Safety Data Sheet

according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

Section 1. Identification of the substance/ mixture and of the company/ undertaking

1.1 Product identifier

Product name: KIBILAC ®
This safety data sheet pertains to the following products: PW-957, PW-997, PW-997G and PW-997S.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Mixture used for the production of molded plastic articles

1.3 Details of the supplier of the Safety Data Sheet

Supplier: Chi Mei Corporation
Address: 59-1, San Chia, Jen Te Village
Tainan City
Taiwan R.O.C.
Telephone: +886 6 2663000 Ext. 1347
Email: service@mail.chimei.com.tw

1.4 Emergency telephone number

Emergency telephone : +886 6 2663000 Ext. 2501

Section 2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Directive 67/548/EEC or 1999/45/EC: Not classified as hazardous (polymeric state)

Classification according to Regulation (EC) N° 1272/2008 (CLP): Not classified as hazardous (polymeric state)

2.2 Label elements

Not labelled as hazardous

2.3 Other hazards

vPvB/PBT assessment: not available
Swallowing may cause gastrointestinal irritation and pain of guts.

Section 3. Composition/information on ingredients

3.1 Composition of the substance/ preparation

Substance or Preparation Substance
Content
CAS Name content
26299-47-8 Acrylonitrile-Styrene-Acrylate Copolymer ＞97 %
- Additives ≦3 %
Impurities Contributing to Hazard None

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

3.2 Additional information:

Reach Info:
Registration No.
Acrylonitrile 01-2119474195-34-0045
01-2119457861-32-0006
01-2119457861-32-0007
Styrene 01-2119457861-32-0057
01-2119457861-32-0065
01-2119457861-32-0081
Butyl acrylate 01-2119453155-43-0017
Pentaerythritol stearate (PETS) 01-2119971071-44-0006

3.3 For full text of R- and H-phrases: see section 16

Section 4. First-aid measures

4.1 Description of first aid measures
General notes: Remove affected persons from the danger area, at the same time ensuring your own safety. Remove all
contaminated clothing immediately
Following inhalation: In case of gases evolving from melted resin, move subject to fresh air. Treat symptomatically
Following skin contact: In case of pellets or powder, wash with water. In case of smelt, wash affected skin area and clothing with
plenty of (soap and) water. Seek medical advice
Following eye contact: In case of pellets or powder, flush with plenty of water for at least 15 minutes. Seek medical advice if any
dust particles still remain.
In case of gases evolving from melted resin of high temperature, flush with plenty of water for at least 15 minutes. Seek medical
advice if necessary
Following ingestion: Induce vomiting. Rinse mouth with water. Seek medical advice if necessary
Self-protection of the first aider: -

4.2 Most important symptoms & effects both acute & delayed
Dust: Skin irritation, eye irritations and redness

4.3 Indication of any immediate medical attention and special treatment needed: -
Treat symptomatically.(Decontamination, vital functions)

Section 5. Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing agents: Water, foam, dry chemical powder
For safety reasons unsuitable extinguishing agents: -

5.2 Special hazards arising from the substance or mixture: -

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

5.3 Advice for firefighters

Protective equipment: Self-contained breathing apparatus
Further measures: -

5.4 Additional information: -

Section 6. Accidental release measures

6.1 Personal precautions, protective equipment & emergency procedures
Pellets or powder remained on ground may cause slipping
Wear protective equipment
Ensure adequate ventilation
Keep away from ignition sources
Keep unprotected persons away

6.2 Environmental precautions

Gather pellets and powder thoroughly to avoid birds or fishes taking from draining water.
Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water,
sewage system or soil

6.3 Methods and material for containment and cleaning up

Recovery if not contaminated or disposal

6.4 Reference to other sections

See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment.

Section 7. Handling and storage

7.1 Precautions for safe handling
Protective measures: -
Measures to prevent fire: Prevent from fire around handling area
Measures to prevent aerosol and dust generation: maintain good housekeeping standards to prevent accumulation of dust. To
avoid dust explosion resulting from the existence of powder, electrostatics eliminators and grounding should be fixed to such
equipment as air transferring pipes, bag filters and hoppers. Use electrically conductive filters for bag filters.
Measures to protect the environment: -
Advice on general occupational hygiene: -

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions: Keep the material at a cool dry place. Protect from direct sunlight, rain and violent
temperature fluctuation. Fire is inhibited around storage area.
Requirements for storage rooms and vessels: -
Suitable materials and coating: -
Unsuitable materials or coatings: -
Further information on storage conditions: -

