Beruflich Dokumente
Kultur Dokumente
&
Environmental Management Plan
Report
for
1. Energy improvement project of Ammonia and Urea plant
2. 1 million t/y DAP/NPK project
3. Poly Carboxyl Ether project
By
At
Panambur, Mangalore - 575010
Submitted by:
EIA Consultant:
August-2017
Doc No.: EIA
Energy improvement project of Ammonia and Urea plant, 1 million Rev No. 0
t/y DAP/NPK project, Poly Carboxyl Ether project at Mangalore,
Karnataka Issue Date: 20.08.2017
Page 2 of 238
Contents
Executive Summary..............................................................................................................I-XII
Chapter 1. Introduction .................................................................................................... 7
1.1. Prelude ............................................................................................................................... 7
1.2. History of Existing Plant ...................................................................................................... 7
1.3. Justification for Proposed Projects ...................................................................................... 7
1.4. Need of the Study ............................................................................................................... 8
1.5. Project Location .................................................................................................................. 8
1.6. Scope of Study ................................................................................................................. 11
1.7. Regulatory Framework ..................................................................................................... 11
1.8. Approved ToR for EIA Study by MoEF- EAC .................................................................... 11
1.9. Methodology for Environmental Impact Assessment......................................................... 18
1.10. Contents of the EIA Report ............................................................................................... 19
Chapter 2. Project Description ....................................................................................... 21
2.1. Brief Overview of Existing Plant and Proposed Expansion................................................ 21
2.2. Energy improvement: Ammonia and Urea plants. ............................................................. 30
2.3. Process Description of existing Ammonia Plant ................................................................ 33
2.4. Revamp of Urea Plant ...................................................................................................... 38
2.7. Products with Capacities (Existing & Proposed) ............................................................... 51
2.8. Raw Materials (Existing & Proposed) ................................................................................ 52
2.9. Infrastructure& Utilities Required For Proposed Expansion Project................................... 52
2.10. Employment ..................................................................................................................... 57
2.11. Environmental Aspects: .................................................................................................... 57
Chapter 3. DESCRIPTION OF THE ENVIRONMENT ................................................... 69
3.1. Background and Salient Environmental Features of the Study Area ................................. 69
3.2. Environmental Setting and Salient Environmental Features of the Project Area ............... 69
3.3. Primary Data Collection: Monitoring Plan and Quality Assurance Procedures .................. 74
3.4. Physical Environment ....................................................................................................... 75
3.5. Meteorology ...................................................................................................................... 85
3.6. Ambient Air Quality ........................................................................................................... 88
3.7. Noise Environment ........................................................................................................... 92
3.8. Water Quality .................................................................................................................... 94
3.9. Soil................................................................................................................................. 100
3.10. Biological Environment ................................................................................................... 104
3.11. Socio-Economic Environment ......................................................................................... 116
3.12. Traffic Analysis ............................................................................................................... 131
Chapter 4. ANTICIPATED ENVIRONMENTAL IMPACTS AND MITIGATION Measures134
4.1. Introduction..................................................................................................................... 134
4.2. Identification of Impacts .................................................................................................. 134
4.3. Impact on Topography .................................................................................................... 135
4.4. Impact on Climate ........................................................................................................... 136
4.5. Land Environment .......................................................................................................... 136
4.6. Air Environment .............................................................................................................. 138
4.7. Impact on Noise Levels .................................................................................................. 149
4.8. Impact on Water Quality ................................................................................................. 151
4.9. Solid / Hazardous Waste ................................................................................................ 154
4.10. Ecology........................................................................................................................... 155
4.11. Impact of Earthquake...................................................................................................... 157
4.12. Transport ........................................................................................................................ 157
4.13. Occupational Health and Risk......................................................................................... 157
Chapter 5. Analysis of alternatives (Site and Technology)........................................... 159
LIST OF TABLES
Table 1.1 Terms of Reference Compliance ......................................................................... 12
Table 2.1 : Salient Features (Existing & Proposed) ............................................................. 21
Table 2.2 : Co-ordinates (lat-long) of all four corners of the site ................................ 22
Table 2.3 Comparison of Fossil Fuel & Power consumptions between present and post
revamp conditions ........................................................................................................ 31
Table 2.4 Products with capacities (Existing & Proposed) ................................................... 51
Table 2.5 List of Raw materials required /Source /Transportation/Storage .......................... 52
Table 2.6 Land Distribution at Site (Acres) .......................................................................... 53
Table 2.7 Power Supply Details .......................................................................................... 53
Table 2.8 Stack Parameters and Emission Details of Proposed Sources ............................ 66
Table 2.9 Stack emission Rate – (Existing & Propose) ....................................................... 67
Table 3.1 : Salient Environmental Features of Proposed Site ............................................. 70
Table 3.2 Summary of Methodology for Primary/Secondary Baseline Data Collection ........ 74
Table 3.3 : Land use of the Study Area ............................................................................... 83
Table 3.4 : Long Term Meteorological Data of Mangalore (30 years average) .................... 85
Table 3.5 : No. of days with zero octas of cloud cover (Mangalore) .................................... 86
Table 3.6 : Monthly Percentages of Calm Periods (IMD Mangalore) ................................... 86
Table 3.7 : Site Specific Meteorological Data ...................................................................... 87
Table 3.8 : Ambient Air Quality Monitoring Locations .......................................................... 88
Table 3.9 : Ambient Air Quality Monitoring Results (24-hour average)................................ 89
Table 3.10 : Ambient Noise Quality Monitoring Locations ................................................... 93
Table 3.11 Ambient Noise Quality in the Study Area ........................................................... 93
Table 3.12 : Ground Water Sampling Locations .................................................................. 95
Table 3.13 : Ground Water Quality in the Study Area ......................................................... 96
Table 3.14 : Ground Water Quality in the Study Area ......................................................... 97
Table 3.15 : Surface Water Sampling Locations ................................................................. 99
Table 3.16 : Surface Water Quality in the Study Area ......................................................... 99
Table 3.17 : Soil Sampling Locations ................................................................................ 102
Table 3.18 : Physicochemical Characteristics of Soil ........................................................ 102
Table 3.19 : Abstract of various categories of forests in different ranges of Mangalore
division ....................................................................................................................... 104
Table 3.20 : List of the vegetation observed/ reported in the study area ........................... 108
Table 3.21 : List of the Mammals Recorded in Study Area ................................................ 111
Table 3.22 : List of Amphibians and Reptiles Recorded in Study Area .............................. 112
Table 3.23 : List of the Birds Surveyed / Recorded in the Study Area ............................... 112
Table 3.24 : Caste-wise Population Distribution of Study Area Villages ............................ 117
Table 3.25 : Male-female wise Literates & Illiterates ......................................................... 121
Table 3.26 : Distribution of Work Participation Rate .......................................................... 122
Table 3.27 : Village-wise Occupational Pattern in the Study Area ..................................... 124
LIST OF ANNEXURE
Annexure I: NABET Certificate
Annexure II: Land Document
Annexure III: ToR Letter
Annexure IV: Compliance of Earlier EC Letter
Annexure V: Agreement with GAIL for Gas Supply
Annexure VI: Compliance of CREP Guideline
CHAPTER 1. INTRODUCTION
This chapter provides background information of the project proponent, Need for
the EIA study as per prevailing legislation, location and brief description of the
project, methodology adopted for EIA study and structure of the report.
1.1. Prelude
Mangalore Chemicals & Fertilizers Ltd (MCF) is an 'Adventz' Group Company, a large
and diversified business house. The main products of MCF are Urea, Di-Ammonium
Phosphate (DAP), NP 20:20:00:13, Ammonium Bi-Carbonate (ABC) - Food grade,
Sulphuric Acid, Specialty Mixtures of Plant Nutrients consisting of Water Soluble
Fertilizers, Micronutrients & Soil Conditioners and an Industrial Product called
Sulphonated Naphthalene Formaldehyde (SNF) used in construction industry. MCF is
an ISO 14001, OHSAS 18001 and ISO 22000 certified Company.
Government of India announced new Urea policy No. 12012/1/2015-FPP dated 25-05-
2015 which mandated all Ammonia, Urea manufacturer to improve the energy norms
to particular levels by 2018-19. The norms prescribed for MCF vintage is 6.5 Gcal/t of
urea from present 6.9015 Gcal/t. As the operation profitability depends only on actual
energy consumption and payment of all subsidies are energy dependent, it becomes
necessary for manufacturers like MCF to bring down energy norms to best achievable
industry levels to continue profitable operation. Current energy consumption of Urea
production at MCF is 6.5 Gcal/t and MCF intends to do energy improvement revamp
of existing Ammonia / Urea plants to reduce its energy consumption from present
levels.
Also, Urea is an important fertilizer segment. The supply/demand gap is huge and
more than 8 million tons of urea imports are done as of now. The estimated total
demand supply gap in 2015- 2016 was 8.2 Million MT of urea alone. Government of
India is bound to support this industry through conducive policies/subsidies. All
southern states of India namely Karnataka, Tamilnadu, Kerala and Andhra Pradesh
have enough demand for Urea. In view of this, MCF proposes capacity enhancement
of Ammonia from 2,47,500 t/y to 3,28,500 t/y and Urea from 4,29,000 t/y to 5,69,400
t/y. The capacity enhancement proposed by MCF will help towards filling the
supply/demand gap.
There is increasing demand of DAP/NPK fertilizers in the country. The estimated total
demand supply gap of DAP/NPK would be 11 Million MT by 2017-2018. The proposed
expansion project of DAP/NPK would contribute in reducing the dependence on
import of DAP/NPK fertilizers.
Higher grade (> M45 Grade) concrete requires different type of admixtures known as
super plasticizers. Poly Carboxyl Ether (PCE) acts as Super plasticizers and is
currently being imported in the country. The proposed new facility within MCF plant
would be contributing in our country’s “Make in India” Program.
Source: EQMS
approved ToR by EAC (MoEF) and taking into consideration the structure of the report
given in the EIA Notification 2006. The compliance to the approved TOR has been
presented in Table 1.1:
S.
ToR Points Tor Compliance
No.
1. Executive Summary Enclosed with EIA Report
Introduction
I. Details of the EIA Consultant including NABET Enclosed as an Annexure I.
2. accreditation
II. Information about the project proponent Importance Details are given section 1.1 & 1.2 of
and benefits of the project. chapter 1.
Project Description
Section 2.11.6 of Chapter 2.
i. Cost of project and time of completion.
Existing and proposed capacity of plant
ii. Products with capacities for the proposed project.
is given in Table 2.4 of chapter 2.
iii. If expansion project, details of existing products with
Existing and proposed land distribution
capacities and whether adequate land is available for
is given Table 2.6 of Chapter 2.
expansion, reference of earlier EC if any.
Existing and proposed raw material
iv. List of raw materials required and their source along
details are given Table 2.5 of Chapter
with mode of transportation.
2.
Detailed bulk storage with item and
v. Other chemicals and materials required with quantities
quantity is given in Table 7.1 of Chapter
and storage capacities
7.
vi. Details of Emission, effluents, hazardous waste Detailed environmental aspect covered
generation and their management. in section 2.11 of Chapter 2.
vii. Requirement of water, power, with source of supply, Details of infrastructure, Power, water
status of approval, water balance diagram, man-power etc are given in section 2.9 of chapter
requirement (regular and contract) 2.
viii. Process description along with major equipment and
From section 2.3 to 2.6 all process
machineries, process flow sheet (quantitative) from raw
3. details are given in chapter 2.
material to products to be provided
ix. Hazard identification and details of proposed safety Details are given different section of
systems. chapter 7.
x. Expansion/modernization proposals:
a. Copy of all the Environmental Clearance (s) including
Amendments thereto obtained for the project from
MOEF/SEIAA shall be attached as an Annexure . A
certified copy of the latest Monitoring Report of the
Regional Office of the Ministry of Environment and
Forests as per circular dated 30th May, 2012 on the
status of compliance of conditions stipulated in all the Details are given in Annexure IV.
existing environmental clearances including
Amendments shall be provided. In addition, status of
compliance of Consent to Operate for the on-going
existing operation of the project from SPCB shall be
attached with the EIA-EMP report.
b. In case the existing project has not obtained
environmental clearance, reasons for not taking EC
I.
Permission and approval for the use of forest land
(forestry clearance), if any, and recommendations of
the State Forest Department. (if applicable).
II. Land use map based on High resolution satellite
imagery (GPS) of the proposed site delineating the
forestland (in case of projects involving forest land
more than 40 ha)
III. Status of Application submitted for obtaining the
stage I forestry clearance along with latest status
shall be submitted.
IV. The projects to be located within 10 km of the
5. Not Applicable
National Parks, Sanctuaries, Biosphere Reserves,
Migratory Corridors of Wild Animals, the project
proponent shall submit the map duly authenticated by
Chief Wildlife Warden showing these features vis-à-
vis the project location and the recommendations or
comments of the Chief Wildlife Warden-thereon.
