ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE 2021 CHEMISTRY ASSIGNMENT DATE:28/06/19

TOPIC: MOLE CONCEPT & ATOMIC STRUCTURE

SECTION–I (Multiple Choice Questions)

This section contains 75 multiple choice questions. Each question has 4 choices (1), (2), (3) and
(4) for its answer, out which ONLY ONE is correct.

1. Calculate the number of oxygen atoms required to combine with 7g of N2 to form N2O3 when only
80% of N2 reacts to form N2O3.
(1) 2.3  1023 (2) 3.6  1023 (3) 1.8  1021 (4) 5.4  1021

2. If half mole of oxygen combine with Al to from Al2O3, the weight of Al used in the reaction is:
(Al = 27)
(1) 27g (2) 40.5g (3) 54g (4) 18 g

3. The number of grams of oxygen in 0.10 g-molecule of Na2CO3.10H2O is

(1) 13 g (2) 20.8 g (3) 18 g (4) 2.8 g

4. Calculate number of lines emitted in IR region when electron in H atom make transition from n2 = 5
to n1 = 1.
(1) 6 (2) 7 (3) 8 (4) 3

5. A light source of wavelength  illuminates a metal and ejects photo-electrons with (K.E.)Max = 1 eV
Another light source of wavelength  , ejects photo-electrons from same metal with K.E.Max  4 eV
3
Find the value of work function?
(1) 1 Ev (2) 2eV (3) 0.5 eV (4) None of these

6. Which of the following atomic orbital representation violates the Pauli’s exclusion principle, Hund’s
rule as well as Aufbau’s principle simultaneously?
2s 2p 4s 3d 4p
(i) (ii)
4f 5d
3p 4s
(iii) (iv)

(1) iii (2) i, iv (3) ii, iii (4) None of these

7. Degeneracy of H-atom at n=3 is

(1) 3 (2) 9 (3) 4 (4) 1

8. Which of the following statements are true ?

(1) The no. of radial nodes for 4p orbital are ' 2 '
(2) The no. of Angular nodes for 3d xy orbital are ' 2 '
(3) The total no. of nodes of 3d 2 2 are ' 2 '
x y

(4) All of above

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9. Possible set of four quantum numbers for unpaired electron of di-positive ion of Cu is:
(1) n = 3, l = 2, m = 2, s = 1/2 (2) n = 4, l = 0, m = 0, s = 1/2
(3) n = 4, l = 3, m = 2, s = 1/2 (4) n = 3, l = 3, m = –3, s = 1/2

10. What is the radius ratio for 2nd orbit of Li+2 ion and 3rd orbit of Be+3 ion?
(1) 3 : 1 (2) 16 : 27 (3) 4 : 9 (4) 3 : 4

11. The difference between nth and (n + 1)th Bohr’s radius of H–atom is equal to its (n – 1)th Bohr’s
radius. The value of n is
(1) 3 (2) 4 (3) 5 (4) 6

12. The radius of which of the following orbit is same as that of the first Bohr’s orbit of hydrogen atom:
(1) He+ (n = 2) (2) Li2+ (n = 2) (3) Li2+ (n = 3) (4) Be3+ (n = 2)

13. Consider the ground state of Cu atom (z = 29). The number of electrons with the azimuthal quantum
numbers l = 1 and 2 are respectively
(1) 16 and 6 (2) 12 and 10 (3) 12 and 9 (4) 16 and 5

14. Splitting of spectral lines when atoms are subjected to strong electric field is called:
(1) Zeeman effect (2) Stark effect
(3) Decay (4) Disintegration

15. The ionization energy of hydrogen atom in the ground state is x kJ. The energy required for an
electron to jump for 2 nd orbit to 3rd orbit is
5x x
(1) (2) 5x (3) 7.2x (4)
36 6

16. The nodes present in 3porbital are

(1) one spherical, one planar (2) two spherical
(3) two planar (4) one planar

17. Volume of CO2 obtained from complete decomposition of 20 g CaCO3 at STP is

(1) 2.24 litre (2) 4.48 litre (3) 20 litre (4) 22.4 litre

18. How many moles of NaOH are contained in 27 cm3 of 0.15 M NaOH?
(1) 0.2 (2) 4.05 × 103 (3) 4.05 × 103 (4) 0.2 × 10 3

19. 0.1g of an Organic compound containing phosphorus gave 0.222g of Mg2 P2 O 7 . The % of
Phosphorus in it will be: (Mg – 24; P – 31)
(1) 62 (2) 6.2 (3) 31 (4) 13

