Part Test - 1 Chemistry (Main)

PART (B) : CHEMISTRY

SECTION-I : (SINGLE ANSWER CORRECT TYPE)

This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.

26. Percentage of Se in peroxidase anhydrase enzyme is 0.5% by weight (at.wt=78.4) then minimum
molecular weight of peroxides anhydrase enzyme is
(A) 1.568  103 (B) 15.68 (C) 2.136  104 (D) 1.568  10 4

27. Arrange the following sub-shell in increasing order of energy,

(i) n = 4, l = 1, (ii) n = 4, l = 0, (iii) n = 3, l = 2, (iv) n = 3, l = 1,
from the lowest to highest
(A)  iv    ii    iii    i  (B)  ii    iv    i    iii 
(C)  i    iii    ii    iv  (D)  iii    i    iv    ii 

28. If the nitrogen atom has electronic configuration 1s 7 it would have energy lower than that of the
normal ground state configuration 1s 2 2s 2 2p3 because the electrons would be closer to the nucleus.
Yet 1s 7 is not observed. It violates
(A) Heisenberg’s uncertainty principle
(B) Hund’s rule
(C) Pauli exclusion principle
(D) Bohr postulate of stationary orbits

29. For a gas, maximum deviation from ideal gas behaviour is observed at:
(A) 0oC and 1.0 atm (B) 100oC and 2.0 atm
o
(C) –100 C and 2.00 atm (D) –100oC and 5.0 atm

30. A container contains 1 mole of a gas at 1 atm pressure and 27oC, while its volume is 24.6 litre. If its
pressure is 10 atm and temperature 327oC, then the new volume is
(A) 2.56 litres (B) 3.15 litres (C) 4.92 litres (D) 5.44 litres

31. A spontaneous reaction is impossible if

(A) both H and S are negative (B) both H and S are positive
(C) H is negative and S is positive (D) H is positive and S is negative

32. The values of heat of formation of SO 2 and SO3 are 298.2 kJ and 98.2 kJ . The heat of
reaction of SO 2  1/ 2  O 2  SO3 will be
(A) 200 kJ (B) 356.2 kJ (C) 200 kJ (D) 396.2 kJ

33. Which one of the following compounds is not protonic acid?

(A) SO 2  OH 2 (B) B  OH 3 (C) PO  OH 3 (D) SO  OH  2

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Part Test - 1 Chemistry (Main)

34. About buffer solution which is incorrect?

(A) It contains a weak acid and its conjugate base
(B) It contains a weak base and its conjugate acid
(C) It shows change in pH on adding small amount of acid or base
(D) All of the above

35. In which of the following solvents. AgBr will have the highest solubility?
(A) 103 M NaBr (B) 103 M NH 4 OH (C) Pure water (D) 103 M HBr

36. Calculate the pOH of a solution at 25 C that contains 1 1010 M of hydronium ions, i.e. H3 O .
(A) 4.000 (B) 9.0000 (C) 1.000 (D) 7.000

37. When sodium acetate is added to an aqueous solution of acetic acid:

(A) The pH of the solution decreases
(B) The pH of the solution increases
(C) The pH of the solution remains unchanged
(D) An acid salt is produced

38. Which of the following arrangements represent increasing oxidation number of the central atom?
(A) CrO 2 , ClO 3 , CrO 42  , MnO 4 (B) ClO 3 , CrO 42  , MnO 4 , CrO 2
(C) CrO 2 , ClO 3 , MnO 4 , CrO 42  (D) CrO 24  , MnO 4 , CrO 2 , ClO 3

39. CsBr has bcc structure with edge length 4.3 Å. The shortest inter ionic distance in (Å) between Cs 
and Br  is
(A) 3.72 (B) 1.86 (C) 7.44 (D) 4.3

40. All are ideal solution except

(A) C 6 H 6 and C6 H5 CH 3 (B) C 2 H 6 and C 2 H 5 I
(C) C6 H 5Cl and C6 H 5 Br (D) C 2 H 5 I and C2 H 5 OH

41. Which of the following aqueous solutions has minimum freezing point?
(A) 0.01m NaCl (B) 0.005m C 2 H 5 OH
(C) 0.005m MgI2 (D) 0.005m MgSO4

42. Molarity of liquid HCl will be, if density of solution is 1.17 gm/cc
(A) 36.5 (B) 32.05 (C) 18.25 (D) 42.10

43. Standard electrode potential for Sn 4 / Sn 2  couple is 0.15 V and that for the Cr 3 / Cr couple is
0.74 V . These two couples in their standard state are connected to make a galvanic cell. The cell
potential will be:
(A) 1.19V (B) 0.89 V (C) 0.18 V (D) 1.83 V

44. If 0.5 amp current is passed through acidified silver nitrate solution for 100 minutes. The mass of
silver deposited on cathode, is (eq. Wt of silver nitrate =108)
(A) 2.3523 g (B) 3.3575 g (C) 5.3578 g (D) 6.3575 g

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45. Specific conductance of a 0.1 N KCl solution at 23 C is 0.012 ohm 1 cm 1 . Resistance of cell
containing the solution at same temperature was found to be 55 ohm. The cell constant is
(A) 0.918cm 1 (B) 0.66 cm 1 (C) 1.142 cm 1 (D) 1.12cm1

SECTION-II : (INTEGER ANSWER TYPE)

This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the
second decimal place; e.g. 6.25, 7.00, 0.33, 30.27, 127.30)

46. In a buffer solution containing equal concentration of B and HB, the K b for B is 10 10 . The pH of
buffer solution is

47. In the balanced chemical reaction (with lowest possible integers)

IO3  aI   bH  
 cH 2 O  dI 2
Determine value of a + c?

48. Consider a reaction aG  bH   Products. When concentration of both the reactants G and H is
doubled, the rate increases by eight times. However, when concentration of G is doubled keeping the
concentration of H fixed, the rate is doubled. The overall order of the reaction is

49. The following mechanism has been proposed for the reaction of NO with Br2 to form NOBr:
 NOBr2  g 
NO  g   Br2  g  
NOBr2  g   NO  g  
 2NOBr  g 
If the second step is the rate determining step, the order of the reaction with respect to NO(g) is

50. The number of orbital(s) among the following having zero probability of finding electron along
z-axis?
(i) 3Pz (ii) 2Px (iii) 3d xy (iv) 4d xz
(v) 4s (vi) 3d yz (vii) 4d z 2

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