V. Wildlife Conservation Plan duly authenticated by the
Chief Wildlife Warden of the State Government for
conservation of Schedule I fauna, if any exists in the
study area
VI. Copy of application submitted for clearance under the
Wildlife (Protection) Act, 1972, to the Standing
Committee of the National Board for Wildlife
Environmental Status:
I. Determination of atmospheric inversion level at the
project site and site-specific micro-meteorological Detailed metrology data given in
data using temperature, relative humidity, hourly wind section 3.5 of chapter 3.
speed and direction and rainfall.
II. AAQ data (except monsoon) at 8 locations for PM10,
PM2.5, SO2, NOX, CO and other parameters
relevant to the project shall be collected . The
Detailed ambient air quality data is
6. monitoring stations shall be based CPCB guidelines
given in Section 3.6 of chapter 3.
and consider the pre-dominant wind direction,
population zone and sensitive receptors including
reserved forests.
III. Raw data of all AAQ measurement for 12 weeks of all
stations as per frequency given in the NAQQM
Notification of Nov. 2009 along with - min., max., The air monitoring was conducted at 8
locations in the study area.
average and 98% values for each of the AAQ
parameters from data of all AAQ stations should be
The methodology adopted in preparing this EIA report is outlined in the following
sections:
Project Setting and Description: In this section, Environmental setting of the
existing plant and details of proposed facilities will be defined. The description also
gives details of effluents (gaseous/liquid/solid/noise) generation sources. Coverage on
environmental setting of the proposed plant in terms of site details, project description,
products, its storage, existing pollution control devices/measures, emission summary,
hazardous waste / chemicals management, etc. will be described.
Identification of Impacts: To identify the impacts comprehensively, all the activities
associated with the proposed project during the construction as well as operational
phase are identified and listed. The environmental impacts associated with the
proposed project on various environmental components such as air, water, noise, soil,
flora, fauna, land, socioeconomic, etc. Shall be identified using Impact Identification
Matrix.
Baseline Data Collection: Once the affected environmental parameters are
identified, various environmental parameters of concern are identified to establish its
baseline quality. M/s JP Test and Research Center (A NABL recognized Laboratory)
was entrusted for carrying out environmental baseline data collection from 1st
December 2016 to 28th February 2017. Data thus collected has been utilized here to
establish baseline quality of various environmental parameters.
Environmental Impact Prediction & Evaluation: In this part of the report, the
sources of emissions (Gaseous, Liquid, Solid, Noise) due to the proposed activities
have been identified and based on their emission loads their impacts are to be
predicted. Such predictions are then superimposed on baseline quality (wherever
there is an additional impact) and quantitative/qualitative assessments have been
made for the impacts and synergistic impact is evaluated using the matrix method.
The resultant matrix attempts to give an objective assessment to identify the
mitigation measures needed for abatement of various impacts.
Environment Management Plan (EMP): To mitigate or minimize the negative
impacts (if any) of the proposed project, an effective EMP is delineated. Therefore, in
the final part of the report, the planning and implementation of various pollution
abatement strategies including the proposed monitoring/surveillance network has
been described. Detailed Environment Management Plan (EMP) with specific
reference to details of air pollution control system, water & wastewater management,
monitoring frequency, responsibility and time bound implementation plan for mitigation
measure is formulated.
Qualitative and Quantitative risk assessment was also carried out using the latest
Phast 6.6 and finds considered for safe operation planning.
1.10. Contents of the EIA Report
An “Executive Summary” indicating a brief note on various chapters of EIA report is
prepared which provides a statement on various environmental issues. Further, the
contents and its coverage are explained below:
This chapter provides overview and technical details of existing plant and
proposed expansion along with land, input materials, utilities and pollution
control measures. This chapter includes the following section namely- brief
summary, overview of the project, site location and features, existing plant and
proposed expansion details, input material with its transportation and storage
details, utilities, waste management and pollution control details.
Details
S.No. Features
Existing Proposed
A. Location Details
Coordinates 12°56'8.99"N, 74°49'25.08"E
Village: Panambur
Village, Tehsil, District, State Tehsil/Taluk: Mangalore
District: Dakshina Kannada
Nearest Railway Station Railway Station: Mangalore – 10 km
1
Nearest Highway NH-66
Nearest City, Town Mangalore – 10 km
Nearest Airport Bajpe International Airport- 10 km
Lakes/Reservoir/Dams/River Gurupura River – 1.0 km
Sensitive Places None within 10 km radius
B. Technical Details
Products & Handling of Fertilizers (t/y)
Ammonia 2,47,500 3,28,500
Urea 4,29,000 5,69,400
DAP/NPK (Multi-grade) 4,01,500 14,01,500
2
Poly Carboxyl Ether (PCE) - 18,000
Sulphuric Acid 1,46,000 No Change
Ammonium Bicarbonate
24,750 No Change
(ABC)
Sulphonated Naphthalene
85,000 No Change
Formaldehyde
Specialty mixtures of plant
2,21,000 No Change
nutrients
No Additional requirement,
3 Total Plot Area 192 Expansion is coming in Existing
Premises
4 Water Requirement (KLD) 9000 No Additional Water Required
48 MW through Existing capacity will meet the
5 Power
Captive power additional Power required for
The coordinates of the project site boundary are given in Table 2.1 and Figure 2.2 below.
Table 2.3 Comparison of Fossil Fuel & Power consumptions between present and post
revamp conditions
Figure 2.8 Improvement in Specific Energy Consumption in Ammonia & Urea over the
period
MCF has continuously upgraded its Ammonia-Urea plants of 1976 vintage with
significant investment to improve reliability and energy consumption. Further
improvement is possible only with major technological modifications involving large
investment. The proposed revamp of the Ammonia – Urea plants will take up their
performance in terms of energy consumption to best operating plants in India. Some of
the major schemes implemented so far are listed below:
Purge Gas Recovery Unit (PGRU) was installed in 1984 for recovery of Hydrogen
from purge gas
Captive Power Plant was installed in 1985 for reliable power source
Axial type ICI Ammonia Converter basket internals were replaced with S-200 axial
type of HTAS design in 1994 for Lower loop pressure and higher Ammonia
conversion per pass.
Reformer Tube replacement (new material), Reformer wall refractory was upgraded
from castable to new ceramic modules lining to reduce heat losses and to increase
reformer tube life due to lower skin temperature.
Replacement of Reformer Burners with Low NOx burners.
Replacement of make gas boiler with improved design.
Replacement of Packing and internals of CO2 absorber.
Implementation of Distributed Control System (DCS) and Advanced Process Control
(APC)
VAM Chiller installation to supply chilled cooling water to for syngas compressor
suction chilling.
Burner Management System (BMS) for fired heaters F210 & F202 to improve safety
of operation.
Installation of Seal Gas recovery unit to Syngas compressor.
Safe shut down PLC for improved safety.
Ammonia plant and Power plants NG conversion to use Natural Gas as feed and
fuel.
Hydraulic Power Recovery Turbine in CO2 removal section
Urea Hydrolyser stripper installation to reduce ammonia in effluent stream.
Urea reactor trays replacement with high efficiency trays and relining of Autoclave.
Pre evaporator and LP scrubbers were installed.
Change of material of construction of HP stripper & HP condensers were to Safurex.
Medium Pressured scrubbing section was introduced for improved reliability.
MCF has installed urea hydrolyser stripper at a cost of Rs. 8.5 crores in 1990 for the
treatment of effluent streams from ammonia process, urea process and condensates
from urea plant compressors. The urea hydrolyser stripper system consists of
hydrolyser, which hydrolyzes urea in feed stream into ammonia and carbon di
oxides. Ammonia thus formed is separated in the second desorption column. The
bottom outlet (liquid) of second desorption column contains less than 10 ppm of
ammonia and urea. The overhead gas (ammonia vapors) from second desorption
column is fed to first disrober. The disrober overhead vapors (essentially ammonia &
CO2) are condensed in a condenser and reused in Urea plant. The treated effluent
from the second desorber which contains about 10 ppm of ammonia is used as
cooling tower makeup water.
8.0 Gcal/t when operated on natural gas. However, the plant can be operated on
Naphtha also and in naphtha based operation, plant capacity will remain at present level,
but energy consumption will reduce to 8.5 Gcal/t.
of 45m³. This additional converter will increase the per pass conversion. This converter
will be a cold walled. Additional BFW heater is provided for heat balance.
e) PGRU
The current PGRU though may not be able to take the additional load and hence will be
left untouched. The additional purge will be used as fuel in the primary reformer.
f) Naphtha Pre-treatment:
The whole revamp is considered with the NG as feed and fuel, hence the pretreatment
of Naphtha section is not considered for any change.
g) MP stripper:
Process condensate from the plant will be stripped using a medium pressure stripper.
The treated condensate produced from this stripper can be used as a make up to the de-
aerator thereby bringing down the fresh DM water requirement for Boiler feed water.
In the first reaction carbon dioxide and ammonia are converted into ammonium
carbamate. This reaction is fast and exothermic. In the second reaction, which is slow
and endothermic, the ammonium carbamate dehydrates to produce urea and water.
Urea Plant is designed based on CO2 striping process licensed by Stamicarbon BV
Netherlands. Ammonia (NH3) and Carbon Dioxide (CO2) are the main raw materials for
Urea production.
Initially, NH3 and CO2 are passed through a High Pressure Condenser where
Ammonium Carbamate is formed. This is sent to autoclave where a portion of it is
converted to Urea. The unconverted Ammonium Carbonate is stripped into NH3 and
CO2 gases in a High Pressure Stripper using fresh CO2 and recycled back to the HP
condenser along with fresh Ammonia and dilute Ammonium Carbamate to again form
concentrated solution of Ammonium Carbamate. This cycle thus continues. The Urea
solution thus coming from the Stripper is separated and concentrated in low pressure
section consisting of a rectification column, a flash vessel, Pre-evaporator and two
stages of evaporation.
The molten Urea solution coming from the final evaporator is sent to a revolving prill
bucket at the top of the Prill Tower. The Urea solution is sprayed in the form of fine
droplets by rotation of the prill bucket. The droplets solidified into prills before reaching
the bottom of the Prill Tower as they come in contact with an upward flow of air. The
prills are collected at bottom and conveyed to bagging plant or for storage in silo.
to achieve 550 - 600 kg/t (38 bar A & 400° C). b) Capacity expansion from 4,19,750 t/y
to 5,69,400 t/y. c) To improve the quality of the prilled Urea product.
Process retrofit concepts to fulfil the revamp objectives
Urea is produced by reacting liquid ammonia and gaseous carbon dioxide at about 170 -
185 C and 135 - 145 bar according to the following reactions:
2 NH3 + CO2 <=====> NH2COONH4 (1)
NH2COONH4 <=====> NH2CONH2 + H2O (2)
In the first reaction, carbon dioxide and ammonia are converted into ammonium
carbamate. This reaction is fast and exothermic. In the second reaction, which is slow
and endothermic, the ammonium carbamate dehydrates to produce urea and water.
Ammonia and Carbon dioxide compression
Liquid ammonia is supplied from battery limits to the high pressure ammonia pump and
compressed to about 165 bar. It is then sent to the pool condenser via the high pressure
ammonia ejector. Additional ammonia is supplied to the MP section. As the normal
operating pressure of the MP section is lower than the supply pressure of the ammonia,
this is done via a let-down valve. In case of increased pressure in the MP section, a new
MP NH3 pump is foreseen to transfer ammonia to the MP section. Carbon dioxide from
battery limits is supplied, together with a small amount of air, to the carbon dioxide
compressor before it is compressed to synthesis pressure. A hydrogen converter is
integrated in the carbon dioxide compressor. In this converter the hydrogen, present in
the carbon dioxide, is removed by catalytic combustion. A portion of the supplied air is
used for this catalytic combustion while the remainder being used to passivate the
equipment of the synthesis section and so prevent corrosion. The dehydrogenated
carbon dioxide is introduced into the bottom part of the high pressure stripper. Additional
carbon dioxide is supplied to the LP section via the newly installed LP CO2 compressor.
Additional air is supplied to this compressor and a hydrogen converter is placed in the
discharge. The two feedstocks, ammonia and carbon dioxide, are fed to the synthesis
section at a molar ratio of 2 : 1.
