packing III III III III

group
14.5 Yes. Yes. Yes. Yes.
Environmental
hazards
Additional information
ADR/RID : This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg,
provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
Hazard identification number 90
Limited quantity 5 L
Special provisions 274, 335, 601, 375
ADN : This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg,
Special provisions 274, 335, 375, 601
IMDG : This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg,
Emergency schedules F-A, S-F
Special provisions 274, 335, 969
IATA : This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg,
provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.
Quantity limitation Passenger and Cargo Aircraft: 450 L. Packaging instructions: 964. Cargo
Aircraft Only: 450 L. Packaging instructions: 964. Limited Quantities - Passenger Aircraft: 30 kg.
Packaging instructions: Y964.
Special provisions A97, A158, A197

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are upright and
user secure. Ensure that persons transporting the product know what to do in the event of an accident or
spillage.
14.7 Transport in bulk : Not available.

according to Annex II of
Marpol and the IBC Code
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
Product/ingredient name Carcinogenic effects Mutagenic effects Developmental Fertility effects
effects
Reaction mass of 2-ethyl-2-[[3- - Muta. 2, H341 - -
(2-methylaziridin-1-yl)propionyl]
and 2,2-bis({[3-
(2-methylaziridin-1-yl)
propanoyl]oxy}methyl)butyl 3-2,
2-bis({[3-(2-methylaziridin-1-yl)
propanoyl]oxy}methyl)butoxy]
propanoate
2-methylaziridine Carc. 1B, H350 - - -
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)

Not listed.
National regulations
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Ingredient name List name Status

Not listed.
Montreal Protocol (Annexes A, B, C, E)
Ingredient name Status
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)

Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals


Not listed.
15.2 Chemical safety : No Chemical Safety Assessment has been carried out.
assessment
Remarks : Note: see section 8 for personal protective equipment and section 13 for waste disposal.
SECTION 16: Other information

Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Acute Tox. 4, H302 On basis of test data
Eye Dam. 1, H318 On basis of test data
Skin Sens. 1A, H317 On basis of test data
Muta. 2, H341 On basis of test data
STOT RE 2, H373 (kidneys) (oral) On basis of test data
Aquatic Chronic 2, H411 On basis of test data
Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H300 Fatal if swallowed.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H310 Fatal in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H373 (oral) May cause damage to organs through prolonged or repeated
exposure if swallowed.
H373 May cause damage to organs through prolonged or repeated
exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Acute Tox. 1, H310 ACUTE TOXICITY (dermal) - Category 1
Acute Tox. 2, H300 ACUTE TOXICITY (oral) - Category 2
Acute Tox. 2, H330 ACUTE TOXICITY (inhalation) - Category 2
Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4
Aquatic Chronic 2, H411 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 2
Aquatic Chronic 3, H412 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1
Carc. 1B, H350 CARCINOGENICITY - Category 1B
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Muta. 2, H341 GERM CELL MUTAGENICITY - Category 2
Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1A, H317 SKIN SENSITISATION - Category 1A
STOT RE 2, H373 (oral) SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE (oral) - Category 2
STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - Category 2

STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE

(Respiratory tract irritation) - Category 3
Alterations compared to the : Alterations compared to the previous version are marked with a little (blue) triangle.
previous version
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Sources of key data : Literature data and/or investigation reports are available through the manufacturer.
Internal code : 030119WW53246 - EU - TR
Training advice : Handling of this substance or preparation is restricted to skilled personnel only.
Notice to reader
The information contained in the Safety Data Sheet is based on our data available on the date of publication. The
information is intended to aid the user in controlling the handling risks; it is not to be construed as a warranty or
specification of the product quality. The information may not be or may not altogether be applicable to combinations of
the product with other substances or to particular applications.
The user is responsible for ensuring that appropriate precautions are taken and for satisfying themselves that the data
are suitable and sufficient for the product's intended purpose. In case of any unclarity we advise consulting the supplier
or an expert.
History
Date of printing : 4 March 2019.
Date of issue : 4 March 2019
Version : 7

CROSSLINKER CX-100
01-2119963929-15 ES2
Annex to the extended Safety Data Sheet (eSDS)

