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SPCI Pte.

Ltd (200101807)
26 Jurong Port Road, 619099 Singapore

SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE / PREPRATION AND COMPANY / UNDERSTANDING

Material Name : Sodium silicate solution

MFG & SUPPLIER SPCI Pte Ltd


26 Jurong Port Road , Singapore ( 619099)
Tel : 2651654
Fax : 2655000

2. HAZARDS IDENTIFICATION

GHS Classification Skin corrosion (Category 1)

Specific target organ toxicity - single exposure (Category 3)

GHS Label Elements :


Symbol (s)

Signal Words DANGER

Hazard statement(s)
H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irrita Causes serious eye damage.

Precautionary statement(s)

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a doctor/ physician.

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SPCI Pte.Ltd (200101807)
26 Jurong Port Road, 619099 Singapore

SAFETY DATA SHEET

R-phrase(s)
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.

R34 Causes burns.


R37 Irritating to respiratory system.

S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).

Other hazards None

3. COMPOSITION / INFORMATION ON INGEREDIENTS

Formula :Na2O7Si3
Molecular Weight : 342,15 g/mol
Component Concentration
Disodium metasilicate
CAS-No. 6834-92-0 >= 21 - <= 50%
EC-No 229-912-9
Index No. 014-010-00-8
Silicon dioxide
CAS-No. 7631-86-9 >= 16 - <= 17%
EC-No 231-545-4
Water
CAS-No. 7732-18-5 >= 33 - <= 63%
EC-No 231-791-2

4. FIRST AID MEASURES

Inhalation If breathed in, move person into fresh air. If not breathing, give artificial respiration

Skin Contact Wash off with soap and plenty of water.

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and
consult a physician.

Indestion Never give anything by mouth to an unconscious person.


Rinse mouth with water. Consult a physician
Most important symptoms and effects, both acute and delayed

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SPCI Pte.Ltd (200101807)
26 Jurong Port Road, 619099 Singapore

SAFETY DATA SHEET

5. FIRE FIGHTING MEASURES

Suitable extinguishing media


Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture


Sodium oxides, silicon oxides

Precautions for fire-fighters


Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures


Avoid breathing vapors, mist or gas.

Environmental precautions
Do not let product enter drains.

Methods and materials for containment and cleaning up


Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe Normal measures for preventive fire protection


Handling

Condition for safe Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Storage Containers which are opened must be carefully resealed and kept upright to prevent leakage.

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SPCI Pte.Ltd (200101807)
26 Jurong Port Road, 619099 Singapore

SAFETY DATA SHEET

8. EXPOSURE CONTROLS / PERSONAL PROCTECTION

Control parameters
Components with workplace control parameters

Respiratory protection
Respiratory protection not required. For nuisance exposures use type OV/AG (US) or type ABEK
(EU EN 14387) respirator cartridges. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU).

Body protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.

Eye protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU

Skin and body protection


The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Form : Liquid

Odour no data available

pH no data available

Boiling point no data available

Flash point no data available

Ignition temperature no data available

Relative density 1,39 g/cm3 at 25 °C

Lower explosion limit no data available

Upper explosion limit no data available

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SPCI Pte.Ltd (200101807)
26 Jurong Port Road, 619099 Singapore

SAFETY DATA SHEET

10. STABILITY AND REACTIVITY

Chemical Stability no data available

Condition to Avoid no data available

Incompatible Materials no data available


Hazardous

Decomposition Products Other decomposition products - no data available

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not applicable

Skin corrosion/irritation
Not applicable

Carcinogenicity
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Silicon dioxide)

Reproductive toxicity
Not applicable

Potential health effects


Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.

Additional Information
RTECS: Not available

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SPCI Pte.Ltd (200101807)
26 Jurong Port Road, 619099 Singapore

SAFETY DATA SHEET

12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available

13.DISPOSAL CONSIDERATIONS

Product
Offer surplus and non-recyclable solutions to a licensed disposal company

Contaminated packaging
Dispose of as unused product.

14. TRANSPORT INFORMATION

UN-Number
ADR/RID: 3266 IMDG: 3266 IATA: 3266

UN proper shipping name


ADR/RID : CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
IMDG : CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
IATA : Corrosive liquid, basic, inorganic, n.o.s

Transport hazard class(es)


ADR/RID: 8 IMDG: 8 IATA: 8

Packaging group
ADR/RID: III IMDG: III IATA: III

Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

The information in this document should be made available to all who may handle the product.
This information is based on our current knowledge and is intended to describe the product for
the purposes of health,safety and environmental requirements only. It should not therefore be
construed as guaranteering any specific property of the product.

Prepared By: QA Department


Date of Issue: 01.01.2012
Revesion: 01

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