Synthesis
The dehydration of ammonium carbamate into urea and water takes place in the
poolcondenser and subsequently in the reactor. The reactor effluent is partially
distributed over the tubes of the high pressure stripper, which is a falling film type shell
and tube heat exchanger. Here, the reactor effluent is contacted counter-currently with
carbon dioxide, causing the partial ammonia pressure to decrease and the carbamate to
decompose. The heat, required for this purpose, is supplied by passing saturated high
pressure steam around the tubes of the high pressure stripper. A part of the liquid from
the reactor is bypassing the stripper and is sent directly to the MP section. By means of
the pressure of the HP steam to the stripper and the ratio between liquid sent to the
stripper and liquid that bypasses the stripper, the ammonia concentration in the liquid to
the MP section is controlled at about 15% by weight.
The urea solution from the high pressure stripper, flows to the low pressure recirculation
section whilst the high pressure stripper off gases are sent to the poolcondenser which is
special design U-tube type heat exchanger. In the pool condenser condensation of
stripgasses takes place through the principle of poolcondensation, i.e. the gases are
dispersed into a pool of liquid, where the heat of condensation is being dissipated by
submerged heat exchanger tubes. This heat of condensation is used for two purposes:
1: to dissociate carbamate from the urea solution in the MP stage (in the lower bundle).
2: to generate low pressure steam of 4.5 bar (in the upper bundle). This steam is used
for heating and desorption as well as for the vacuum ejector. The steam pressure at the
tube side of the high pressure carbamate condenser is controlled by a pressure control
valve in the steam discharge line of the steam drums. A change in this pressure will
change the steam condensate temperature and hence the temperature difference
between the shell side and the tube side. The steam drum pressure is set to such a
value that the synthesis pressure is about 145 bar.
The pool of liquid in the poolcondenser allows for a considerable amount of urea
formation to take place here. The formed urea, non-converted carbamate, excess
ammonia and some non-condensed ammonia and carbon dioxide are subsequently
introduced into the bottom of the reactor where further conversion of carbamate into
urea takes place. The reactor volume allows sufficient residence time for the reaction to
approach equilibrium. The heat, required for the conversion and for heating the solution
in the reactor, is supplied by additional condensation of ammonia and carbon dioxide.
The reactor contains a number of high efficiency trays to ensure that the flow of liquid
through the reactor approaches piston flow. Moreover the trays are designed such that
negative effects (such as back-mixing, by-passing and stagnant zones in the reactor) are
avoided. The reactor effluent goes through the downcomer to the high pressure stripper.
The inert, introduced with the carbon dioxide and part of the unreacted ammonia and
carbon dioxide, go overhead to the high pressure scrubber which contains a shell and
tube heat exchanger in the lower part and a packed bed in the upper part. In the lower
part of the high pressure scrubber the bulk of the ammonia and carbon dioxide are
condensed, the heat of condensation being dissipated into tempered cooling water. This
heat is recovered in the pre-evaporator. In the upper part of the scrubber the gases,
leaving the bottom section, are contacted counter currently with the carbamate solution
coming from the medium pressure recirculation section. The gases, substantially
consisting of nitrogen and oxygen and containing only small amounts of ammonia and
carbon dioxide, are vented to the atmosphere via a LP absorber. The carbamate solution
from the high pressure scrubber flows to the high pressure ammonia ejector. The
ammonia feed pressure is such as to induce sufficient head in the high pressure
ammonia ejector to convey the carbamate solution from the high pressure scrubber to
the high pressure carbamate condenser.
Liquid leaving the stripper is flashed to MP conditions. The liquid from this flash is led
through the bottom bundle of the pool condenser where the supplied heat enables the
dissociation of carbamate into ammonia and carbon dioxide. The gas from this
dissociation is combined with the off gas from the flash and is led to the first stage
evaporation heater, which acts as a MP carbamate condenser. The heat of
condensation of the carbamate is used to evaporate water from the urea solution. The
formed carbamate is sent to the HP scrubber. Small amounts of non-condensed
ammonia and carbon dioxide as well as inerts are vented to the existing LP absorber.
Liquid, leaving the dissociation heater is counter-currently contacted with the off gas
from the MP flash and then discharged to the existing LP section.
Low pressure recirculation section
In this section essentially all of the small amounts of non-converted ammonia and
carbon dioxide are recovered from the urea/ carbamate solution, leaving the MP section.
This solution is expanded to about 4 bar. As a result a portion of the carbamate, left in
the solution, decomposes and evaporates. The remaining liquid is divided onto a bed of
Pall rings in the rectifying column. The urea/ carbamate solution is sent from the bottom
of the rectifying column to a new heater where its temperature is raised to about 135 C
in order to decompose the remaining carbamate. The heat required is supplied by low
pressure steam. In the separator (i.e. the bottom part of the rectifying column) the gas
phase is separated from the liquid phase. The gases are sent to the rectifying column
where they are cooled by the colder urea/ carbamate solution. This causes a portion of
the water vapour contained in the gases to condense. The gases leaving the rectifying
column are introduced into the bottom part of the low pressure carbamate condenser
where they are condensed almost completely. The heat of condensation is dissipated
into tempered cooling water. Process condensate is also supplied to the low pressure
carbamate condenser together with the condensed overhead vapours from the first
desorber and from the atmospheric section in order to control the water concentration in
the carbamate solution. The optimum ammonia/ carbon dioxide ratio allows the water
concentration to be as low as 31 % by weight. The pressure in the low pressure
carbamate condenser is controlled at about 3.3 bar. From the level tank of the low
pressure carbamate condenser, the carbamate solution flows to the medium pressure
carbamate pump where its pressure is raised and from where the carbamate solution is
carried to the MP section. The urea solution, leaving the bottom of the rectifying column,
flows to the atmospheric flash separator via a level control valve. Due to the adiabatic
flash to about atmospheric pressure, a portion of the water evaporates and some
ammonia, carbon dioxide and inert are liberated. These vapours are partly condensed in
the flash separator condenser and the remaining vapours are sent to the condensers of
the evaporation section. Condensate from the flash separator condenser is recycled to
the LP carbamate condenser.
The solution from the atmospheric flash separator is sent to the flash separator heater. A
portion of the water in the solution is evaporated so as to increase the urea
concentration. The heat of evaporation is taken from the tempered cooling water system.
Finally, the urea solution is sent to the urea solution tank. The urea solution is pumped
from the urea solution tank to the evaporators, where it is concentrated to about 99.5 %
by weight. In the separator of the evaporator, the outlet from the evaporator heater is
separated into a gas phase and a liquid phase. The vapour, leaving this separator, is
condensed in the evaporator condenser together with the vapours from the separator
pre-evaporator. The urea solution from the evaporation separator flows to the suction
side of the urea melt pump and is sent to the prilling tower. The condensate, leaving the
evaporator condenser is sent to the ammonia water tank via a barometric leg.
Process condensate treatment
gas will be scrubbed in venturi type scrubber. Wet gases will be directly scrubbed in
venturi scrubbers. Venturi scrubber outlet will be again scrubbed in final tail gas scrubber
before letting to atmosphere.
The technology also incorporates special scrubbing scheme like Dual Mole Scrubbing
System and Dedusting system. Air pollution control equipment viz. Cyclone, Scrubber,
Mist eliminator etc of adequate capacity shall be installed during the commissioning of
the plant itself.
There will be no liquid waste and solid waste generation from the plant. All liquid
spillages shall be collected and recycled back to the process.
The flow of gaseous emission from the stack (3 No. 45 m each) is expected to be
maximum 720000 Nm³/hr, particulate Matter 50 Mg/Nm³, fluorine 20mg/Nm³ and
Ammonia 150mg/Nm³.
Considering the sufficient pollution control measures incorporated in the process
technology and plant design towards reducing emissions and maintaining the emissions
within specified norms, the proposed project will not have any significant adverse impact
on the existing environment.
2.5.1. Process description of 1 MILLION t/y DAP / NPK PROJECT
NH3 + H3PO4 NH4H2PO4 + Q2A (1)
Ammonia + Phosphoric Acid -> Mono Ammonium + Heat
Phosphate
a) Dry Section
With reference to the simplified process flow diagram for the Dry Section of the Slurry
Process, a detailed description is furnished as follows:
Phosphoric acid, gaseous Ammonia, and scrubber liquor enter into the Preneutralizer
where it is controlled at a specific gravity of 1.53 and a mole ratio of 1.5, which
corresponds to moisture content in the slurry of 18%. The Preneutralizer is maintained at
a mole ratio of 1.5 to ensure maximum solubility of the slurry. The Ammonium
Phosphate slurry is pumped from the Preneutralizer to the Pipe Reactor where it is
combined with strong phosphoric acid, and gaseous Ammonia and sprayed onto the bed
of the Rotary Granulator at a mole ratio of 1.5 and moisture of 10%. Underneath the bed
in the Granulator is the Ammonia sparger that supplies liquid Ammonia to raise the mole
ratio of the fertilizer up to the desired value.
The material leaves the Granulator and enters into the Rotary Dryer where the DAP is
dried, using hot gases leaving the Combustion Chamber, to a moisture of 1.0-1.5% or
even lower if needed. After exiting the Dryer the material enters into the Primary Elevator
to be distributed over the Oversize Screens. The Oversize Screens are double deck
screens where the oversize is sent to the chain mills, the undersize falls onto the
Recycle Belt along with the crushed material, and the product size material is sent to the
Product Screen Elevator for distribution on the Product Screens.
The purpose of the Product Screens is to remove the remaining fines that were not
removed by the Oversize Screens. The fines fall onto the Recycle Belt and the on spec
material enters into the Fluidized Bed Cooler or is recycled for control of the recycle
ratio. The air entering into the Fluidized Bed Cooler can be chilled using the Ammonia
Air Chiller which will be discussed later.
Once leaving the Fluidized Bed Cooler the material enters into the Product Elevator and
is distributed onto the Polishing Screens. The on spec material then enters into the
Coating Drum and is then conveyed to the storage building. The gases leaving the
Dryer, Product Cooler, and Dedusting system are each sent through a separate set of
cyclones. After the dedusting system offgas exits the cyclones it is sent through a
baghouse to be sent to the Combustion Chamber.
If this method of recycling dedusting offgases is not in place then the gases are sent to
the RG Scrubber. The gases leaving the Dryer Cyclones go to the Dryer Scrubber and
the gases leaving the Cooler Cyclones go the Tail Gas Scrubber.
b) Wet Section
With reference to the simplified process flow diagram for the Wet Section of the Slurry
Process, a detailed description is furnished as follows:
Ammonia laden gases exiting the Preneutralizer and Granulator first enter into the
Prescrubber where they are scrubbed with liquor at a mole ratio of 1.4 where 60-70% of
the Ammonia is absorbed. Once exiting the Prescrubber the gases enter into the
Reactor Granulator Scrubber (RG Scrubber) where the gases are scrubbed with liquor at
a mole ratio of 0.7. The gases exiting the Dryer go through a cluster of cyclones and
enter into the Dryer Scrubber where the gases are scrubbed with the same liquor that is
used in the RG Scrubber. The liquor that is used in the RG Scrubber and the Dryer
Scrubber is circulated from the Scrubber Tank. Gases from the RG Scrubber and Dryer
Scrubber along with the gases that exit the Cooler Cyclones enter into the Tail Gas
Scrubber and then exit into the atmosphere. The circulating liquor in the Tail Gas
Scrubber is sent through a kettle type heat exchanger to vaporize Ammonia.
Reactor. The average Citrate Insoluble P2O5 can be reduced by 0.2% when a Pipe
Reactor is used. The Preneutralizer mixes Phosphoric acid, Ammonia, and Scrubber
liquor to be sent to the Pipe Reactor or directly to the Granulator. The Phosphoric acid
and Scrubber liquor are fed through the top of the reactor while the gaseous anhydrous
Ammonia is fed through spargers located at the bottom.
The process uses the reduced retention time Preneutralizer where the diameter at the
bottom of the tank is smaller than the top. The advantage of this design is that the
Citrate Insoluble losses are decreased while still maintaining the liquid level necessary to
absorb Ammonia and not to entrain liquid in the exiting gas. The Citrate Insoluble losses
increase with increased retention time so it is necessary to minimize the liquid volume in
the Preneutralizer. The Preneutralizer is much simpler to operate than the Pipe Reactor
and when used in conjunction with the Pipe Reactor it gives the plant a stable baseline
and increased controllability.
Using a Preneutralizer reduces the amount of water that is vaporized in the Granulator
by the Pipe Reactor. If less water is vaporized in the Granulator then less air is needed
to keep the gas leaving the Granulator below the saturation point. For a 120 MT/hr.
plant, the required airflow in the Granulator when a Pipe Reactor and Preneutralizer are
installed is 44,000 ACFM and when there is only a Pipe Reactor present is 88,000
ACFM. This reduced airflow reduces the size of the Granulator, Prescrubber, RG
Scrubber, RG Fan, Scrubber Pump and the Tail Gas Scrubber and Pump.
d) Dual Mole Scrubbing
Dual Mole Scrubbing is a two stage process where gases from the Preneutralizer and
Granulator are scrubbed with a high N/P mole ratio liquor followed by scrubbing at a low
mole ratio. The gases first enter the Prescrubber, which operates at a mole ratio of 1.4,
where about 60-70% of the Ammonia is removed. Next the gases enter into the Reactor
Granulator (RG) Scrubber where the rest of Ammonia as well as the fluorine are
removed and this scrubber operates at a mole ratio of 0.7.