20. Sodium nitrate, heated in the presence of an excess of hydrogen, forms water according to the two-
step process.
2NaNO3  2NaNO2 + O2
2H2 + O2  2H2O.
How many grams of sodium nitrate are required to form 9 grams of water?
(1) 21.3 (2) 42.5 (3) 69.0 (4) 85.0

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21. If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass
unit, the mass of one mole of a substance will
(1) be a function of the molecular mass of the substance
(2) remain unchanged
(3) increase two fold
(4) decrease twice

22. 1 g of Mg is burnt in a closed vessel which contains 0.5 g of O2. Which reactant is left in excess?
(1) Mg (2) O2
(3) Both the reactants are consumed (4) Mg and O2 are left in excess

23. The mass of chromium atoms in 85 g of Cr2S3 is (atomic mass of S = 32, Cr = 52)
(1) 22.1 g (2) 85 g (3) 44.2 g (4) 50 g

24. The ratio of energy of photon having wavelength 4000 A0 & 2000 A0 will be
(1) 2 : 1 (2) 1 : 2 (3) 3 : 1 (4) 1 : 1

o
25. In an atom of hydrogen, the atom is exposed to a radiation of wave length 970.58 A and atom got
excited, find out the maximum number of waves can be obtained during de excitation
(1) 3 (2) 6 (3) 4 (4) 10

26. Following figure shows a radial probability curve for an atomic orbital without specifying the name
of orbital. The orbital can be

    
r

(i) 4s (ii) 5p (iii) 6d

(1) (i) only (2) (i) and (ii)
(3) (i), (ii) and (iii) (4) Can not be predicted

27. Which of the following represents the De Broglie wavelength of electron if it’s kinetic energy is E.
6.12 0 12.24 0 3.06 0 1 0
(1) A (2) A (3) A (4) A
E E E E

28. The ratio between kinetic energy and total energy of electron in hydrogen atom will be
(1) 1 (2) 2 (3) –1 (4) –2

29. Calculate the number of oxygen atoms required to combine with 7g of N2 to form N2O3 when only
80% of N2 reacts to form N2O3.
(1) 2.3  1023 (2) 3.6  1023 (3) 1.8  1021 (4) 5.4  1021

30. The number of grams of oxygen in 0.10 g-molecule of Na2CO3.10H2O is

(1) 13 g (2) 20.8 g (3) 18 g (4) 2.8 g

31. The total number of atoms in 8.5 g of NH3 is

(1) 9.03  1023 (2) 3.01 1023 (3) 1.2044 1024 (4) 6.02  1023

32. The mole fraction of ethanol (C2H5OH) in water is 0.08. Its molality will be
(1) 2.41 mol/kg (2) 4.83 mol/kg (3) 3.33 mol/kg (4) 6.41 mol/ kg
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33. Calculate no lines emitted in IR region when Bohr electron make transition from n2 = 5 to n1 = 1.
(1) 6 (2) 7 (3) 8 (4) 3

34. A light source of wavelength  illuminates a metal and ejects photo-electrons with (K.E.)Max = 1 eV
Another light source of wavelength  , ejects photo-electrons from same metal with K.E.Max  4 eV
3
Find the value of work function?
(1) 1 Ev (2) 2eV (3) 0.5 eV (4) None of these

35. Which of the following atomic orbital representation violates the Pauli’s exclusion principle, Hund’s
rule as well as Aufbau’s principle simultaneously?
2s 2p 4s 3d 4p
(i) (ii)
4f 5d
3p 4s
(iii) (iv)

(1) iii (2) i, iv (3) ii, iii (4) None of these

36. Which of the following statements are true ?

(1) The no. of radial nodes for 4P orbital are ' 2 '
(2) The no. of Angular nodes for 3d xy orbital are ' 2 '
(3) The total no. of nodes of 3d 2 2 are ' 2 '
x y

