Boiler Exit Flue Gas Carbon Di Oxide(Co2% to O%) to Oxygen conversion

UNIT

Theoritical CO2% as per stochemetric fuel analysis calc. %

12.5
CHEMICAL EQUATION FOR COMBUSTION OF METHANOL FUEL
METHANOL ( CH3OH)

METHANOL ⁺ OXYGEN ⁼ CARBON DI OXIDE ⁺ WATER ⁺ Nitrogen

CH3OH ⁺ O2 ⁼ CO2 ⁺ H20 ⁺ N2

solve the eqaution
2CH3OH ⁺ 3(O2+3.76N2) ⁼ 2CO2 ⁺ 4H20 ⁺ 11.28N2
or
CH3OH ⁺ 1.5(O2+3.76N2) ⁼ CO2 ⁺ 2H2O ⁺ 5.64N2

MOLAR WEIGHT CALCULATION OF METHANOL

CHEMICAL M.W g/MOL C NUMBER OF ELEMENT TOTAL

CH3OH
CARBON 12 1 12
HYDROGEN 1 4 4
OXYGEN 16 1 16
32

ACETONE ( C3H6O)

ACETONE ⁺ OXYGEN ⁼ CARBON DI OXIDE ⁺ WATER ⁺ NITROGEN

C3H6O ⁺ O2 ⁼ CO2 ⁺ H20 ⁺ N2

solve the eqaution
C3H6O ⁺ 4(O2+3.76N2) ⁼ 3CO2 ⁺ 3H20 ⁺ 15.04N2

MOLAR WEIGHT CALCULATION OF ACETONE

CHEMICAL M.W g/MOL C NUMBER OF ELEMENT TOTAL

CH3OH
CARBON 12 3 36
HYDROGEN 1 6 6
OXYGEN 16 1 16
58
 RESIN ( C2H4O)

RESIN ⁺ OXYGEN ⁼ CARBON DI OXIDE ⁺ WATER ⁺ NITROGEN

C2H4O ⁺ O2 ⁼ CO2 ⁺ H20 ⁺ N2

solve the eqaution
C2H4O ⁺ 2.5(O2+3.76N2) ⁼ 2CO2 ⁺ 2H20 ⁺ 9.4N2

MOLAR WEIGHT CALCULATION OF RESIN

CHEMICAL M.W g/MOL C NUMBER OF ELEMENT TOTAL

CH3OH
CARBON 12 2 24
HYDROGEN 1 4 4
OXYGEN 16 1 16
44

IPA ( C3H8O)

IPA ⁺ OXYGEN ⁼ CARBON DI OXIDE ⁺ WATER ⁺ NITROGEN

C3H8O ⁺ O2 ⁼ CO2 ⁺ H20 ⁺ N2

solve the eqaution
C3H8O ⁺ 4.5(O2+3.76N2) ⁼ 3CO2 ⁺ 4H20 ⁺ 16.92N2

MOLAR WEIGHT CALCULATION OF IPA

CHEMICAL M.W g/MOL C NUMBER OF ELEMENT TOTAL

CH3OH
CARBON 12 3 36
HYDROGEN 1 8 8
OXYGEN 16 1 16
60

THF ( C4H8O)
 THF ⁺ OXYGEN ⁼ CARBON DI OXIDE ⁺ WATER ⁺ NITROGEN

C4H8O ⁺ O2 ⁼ CO2 ⁺ H20 ⁺ N2

solve the eqaution
C4H8O ⁺ 5.5O2+3.76N2 ⁼ 4CO2 ⁺ 4H20 ⁺ 20.68N2

MOLAR WEIGHT CALCULATION OF THF

CHEMICAL M.W g/MOL C NUMBER OF ELEMENT TOTAL

CH3OH
CARBON 12 4 48
HYDROGEN 1 8 8
OXYGEN 16 1 16
72
 Total Fuel Quanity
CHEMICAL M.W g/MOL C NUMBER OF EL TOTAL 110
1.5O2
OXYGEN 16 3 48
48
CO2
CARBON 12 1 12
OXYGEN 16 2 32
44
2H20
HYDROGEN 1 4 4
OXYGEN 16 2 32
36