Recycling Dedusting system off gas to the Combustion Chamber takes the heat given off
by the DAP throughout the plant and reuses it in the Dryer. There are various dedusting
pickup points within a DAP plant which mainly come from the belt conveyors, screens,
and elevators.
The proposed project site is located within the boundary of Mangalore Chemicals and
Fertilizers Ltd., Mangalore. No additional land will be required for this project.
2.9.2. Power
The present power requirement is 36MW. After implementation of proposed projects, power
requirement for Ammonia and Urea plants will reduce by about 6 MW. This will cater to the
requirement of the new DAP/NPK and PCE plants.
So no additional power will be required for this project.
2.9.4. Fuel
Naptha / FO will be used as fuel. Comparison of fuel in present and post revamp
conditions are given in table 2.1Control Measures provided in the tank farm area:
Underground pipelines are protected from corrosion by protective coating and
over ground pipelines by painting.
Pipelines are periodically inspected and hydraulic testing of underground
pipelines is done as per preventive maintenance schedule.
Jumper connections are provided across the flanges of Naphtha carrying
pipelines to prevent buildup of static electricity.
Storage tanks are constructed as per API 650 standards.
The tanks are provided with level indicators, temperature indicators and earthing
arrangements.
Raw Naphtha tank is a floating roof tank. Swivel joints are provided for roof drain,
which are inspected periodically. Double earthing protection is provided for the
pontoon. Breather valve with flame arrestor is provided to avoid buildup of
pressure / vacuum in the tank.
Sweet Naphtha tank is provided with Nitrogen blanket. Low Nitrogen flow alarm
is provided. Relief valve with flame arrestor is provided to prevent excessive
buildup of pressure in the tank.
Fuel oil storage tanks are provided with a vent with a flame arrestor. Steam
heating coil is provided to maintain the Fuel oil/LSHS at the proper temperature
to facilitate easy handling.
Regular draining of the tanks is done to avoid contamination of the contents with
water.
Periodic inspection of raw naphtha tanks, tank seals, inspection of pipeline
supports, phased replacement of flanged bolts and gaskets would ensure
prevention of any leaks and emergencies.
Tanks are provided with containment dykes and fire break walls as per relevant
standards, rules and regulations.
Oil water separators and fire seals are provided to avoid contamination of storm
water drains with Naphtha and Fuel oil spills.
Adequate firefighting facilities are provided which include TAC approved fire
hydrant system. One fire tender and one trolley mounted fire pump are available
at site.
Both the Raw Naphtha tanks are provided with 10 fixed foam pourers each and
furnace oil with 2 fixed foam pourers. 2 Nos fixed foam pourers for sweet
Naphtha tank. 2 nos. foam compound tanks with a capacity of 10,000 litres are
provided at the tank farm area. 1000 litres of foam is kept available at the fire
station. In addition 10,000 litres of foam is maintained spare for mutual aid with
MRPL.
2.10. Employment
The unit proposes to provide employment to various skilled and unskilled persons. The
existing employment at the site is 680 no of persons and proposed employment
generation from the project is estimated to be 200 no of persons including contract labor
during operation phase.
2.11. Environmental Aspects:
2.11.1. Liquid Effluent
Ammonia Plant
There is no additional liquid effluent generation from the plant and will remain zero liquid
effluent discharge plant. It is proposed to replace the present low pressure stripper with
medium pressure (MP) stripper which will ensure removal of Ammonia from process
condensate. The gases from the MP stripper will go to primary reformer along with
steam. The effluent generated in the plant shall be treated in the existing effluent
treatment facility and recycled back to the system.
Urea Plant
There will not be any additional effluent generation because of the proposed expansion.
Because of the various energy improvement schemes, effluent generation will reduce.
For the existing system, MCF has installed and commissioned urea hydrolyser stripper
and operated for the treatment of effluent streams from ammonia plant process, urea
plant process and condensates from urea plant compressors. The urea hydrolyser
stripper system consists of hydrolyser, which is operated at high temperature' and high
pressure, where urea gets hydrolyzed to ammonia and carbon dioxide. Ammonia thus
produced is separated in the second desorption column. The liquid outlet of second
desorption column contains less than 10 ppm of ammonia and urea. The ammonia
vapours from the second desorption column is fed to the first desorber. The desorber
overhead vapours are condensed in a condenser and reused in Urea plant.
DAP/NPK Plant
No trade effluent generation from the proposed DAP/NPK plant. No solid waste will be
generated. Any spillage will be recycled and reused in the proposed plant. The marginal
increase in the water requirement after the commissioning of DAP/NPK plant will be met
by effluent water recovery unit installed.
Poly carboxyl ether (PCE) Plant
There will be no liquid effluent generated in the plant. The spillages if any from the plant
floor will be collected and recycled back.
Mangalore Chemicals & Fertilizers Ltd. (MCFL) has given top priority to its effluent
treatment and disposal system right from the design stage of its plants.
TRADE EFFLUENT TREATMENT SYSTEM
In Mangalore Chemicals & Fertilizers Ltd., (MCF), the Liquid Effluent streams generated
are only from Ammonia, Urea and Water Treatment Plants. The Ammonium Bi-
carbonate and Di-Ammonium Phosphate Plants are designed to have zero effluent
discharge. In Di-Ammonium Phosphate (DAP) Plant a part of ammonia and urea bearing
effluent from Urea/Ammonia plant is used as process condensate. MCF already installed
the ETP in existing plant and the same will be used for the treatment of additional
effluent generated in the proposed projects.
MCF has installed and commissioned urea hydrolyser stripper at the cost of Rs.8.5
crores in 1990 and same is being operated for the treatment of effluent streams from
ammonia plant process, urea plant process and condensates from urea plant
compressors. The urea hydrolyser stripper system consists of hydrolyser, which is
operated at high temperature and high pressure where urea gets hydrolysed to ammonia
and carbon dioxide. Ammonia thus produced is separated in the second desorption
column. The liquid outlet of second desorption column contains less than 10 ppm of
ammonia and urea. The ammonia vapours from the second desorption column is fed to
the first desorber. The desorber overhead vapours are condensed in a condenser and
reused in Urea plant. The treated effluent from urea hydrolyser stripper is reused as
cooling tower makeup water.
Urea Hydrolyser Stripper:
Urea Hydrolyser stripper system consists of mainly first Desorption column, Urea
Hydrolyser, Second desorption column, Reflux condenser and Level tank reflux
condenser.
Pre-Desorber or First desorber: Process condensate (design = 11% NH3) from
ammonia water tank is fed to desorption column through heat exchanger. Process
condensate from Urea plant oil separator is also fed to desorption column after
preheating to 128oC. Steam, water vapour from urea hydrolyser and 2nd desorption
column are introduced to the bottom part of desorption column as stripping medium.
The desorption column is operated at 2.6 Kg/cm2 and in this a part of ammonia and CO2
in the solution is stripped off. To control the water percentage at about 46% in the top of
the first desorber, reflux is added to the top tray of first desorption column. The reflux
comes from level tank reflux condenser.
The pre-desorbed solution at a temperature of 140 oC from the bottom of desorption
column is pumped upto 20 Kg/cm2 and after heating to about 182 oC in the hydrolyser
heat exchanger; it is fed to the hydrolyser.
Hydrolyser: In the hydrolyser, most of the urea is hydrolysed into NH3 and CO2 at an
average temperature of about 200 oC at 16.5 Kg/cm2. The feed flow to hydrolyser
exchanges heat with the bottom effluent of the hydrolyser in hydrolyser heat exchanger.
The feed temperature increases from 138 oC to about 189 oC. The feed inlet is at the first
tray. The column has 16 sieve trays to ensure a good contact between the process liquid
and vapours. The column is almost completely filled with liquid except for the space
above the first tray.
The heat required for hydrolysation and maintaining a temperature of about 189 oC in the
top of the hydrolyser is supplied by 38Kg/cm2 steam with a temperature of about 390 oC.
The temperature of the bottom effluent is about 208 oC before hydrolyzer heat
exchanger exchanges heat with the feed flow thereby decreasing the temperature to
about 146 oC.
Second desorption column: The effluent is then fed to the top of 2nd desorption column
for final stripping. Process condensate from Ammonia plant is also introduced into
second desorption column after preheating to about 146 oC, with second desorption
column outlet liquid stream.
In the second desorber, operated at 2.8 Kg/cm2, L.P. steam is used to strip the residual
ammonia and CO2 and is fed underneath tray 41. Separated hot ammonia and CO2
gases with water vapour are sent to the first desorption column. Second desorber is a
vertical column consisting of 41 Nos. of double flow sieve trays each with 538 holes of
12.7 mm diameter.
The second desorber liquid discharge, which contains less than 10 ppm of ammonia and
urea (Guaranteed 30 ppm NH3 and 30 ppm urea) at a temperature of 143 oC is
extracted from the bottom of second desorber and is split into two steams. One stream
after heat exchange with process condensate feed from NH3 plant is sent to cooling
tower. The other stream after heat exchange with process condensate feed from urea
plant oil separator and with process condensate from ammonia water tank is cooled at
40 oC with cooling water in coolers and this also is sent to cooling tower.
Block diagram is attached.
Static mixer, Lamella clarifier, centrifuge and sand filter are major equipment for treating
the high suspended solids effluent streams. Back wash water of sand filter and
activated carbon filter from water treatment plant and cooling tower side stream filter are
treated in this unit. Lamella clarifier are proven equipment and technically suitable for
treating the above streams. The treated water is reused in cooling tower as makeup.
The Lamella Clarifier consists of a series of inclined overlapping plates, which are
arranged to form a sedimentation chamber. Before entering to Lamella clarifier, water is
first fed to Flocculation tank through Static mixer.
Chemicals like Alum, Polymer and Chlorine are added prior to static mixer in which
zigzag vanes are provided for proper mixing of chemicals in water. Water from static
mixer enters in flocculation chamber in which paddle type agitator is provided for gentle
mixing. Polymer is added for flocculation of coagulated particles. Sufficient residence
time is provided in this chamber for particles to become heavy before entering into
Lamella Clarifier. The pretreated feed stream enters the Lamella and transverses
through feed ducts longitudinally, along each side of the Lamella plates, through a
bottomless distribution duct. As the feed stream moves upwards, solids settle down.
The backwash water from clarifier is recycled to static mixer. The slurry containing solids
is pumped to a centrifuge for separating liquid which is recycled to static mixer. The
thickened slurry is used in DAP plant.
SF B/W
ACF B/W
LAMELL
FLOCUL
STATIC A
ATION SLURRY TO
MIXER CLARIF
TANK CENTRIFUGE
IER
SOLIDS TO
DAP PLANT
LIQUID TO
POLYMER STATIC MIXER
CLARIF
DOSING
IED
WATER
COAGULA TANK MGF
COOLI NT
NG DOSING
TOWE
R
BLOW
DOWN
PIT
COOLIN RECOV
G ERED
TOWER WATER
SS FOR
FILTER REUSE
B/W Figure 2.16 Lamella clarifier
WATER
The high dissolved solids effluent stream containing water treatment plant resin
regeneration effluent and cooling tower blow down is passed through clarifier, pressure
sand filter and Ultra Filtration (UF) units to remove suspended solids and colloidal
particles. Then it is treated in Reverse Osmosis (RO) units to remove dissolved solids.
Treated water is reused in cooling tower as makeup.
The high dissolved solids effluent streams are collected in an equalisation tank. This
stream after dosing with NaOCl, Coagulant, Lime, Dolomite & Polymer will be pumped to
High Rate Solids Contact Clarifier (HRSCC). The clarified water from HRSCC is passed
through Multi Grade filter for reduction of suspended solids. Then the filtered water is fed
into the Ultra filtration unit (UF) to remove colloidal silica and related colloids of iron and
aluminium in water causing fouling, scaling and poor performance of the plant. The
stream which is free from suspended and colloidal particles will be passed through
Reverse Osmosis unit (RO). The Dissolved solids are removed in 2 stages of RO unit. In
the first stage RO1 about 75 % of desired quality water will be recovered and reject is fed
to second stage RO2 wherein further 10% is recovered. The RO2 reject containing high
dissolved solids is used in DAP plant. The sludge collected in the HRSCC is pumped to
centrifuge to remove water. The separated liquid is recycled to equalizing tank and
sludge is used in DAP plant.
SAC REGN.