(4) All of above

37. Bohr’s Principle applicable to

(1) H  (2) Be2 (3) Li  (4) B4

38. Select the correct combination of four quantum number for the outermost electron of Na atom
(1) n  4 l  0 ml  0 s  1 2 (2) n  3 l  1 ml  0 s  1 2
(3) n  3 l 1 ml  0 s 1 2 (4) n  3 l0 ml  0 s  1 2

39. If uncertainity in the momentrum of electron is zero. It’s uncertainity in the position is
(1) 0 (2) 1 (3) infinity (4) –1

40. Orbital angular momentum of ‘6p’ orbital

h h h h
(1) 3 (2) 2 (3) 6 (4) 5
2 2 2 2

41. Splitting of spectral lines when atoms are subjected to strong electric field is called
(1) zeeman effect (2) stark effect (3) decay (4) Integration

42. The correct set of 4 quantum numbers of a 4d electron is

(1) 4, 3, –2, –1/2 (2) 4, 2,  1, 0 (3) 4, 3,  2,  1/ 2 (4) 4, 2,  1,  1/ 2

43. If uncertainity in position and momentum are equal than uncertainity in velocity is
h 1 h h 1 h
(1) (2) (3) (4)
2 m   2m 

44. The quantum numbers for the last electron in an atom n = 3, l = 1 and m = –1. The atom is
(1) Al (2) Ti (3) Mg (4) C

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45. A light source of wavelength  ejects photo-electrons with maximum kinetic energy 1eV. Another
light source of wavelength 0.25  , ejects photo-electrons from the same metal with maximum kinetic
energy 8.5eV. Find the work function of the metal
(1) 0.5eV (2) 1.0eV (3) 1.5 eV (4) 2.0 eV

46. An organic dye absorbs a photo of wavelength  and re-emits the same energy into two photons of
wavelengths 1 and  2 respectively. The wave length  is related to the wavelength 1 and  2 as :
1 1 1 1 1 1
(1)   1   2 (2)   (3)    (4)  1   2
 1  2 1  2 

47. Which of the following sets of quantum numbers represent an impossible arrangement?
n  m s
(1) 3 2 –2 1
2
(2) 4 0 0  1
2
(3) 3 2 –3 1
2
(4) 5 3 0 1
2

48. A 3p orbital has

(1) Two spherical nodes
(2) Two non-spherical nodes
(3) One spherical and one non-spherical nodes
(4) One spherical and two non-spherical nodes

49. The valence configuration of chromium is

(1) (2)

(3) (4)

50. The ratio of velocity of the electron in 4th and 5th orbit of Be3+ would be –
(1) 5 : 4 (2) 4 : 5 (3) 25 : 16 (4) 16 : 25

51. According to the graph.

R2

Where R 2  Radical probability density r = distance from the nucleus. If there as no nodal plane in
the given orbital. The orbital is
(1) 3 s (2) 4 s (3) 5 dz 2 (4) 6 dz 2

52. How many nodal planes are there in 3rd shell?

(1) 3 (2) 13 (3) 11 (4) None of these

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 x
53. An electron in an atom jumps in such a way that its kinetic energy changes from x to . The change
9
in its potential energy will be –
x 16x 9
(1) (2) (3) 9x (4) x
9 9 16

54. According to Bohr model ,If the kinetic energy of electron in hydrogen atom in first excited state is
X then if the mass of electron is double then the magnitude of potential energy of electron in ground
state of that hypothetical hydrogen atom will be N times X . Then N is?
(1) 8 (2) 16 (3) 3 (4) 2

55. Calculate the atomic weight of a metal that forms an oxide having empirical formula M2O3 and
contains 70% metal by weight.
(1) 52 (2) 56 (3) 27 (4) 75

56. A mixture of 1 mole of Al and 3 mole of Cl2 are allowed to react as:
2Al (s) + 3Cl2(g) → 2AlCl3(s)
Then limiting reagent and moles of AlCl3 formed are:
(1) Al, 2 (2) Cl2,1 (3) Al,1 (4) Al, 1.5

57. 3.68 g of a mixture of CaCO3 and MgCO3 is heated to liberate 0.04 mole of CO2. The mole % of
CaCO3 and MgCO3 in the mixture is respectively;
(1) 50%, 50% (2) 60%, 40% (3) 40%, 60% (4) 30%, 70%

58. Assuming that petrol is iso-octane (C8H18) and has a density 0.8g mL–1; 1.425 L of petrol on
complete combustion will consume what amount of oxygen:
(1) 250 L (2) 125 L (3) 125 mole (4) 250 mole

