ANNEXURE – 3

DETAILS OF MANUFACTURING PROCESS

 3,5-Dichloro-4-(1,1,2,2-tetrafluoroethoxy)aniline
( 3,5-DCTFEA ) :

The process involves addition reaction of Tetrafluoroethylene (TFE)

with 4-Amino-2,6-dichlorophenol in presence of DMF and K2CO3 as
catalyst to obtain the product 3,5-Dichloro-4-(1,1,2,2-
tetrafluoroethoxy)aniline ( 3,5-DCTFEA ).

 Chemical reaction

K2CO3 , DMF

4-Amino-2,6-dichlorophenol TFE 3,5 DCTFEA

Molecular C6H5Cl2NO2 CF2CF2 K2CO3 C8H5Cl2F4NO DMF

Formula :
Molecular 178.02 100 138.205 278.02 73.1
Weight :
Boiling Point - -78.4 - 305 154
(°C) :

 Process Flow Diagram:

TFE

C6H5Cl2NO2
Reactor DMF + K2CO3
Distillation
K2CO3
DMF
PRODUCT
3, 5 DCTFEA

M/s. Gujarat Fluorochemical Limited – Dahej

  Material Balance
INPUT OUTPUT
Component Qty Component Qty (kg)
(Kg)
C6H5Cl2NO2 640.3 Product

TFE 359.7 C8H5Cl2F4NO 1000

DMF 2504
K2CO3 150 Recovery
DMF 2504
K2CO3 150

TOTAL 3654 TOTAL 3654

 EFFLUENT LOAD: (kg/t)

Effluent to ETP:
Waste Stream Constituent Quantity, COD Load
(L/t) (kg/t)
Stream:1 Aqueous effluent 0
0
TOTAL 0

 HAZARDOUS WASTE LOAD: (kg/t)

Sr. No. Particulars Hazardous Waste Generation (kg/t)
1 Distillation Residue -
2 Solid waste -

 PROCESS EMISSION LOAD:- (kg/t)

From Reactor vent (kg/t)
0 0

M/s. Gujarat Fluorochemical Limited – Dahej