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~NDRIYA VIDYALAYA SANGATHAN

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v :S}ON ENDING EXAMINATION
Slass XI CHEMISTRY
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Time Allowed : 3
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" Maximum Marks : 70

<?eneral Instructions: , /
(1) All questions a r.e..,eo mpulsory.
(ii) Questions nos. f to 5 are very short answer questions and carry 1 mark each.
(iii) Questions nos. 6 to 10 are short answer questions and carry 2 marks each.
(iv) Questions nos. 11 to 22 are also short answer questions and carry 3 marks each.
(v) Questions no.23 is value based question and carry 4 marks.
(vi) Questions nos. 24_to 26 are long answer questions and carry 5 marks each.
(vii) Use log tables if necessary, use of calculators is not allowed.

<G What happens to the surface tension of a liquid when the temperature is
in'c reased?
2. Why 1s air sometime considered as a heterogeneous mixture? l
~ Which quantum number specifies the shape of an orbital? I
4. Whicq two elements of the following belong to the same period? Al, Si, Ba and 0 . 1
5. What makes lithium to show property uncommon to the rest of the alkali metals? . l
What is the total number of sigma and pi bonds in the following molecules? 2
(a) CH2=CHCl (b) _CH 3CH=CH-C=CH

7. The equilibrium constant for areaction is 10. What will be value of ~G ? 0

2
<&) A sample fresh apple juice has a pH of 3.76. Calculate [H ].
+
2
(OR)
For the reaction
Ni(g) + 3H2(g) ~ 2NH 3(gj+ heat
The equilibrium constantKc = 0.50 at 673K
Ja) What will be equilibrium constant for reverse reaction at same temperature
(b) What is the effect of increase in temperature in the yield of NH 3 _.

· Give the IUP AC name <?f 2

(a) CH 3-CHOH-CH2-CHO (b) CH3-CH2-CH=CH-COOH

What happens when (a) propene reacts with ozone (b) pen~l-ene reacts with HBr 2
in the pr~sence of peroxide. Give chemical equations. '

11. Define molarity? The density of 3M solution of NaCl is 1.25 g L- 1 • Calculate the 3
molality of solution?
11th Chem Page 1 of 4
 12. (a)Give the IUPAC name of the element with atomic number 114?
(b)Predict the formulae of the stable binary compounds that would _b e formed .by
the combination of the following pairs of elements.
(i)Lithium and oxygen (ii) magnesium and nitrogen
(iii) Silicon and oxygen (iv)Carbon and chlorine

13 . Write the molecular orbitakonfiguration of 0 2, O/, 0 2·. Find the bond order and 3
magnetic properties

14. · (a) Write the conditions in terms of ~Hand ~S when a reaction w·o uld always 3
spontaneous.
(b) For the reaction at 298 K 2A +B ➔ C
~H = 400 KJ mor 1~s = 0.2K.Jmor 1K-I.
At what temperature will the reaction become spontaneous?

(OR)
Enthalpies of formation of CO(g), CO 2(g), N 2O(g) and N 2O4(g) are -110, -398,
81 and 97 KJ mor 1 respectively. Find the value o~H for the reaction.
N2O4(g) + 3CO(g) ➔ N2O (g) + 3CO2 (g)

15 . (a) What causes the permanent hardness of water? Mention one method to 3
remove permanent hardness?
(b) What do you understand by electron deficient hydrides? Give examples.
(c) Complete the following chemical reaction
MnO4- (aq) + H2O2 (aq) + H+ ➔

16. Account for the following : 3

(a) Alkali metals .are good reducing agents.
(b) LiCl is predominantly covalent while NaCl is ionic .
. (c) Lithium on being heated in air mainly forms the monoxide not peroxide. 3

17. What happens when

(a) Borax is heated strongly 3
3
(b) Boric acid is added to water
(c)Aluminium is treated with dilute NaOH.

18. What are silicones? How is it prepared? Give one use if it.

19. Balance the following redox reaction by ion-electron method.

MnO:; (aq) + r (aq) ➔ Mn02 + h(s) (in acidic medium)
11th Chem Page 2 of 4

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 20. Derive the expression for partial pressure ofa gas in terms of mole fraction. 3

21. State Hund's rule and its importance in filling the orbitals in various energy 3
levels take atomic number 17 as an example.

22 . Calculate the wavelength, frequency and wave num~er of a light wave whose 3
period is 2.0 x 1o·' 0s.

23. Ram is a boy studying in class XII, who Jives in a small village in Rajasthan. His -4
family depends upon the Village pond fo r water supply. He saw that the pond
surface was getting covered with algae. One day larg~ number of fish were found
dead on the ·pond. Ram understood the reason for this. He explained the reason-
of this problem to his family members and villagers. He .asked the villagers to act
swiftly to prevent much more damage to the pond.
Read the passage and answer the questions given below:
(a) Explain the problem and solutions for that problem occurred in the pond.
(b) Wh~t may be the reasons for the problems?
(c) What are the values .shown by Ram? .

24. Exp lain the fol1bwing name reactions with suitable equations: 5
(a) Wurtz Reaction

(b) Hydrogenation reaction

(c) Frieda] crafts alkylation reaction
(d) Markownikov's rule'

( e) Decarboxyla~ion reaction

(OR)

Convert the following compounds and write equations:

a) Phenol to Benzene
b) Benzene to Nitro Benzene

c) Benzene to BHC
d) ethyne to ethanol
c) Benzene to Cyclohexane

11th Chem Page 3 of 4

 25. (a) The species: H 20 , HC0 3, HS04 can act both as Bronsted acid~ and ba,'<.:~ 5_ ,,,.,.
For each case give the corresponding conjugate acid and conj ugate ba~c . ·
(b) Classify the following species into Lewis acids and Lewis base~ and ~hc,w
how these act as such:
(i) OH- (ii) p· ( iii) Ir (iv) BC b

(OR)
(a) Define pH
3
(b) The cone. of Hydrogen ion in a sample of soft drink is 3.8 x IO- M.
What is_it~ pH ? . .

(c) The pKa of acetic ~cid and pKb of ammonium Hydroxide are 4 .76 and 4 .75
respectively. Calculate the pH of ammonium acetate solution .

26. (a) Explain the Lassaign' s test for the detection of nitrogen with chemical 5
equations.
(b) In sulphur estimation 0. 157 g of an organic compound gave 0 .4813g of
BaSO4 •
What is the percentage of sulphur ir- the organic compound?
(M .Mass of BaSO4 = 233 gm/inol)
(OR)
(a) Explain the principles involved in the following purification techniques:
(i) Distillation under reduced pressure ·
( ii) Crystallization
(iii) Chromatography
(b) Define and explain Hyperconjugation with one example.

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