Industrial
Identification of the substance or mixture
Product definition : Multi-constituent substance
Code : 030119WW53246 - EU - TR
Section 1 - Title
Short title of the exposure : 01-2119963929-15 ES2
scenario
List of use descriptors : Identified use name: Industrial use : monomer
Process Category: PROC01, PROC03, PROC08b, PROC09, PROC15
Substance supplied to that use in form of: As such
Sector of end use: SU12
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC06c
Market sector by type of chemical product: PC32
Environmental : Use of monomer in polymerisation processes at industrial site (inclusion or
contributing scenarios not into/onto article)
Health Contributing : Chemical production or refinery in closed process without likelihood of
scenarios exposure or processes with equivalent containment conditions - PROC01
Manufacture or formulation in the chemical industry in closed batch
processes with occasional controlled exposure or processes with equivalent
containment condition - PROC03
Transfer of substance or mixture (charging and discharging) at dedicated
facilities - PROC08b
Transfer of substance or mixture into small containers (dedicated filling line,
including weighing) - PROC09
Use as laboratory reagent - PROC15
Number of the ES : 2
Section 2 - Exposure controls
General information
General measures applicable to all activities
Operational conditions and risk management :

measures
Concentration of substance in product : As such
Amounts used :
Frequency and duration of use : < 8 h (full shift).
Other conditions affecting workers exposure : Temperature ( for Liquid ) :<= 40 °C
Exposed skin surface assumed Palm of both hands
(480 cm2)
Contributing scenario controlling environmental exposure for 0: Use of monomer in polymerisation processes
at industrial site (inclusion or not into/onto article)
Amounts used : Daily amount per site :<= 100 kg/day
based on Emission days 300 (1 EU site)
Annual site tonnage <= 30
Percentage of tonnage used at regional scale: 100%
Other conditions affecting : Receiving surface water flow>= 1.8E4 m³/day
environmental exposure
Risk management : Not applicable.
measures - Air
Conditions and measures : Municipal Sewage Treatment Plant : Not applicable. (no emission to STP)
related to sewage Size of municipal sewage system/treatment plant (m3/d) >= 2E3
treatment plant Application of the STP sludge on agriculturl soil: Yes
Date of issue/Date of revision : 4 March 2019 Page: 16/59

CROSSLINKER CX-100
01-2119963929-15 ES2
Conditions and measures : Process with efficient use of raw materials. External treatment and disposal of waste
related to external should comply with applicable local and/or national regulations.
treatment of waste for
disposal
Waste management : Limit release rate to waste water to 40 g/d
measures - Water
Contributing scenario controlling worker exposure for 0: Chemical production or refinery in closed process
without likelihood of exposure or processes with equivalent containment conditions
Concentration of : As such
substance in mixture or
article
Frequency and duration of : < 8 h (full shift).
use
Other conditions affecting : Temperature ( for Liquid ) :<= 40 °C
workers exposure Exposed skin surface assumed Palm of one hand (240 cm2)
Area of use: : Indoor and outdoor use.
Technical conditions and : Closed system
measures at process level
(source) to prevent release
Ventilation control : General ventilation : Provide a good standard of general or controlled ventilation
measures Minimum extraction rate for the area of use (air changes per hour): 1-3
Local exhaust ventilation - efficiency of at least 0 % ( Inhalation )
Organisational measures to : Supervision in place to check that the RMMs in place are being used correctly and
prevent/limit releases, OCs followed
dispersion and exposure
Conditions and measures related to personal protection and hygiene
Personal protection : Dermal : Wear chemical-resistant gloves (tested to EN374) in combination with
specific activity training. Efficiency of at least 95 %
Protective clothing : Wear suitable coveralls to prevent exposure to the skin.
eye protection (e.g. protective goggles).
Respiratory protection : Use a NIOSH certified respirator with an Assigned Protection Factor (APF) of at
least 10.
Efficiency of at least 90%
Contributing scenario controlling worker exposure for 1: Manufacture or formulation in the chemical industry
in closed batch processes with occasional controlled exposure or processes with equivalent containment
condition
article
use
Area of use: : Indoor
Technical conditions and : Closed system
Local exhaust ventilation - efficiency of at least 90 %.
Personal protection : Dermal: Wear chemical-resistant gloves (tested to EN374) in combination with
specific activity training. Efficiency of at least 95 %.
least 10.