5.64N2
OXYGEN 16 3 48
48

CHEMICAL M.W g/MOL C NUMBER OF EL TOTAL

4O2
OXYGEN 16 8 128
128
3CO2
CARBON 12 3 36
OXYGEN 16 6 96
132
3H2O
HYDROGEN 1 6 6
OXYGEN 16 3 48
54
CHEMICAL M.W g/MOL C NUMBER OF EL TOTAL
2.5O2
OXYGEN 16 5 80
80
2CO2
CARBON 12 2 24
OXYGEN 16 4 64
88
2H20
HYDROGEN 1 4 4
OXYGEN 16 2 32
36

CHEMICAL M.W g/MOL C NUMBER OF EL TOTAL

4.5O2
OXYGEN 16 9 144
144
3CO2
CARBON 12 3 36
OXYGEN 16 6 96
132
4H20
HYDROGEN 1 8 8
OXYGEN 16 4 64
72
CHEMICAL M.W g/MOL C NUMBER OF EL TOTAL
5.5O2
OXYGEN 16 5.5 88
88
4CO2
CARBON 12 4 48
OXYGEN 16 8 128
176
4H20
HYDROGEN 1 8 8
OXYGEN 16 4 64
72
Fuel Quanity
 FUEL M.W % LITRES DENSITY( Kg/m3) KG
METHANOL 32 25 27.5 0.79 21.725
ACETONE 58 12.5 13.75 0.78 10.725
HTPB 44 25 27.5 0.9 24.75
IPA 60 25 27.5 0.79 21.725
THF 72 12.5 13.75 0.889 12.22375
266 100 110 91

FUEL Mass of CO2 Mass of H20 Mass of N2 Total Mass CO2 in %

METHANOL 1 2 5.6 8.6 2.9
ACETONE 3 3 15.4 21.4 1.8
HTPB 2 2 9.4 13.4 3.7
IPA 3 4 16.9 23.9 3.1
THF 4 4 20.68 28.68 1.7
13 15 67.98 95.98 14

FD FAN POWER CONSUMPTION

FD fan capacity (% MCR ) 100 %
MCR airflow required for combustion 0.42 m3/s
MCR airflow of FD fan 0.42 m3/s

Margin on FD fan flow 25 %

Design Flow for FD fan 0.52 M3/s

FD fan Design head 150 mmwc

Assumed FD fan efficiency 65 %
FD fan operating power required 1.2 KW

Minimum motor power required 3 KW

Minimum motor power required for FD fan 3 KW
Kmoles M.W OF OXYGEN mass of Oxygen Kmol OF O2 M.W OF CO2 Mass of CO2
0.679 48.0 1.5 1.018 44.000 1.0
0.185 128.0 4.0 0.740 132.000 3.0
0.563 80.0 2.5 1.406 88.000 2.0
0.362 144.0 4.5 1.629 132.000 3.0
0.170 88.0 5.5 0.934 176.000 4.0
1.958 488.0 18.0 5.727 572.0 13.0

H2O% M.W OF OXYGEN mass of Oxygen N2% M.W OF CO2 Mass of CO2
6.4 17.907
1.9 9.895
4.1 19.291
4.6 19.446
1.9 9.915
16 502 614 71

Combustion air required for Total fuel

Stocheometric Air flow required Kg/Kg

Stochemetric air inluding 150% of EA

Oxygem % in Atmosphere air

Total air required for Comnustion

Total air required as per fuel flow rate

Total air required as per fuel flow rate@ 0 Deg C

Total air required as per fuel flow rate@ 0 Deg C
Total air required as per fuel flow rate@ 30 Deg C
 K mol CO2 M.W OF WATER Mass of H20 K mol OF H2O
0.679 36 2 1.358 0.25 0.5 4.476744
0.555 54 3 0.555 0.375 0.375 1.236857
1.125 36 2 1.125 0.5 0.5 4.822761
1.086 72 4 1.448 0.75 1 4.861402
0.679 72 4 0.679 0.5 0.5 1.239322
4.124 270.0 15.0 5.2 2.375 2.875 16.63709

M.W OF WATER Mass of H20

uired for Total fuel

1.83 Kg/Kg

4.59 kg/kg 2.7518796992

23.00 %

19.94 Kg/Kg

1817.61 Kg/Hr

1348.60 Nm3/hr
0.37 Nm3/sec
0.42 M3/Sec