EFFLUENTS
POLYMER CLARIFIED
CLARIFIER CLARIFIER WATER
FEED TANK STORAGE TANK
NaOCl
REGN. COAGULANT
EFFLUENT
SOLIDS TO DAP
WATER TANK CT BLOWN DOWN WATER SLURRY TO CENTRIFUGE
CLARIFIER FEED PLANT
PUMPS
LIQUID TO
SBMS DOSING FEED TANK
MB/SBA/WBA
REGN.
EFFLUENTS UF
ANTISCALANT PERMEATE U.F
HCl DOSING
TANK
MULTI GRADE
FILTER
RO SKID
RO REJECT
RECOVRED DAP PLANT
WATER
WATER FOR
REUSE IN
COOLING
TOWER
Effluent from the equalization tank is fed to the Membrane Bio-Reactor (MBR) tank at
constant flow rate. In MBR tank, MLSS (mixed liquor suspended solids) in the range of
10,000 mg/l is maintained. The high amount of bacteria gives better and complete
removal of organic matter from the raw effluent in relatively small area. Aeration is done
both to the equalization and MBR tanks through diffuser membranes by using blowers.
The suction pumps directly sucks permeate and the filtration is carried out by the
membrane. The suspended solids, turbidity, bacteria and viruses in permeate water are
removed to the levels required for reusing treated water. The treated water is reused in
cooling tower as makeup.
There will not be any significant increase in pollution load after the implementation of
energy improvement project. Capacity of Urea plant will be increased from 4,29,000 t/y
to 5,69,400 t/y after the availability of NG in Mangalore.
The emission of Particulate matter from the urea prill tower will be about 110 mg/Nm3
which is well within standard of 150 mg/Nm³.
The Ammonia / Urea revamp project will not have impact on Environment as energy
norms will improve further there by reducing the consumption norms on fuel resulting in
reduction of emissions. The proposed project will not have any adverse impact on the
existing environment as sufficient pollution control measures are incorporated in the
process technology. Additional CO2 required for Urea production will be recovered from
reformer flue gas by Carbon dioxide Recovery (CDR) unit which inturn reduces the
emission of CO2, a greenhouse gas.
DAP/NPK Plant.
The proposed project will not have any significant adverse impact on the existing
environment as sufficient pollution control measures are incorporated in the process
technology and plant design. The technology also incorporates special scrubbing
equipment like Dual Mole Scrubbing System and also Dedusting system. In DAP / NPK
plant Air pollution control equipment viz. Cyclone, Scrubber, Mist eliminator etc. shall be
installed during the commissioning of the plant itself.
The flow of gaseous emission from the stack (3 no. 45 m each) is expected to be
maximum of 720000 Nm³/hr., particulate Matter 50 mg/Nm³, fluorine 20 mg/Nm³ and
Ammonia 150 mg/Nm³.
POLY CARBOXYL ETHER (PCE) Plant
There will not be any gaseous emission from the proposed plant.
The details of stacks and vents along with height, type of fuel, fuel consumption rate,
control measure etc. is referred in Table below
This Chapter describes the baseline environmental conditions around the proposed MCF
project site for various environmental attributes, i.e. physical, biological and socio-economic
conditions, within the 10-km radial zone of the proposed project site, which is termed as the
study area. Topography, drainage, meteorology, air, noise, water, soil and land constitute
the physical environment, where as flora and fauna constitute the biological environment.
Demographic details and occupational pattern in the study area constitute socio-economic
environment.
Secondary data from literature search were also obtained from the Govt. sources i.e.
Meteorological Department, CPCB publications; Forest Department and other Govt.
Sources. The baseline environmental data generation has been done for the period from
1st December 2016 to 28th Feb 2017. M/s JP Test & research centre, Sahibabad, Uttar
Pradesh with EQMS Team, carried out sampling and testing. The study area within a 10-
km radius around the proposed plant site has been considered as impact zone for EIA
study. Primary and secondary data has been collected for 10 Km radius of the project
site.
Mangalore town is located about 10 km south of the plant site. Eddap ally-Panvel
highway is passing along the western boundary of the plant. Sea coast is located about
2.0 km west of the plant site. Nearest settlement is Kulur located about 2.0 km southeast
of the project site. Nearest railway station is Thokur railway station which is located
about 4.0 km north in direction. Mangaluru Central Railway station is located about 10.0
km in south direction. Nearest Airport is Mangaluru International Airport located at 8.0
from the site in north east direction. Nearest city is Mangalore which is located about
10.0 km from the site in southeast direction. Gurpura River is passing about 1.0 km
southeast of the project site. Netravathi River is flowing at more than 10 km from site in
south direction. Panambur beach is located at about 3.0 km west of the site.
about 82% area fall in safe category and and 18% area falls
O Groundwater
in critical category
Silty loam sandy
Silty loam sandy
clay loam,
Silty loam clay loam,
Vegetation,
P Soil and Land-use Industrial,
industrial,
Industrial settlement and
settlement, water
mixed-use area
body ect.
3. Social Environment
Industrial, Rural &
S Physical Setting Industrial Mixed use
Urban
Physical Sensitive School, Hospitals, School, Hospitals,
T None
Receptors Temple etc. Temple etc.
Archaeological
U None None None
Monuments
Figure 3.1 Google Map showing Site & Surrounding Environmental Features within 10 km area
No. Of
Frequency
Parameters sampling Remark
/ season
locations
Ambient Air Quality
AAQ monitoring was carried out at
8 locations (representing upwind,
Twice a
downwind and sensitive locations).
PM10, PM2.5, SO2, NOx, 8 Week
24 hours sampling at each location
CO, NH3, HC, HF locations For winter
was carried out as per CPCB guide
season
lines (CPCB Gazette notification
dated 18.11.2009 on AAQ).
Meteorology
Temperature, Humidity, Hourly for Met station was established close
One
Wind speed, Direction, winter to the site to record the site-specific
location
Rainfall etc. season hourly met data.
Ground Water Quality
Ground water: Sampling was
conducted at 8 locations. Samples
8
Physical, chemical and were preserved, transported and
locations
biological parameters as per Once in a analyzed for different parameters
in study
IS 10,500 season based on APHA methods. Temp,
area
conductivity and pH which were
measured instantly at site itself.
Surface Water Quality
Surface Water: Sampling was
conducted at four locations.
3 Samples were preserved and
Physical, chemical and locations Once in a transported for analysis for different
biological parameters as per in study season parameters based on APHA
IS: 10,500 area methods. Temp, conductivity, DO
and pH which were measured
instantly at site itself.
Soil
No. Of
Frequency
Parameters sampling Remark
/ season
locations
Texture, bulk density, pH, 6
conductivity, cation locations Soil samples were collected at six
Once in a
exchange capacity, organic in study locations within the study area and
season
matter, Total N, P, K, and area analyzed as per IARI method
Heavy metals etc
Noise
8 Noise monitoring was conducted
locations within the 10-km area of project
Once in
Noise profiling for 24 hrs. in study site for noise profiling for 24 hrs
season
area using integrated sound level meter,
as per CPCB guidelines.
Ecology (Flora & Fauna)
Primary survey and Secondary
Flora & Fauna Once
sources
Demography & Socio-economics
Demography & Primary survey/ Secondary
- Once
Socioeconomic sources
Standard methods and procedures have been strictly adhered to during this study.
QA/QC procedures were strictly followed which covers all aspects of the study, and
includes sample collection, handling, laboratory analysis, data coding, statistical
analysis, presentation and communication of results. All analysis was carried out in
NABL/MoEF accredited/recognized laboratory.
3.4. Physical Environment
3.3.1 Topography
The topography of proposed site is almost plain. The site elevation ranges between 19
to 27 amsl. Topography around 10 km area of the proposed site is slightly undulating.
The average elevation in 10 km area around the site ranges between 0 to121 metres
above mean sea level. The eastern and south-eastern part of the study area is hilly.
Digital elevation map of the study area is provided in Figure3.4.
3.3.2 Drainage
The study area falls in Netravathi and Gurpura river basin. Drainage pattern of the study
area is mainly controlled by Gurpura River and Netravathi River. The Nethravati and
Gurupur rivers originate in the Western Ghats and flows towards the Arabian Sea. The
area is sloping towards sea coast and all the drainage of the study area is towards sea.
Drainage map of study area is presented in Figure 3.5.
The study area falls in Netravathi and Gurupura river basin. Gurupura river basin lies in
the south-western part of the Dharwar Craton i.e., coastal stretch of the Western
Dharwar Craton (Fig. 3.6). The coastal stretch and the adjacent Western Ghats are
composed of Precambrian (Archean) rocks and the Phanerozoic formations.
The study area falls in Mangluru block of Dakshina Kannada District. The depth to water
level in study area during pre-monsoon season varies from 2 m bgl to 10 m bgl and in
post monsoon season depth to water tableranges 0 m to 10 m. Depth to water table in
District is provided in Figure 3.7.
The site is located in the Karnataka Industrial Area Development Board notified
Baikampady/ Panambur industrial area, Mangalore, Dakshina Kannada (Mangalore
Industrial Cluster) for industrial land use. Most of the land within the 10-km area of the
project site is Water body and Vegetation/Plantation. As per the land use based on
satellite image, about 30% land in study area is under Vegetation\Plantation, about 39%
of land is under water body, about 21% land is under settlement, only 5% of the land is
under agricultural and rest of the land is under other uses (Refer Figure3.10 and Table
3.3).
1 The satellite Imagery of Indian Remote Sensing Satellite (IRS- ID, sensor P6, LISS III) of 24 m resolution was used. The Swath of the imagery is 141 Km x 141
Km. Band used are 4, 3, 2 and 5. LANDSAT imagery of 30 meter resolution and 185 x 185 km swath is also used for the comparative and overall analysis of the
area. LISS III imagery and LANDSAT 4-5 TM imagery were used for the complete coverage of the study area
Figure 3.10 Land Use Map of the Study Area (10 km Radial Zone)
3.5. Meteorology
Historical meteorological data was obtained from nearest IMD station located at district
headquarter Mangalore (Bajpe- A). The predominant wind direction is from east,
southeast and west. Details provided in Table 3.4.
Table 3.4 : Long Term Meteorological Data of Mangalore (30 years average)
Temperature– December, January and February constitutes winter months with daily
mean minimum temperature around 21.7°C and daily mean maximum temperature
around 32.0°C. Daily mean minimum temperature at 25.4°C.
Relative Humidity– The air is generally dry in the region except during monsoonDec,
2016 and Feb 2017 with relative humidity ranges between 74-70%. The maximum
humidity during rainy season is 90%.
Rainfall–The annual total rainfall is 3774.1 mm (for which year). Over 77% of the total
annual rainfall is received during the monsoon period between June to August.
Cloud Cover – In the study area, clear weather prevails in most of the time during post
monsoon, winter and summer seasons. Only during monsoon months of June July and
August moderate to heavy clouds are observed. Relevant details about the number of
days with zero octas of cloud cover (all clouds) for all months are presented in Table 3.5.
Table 3.5 : No. of days with zero octas of cloud cover (Mangalore)
Time Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec
08:30 1 3 3 1 0 0 0 0 0 0 1 1
17:30 5 7 5 1 1 0 0 0 0 0 1 2
(Source: IMD Mangalore)
Wind Speed– The mean wind speed ranges from 8.4 to 9.2 kmph during winter season,
8.3 to 8.6 kmph during monsoon and 8.9 to 9.8 kmph in pre-monsoon season.
Calm Periods– The calm period constitute an important factor in the dispersion of air
pollution. The calm period is more during 8:30 AM compared to 17:50 PM. The maximum
calm period occurs during October to February months. Monthly calm period values
obtained from nearest IMD is shown in Table 3.6.
Calm (%) Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec
08:30 0 3 3 5 6 7 6 6 4 4 1 1
Time
17:30 0 0 0 0 0 3 4 0 0 1 0 0
(Source: IMD Mangalore)
Special Weather Phenomena- The occurrence of thunderstorm is 12.2 days per year,
mostly spread across the months of May to September. Annual Dust Storm is 0 day.
Annually 0.8days have visibility less than 1 km, 22.7 days has visibility in the range of 1 -
4 km, 61 days have visibility in the range of 4 -10 km, 154.9 days between 10 - 20 km
and 125 days have visibility above 20 km. No dust storm or thunderstorm occurred during
the study period.
Met data for 1st December 2016 to 28th February 2017 month was generated at site. An
automatic weather monitoring station was installed near Project site, keeping the sensors
free exposed to the atmosphere and with minimum interference with the nearby
structures. The micro-meteorological data like wind speed, wind direction, temperature,
relative humidity and atmospheric pressure were collected using the weather stationed
cloud cover was recorded manually for the study period.
The wind directions, wind speed, temperature, rainfall and humidity recorded at site
during study period are presented in Table 3.7. Site specific wind rose diagram for study
period (Dec-16 to Feb-17) is presented in Figure3.13.