CROSSLINKER CX-100
01-2119963929-15 ES2
Contributing scenario controlling worker exposure for 2: Transfer of substance or mixture (charging and
discharging) at dedicated facilities
article
use
workers exposure Exposed skin surface assumed Both hands (960 cm2)
Efficiency of at least 98 %.
least 10.
Contributing scenario controlling worker exposure for 3: Transfer of substance or mixture into small
containers (dedicated filling line, including weighing)
article
use
workers exposure Exposed skin surface assumed Palm of both hands (480 cm2)
least 10.
Contributing scenario controlling worker exposure for 4: Use as laboratory reagent

article
use

CROSSLINKER CX-100
01-2119963929-15 ES2
Respiratory protection : Not applicable. Efficiency of at least 0 %.
Section 3 - Exposure estimation and reference to its source

Website: : Not applicable.
Exposure estimation and reference to its source - Environment: 2: Use of monomer in polymerisation
processes at industrial site (inclusion or not into/onto article)
Exposure assessment : The exposure estimates have been obtained with EUSES although the following
(environment): parameter(s) is/are outside the boundaries of the EUSES model:
• Half-life in Hydrolysis (4.3 h)
Exposure estimation and : Final release factor

reference to its source water : 0.04 %
air : 0 % . Justification : This product is not likely to volatilise rapidly into the
air because of its low vapour pressure.
Soil : 0%
Fresh water : Local Predicted effect concentrations : 0.002 mg/L

RCR = 0.36
Fresh water sediment : Local Predicted effect concentrations :0.024 mg/kg dw
RCR = 0.362
Marine water : Local Predicted effect concentrations : 1.979E-4 mg/L
RCR =0.36
Marine water sediment : Local Predicted effect concentrations : 0.002 mg/kg dw
RCR =0.796
Sewage Treatment Plant : Local Predicted effect concentrations : 0.02 mg/L
RCR < 0.01
Soil : Local Predicted effect concentrations : 0.003 mg/kg dw
RCR = 0.922
Human via the environment - Inhalation : Local Predicted effect concentrations :
6.608E-12 mg/m³ RCR < 0.01
Human via the environment - Oral : 4.366E-4 mg/kg bw/day
RCR < 0.01
Exposure estimation and reference to its source - Workers: 0: Chemical production or refinery in closed
process without likelihood of exposure or processes with equivalent containment conditions
Exposure assessment : The ECETOC TRA tool has been used to estimate workplace exposures unless
(human): otherwise indicated. Version 3.0
Exposure estimation and : Long term exposure Systemic Inhalation : 0.017 mg/m³ RCR = 0.011
reference to its source Long term exposure Systemic Dermal : 0.002 mg/kg bw/day RCR = 0.074
Short term exposure Systemic Inhalation : 0.017 mg/m³ RCR < 0.01
Short term exposure Local Inhalation : 0.017 mg/m³ RCR < 0.01
Exposure estimation and reference to its source - Workers: 1: Manufacture or formulation in the chemical
industry in closed batch processes with occasional controlled exposure or processes with equivalent
containment condition

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Exposure estimation and reference to its source - Workers: 3: Transfer of substance or mixture (charging and
Exposure estimation and : Long term exposure Systemic Inhalation : 0.009 mg/m³ RCR < 0.01
Exposure estimation and reference to its source - Workers: 4: Transfer of substance or mixture into small
Exposure estimation and reference to its source - Workers: 5: Use as laboratory reagent
Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environment : Not available.
Health : Guidance is based on assumed operating conditions which may not be applicable to
all sites; thus, scaling may be necessary to define appropriate site-specific risk
management measures.
Additional good practice advice beyond the REACH CSA

Health : Not available.

CROSSLINKER CX-100
01-2119963929-15 ES3

Industrial
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Formulation for Adhesives
Process Category: PROC03, PROC04, PROC08b, PROC09, PROC15
Substance supplied to that use in form of: As such
Environmental Release Category: ERC02
Environmental : Formulation into mixture - ERC02
contributing scenarios
Health Contributing : Manufacture or formulation in the chemical industry in closed batch
scenarios processes with occasional controlled exposure or processes with equivalent
Chemical production where opportunity for exposure arises - PROC04
General information

measures
Amounts used :
(480 cm2)
Contributing scenario controlling environmental exposure for 0: Formulation into mixture

based on Emission days 220 ( FEICA SPERC 2.1a.v2)
The total use volume is 240 t/y. It is assumed that this is equally distributed over 3
sites.
measures - Air

CROSSLINKER CX-100
01-2119963929-15 ES3
Conditions and measures : FEICA SPERC 2.1a.v2 : Negligible wastewater emissions as process operates
related to external without water contact. Process with efficient use of raw materials. External treatment
treatment of waste for and disposal of waste should comply with applicable local and/or national regulations.
disposal
condition
article
use
least 10.
Contributing scenario controlling worker exposure for 1: Chemical production where opportunity for
exposure arises
article
use
specific activity training.
least 10.