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

7.3 Specific end use(s)

Recommendations: -

Section 8. Exposure controls/personal protection

8.1 Control parameters
Exposure Limits:None established

8.2 Exposure control

Appropriate engineering controls: Install eyes washer and shower in the place of operation. Provide local exhaust ventilation
system. Ensure compliance with applicable exposure limits
Personal protection:
- Respiratory protection: Wear masks for cleaning molding machines
- Hand protection: Heat-insulting gloves when handling molten form
- Eye protection: Wear safety glasses for general purpose. Wear chemical goggles for cleaning molding machines
- Skin and body protection: Gloves necessary for handling melted resin
- Hygiene measures: Wash hands after handling

8.3 Environmental exposure controls

Product related measures to prevent exposure: None specific
Instruction measures to prevent exposure: None specific
Organizational measures to prevent exposure: None specific
Technical measures to prevent exposure: None specific
Environmental exposure controls: Do not allow product to reach sewage system or water bodies

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance Physical state: solid, granulate

Odour Odourless or negligible
Colour Off-white
Odour threshold None
pH Not applicable
Melting point / freezing point Not determined
Initial boiling point and boiling range Not applicable
Flash point 404 °C
Evaporation rate Not available
Flammability (solid, gas) Not available
Vapour pressure Not applicable
Vapour density Not applicable
Specific Gravity 1.03 ~ 1.10
Bulk density Not available
Solubility(ies) Insoluble in water
Partition coefficient (n-octanol/water) Not available
Auto-ignition temperature 466 °C
Decomposition temperature > 300 °C
Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties Not oxidizing
Combustion Energy 3.53 x 107 J/kg (8424 Kcal/kg)

9.2 Other safety information: -

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

Section 10. Stability and reactivity

10.1 Reactivity: Non-reactive under normal handling and storage conditions

10.2 Chemical stability: Stable under normal handling and storage conditions

10.3 Possible hazardous reaction: -

10.4 Conditions to avoid: Avoid excessive heat, flames and all sources of ignition

10.5 Incompatible materials: not applicable

10.6 Hazardous decomposition products: not applicable

Section 11. Toxicological information

11.1 Information on toxicological effects

Information on the likely routes of exposure: Oral, Dermal, Inhalation.

Potential acute health effects

Skin contact : No known significant effects or critical hazards.
Eye contact : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Ingestion: No specific data.
Inhalation :No specific data.
Eye contact : No specific data.

Section 12. Ecological information

12.1 Toxicity
no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

To avoid bioaccumulation plastics should not be disposed in the sea or in other water environments.

12.4 Mobility in soil

no data available
12.5 Results PBT & vPvB assessment
According to the revised Annex XIII of regulation (EC) 1907/2006 and (EC) 253/2011: No information available on the product
as such

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

12.5 Other adverse effects:

General information: Do not allow to enter into ground-water, surface water or drains.

12.7 Additional information: -

Section 13. Disposal considerations

13.1 Waste treatment methods

Product / Packaging disposal: Dispose in accordance with the current local regulations.
Waste codes according to European Waste Catalogue: -
Waste treatment-relevant information: Inadequate incineration may generate toxic gases such as CO, HCN, AN and SM
Sewage disposal-relevant information: -
Other disposal recommendations: -

Section 14. Transport information

ADR/RID
14.1 UN number
Not applicable
14.2 UN proper shipping name
Proper Shipping Name: NOT REGULATED
14.3 Transport hazard class(es)
Not applicable
14.4 Packing Group
Not applicable
14.5 Environmental hazards
Not considered environmentally hazardous based on available data
14.6 Special precautions for user
Special Provisions: no data available
Hazard identification No:no data available

ADNR / ADN
14.1 UN number
Not applicable
14.2 UN proper shipping name
Proper Shipping Name: NOT REGULATED
14.3 Transport hazard class(es)
Not applicable
14.4 Packing Group
Not applicable
14.5 Environmental hazards
Not considered environmentally hazardous based on available data
14.6 Special precautions for user
no data available

IMDG
14.1 UN number
Not applicable
14.2 UN proper shipping name
Proper Shipping Name: NOT REGULATED
14.3 Transport hazard class(es)
Not applicable

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

14.4 Packing Group

Not applicable
14.5 Environmental hazards
Not considered environmentally hazardous based on available data
14.6 Special precautions for user
EMS Number: Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

ICAO/IATA
14.1 UN number
Not applicable
14.2 UN proper shipping name
Proper Shipping Name: NOT REGULATED
14.3 Transport hazard class(es)
Not applicable
14.4 Packing Group
Not applicable
14.5 Environmental hazards
Not considered environmentally hazardous based on available data
14.6 Special precautions for user
no data available

Section 15. Regulatory information

15.1 Safety, health and environmental regulations /legislation specific for the substance or mixture
Authorization and / or restrictions on use: None
Other national regulations: -
15.2 Chemical Safety Assessment
For this substance a chemical safety assessment is not yet required.