Relative Humidity –The maximum humidity during study period was 100 % and
minimum was 21 %. High humidity is found during daytime and low humidity values
during night time.
Wind Speed– The wind speed ranges between 0.5 to 4.5 m/s during study period except
calm conditions. Most of the time wind speed ranges between 1.5 to 3.5 m/s. Wind
frequency distribution during the study period is presented inFigure 3.12.
Wind Direction – The predominant wind direction at site is from E, SE and W direction.
Wind rose diagram is presented in Figure 3.13.
Calm Periods – Calm period is more during night time than day time. Percentage calm
periods during study period was 14.63%.
Direction wrt
S.No. Location Terrain Features Tentative Geo-coordinates
Plant site
AAQ-1 Project Site -- Flat terrain, industrial 12°56′11.11″N,74°49′27.36″E
Undulating, urban area,
AAQ-2 Lalbagh 5.6km,S located in cross wind 12°53′6.40″N,74°50′17.96″E
direction
Flat terrain, mixed use
AAQ-3 Kulur 2.0 km, SE area, located in upwind 12°55′30.77″N,74°49′49.40″E
wind direction
CO, HC (µg/m³)
mg/m3 HF
NH3 (µg/m³) None-
Location (1hrs Methane (µg/m³)
Location methane
Code Conc.)
98 Mean Mean Mean Mean
Min Max Mean
%tile Value Value Value Value
AAQ-1 Project Site 14.2 29.7 22.1 29.0 <0.1 <0.1 <0.1 <0.1
AAQ-2 Lalbagh 10.0 19.2 13.4 18.8 <0.1 <0.1 <0.1 <0.1
AAQ-3 Kulur 10.8 21.6 15.6 20.9 <0.1 <0.1 <0.1 <0.1
AAQ-4 Marakada 10.4 23.0 14.0 21.9 <0.1 <0.1 <0.1 <0.1
AAQ-5 Kodikal 9.2 21.2 13.6 20.8 <0.1 <0.1 <0.1 <0.1
AAQ-6 Kulai 10.0 24.4 17.5 23.7 <0.1 <0.1 <0.1 <0.1
AAQ-7 Purkodi 9.1 18.6 12.2 18.3 <0.1 <0.1 <0.1 <0.1
AAQ-8 Baikampady 11.5 27.4 19.2 26.8 <0.1 <0.1 <0.1 <0.1
NAAQ Standard: NH3 (400 g/m3), CO (4 mg/m3)
(Source: Primery Data Collection and analysis during study period by Laboratory)
conc. of all location ranges between 23-36 µg/m³. The PM2.5 level in all the monitoring
locations was found well within the National Ambient Air Quality Standards i.e. 60 µg/m³.
Oxides of Nitrogen (NOx): The highest NOx level was found at Baikampady (18.6
µg/m³) and lowest NOx level were observed at Purkodi village (8.3 µg/m³) while the mean
conc. of all location ranges between 11.0-16.0 µg/m³. The NOx level in all monitoring
location was found well within the National Ambient Air Quality Standards i.e. 80 µg/m³.
The monitored levels were compared against the Noise Pollution (Regulation and
Control) Rules 2000, as amended through the Noise Pollution (Regulation and Control)
Amendment Rules 2010 dated 11th January 2010. The project site falls in designated
industrial area and the noise levels at all the locations were found within the ambient
noise standards.
Figure 3.17 : Graphical representation of ambient Noise Level in the study area
The ambient noise quality of the study area is within the prescribed National Ambient
Noise Quality Standards prescribed for industrial (Standards - 75 dBA during day time
and 70 dBA during night time) residential area (Standards - 55 dBA during day time and
45 dBA during night time) and commercial area (Standards - 65 dBA during day time and
55 dBA during night time). However, the night time noise level (dB(A) Leq) at Eddapally-
Panvel Highway is slightly high than the Standards i.e.55 dBA due to vehicular
movement.
The name of sampling locations is presented in Table 3.12. The analysis results of
surface water and groundwater are presented in Table 3.13 and Table 3.14.
S.N. Parameters Project Lalbagh Kulur Markada Method Desired Limit /Permissible
site Limit
1 pH Value 6.91 7.23 6.87 7.10 APHA-4500 6.5-8.5/ No relaxation
2 Temperature 0C 25.0 25.3 25.2 25.1 Part 9 --
3 Conductivity, mhos/cm 152 140 302 244 APHA-4500 --
4 Turbidity (NTU) 0.26 0.38 0.46 0.30 APHA-2030B 1-5
5 Total Dissolved solids mg/l 93 88 196 143 APHA-2540B 500/2000
6 Total Suspended solids mg/l 0.6 0.8 0.9 0.4 APHA-2540D --
7 Total Hardness as CaCO3 50 32 84 56 APHA-2340C 200/600
mg/l
8 Chloride as Cl mg/l 18 17 42 46 APHA-4500B 250/1000
9 Total Alkalinity mg/l 56 50 92 74 Part -23 200/600
10 Sulphates as SO4 mg/l 02 02 15 04 APHA-4500E 200/400
11 Nitrates as NO3 mg/l 0.8 0.6 1.0 0.8 APHA-4500 45/No relaxation
12 Fluoride as F mg/l 0.14 0.11 0.16 0.24 APHA-4500D 1/1.5
13 Iron as Fe mg/l 0.22 0.30 0.38 0.25 APHA-3111B 0.3/No relaxation
14 Zinc as Zn mg/l <0.1 <0.1 <0.1 <0.1 APHA-3111B 5/15
15 Calcium as Ca mg/l 11 6 28 13 APHA-3500B 75/200
16 Magnesium as Mg mg/l 5.4 4.2 3.4 5.7 APHA-3500B 30/100
17 Sodium as Na mg/l 10 8 12 9 APHA-3500 --
18 Potassium as K mg/l 2.3 2.8 2.2 2.6 APHA-3500 --
KB
19 Cadmium as Cd mg/l <0.003 <0.003 <0.003 <0.003 APHA-3111B 0.003/No relaxation
20 Copper as Cu mg/l <0.02 <0.02 <0.02 <0.02 APHA-3111B 0.05/1.5
21 Nickel as Ni mg/l <0.01 <0.01 <0.01 <0.01 APHA-3111B 0.02/No relaxation
22 Lead as Pb mg/l <0.01 <0.01 <0.01 <0.01 APHA-3111B 0.01/No relaxation
23 Mercury as Hg mg/l <0.001 <0.001 <0.001 <0.001 APHA-3112 0.001/0.001
24 Chromium (Total as Cr) <0.05 <0.05 <0.05 <0.05 APHA-3111B 0.5/No relaxation
mg/l
25 Arsenic as As mg/l <0.01 <0.01 <0.01 <0.01 APHA-3114 0.01/0.05
Electric Conductivity levels vary from 132 to 302µmho/cm. Total dissolved solids range
from 84 to 196 mg/l which is within desirable limit.
The total hardness is an important parameter of water quality. The hardness values in
ground water of the study area ranges between 28 to 84 mg/l which is well within the
desirable limit. The calcium and magnesium values in ground water of the study area are
well within the specified desirable limit of Indian drinking water standard.
The chloride values in ground water of the study area ranges between 17 to 50 mg/l
which is well within the desirable limit.
No biological and metallic contamination has been found in any of the ground water
sample of the study area.
Overall the parameters in ground water sample were well within the desirable limit of
Indian Standard IS: 10500-2012.
The sea water quality parameters are compared with water quality standards for coastal
waters marine Outfalls (EPA Rule 1986). The sea water quality is complying with the
Class SW-II of coastal waters marine Outfalls (EPA Rule 1986) which suits for Contact
Water Sports and Commercial marine fishing.
3.9. Soil
Soils may be defined as a thin layer of earth's crust that serves as a natural medium for
the growth of plants. It is the unconsolidated mineral matter that has been subjected to
and influenced by genetic and environmental factors. Soils serve as a reservoir of
nutrients for plants and crops and provide mechanical anchorage and favorable tilts. Soil
is our most important natural resource and a natural resource is anything that comes from
the earth and is used by us. We depend on the soil for food, clothing, shelter, minerals,
clay & water. Soil is the seat of many macro & micro flora like algae, fungi, earthworms,
bacteria etc. These are very beneficial in promoting soil reactions and decomposing the
organic matter by which essential nutrients for plants are liberated. Most of the soils are
made-up of two main parts:
Tiny bits of mineral particles which come from larger rocks, and humus, which is dark
brown in color and consists of decaying remains of plants and animals.
Soil also contains water, air and living organisms, such as fungi, bacteria, earthworms,
roundworms, insects, etc. More living organisms live in the soil than above it.
For general characterization of soil a few random samples from the study area to the
depth of about 15-cm may be sufficient. Deeper soil samples may be needed only for the
study of soil profile.
The soil in the district is mostly lateritic type, found distributed in the Pedi plain area
characterized by high iron and aluminum content. Lateritic soil is mostly red in color and
yellow loamy, pale to bright red colors are also seen. Red lateritic soil is the most
dominant soil type in the area. Soil Map of Mangalore District in Karnataka is shown as
Figure3.19.
(Source-
http://maps.icrisat.org/gallery/RSGIS_gallery/GIS/Images/Soils/Karnataka_atlas/DKannada/DKannadaBoron.jpg
)
As per the satellite imagery in study area there is only 5 % of the land is under
agriculture. The common crops grown in the area are cash crops like coconut, mango
etc. the other crops grown in the study area are paddy and vegetable crops.
Soil sampling was conducted once during the study period of winter season. Six (06) soil
samples were collected from selected locations near the proposed project. For studying
soil quality in the study area, sampling locations were selected to assess the existing soil
conditions in and around the site area representing various land use conditions. The
samples collected from all the locations were homogeneous representatives of each
location. At random five sub-locations were identified at each location and soil samples
were collected from 5 to15-cm below the surface. It was uniformly mixed before
homogenizing the soil samples. The samples about 500-gms were packed in polythene
bags labelled in the field with location & number and sent to the laboratory for the
analysis of major physicochemical parameters. The homogenized samples were
analysed for physicochemical characteristics. Soil sampling locations with their distance
& directions with respect to the proposed project site are presented in Table: 3.17.
The soil samples were examined for various physicochemical parameters, to determine
the existing soil characteristics of the study area. Soil samples were collected from the
vicinity of project site. Physicochemical characteristics of soil are presented inTable: 3.18.
Suspension
9. Conductivity µmhos/cm 136.2 139.6 133.4 166.4 128.7
(EC) 145.5
10. CEC Meq/100gm 19.5 16.6 18.8 17.4 22.8 17.5
11. Organic %
0.66 0.69 0.72 0.48 0.55 0.62
Carbon
12. Organic Matter % 1.14 1.19 1.24 0.83 0.95 1.07
13. Chlorides as Cl mg/kg 46.8 34.7 45.6 55.8 35.3 44.5
14. Iron as Fe mg/kg 5.15 4.75 8.34 6.25 5.28 4.78
15. Copper as Cu mg/kg 8.2 6.9 7.5 6.5 9.2 10.8
16. Zinc as Zn mg/kg 11.5 16.2 14.8 21.6 18.4 14.6
17. Manganese as mg/kg 6.25 5.44 3.77 7.52 5.88 8.15
Mn
18. Boron as B mg/kg 0.62 0.85 0.98 0.74 1.82 1.55
19. Available Nutrients
i) Nitrogen as N kg/ha 265.6 298.2 374.8 285.4 365.4 288.5
ii) Phosphorus as kg/ha
16.1 14.5 15.8 15.2 16.6 12.5
P
iii) Potassium as kg/ha
148.6 106.2 135.8 112.4 159.4 164.6
K
(Source: JP Test House)
Physical Properties
Reddish colour soils are observed in the study area. Texturally the soils of study area are
observed as Silty Loam and Sandy Clay Loam Soils. The bulk density of the soils was
found in the range of 1.35 to 1.49-gm/cm3. Water holding capacity of the study area soil
was observed as 28.6 to 31.8%.
Chemical Properties
The soil pH ranges from 6.2 to 7.0, thereby indicating the soils are slightly acidic to
neutral. The Organic Carbon content of soil varied from 0.48 to 0.72 %( 0.83 to 1.24% as
Organic Matter) thereby implying that soils are low to medium in organic content.
Available nitrogen content in the surface soils ranges between 265.6 & 374.8-kg/ha,
thereby indicating that soils are low to medium in available nitrogen content. Available
phosphorus content ranges between 12.5 & 16.6-kg/ha, thereby indicating that soils are
medium in available phosphorus content. Available potassium content in these soils
ranges between 106.2 & 164.6-kg/ha, thereby is indicating that the soils are medium in
potassium content. The available manganese content in surface soils were recorded as
3.77 to 8.15-mg/kg, as the critical limit of available manganese is <2.0-mg/kg. As per the
critical limit of available zinc is <0.5-mg/kg, most of the study area soils are more than
sufficient in available zinc near the project. The available boron content in the soils
ranges from 0.62 to 1.82-mg/kg. The critical limit for deficiency of the available boron is
<0.5-mg/ kg. Based on the above physicochemical properties it is revealed that overall
moderate Soil fertility potential is observed in the study area.