CROSSLINKER CX-100
01-2119963929-15 ES3
article
use
least 10.
Concentration of : 1-5%
article
use
Respiratory protection : No. Efficiency of at least 0 %.( Inhalation exposure )

article
use

CROSSLINKER CX-100
01-2119963929-15 ES3

Exposure estimation and reference to its source - Environment: 2: Formulation into mixture
FEICA SPERC 2.1a.v2
Exposure estimation and : Final release factor (based on FEICA SPERC 2.1a.v2)
reference to its source water : 0.005 %
Soil : 0 %
Fresh water : Local Predicted effect concentrations : 8.911E-4 mg/L

RCR = 0.162
Fresh water sediment : Local Predicted effect concentrations : 0.011 mg/kg dw
RCR = 0.163
RCR = 0.162
RCR = 0.358
RCR < 0.01

RCR = 0.415
2.935E-12 mg/m³ RCR < 0.01
RCR < 0.01
Exposure estimation and reference to its source - Workers: 1: Chemical production where opportunity for
exposure arises

CROSSLINKER CX-100
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Short term exposure Systemic Inhalation : 0.171 mg/m³ RCR = 0.02
Short term exposure Local Inhalation : 0.171 mg/m³ RCR = 0.015


CROSSLINKER CX-100
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Industrial
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Industrial use : Adhesives
Process Category: PROC05, PROC07, PROC08a, PROC08b, PROC09, PROC10,
PROC13, PROC15
Substance supplied to that use in form of: In a mixture
Environmental : Use at industrial site leading to inclusion into/onto article - ERC05
Health Contributing : Mixing or blending in batch processes - PROC05
scenarios Industrial spraying - PROC07
Transfer of substance or mixture (charging and discharging) at non-dedicated
facilities - PROC08a
Roller application or brushing - PROC10
Treatment of articles by dipping and pouring - PROC13
General information

measures
Concentration of substance in product : 1-5%
Amounts used :
(480 cm2)
Contributing scenario controlling environmental exposure for 0: Use at industrial site leading to inclusion into/
onto article
based on Emission days 20 (1 EU site)

CROSSLINKER CX-100
01-2119963929-15 ES4
Conditions and measures : Negligible wastewater emissions as process operates without water contact.
related to external External treatment and disposal of waste should comply with applicable local and/or
treatment of waste for national regulations.
disposal
Waste management : Limit release rate to waste water to 40 g/d
measures - Water
Contributing scenario controlling worker exposure for 0: Mixing or blending in batch processes
article
use
'basic' employee training. Efficiency of at least 95 %.
Eye protection : Chemical splash goggles.
Contributing scenario controlling worker exposure for 1: Industrial spraying

article
use
workers exposure Exposed skin surface assumed Both hands and main part of the arms (1500 cm2)
'basic' employee training. Efficiency of at least see CPC
least 20.
discharging) at non-dedicated facilities
article
use
CROSSLINKER CX-100
01-2119963929-15 ES4
Local exhaust ventilation - efficiency of at least 90 %
'basic' employee training. Efficiency of at least 95 %
Respiratory protection : No. Efficiency of at least 0 %. ( Inhalation exposure )
article
use
article
use

CROSSLINKER CX-100
01-2119963929-15 ES4
Contributing scenario controlling worker exposure for 5: Roller application or brushing

article
use
Efficiency of at least 99.9 %.
Eye protection :Chemically resistant face shield
Contributing scenario controlling worker exposure for 6: Treatment of articles by dipping and pouring
article
use

article
use

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Exposure estimation and reference to its source - Environment: 3: Use at industrial site leading to inclusion
into/onto article

reference to its source water : 4.2E-4 %
Soil : 1 %
Fresh water : Local Predicted effect concentrations : 0.002 mg/L

RCR = 0.359
RCR = 0.361
RCR = 0.359
RCR = 0.794
RCR < 0.01

RCR = 0.92
1.464E-12 mg/m³ RCR < 0.01
RCR < 0.01
Exposure estimation and reference to its source - Workers: 0: Mixing or blending in batch processes
reference to its source Long term exposure Systemic Dermal : 0.014mg/kg bw/day RCR = 0.596
Exposure estimation and reference to its source - Workers: 1: Industrial spraying