Section 16. Other information

16.1 Indication of changes

Version 1: First issue according to Regulations (EC) 1907/2006 (REACH) & 1272/2008 (CLP)

16.2 Abbreviations and acronyms

AGS Ausschuss für Gefahrstoffe LoW List of Waste

AF Assessment Factor MARPOL MARine POLlution
BCF BioConcentration Factor MIE Minimum Ignition Energy
CAS Chemical Abstract Service N°EC European Commission number
CMR Carcinogenic, Mutagenic and Reprotoxic NFPA National Fire Protection Association
CSR Chemical Safety Report NIOSH National Institute of Occupational Safety and Health
DFG German Research Foundation NOEC No Obseved Effect Concentration
DNEL Derived No Effect Level NOELR No Observed Effect Loading Rate
EC European Commission OECD Organisation for Economic Co-operation
and Development
EC50 Effective Concentration OEL Occupational Exposure Limit
(required to induce a 50% effect)
EEC European Economic Community OSHA Occupational Safety and Health Administration
EWC European Waste Catalogue Code PBT Persistant Bioaccumulable Toxique

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 Safety Data Sheet
according to EC 1907/2006 (REACH) and 1272/2008 (CLP)

Revision Date: June 19,2018

Product name: KIBILAC ® ASA Version 2 Print Date: July 23, 2018

IDLH Immediately Dangerous to Life or Health PNEC Previsible Non Effect Concentration
IBC International Bulk Chemical QSAR Quantitative Structure-Activity Relationship
Koc Soil/Water Partition Coefficient STOT Specific Target Organ Toxicity
Kow Octanol/Water Partition Coefficient TCLo Toxic Concentration Low
LC50 Lethal Concentration 50 TDLo Toxic Dose Low
LD50 Lethal Dose 50 UN United Nations
LEL Lower Explosive Limit UVCB Unknown or Variable Composition Complex
Reaction Products, or Biological Materials
LL100 Lethal Loading vPvB very Persistent, very Bioaccumulative
LOEC Lowest Observed Effect Concentration

16.3 Key literature references and sources for data

http://esis.jrc.ec.europa.eu/
http://echa.europa.eu/
http://gestis-en.itrust.de

16.4 Relevant R-phrases and/or H-statements (number and full text):

H220 Extremely flammable gas R10 Flammable

H225 Highly flammable liquid and vapour R11 Highly flammable
H226 Flammable liquid and vapour R12 Extremely flammable
H301 Toxic if swallowed R20 Harmful by inhalation
H311 Toxic in contact with skin R23/24/25 Toxic by inhalation, in contact with skin and if
H315 Causes skin irritation swallowed
H317 May cause an allergic skin reaction R36 Irritating to eyes
H318 Causes serious eye damage R37 Irritating to respiratory system
H319 Causes serious eye irritation R38 Irritating to skin
H331 Toxic if inhaled R40 Limited evidence of a carcinogenic effect
H332 Harmful if inhaled R41 Risk of serious damage to eyes
H335 May cause respiratory irritation R43 May cause sensitisation by skin contact
H340 May cause genetic defects R45 May cause cancer
H350 May cause cancer R46 May cause inheritable genetic damage
H351 Suspected of causing cancer R50/53 Very toxic to aquatic organisms, may cause long-term
H400 Very toxic to aquatic life adverse effects in the aquatic environment
H411 Toxic to aquatic life with long lasting effects R51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment

16.5 Training advice: -

16.6 Further information: According to the guidance version 2.0 for monomers and polymers from the European Chemicals Agency
dated as of April 2012, the classification of the polymer takes into account the classification of all its constituents, such as unreacted
monomers. These constituents in fact should be taken into account for classification of the polymer. This means that the same
classification methods as for mixture should be applied to polymer substances.
In order to determine a classification for the studies about the water soluble fraction as well as the absorption should be performed on
the polymer as such.

To the best of our knowledge and belief, the information contained herein is accurate and obtained from sources believed to be reliable. No representation is made that
the information is complete or the material is suitable for all purposes. The final determination as to the suitability of the user’s intended use of the material is the sole
responsibility of the user. All materials may present unknown hazards even when used in common applications and accordingly, it is the sole responsibility of the user
to understand and address all potential hazards, including those identified herein. The information set forth in Sections 11 and 12 reflects data available as of the date
hereof. It is anticipated that such data will be updated.

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