MULTIORGANICS PVT LTD

Prep by AKK
Checked by SNP STEAM LINE SIZE Date: 18.12.2019
Approved by Assumed: Pressure St1 Units
Rev No 0 7.5 kg/cm2 35 m/s
Pressure St2 Units
2 kg/cm2 25 m/s
ST2
Details of Heating
Calculated Nearest
Average Average Steam Steam Steam Volumetric Line size
Start End Heat Heat Density Velocity Line Standard Final Line size
S.No Tag No Operation Mass Latent Specific Time Flowrate Pressure Latent Heat Flow in P&ID
Temp. Temp. Load Duty Size Line Size
Heat Heat
°C °C kg kcal/kg kcal/kg.°C kcal hrs kcal/hr kg/hr kg/cm2 kcal/kg kg/m3 m3/hr m/s mm NB NB NB
1 V-7101A Distill MeOH and EDC completely under high vacuum 35 35 3148 338.7 269666.2 15.5 17397.8 33.1 2 525.84 1.129 29.3 25 23 50
2 V-7301 Heat to 60 °C 25 60 4458 1.0 156026.4 1 156026 296.6 2 525.84 1.129 262.7 25 69 80
3 V-7301 EDC Distillation 60 60 2851 77.4 220635.6 5 44127 83.9 2 525.84 1.129 74.3 25 37 40

413.6 kg/hr

ST1
 Batch Size 475 kg.
Output of CPPM 1032 kg.
Yield 95%
Purity ?
Reaction
B-lanine Methanol TC EDC CP-1
3- Amino
3-Amino Propionic Acid Propionic
methyl ester
M.W 89 32 119 99 140
Qty in Kg 475.000 342 699 2849 745
Mole 5.337 11 6 29 5
Mole Ratio 1.000 2 1 5 1
Qty consume 5.337 171 635 0 5
Qty UnReacted 0 171 64 2849 745

Alanine Methanol EDC

475 342 kg
5.34 10.674 mole
99% 99% Purity
475 438 Lit

MSGL-1 6.3 0KL

TC Chill @ 15-20
 3666 KG
SOCl2
KG 699
LTR 429
SO2 addition 35°C to 40°C & Mainatin Reaction
Mole 5.9 @40 for 3 Hrs

3828 KG
SPG r 1.17

3272 Ltr
EDC
1424.6
MSGL-1 MeoH & EDC Distillation @ 80°C &
1140 550mmHg

743 KG

CP-1 after Distilled

SP Gr 1.01 743 Kg
736 Ltr
Assay on 100% Output Kg
Prepared by : SNP

So2 HCl EDC MeoH

64 37 99 32
342 195 2849 342
5 5 29 11 179.8
1 1 5 2 66.85
5 5 0 171 2999.1
342 195 2850 171 784
205.1
4234.85

2849 Kg
28.82 Mole
99% Purity
2374 Lit

Water NaOH 427

500 kg H20 2135
 2562
195 16.7%
KG
HCL=
0.410 SO2 Alkali
Water
Scrubber Scrubber

SO2 = 342
KG
0.72

695 kg 2904 kg Effluent

( 30% HCl) (Na2SO3) 23.16%
KG 672.4719101

MeoH 234 300.38173 Ltr

2135
TC 64 MEE Water
EDC KG
2850 2375.2669 Ltr

3148 2623.441

Salt 672 KG
 Prepared by SNP

Batch Size
Output of CPPM
Yield
Purity
Reaction
CP-1 CPC EDC CP-2 CO2 EDC HCl
Chloro
3- Amino Propionic Acid 2-2 Dichloro Propionic Acid Propionic Acid
Methyl Ester
M.W 139.5 126.5 98.9 193.6 44.0 98.9 73
Qty in Kg 743 924 1425 1032 222 1425 389
Mole 5.33 7.30 14.41 5.33 5.06 14.41 10.66
Mole Ratio 1.00 1.37 2.705 1.0 2 2.705 2
Qty consume 5.33 674 0.00 5.062 5.06 0.00 10.66
Qty UnReacted 0 249.42 1425 0 0 1426 389

CP-1 CPC EDC

743 924 kg 1425 Kg
5.33 7.300 mole 14.41 Mole
99% 99% Purity 99% Purity
736 669 Lit 1140 Lit

MSGL-2 6.3 0KL Cool to Reaction Mass

Chill @ 0-5

SPG r 1.22 2168 Kg

1876 Ltr
1777 Ltr

Water
KG 1663
LTR 1663 Water addition 0°C into Reaction Mass. Water Na2Co3 Nacl
Mole 92.4 1663 143 340 CPC
570 566 592 924
0 209
475 125
3831 KG 1.0826228 Sp Gr 2708 1043 932
3539 Ltr

0.2000
95 Ltr
Na2Co3 143 Kg
Water 570 KG

Add Sodium Bicarbonate and Sodium Chloride

Nacl 340 Solution.
 Add Sodium Bicarbonate and Sodium Chloride
Solution.
Na2Co3 566

KG
905 5307 KG
4466 Ltr

Add CPC addition -2 to 0 ° C and maintain

CPC 674 for 1 hr between -2 to 2 ° C
488 5.328814788
KG

5981 KG 1.21
4955 Ltr

Sodium Carbonte 209.320

KG Again Charge Sodium Carbonate Second
Lot 0 ° C.

6190 KG
5060 Ltr

CPC 249.999 1.9762801439

KG
Add CPC Second Lot addition -2 to 0 ° C
and maintain for 1 hr between -2 to 2 °
C
181

6440 KG
5241 Ltr

Water 0.000
KG Water addition 0 to 5 °C into Reaction Mass.

B-Alanine HCl

6440 KG 89 73
5241 Ltr 450 369

Na2Co3 119 1629

Water 475
KG Again Charge Sodium Carbonate
Solution adjust Neutral pH 7 @ 0-5 ° C.
Na2Co3 + 2 HCl 2 Nacl CO2 H2O
106 73 117.16 44 18
7034 KG 536 369
5637 Ltr 1036 592.38202 222.47191 91.011236
 Scrubber reaction
CO2 + 2NaOH Na2CO3 + H2O
CO2 222.47 kg 222 404 536 91
Transfer Mass from MSGL to SSR-01 and
apply heating up to 20 to 25 dc for the 44 80 106 18
evolution of CO2 gas .
EDC 1425 KG
6812 KG 1140
5526 Ltr

Aqueous
Aqueous KG Layer
Take Above Reaction Mass for Aqueous Water 2799 Charge Fresh /Recycle EDC
and Organic Layer Separation @ 20 to 3779 for Extract the aqueous and
25 dc. Transfer Organic Layer in SSR-02. Collect Oranic in SSR-01 and 2799 Ltr
Drain Aqueous. 3779 KG

Organic Layer 3033 Kg

2727 Ltr 1425 KG 16%
1140 Ltr

Organic Layer Distilled EDC

4458 Kg Combine Both Organic Layer for EDC 2851 KG
3867 Ltr Distillation 2280 Ltr

1607 KG
1586 Ltr

Saturated CPPM filtered through aNutch Salt

Filter 575 KG

860 Ltr
CPPM 1032 KG
Chloro Propionic Acid Methyl Ester