CROSSLINKER CX-100
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Exposure estimation and reference to its source - Workers: 6: Roller application or brushing
Exposure estimation and reference to its source - Workers: 7: Treatment of articles by dipping and pouring
reference to its source Long term exposure Systemic Dermal : 3.4E-4 mg/kg bw/day RCR = 0.015


CROSSLINKER CX-100
01-2119963929-15 ES7

Industrial
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Formulation of Coatings
Process Category: PROC01, PROC02, PROC03, PROC05, PROC08a, PROC08b,
PROC09, PROC15
Substance supplied to that use in form of: As such, In a mixture
Market sector by type of chemical product: PC09a
Environmental : Formulation into mixture - ERC02
Chemical production or refinery in closed continuous process with
occasional controlled exposure or processes with equivalent containment
conditions - PROC02
Mixing or blending in batch processes - PROC05
General information

measures
Amounts used :
(480 cm2)
Contributing scenario controlling environmental exposure for 0: Formulation into mixture

based on Emission days 225 ( CEPE SPERC 2.1b.v1 , CEPE SPERC 2.2b.v1)
measures - Air

CROSSLINKER CX-100
01-2119963929-15 ES7
Conditions and measures : CEPE SPERC 2.1b.v1 , CEPE SPERC 2.2b.v1
related to external Process with efficient use of raw materials. External treatment and disposal of waste
treatment of waste for should comply with applicable local and/or national regulations.
disposal
article
use
Local exhaust ventilation - efficiency of at least 0 %. ( Inhalation )
least 10.
Contributing scenario controlling worker exposure for 1: Chemical production or refinery in closed
continuous process with occasional controlled exposure or processes with equivalent containment
conditions
article
use

CROSSLINKER CX-100
01-2119963929-15 ES7
condition
article
use
least 10.
article
use
Respiratory protection : No. Efficiency of at least 0 ( Inhalation exposure )
article
use

CROSSLINKER CX-100
01-2119963929-15 ES7
article
use
least 10.
article
use

CROSSLINKER CX-100
01-2119963929-15 ES7

article
use
Respiratory protection : No. Efficiency of at least 0 %.

Exposure estimation and reference to its source - Environment: 1: Formulation into mixture
CEPE SPERC 2.1b.v1, CEPE SPERC 2.2b.v1
reference to its source water : 0 %
Soil : 0 %

RCR < 0.01
Fresh water sediment : Local Predicted effect concentrations : 7.481E-6 mg/kg dw
RCR < 0.01

RCR < 0.01
Marine water sediment : Local Predicted effect concentrations : 1E-7 mg/kg dw
RCR < 0.01

Sewage Treatment Plant : Local Predicted effect concentrations : 0 mg/L
RCR < 0.01
Soil : Local Predicted effect concentrations : 2.991E-7 mg/kg dw
RCR < 0.01
1.098E-12 mg/m³ RCR < 0.01
RCR < 0.01

CROSSLINKER CX-100
01-2119963929-15 ES7
conditions

CROSSLINKER CX-100
01-2119963929-15 ES7


CROSSLINKER CX-100
01-2119963929-15 ES8

Industrial
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Industrial use of Coatings
Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC07,
PROC08b, PROC10, PROC13, PROC15
Environmental : Use at industrial site leading to inclusion into/onto article - ERC05
Chemical production or refinery in closed continuous process with
occasional controlled exposure or processes with equivalent containment
conditions - PROC02
Industrial spraying - PROC07
General information

measures
Amounts used :
(480 cm2)
Contributing scenario controlling environmental exposure for 0: Use at industrial site leading to inclusion into/
onto article
Amounts used : Daily amount per site :<=240kg/day
based on Emission days 225
measures - Air
CROSSLINKER CX-100
01-2119963929-15 ES8
Conditions and measures : Process with efficient use of raw materials. External treatment and disposal of waste
related to external should comply with applicable local and/or national regulations.
treatment of waste for
disposal
article
use
Local exhaust ventilation - efficiency of at least 0 %. ( Inhalation )
conditions
article
use
condition
article
use