Introduction
The study area (10 km area around the plant site) falls within Mangaluru Forest Division.
Mangalore Division was reorganized vide GO. No.AFD-80-FEG-66, Bangalore dated 13-
9-1966. Mangalore forest division at present consists of eight ranges, namely, Mangalore,
Bantwal, Belthangadi, Uppinangadi, Puttur, Sullia, Panja and Subramanya spread over 5
revenue taluks of Mangalore, Bantwal, Belthangadi, Puttur and Sullia. The division
comprises of three sub-divisions, namely, Mangalore, Puttur and Sullia. Forests account
for about 23 % of the total land area of the Maglore forest division. The forest types found
in the division vary from coastal scrub type to wet evergreen Ghat forests. They are
unevenly distributed, being mostly confined to a continuous stretch of area along the
western slopes of the ghats and being scarce in the densely populated areas towards the
coast. The productivity per hectare is very low which is inherent due to heterogeneous
character of these forests where only certain species are valuable.
Forest
The total area of notified forests in Mangalore division is 112816.01 hectares and these
are distributed in seven ranges. The range headquarters is at Hoiga Bazaar in
Mangalore. There are no notified forests in Mangalore range. The study area falls in this
range of the division. Various categories of forest in different range of Mangalore Forest
Division are given in Table 3.19.
Composition of Forest
The forests of the division exhibit rich diversity. Because of their distribution in widely
varying conditions of locality and many external factors of the ecosystem to which they
are subjected, the forest types of the division are diverse and complex. The present
vegetation is the result of inter-action of several contributing factors of varying intensities.
Variations in climatic, edaphic, topographic and biotic factors have led to variations in the
nature and growth of the vegetation.
The principal forest types of the area dealt in Mangalore Forest Division are
classified\according to the revised survey of the forest types of India by Sir Harry G.
Champion and Sri S.K. Seth are evergreen forest consists 0.5%, Semi evergreen forest
consists 54%, Moist deciduous forest consists 42%, and other forest 3.5%.
The study area falls in Mangalore range and there are no notified forests in Mangalore
range. The vegetation type mostly comprises of Lateritic scrub vegetation. This type of
vegetation is confined to the reserves towards the coast where the soil is dry, shallow and
lateritic due to denudation and exposure, although the climate is otherwise conducive to
growth of semi-evergreen or even evergreen species. The trees are of deciduous nature
and stunted growth, forming open scrub vegetation. The undergrowth is thin including
xerophytic evergreens.
Vegetation at proposed Plant site: The proposed expansion shall be done within the
existing plant premises of Mangalore Chemicals & Fertilizers limited. There is no national
park, wildlife sanctuary, biosphere reserve, reserved & protected Forests, notified forest
is present within the 10-km radius of the proposed plant site.
There is no forest present at proposed site. The identified land is open scrub land and
presently few trees are present in the proposed land. The vegetation type present on the
identified land is scrub vegetation along with Albizia lebback, Acacia auriculiformis and
cassia fistula plantation.
The study area comprises of open scrub, dense scrub, dense scrub hillocks, ravines,
rivulets/river system, flat terrain and sea coast/beach. The natural vegetation of ever
green/decidua’s forest species in the form of dense scrub, open scrub degraded
vegetation in the hilly area are observed along with rural agriculture, semi- urban and
industrial development towards the coast. Accordingly, the survey was planned based on
Topography, land use, vegetation pattern etc.
The natural vegetation of the area may be broadly noted under two types: the hilly
vegetation and river bed vegetation, apart from roadside and avenue trees. Observations
on the Trees, Shrubs, Herbs, climbers, grasses, agricultural fields, medicinal plants, and
social plantations were made for the study area considered. The vegetation cover falls
into following broad categories:
Natural vegetation
Greenbelt Plantation
Agriculture Fields / commercial plantation
Pilikula Nisarga Dhama (Biological Park)
Mangroves
Aquatic flora
Acacia Auriculiformis
Doc No.: EIA
Energy improvement project of Ammonia and Urea plant, 1 million Rev No. 0
t/y DAP/NPK project, Poly Carboxyl Ether project at Mangalore,
Karnataka Issue Date: 20.08.2017
Page 107 of 238
siamea etc. were observed. Shrubs like Lantana camara, Jatropha curas, Annona
squamosa, Alangium salvifolium, Hibiscus cannabinus and Sesbania grandiflora are
found densely in this region. Herbs like Mimosa pudica was found maximum, while
Datura metal and Evolvulus alsinoides were moderately seen.
A significant Biological Park is established in Pilikula Nisarga Dhama Society has major
focus on the wildlife species of Western Ghats and it has now become the hot spot for
people who are looking for scenic beauty & peace. The park is named as Dr. Shivaram
Karanth Biological Park. The park consists of an area of 380 Acre land. In accordance
with prevailing laws, the central Zoo Authority of India has recognized the park. As per
modern Zoological practices, the animal enclosures have been designed to closely
resemble its natural habitat. The park has now become the hot spot for people who are
looking for scenic beauty & peace.
Pilikula has a huge lake & beautifully laid gardens encircling the entire lake. One can see
swans & ducks moving around in the lake & sometimes they even move into the gardens.
Boating facilities are available in the lake. One can either use pedaling boats (mostly
preferred by couples) or bigger boats carry about 10 to 15 persons.
Pilikula Zoo has been classified as a Major Zoo by the Central Zoo Authority of India. It is
the only zoo recognized as a breeding centre for King Cobras. It is also functioning as a
rescue centre for wounded wild life. Today Pilikula Zoo has 400 animals, reptiles and
birds and most of the species are breeding.
An arboretum (a garden comprising woody species of plants, i.e. trees and shrubs)
extending over an area of 35 ha has been established at Pilikula Nisarga Dhama where
about 60,000seedlings belonging to 236 taxa of flowering plants of Western Ghats,
spread over 60 families have been planted randomly as well as family clusters. They
include 70 taxa endemic to the Western Ghats region. The arboretum has a focus on the
conservation of the plants of the Western Ghats. It not only contains manythreatened
species, but also a few Re-discovered species that were extinct earlier. The arboretum
also includes 6 acres devoted to medicinal plants with more than 460 varieties, often
visited by students of botany and Ayurvedic medicine. 9 aquatic Ponds containing aquatic
plants like Lotus, Lilies etc. are seen here.
Aquatic flora: Aquatic plants are plants that have adapted to living in aquatic
environments (saltwater or freshwater). They are also referred to as hydrophytes or
macrophytes. These plants require special adaptations for living submerged in water, or
at the water's surface. The common aquatic plants observed in the study area are
Nelumbo nucifera, Nymphaea stellata, Cyperus rotundus, Nymphoides hydrophylla,
Colocasia esculenta, Azolla pinnata, Pistia stratiotes, Eichhornia crassipes and Salvania
molesta. The list of the vegetation observed/ reported in the study area is presented in
Table 3.20.
Table 3.20 : List of the vegetation observed/ reported in the study area
Faunal Biodiversity
Most of the land around the study area (10 km radius around the proposed Plant site) is
under settlement, industrial, agriculture, and vegetation uses. No national parks, wild life
sanctuary, biosphere reserve, Reserve, Protected and any other notified forests forest is
present within 10 km area of the project site. Speedy industrial development and
urbanization has left the area devoid of any significant faunal species or wildlife. During
the preliminary survey, the sighting of wild animals was negligible in the entire study area.
The assessment of wild life fauna has been carried out based on information collected
from the secondary sources (Forest Officer, Fisheries Department, and local inhabitants).
List of fauna found in the study area is presented in Table 3.21 & 3.22. The listed fauna
has been cross-checked with Red Data Book of Indian Animals (Zoological Survey of
India). There is no endangered or critical faunal species in the study area.
Mammals: No significant carnivorous and herbivorous wild animals are found in the area.
Amphibian & Reptiles: Frog, Indian bull frog, snake like Indian cobra (Naja naja); Krait
(Bungarus coeruleus), and lizard are encountered at various places in study area.
Feeding Schedule
Common Name Scientific Name
Status
1. Striped s squirrel Funambulus pennanti H IV
2. Field rat Bandicota bangalonsis H V
3. Jungle cat Felis chaus C II
4. Mongoose Herpestes edwardsi C IV
5. Bat Cyanopterus gigenticus C -
H – Herbivorous, C – Carnivorous, O – Omnivorous
Avifaunal Investigation
Avifauna is an important part of the ecosystem playing the various roles as scavengers,
pollinators, predators of insect, pest, etc. They are also one of the bio indicators of
different status of environment and affected by urbanization, industrialization and human
interference. They can be used as sensitive indicators of pollution and malfunction of
ecosystem.
There is a wide range of avifauna observed in the study area. The study area is inhabited
by forty-four species of birds belonging to 19 families. The list of avifauna observed in the
study area is given in Table 3.23.
Table 3.23 : List of the Birds Surveyed / Recorded in the Study Area
Motacilla
Woodlands,
28 Large pied Wagtail maderaspatansis Motacillidae R
plantation
House Sparrow Passer Human
29 Passeridae R
domesticus settlement
Ploceus Paddy field,
30 Baya Weaver Ploceidae R
philippinus cultivations
Paddy fiels,
Common Myna Acridotheres
31 human Sittidae R
tristis
settlements
human
32 Black Kite Milvus Migrans Accipitridae R
settlements
Brahminy kite Sturnus Streams, sea
33 Sturnidae R
pagodarum coast
Falco Grassland, open
34 Common Kestrel Falconidea M
tinnunculus area
Charadrius
35 Little ringed Plover Dry open areas Charadridae R
dubilus
Turdoides
36 Common Babbler Scrub jungle Leiothrichidae R
caudatus
Turdoides Plantation scrub
37 Jungle Babbler Leiothrichidae R
striatus jungle
Phylloscopus Plantation scrub
38 Greenish Babbler Leiothrichidae R
trochiloides jungle
Megalaima
39 Brown headed barbet Gardens, forest Megalaimidae R
zeylanica
Megalaima widespread
40 Coppersmith Barbet Megalaimidae R
haemacephala resident
Psittacula Paddy fields,
41 Alexandrine Parakeet Psittacidae R
eupatria cultivation
Psittacula Paddy fields,
42 Rose-ringed Parakeet Psittacidae R
krameri cultivation
Plum Headed Psittacula Paddy fields,
43 Psittacidae R
Parakeet cyanocephala cultivation
Spotted Owlet Human
44 Athene brama Strigidae R
settlement
Woodland,
45 Hoopoe Upupa epops Upupidae R
grasslands
Gardens, parks,
46 Red vented Bulbul Pycronotus cafer Pycnonotidae R
plantation
Pycronotus Gardens, parks,
47 Red whiskered Bulbul Pycnonotidae R
jocosus plantation
Marshes,
Grey-breasted Prinia Prinia hodgsonii Cisticolidae
48 grasslands R
Lonchura Cultivations,
Black-headed Munia
49 malacca grasslands, Passeridae R
gardens
There are 63 ice plants, 19 freezing plants and 10 cold storages in the district. The district
has a fishermen population of 58,218. Out of which 27,597 are active fishermen. The
district ranks at 3rd place in the State in terms of active fishermen. There are 103 fish
market in the district and all are departmental. Apart from the above there are 23 fishing
co-operative societies in the district. From the point of view of developments, the state
government has introduced various welfare schemes such as saving cum relief scheme,
group accident insurance for the active fishermen, development of model villages for
fishermen, establishment of district relief fund with a view to improve the socio-economic
condition of the fishermen. Shoaling fishes like sardines and mackerel’s, tuna, seer
fishes, lacarius, pomfrets, silver bellies, scianids sharks, cat fishes etc. are commonly
fished out.
There are fresh water fishes also found in the study are mainly Minnow (Barilius barila),
Common carp (Cyprinus carpio), Sucker head (Garra gotyla), South Indian barb (Esomus
barbatus), Ticto barb (Puntius ticto), Glass fish (Ambassis ambassis), Tilapia
(Oreochromis mossambicus) and Guppy (Poecilia reticulata).
Fisheries constitute the major economic and characteristic feature of the district. The
district is known for marine fishing and the export of fish and fish products. Though
Dakshina Kannada does not rank amongst the industrially advanced districts of the State,
manufacturing industry makes a significant contribution to the economy of the district.
