wss

(6 pages)

APRIL 2014 50309/SBADB

Time : Three hours Maximum : 75 marks

SECTION A — (10 × 2 = 20 marks)

Answer any TEN questions.

All questions carry equal marks.

Each answer should not exceed 30 words.

1. What are polydentate ligands? Give two examples.

£ÀCÚ DÛPÒ GßÓõÀ GßÚ? C¸ Euõµn[PÒ

u¸P.

2. State effective atomic number rule.

{Pµ AqUP¸ Gs Âvø¯ TÖP.

3. Draw the structure of Nickel dimethyl glyoxime.

{UPÀ øhªøuÀ QøͯõUê® Aø©¨ø£ ÁøµP.

4. What is a reducing sugar? Give one example.

JkUS® \ºUPøµ GßÓõÀ GßÚ? J¸ GkzxUPõmk

u¸P.
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5. What are polysaccharides? Give two examples.

£õ¼ \õUPøµkPÒ GߣøÁ ¯õøÁ? C¸
GkzxUPõmkPÒ u¸P.

6. How does glucose react with excess of phenyl

hydrazine?

AvP¨£i¯õÚ ¤øÚÀ øímµ]Ýhß SÐU÷Põì

GÆÁõÖ ÂøÚ ¦›QßÓx?

7. What are alpha-and beta-amino acids? Give one

example to each.

BÀ£õ–©ØÖ® ¥mhõ Aª÷Úõ Aª»[PÒ GßÓõÀ

GßÚ? JÆöÁõßÖUS® J¸ GkzxUPõmk u¸P.

8. What is a zwitter ion?

_Âmhº A¯Û GßÓõÀ GßÚ?

9. Define – EMF.

EMF-I Áøµ¯Ö.

10. Define a galvanic cell. Give one example.

PõÀÁõÛU P»zøu Áøµ¯Ö. J¸ GkzxUPõmk u¸P.

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11. Calculate the normality of a solution having

9.8g of H 2 SO 4 in 2000 ml of water (Eq.wt. of
H 2 SO 4 = 49 ).
2000 ª.¼ }›À 9.8 Q. \À¤³›U Aª»® PøµUP¨£mh
J¸ vµÁzvß |õº©õ¼miø¯U PnUQkP. ( H2SO4 ß
\©õÚ Gøh = 49).

12. What is a standard solution?

vmh Pøµ\À GßÓõÀ GßÚ?

SECTION B — (5 × 5 = 25 marks)

Answer any FIVE questions.

All questions carry equal marks.

Each answer should not exceed 200 words.

13. Explain any two applications of EDTA.

EDTA-Âß H÷uÝ® C¸£¯ß£õkPøÍ ÂÁ›.

14. Describe the biological role of chlorophyll.

S÷Íõ÷µõL¤À¼ß E°›¯À £[QøÚ ÂÍUSP.

15. What is diabetes? Explain two of its control

measures.
\ºUPøµ ¯õv GßÓõÀ GßÚ? AuøÚU
Pmk¨£kzx® H÷uÝ® C¸ ÁÈ•øÓPøÍ ÂÁ›.

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16. What is muta-rotation? Describe its mechanism.

ª³mhõ–_ÇØ] GßÓõÀ GßÚ? Auß ÁÈ•øÓø¯
ÂÁ›.

17. Describe any Three colour reactions of proteins.

¦÷µõmjßPÎß HuõÁx ‰ßÖ Ásn® u¸®
ÂøÚPøÍ ÂÁ›.

18. Define pH. Calculate the pH of 0.001M HCl.

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19. Write notes on column chromatography.

SÇÀ Ásn¨¤›øP •øÓø¯¨ £ØÔ SÔ¨¦ GÊxP.

SECTION C — (3 × 10 = 30 marks)

Answer any THREE questions.

All questions carry equal marks.

Each answer should not exceed 500 words.

20. Discuss the postulates, applications to [Ni (CO) 4 ]

and [Co(CN ) 6 ]
3−
and demerits of Pauling’s theory.

£õ¼[ öPõÒøP°ß ÷Põm£õkPÒ, [Ni (CO) 4 ] ©ØÖ®

[Co(CN ) 6 ]3 − BQ¯ÁØÔÀ Auß £¯ß£õk ©ØÖ®
Auß SøÓ£õkPøÍ ÂÍUSP.

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[P.T.O.]
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21. Describe any five chemical reactions of fructose.

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22. Describe the primary and secondary structures of

protein.

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Aø©¨¦PøÍ ÂÁ›.

23. What are conductometric titrations? Explain the

conductometric titration curves of

(a) Strong acid Vs strong base

(b) Weak acid Vs strong base and

(c) Strong acid Vs weak base

Write any two advantages of such titrations.

PhzxzvÓÚÔ uµ®£õºzuÀ GßÓõÀ GßÚ?

(A) Á¼ø©ªUP Aª»® Vs Á¼ø©ªUP Põµ®

(B) Á¼ø© SøÓ¢u Aª»® Vs Á¼ø© ªS Põµ®

(C) Á¼ø© ªS Aª»® Vs Á¼ø© SøÓ
PõµzvØPõÚ PhzxzvÓÚÔ uµ®£õºzuÀ
Áøµ÷PõmiøÚ Áøµ¢x ÂÁ›.

Auß H÷uÝ® C¸ ÷©ßø©PøÍ GÊxP.

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24. Write notes on :

(a) Thin layer chromatography.
(b) Gas-liquid chromatography.
SÔ¨¦ GÊxP :
(A) ö©À¼¯ uPk Ásn¨¤›øP •øÓ
(B) Áõ²–}º© Ásn¨¤›øP •øÓ.

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