CROSSLINKER CX-100
01-2119963929-15 ES8

least 10.
exposure arises
article
use
article
use

CROSSLINKER CX-100
01-2119963929-15 ES8
Contributing scenario controlling worker exposure for 5: Industrial spraying

article
use
workers exposure Exposed skin surface assumed Hands and forearms (1500 cm2)
least 20.
article
use

article
use

CROSSLINKER CX-100
01-2119963929-15 ES8

specific activity training. Efficiency of at least 99.9 %.
Eye protection Eye protection : Yes. face shield
article
use

article
use

Exposure estimation and reference to its source - Environment: 0: Use at industrial site leading to inclusion
into/onto article
CEPE SPERC 5.1a.v1

CROSSLINKER CX-100
01-2119963929-15 ES8

air : 0 %
Soil : 0 % Justification : CEPE SPERC 5.1a.v1 ( for Solids)

RCR < 0.01
RCR < 0.01

RCR < 0.01
Marine water sediment : Local Predicted effect concentrations :1E-9 mg/kg dw
RCR < 0.01

Sewage Treatment Plant : Local Predicted effect concentrations : 0 mg/L
RCR < 0.01
RCR < 0.01
1.098E-12 mg/m³ RCR < 0.01
RCR < 0.01
Exposure estimation and : Long term exposure Systemic Inhalation :0.034 mg/m³ RCR = 0.021
conditions
Exposure estimation and : Long term exposure Systemic Inhalation :0.034 mg/m³ RCR = 0.021
exposure arises

CROSSLINKER CX-100
01-2119963929-15 ES8
Exposure estimation and reference to its source - Workers: 6: Industrial spraying



CROSSLINKER CX-100
01-2119963929-15 ES9

Professional
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Professional use of Coatings, Indoor use
Process Category: PROC02, PROC03, PROC04, PROC05, PROC08a, PROC08b,
PROC10
Environmental : Widespread use leading to inclusion into/onto article (indoor) - ERC08c
Health Contributing : Chemical production or refinery in closed continuous process with
scenarios occasional controlled exposure or processes with equivalent containment
conditions - PROC02
General information

measures
Amounts used :
(480 cm2)
Contributing scenario controlling environmental exposure for 0: Widespread use leading to inclusion into/
onto article (indoor)
Amounts used : Daily amount for wide dispersive uses : <= 2 kg/day
Conditions and measures : Municipal Sewage Treatment Plant : Yes. Efficiency of at least1.048
related to sewage Size of municipal sewage system/treatment plant (m3/d) : >= 2E3

CROSSLINKER CX-100
01-2119963929-15 ES9
disposal
conditions
article
use
Advice on general : Assumes a good basic standard of occupational hygiene is implemented
occupational hygiene
In case of possible exposure: Eye protection: Chemical splash goggles. Avoid direct
eye contact with product, also via contamination on hands.
condition
article
use
'basic' employee training. Efficiency of at least 90 % .
exposure arises
article
use

CROSSLINKER CX-100
01-2119963929-15 ES9
'basic' employee training. Efficiency of at leastsee CPC
article
use
article
use

CROSSLINKER CX-100
01-2119963929-15 ES9
article
use
Local exhaust ventilation - efficiency of at least Inhalation : 90 %
Local exhaust ventilation - efficiency of at least Dermal : 80 %

article
use
Efficiency of at least 99.9 %.

Exposure estimation and reference to its source - Environment: 0: Widespread use leading to inclusion into/
air : 0 % Justification : This product is not likely to volatilise rapidly into the
Soil : 0 %
Fresh water : Local Predicted effect concentrations :9.9E-4 mg/L

RCR = 0.18

CROSSLINKER CX-100
01-2119963929-15 ES9
RCR =0.181
RCR = 0.18
RCR = 0.398
RCR < 0.01

RCR = 0.461
Human via the environment - Inhalation : Local Predicted effect concentrations
: 4.45E-12 mg/m³ RCR < 0.01
RCR < 0.01
conditions
exposure arises

CROSSLINKER CX-100
01-2119963929-15 ES9


CROSSLINKER CX-100
01-2119963929-15 ES10

Professional
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Professional use of Coatings , Outdoor
Process Category: PROC03
Environmental Release Category: ERC08f
Environmental : Widespread use leading to inclusion into/onto article (outdoor) - ERC08f
Health Contributing : Manufacture or formulation in the chemical industry in closed batch
scenarios processes with occasional controlled exposure or processes with equivalent
General information

measures
Amounts used :
Exposed skin surface assumed Palm of one hand
(240 cm2)
onto article (outdoor)
Amounts used : Daily amount for wide dispersive uses :<= 8.25E-6 tonne per day