59. An alloy of iron and carbon is treated with sulphuric acid, in which only iron reacts as:
2Fe(s) + 3H2SO4(aq) → Fe2(SO4)3 + 3H2(g)
If a sample of alloy weighing 140g gave 6g of Hydrogen, what is the % by weight of iron in alloy?
(1) 40% (2) 60% (3) 80% (4) 30%

60. A mixture of CO and CO2 has vapour density 20 at STP. 100 g of this mixture contains:
(1) 0.40 moles of CO (2) 0.20 moles of CO
(3) 0.625 moles of CO (4) 0.375 moles of CO

61. Suppose elements X and Y combine to form two compounds XY2 and X 3Y2 when 0.1 mole of
former weight 10 g while 0.05 mole of the letter weight 9 g. What are the atomic weight of X and Y.
(1) 40, 30 (2) 60, 40 (3) 20 , 30 (4) 30, 20

62. What is molarity of H2SO4 solution that has a density 1.84g/cc at 35o C and contains 98% by weight?
(1) 4.18 M (2) 8.14 M (3) 18.4 M (4) 18 M

63. A certain compound has the molecular formula X4O6 . If 10g of X 4O6 has 5.72g X , the atomic mass
of X is
(1) 32 amu (2) 37 amu (3) 42 amu (4) 98 amu

64. Calculate the number of oxygen atoms required to combine with 7g of N2 to form N2O3 when only
80% of N2 reacts to form N2O3.
(1) 2.3  1023 (2) 3.6  1023 (3) 1.8  1021 (4) 5.4  1021

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65. On heating 1.708 g of hydrated BaCl2.xH2O to dryness 1.456 g of anhydrous salt remained?
Calculate x. [At. Wt.(Ba) = 137]
(1) 1 (2) 2 (3) 3 (4) 4

66. 10 mL of oxygen and 60 mL of H2 is sparked till reaction is complete to form H2O(l). After attaining
the initial condition of P and T, the reduction in volume (in mL) of gases after reaction is:
(1) 30 (2) 40 (3) 20 (4) 10

67. Angular momentum of electron in fourth orbit of hydrogen atom will be

h 2h 3h 4h
(1) (2) (3) (4)
2 2 2 2

68. Energy levels A, B, C of a certain atom corresponds to

C
increasing values of energy, i.e., E A < EB < EC. If 1, 2 and 3 1
are the wavelength of radiations corresponding to the B
2 3
transitions C to B, B to A and C to A respectively, which of the
following statement is correct :
A

1 2
(1) 3 = 1 + 2 (2) 3 = (3) 1 + 2 + 3 = 0 (4) 32  12  22
1   2

69. An excited electron of H-atom emit photon of wavelength  and return in the ground state the
principal quantum number of excited state is given by
R 1 R  1
(1) R  R  1 (2) (3) (4)
R  1 R  R  1 R

70. The total number of nodes for 4d orbital will be (excluding the node at infinity)
(1) 2 (2) 3 (3) 0 (4) 1

71. The minimum frequency of photon needed to break bond in x 2  g  having bond energy 158.4 kJ/mol
is a 1014 Hz. Find 'a'. (Take h = 6.6 1034 J s,1eV / atom = 96 KJ/mol)
(1) 8 (2) 6 (3) 4 (4) 2

72. Number of waves made by a Bohr electron during its one complete revolution in an orbit of a H-like
species :
(1) is only dependent on the atomic number of H-like species.
(2) is only dependent on the orbit number in which electron is revolving.
(3) is dependent on both the orbit number in which electron is revolving and the atomic number of
H-like species.
(4) is independent of both the orbit number in which electron is revolving and the atomic number of
H-like species.

73. Which of the following matter waves will have the longest wavelength, if travelling with same
kinetic energy?
(1) Proton (2) Alpha particle (3) Neutron (4) Electron

74. Speed of electron in the third orbit of Li2+.

(1) 2.18  106 m s (2) 1.09 106 m s
(3) 4.36 106 m s (4) 1 106 m s

75. Energy of electron in the fourth orbit of He+ ion will be

(1) 27.2 eV (2) 13.6 eV (3) –27.2eV (4) None of these
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