Conditions and measures : Municipal Sewage Treatment Plant : Yes. Efficiency of at least1.048
disposal

CROSSLINKER CX-100
01-2119963929-15 ES10
condition
article
use
Area of use: : Outdoor
Technical conditions and : Closed batch process with occasional controlled exposure
least 10.

onto article (outdoor)
air : 0 % Justification : This product is not likely to volatilise rapidly into the
Soil : 0.5 %

RCR < 0.01
RCR < 0.01

RCR < 0.01
Marine water sediment : Local Predicted effect concentrations : 5.025E-6 mg/kg dw
RCR < 0.01

Sewage Treatment Plant : Local Predicted effect concentrations : 4.082E-5 mg/L
RCR < 0.01

RCR < 0.01
1.112E-12 mg/m³ RCR < 0.01
RCR < 0.01

CROSSLINKER CX-100
01-2119963929-15 ES10
reference to its source
Long term exposure Systemic Dermal : 0.014 mg/kg bw/day RCR = 0.6


CROSSLINKER CX-100
01-2119963929-15 ES5

Professional
Code : 030119WW53246 - EU - TR
Section 1 - Title
scenario
List of use descriptors : Identified use name: Professional use : Adhesives
Process Category: PROC08a, PROC08b, PROC09, PROC10, PROC13
Environmental : Widespread use leading to inclusion into/onto article (indoor) - ERC08c
Health Contributing : Transfer of substance or mixture (charging and discharging) at non-dedicated
scenarios facilities - PROC08a
General information

measures
Amounts used :
(480 cm2)
Amounts used : Daily amount for wide dispersive uses :<= 0.0275 kg/day
Conditions and measures : Municipal Sewage Treatment Plant : Yes. Efficiency of at least 1.048 %
disposal

CROSSLINKER CX-100
01-2119963929-15 ES5
article
use
article
use
article
use

CROSSLINKER CX-100
01-2119963929-15 ES5

article
use
Efficiency of at least 99,9 %.
article
use


CROSSLINKER CX-100
01-2119963929-15 ES5

Soil : 0 %

RCR < 0.01
RCR < 0.01

RCR < 0.01
Marine water sediment : Local Predicted effect concentrations : 1.652E-5 mg/kg dw
RCR < 0.01

Sewage Treatment Plant : Local Predicted effect concentrations : 1.361E-4 mg/L
RCR < 0.01

RCR < 0.01
1.144E-12 mg/m³ RCR < 0.01
RCR < 0.01

CROSSLINKER CX-100
01-2119963929-15 ES5



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Conforms to Regulation (EC) No.

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

CAS number : Not available.

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.2 Label elements

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 1/59

Signal word : Danger

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Product/ingredient name Identifiers % Classification

Reaction mass of 2-ethyl-2-[[3- REACH #: 100 Acute Tox. 4, H302

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 2/59

2-methylaziridine EC: 200-878-7 0 - 0.0009802 Flam. Liq. 2, H225

allylamine EC: 203-463-9 0 - 0.0000099 Flam. Liq. 2, H225

xylene, mixture of isomers REACH #: 0 - 0.0000099 Flam. Liq. 3, H226

SECTION 4: First aid measures

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 3/59

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.3 Methods and material for containment and cleaning up

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 4/59

6.4 Reference to other : See Section 1 for emergency contact information.

SECTION 7: Handling and storage

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 5/59

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 6/59

Fresh water sediment 12.46 mg/kg Assessment Factors

8.2 Exposure controls

SECTION 9: Physical and chemical properties

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 7/59

Explosive properties : Not available.

9.2 Other information

SECTION 10: Stability and reactivity

10.2 Chemical stability : The product is stable.

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : Acids , Strong oxidising materials .

10.6 Hazardous : No specific data.

SECTION 11: Toxicological information

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 8/59

Conclusion/Summary : Not available.

Conclusion/Summary : Not available.

Conclusion/Summary : Not available.

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 9/59

Skin contact : May cause an allergic skin reaction.

SECTION 12: Ecological information

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 10/59

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 11/59

SECTION 14: Transport information

14.2 UN proper ENVIRONMENTALLY ENVIRONMENTALLY ENVIRONMENTALLY Environmentally

14.4 Packing III III III III

Date of issue/Date of revision : 4 March 2019 Version : 7 Page: 12/59