Agriculture is also an important livelihood for the people of Dakshina Kannada besides
fishing. Paddy is the principal agricultural crop of the district. Sugarcane is confined to the
coastal taluk’s. Cashew nut, areca nut, pepper, cloves and coconut are the important
cash crops in the district. It is in fact, renowned to produce tiles, beedis and cashew
besides chemical and fertilizers. The most important industry of the district is the
Mangalore Refineries and Petrochemicals Limited, popularly known as MRPL. Another
important industry of the district is cashew industry.
As per the district census Handbook, 2011, the total population of the district is observed
as 20, 89,649 persons. Male-female wise population was observed as 10, 34,714 and 10,
54,935 persons respectively. The population of the district is further distributed as 10,
93,563 living in rural areas and 9,96,086 in urban areas, constituting 52.3 & 47.7% of
rural and urban population respectively. The population in the age-group of 0-6 years is
reported as 2, 08,297. This constitutes as 53.3% in rural areas and 46.7% in urban areas.
The proportion of child population is 9.97% to the total population of the district. Dakshina
Kannada district was recorded growth rate as 10.1% during the decade 2001-11. The
decadal growth rate in rural areas is decreased by 6.4%. The decadal growth rate in
urban areas is recorded as 36.9%. As such, the population density recorded as per the
Census records 2011, is 430 persons per sq.km. As per the Census records 2011, the
sex ratio of the district is recorded as 1020 females for every 1000 males. The literacy
rate for Dakshina Kannada district is 88.8% in 2011 as against 83.4% in 2001. Total
Scheduled Castes (SCs) population reported in the district is 1, 48,178 persons,
constituting about 7.1% to the total population of the district. The decadal growth rate of
Scheduled Castes as per the Census records 2011 is observed as 12.97%. The growth
rate of Scheduled Tribes (STs) during the decade 2001-11 is observed as 30.7% and
about 3.9% of the district’s total population is Scheduled Tribes. The decadal change in
the growth rate of SCs and STs in urban areas has reported to be high compared to the
growth rate in rural areas. (Source-District Census Handbook 2011)
Methodology
To assess the Demographic & Socio-economic features of the 10-km radius study area
based on Socio-economic surveys and public consultations undertaken during the
baseline field study period and Census records 2011, for the concerned district Dakshin
Kannada in Karnataka State was compiled and placed in the form of tabulation and
graphical representation. Entire study area is predominantly urban except few revenue
villages. About 45% part of the study area is occupied by Arabian Sea in Westwards.
There are about ten (10) numbers of census towns, one major city (Mangalore city) and
28 villages fall within the study area. As per the census records 2011, the total population
of the study area were recorded as 595733 persons comprise 296554 males and 299179
females. Total number of ‘Households’ was observed as 135462 in the 10-km radius
study area. Caste-wise population distribution of the entire study area is shown in Table
3.24.
Sex Ratio
The ‘Sex Ratio’ of the study area is a numeric relationship between females and males of
an area and bears paramount importance in the present-day scenario where the un-
ethnic pre-determination of sex and killing of female foetus during pregnancy is practiced
by unscrupulous medical practitioners against the rule of the law of the country. It is
evident that by contrast the practice of female foeticide is not prevalent in the study area.
As per the census records 2011, the entire study area is falling in Dakshin Kannada
district of Karnataka. The ‘Sex Ratio’ was observed as 1020 females per 1000 males in
the District. The same was recorded as 1009 females for every 1000 males in the study
area. The child sex ratio of the district was observed as 944 female children per 1000
male children. The village wise male-female population distribution for the study area and
Mangalore (MC+OG) is depicted and shown by graphical representation in Figure3.21.
600000
500000
400000
300000
200000
100000
0
Total Population Male Population Female Population
500000
400000
300000
200000
100000
0
Total Population Male Population Female Population
Based on the village/town wise SC & ST population distribution of the study area during
2011, the ‘Scheduled Castes’ population was observed as 27458 persons consisting of
13492 males and 13966 females respectively in the study area which accounts as 4.6%
to the total population (595733 persons) of the study area. ‘Scheduled Tribes’ population
was observed as 9768 persons, accounting as 1.6% to the total population of the study
area consisting of 4914 males and 4854 females. It implies that the rest 93.8% of the total
population belongs to the General category. Male-female wise distribution of ‘SC’ &‘ST’
population in the study area is graphically shown in Figure3.22& 3.23 as follows.
Total SC Population
30000
25000
20000
15000
10000
5000
0
Total SC Population Male SC Population Female SC Population
Total SC Population
Total ST Population
10000
8000
6000
4000
2000
0
Total ST Population Male ST Population Female ST Population
Total ST Population
population was recorded as 93010 persons (15.6%) in the study area. Male-Female wise
illiterates were 39778 (6.7%) and 53232 (8.9%) respectively. The Male-Female wise
graphical representation of literates & illiterate’s population in study area villages/town is
shown inFigure3.24.
6,00,000
5,00,000
4,00,000
3,00,000
2,00,000
1,00,000
0
Total Literates Male Literates Female Total Male Female
Literates Illiterates Illiterates Illiterates
Literates Illiterates
Name of Village Total Population Person Males Female Person Male Female
Kulur 778 649 326 323 129 43 86
Madya 1624 1320 672 648 304 130 174
Chelliru (OG) 3278 2771 1362 1409 507 194 313
Panja 418 314 162 152 104 46 58
Surinje 3098 2524 1295 1229 574 269 305
Kilenjur 658 548 270 278 110 35 75
Delanthabettu 1464 1177 603 574 287 99 188
Tenkayekkar 3445 2695 1341 1354 750 319 431
Permude 2242 1812 946 866 430 171 259
Hosabettu 2260 1876 942 934 384 153 231
Kuthethur (OG) 3791 3065 1758 1307 726 331 395
Bala (OG) 2637 2137 1100 1037 500 224 276
Kavathar 1529 1187 603 584 342 121 221
Attur 1478 1192 599 593 286 111 175
Nadugodu 1454 1156 594 562 298 100 198
Boliyar 5753 4272 2261 2011 1481 593 888
Kolambe (CT) 5592 4480 2322 2158 1112 439 673
Kenjar (CT) 5338 4150 2261 1889 1188 457 731
Thokur-62 (CT) 7433 6017 3409 2608 1416 665 751
Economic Structure
Most people in rural sector are cultivators & agricultural labors which indicates dominant
agricultural economy. A small section of people is engaged as workers in household
industries. But in urban sector the existing scenario is completely reversed as most of the
people there are engaged in non-agricultural activity especially in local hotels/restaurants
and as drivers some people also operates their vans/jeeps/cars as tourist vehicle.
Annual income helps in identifying families below poverty line. During the field survey,
income of a household through all possible sources was recorded. Agriculture and allied
activities was reported to be the major source of income followed by non-farm wage
labor, business, Government and Private Service etc. The other important sources of
income include government pension and income from selling of fodder.
Workers Scenario
Occupational Pattern’ was studied to assess the skills of people in the study area.
Occupational pattern helps in identifying major economic activities of the area. The main
and marginal workers population with further classification as casual, agricultural,
households and other workers is shown in Table 3.26.In the study area, the Main and
Marginal Workers population was observed as 236519 (39.7%) and 19053 (3.2%)
respectively of the total population (595733) while the remaining 340161 (57.1%) persons
were recorded as non-workers. Thus, it implies that the semi-skilled and non-skilled work-
force required in study area for the project is available in aplenty.
Main
Workers
Non- 39.7%
Workers
57.1%
Marginal
Workers
3.2%
MAIN MAIN_CL MAIN_AL MAIN_HH MAIN_OT MARG MARG_CL MARG_AL MARG_HH MARG_OT
Name of the Village WORK_P _P _P _P _P WORK_P _P _P _P _P
Kulur 349 77 17 104 151 66 1 1 4 60
Madya 619 42 3 177 397 193 1 4 41 147
Chelliru (OG) 1478 82 67 356 973 177 1 13 6 157
Panja 185 48 23 36 78 42 0 2 0 40
Surinje 1105 56 6 230 813 205 2 7 9 187
Kilenjur 320 37 0 135 148 13 1 0 0 12
Delanthabettu 825 100 49 269 407 28 0 3 2 23
Tenkayekkar 1047 70 28 250 699 460 6 78 131 245
Permude 921 122 22 124 653 31 2 8 5 16
Hosabettu 909 95 45 123 646 128 4 0 81 43
Kuthethur (OG) 1842 88 24 283 1447 201 1 23 28 149
Bala (OG) 1022 0 2 64 956 8 2 0 0 6
Kavathar 751 74 99 173 405 121 6 42 24 49
Attur 739 30 18 195 496 13 0 0 2 11
Nadugodu 721 86 26 207 402 9 0 2 0 7
Boliyar 2655 87 108 993 1467 321 6 44 179 92
Kolambe (CT) 2319 67 42 502 1708 334 23 41 39 231
Kenjar (CT) 2417 95 50 462 1810 259 13 9 23 214
Thokur-62 (CT) 3015 12 12 126 2865 325 8 4 15 298
Bajpe (CT) 3964 38 37 327 3562 311 8 14 15 274
Kandavara 1519 64 9 428 1018 72 7 20 10 35
Adyapady 1081 89 22 349 621 29 6 6 1 16
Malavoor 1441 57 60 227 1097 320 8 18 96 198
Mudushedde (CT) 4090 38 54 812 3186 360 0 9 45 306
Mangalore (MC+
OG) 193772 1067 863 11419 180423 14738 221 271 1368 12878
Alike 2233 294 395 438 1106 62 17 3 4 38
Navoor (CT) 2816 129 98 1076 1513 36 0 5 6 25
Bandaru 2364 200 12 743 1409 191 3 1 22 165
TOTAL 236519 3244 2191 20628 210456 19053 347 628 2156 15922
Source-Census Records 2011
The ‘Main Workers’ were observed as 236519 persons (39.7%) to the total population of
the study area and its composition is made-up of Casual laborers as 3244 (1.4%),
Agricultural laborers as 2191 (0.9%), Household workers 20628 (8.7%) and other workers
as 210456 (89.0%) respectively. Composition of Main workers is shown below
asFigure3.26.
MAIN_OT_P
89.0%
MARG_OT_P
83.6%
The total Non-workers population was observed as 340161 which constitute 57.1% to the
total population (595733) of the study area. Male-female wise Non-workers population
was recorded as 122957 Males (36.1%) and 217204 Females (63.9%) respectively.
Details about total Non-workers of the study area with Graphical representation are
tabulated belowand shown in Figure 3.28.
Non-Workers Population
400000
300000
200000
100000
0
Total Non-Workers Male Non-Workers Female Non-
Workers
Non-Workers Population
A review of Basic infrastructure facilities (Amenities) available in the study area has been
done based on the Field survey and Census records, 2011 for the study area inhabited
revenue villages of mainly Three (03) tehsils namely Mangalore, Bantval and Beltangadi
of Dakshin Kannada District in Karnataka. The study area has good level of basic
infrastructure facilities like educational, medical, potable water, power supply, and
transport & communication network. Entire study area is predominantly urban except few
revenue villages.
Education Facilities
As per the Census Records of India 2011, there are a total twenty-eight (28) revenue
villages/towns of Dakshin Kannada District in Karnataka. All the revenue villages/towns
are mainly under three (03) tehsils namely Mangalore, Bantval and Beltangadi of Dakshin
Kannada District in Karnataka. There are about twenty-seven (27) Primary Schools
existing in the rural part/revenue villages of the study area. Middle schools are thirteen
(13 no’s) in the rural part of the study area. Only seven (07 no’s) Higher Secondary
Schools are available in the rural part of the study area. Senior Secondary School facility
is not available in the rural part of the study area. The educational facilities have been
further strengthening now and many private public schools and colleges are also
functioning in the surroundings of the study area. Besides, there are Engineering and
Medical colleges available in Towns and District headquarters only. Higher education
facilities are available in Towns of the area. There is considerable improvement in
educational facility. The villages/towns of the study area have no such facilities can reach
within 5.0 to 10.0-km range. Majority of the villages are little far from their nearest town.
More than 99% of villages of the district have education facility, transport and
communication.
Medical Facilities
The medical facilities are provided by different agencies like Govt. & Private individuals
and voluntary organizations in the study area. As per the district census handbook
information of 2011, Two (02) primary health center / PHC exists in the study area; most
of the study area villages depend upon the towns / district HQ of the study area having
such facility. Fourteen (14) Primary Health Sub-centers /PHSC are exists in the rural part
of the study area. Mother &Child Welfare Centre / MCWC are available in Attur and
Boliyar village of the study area. Family welfare centre (FWC) exists in fourteen (14)
villages of the study area. Overall study area villages are served by good medical
facilities. Specialized medical facilities are available in towns and District Headquarter
(HQ) only.
Potable water facility is available in most of the villages/towns of the study area. The
entire study area has plenty of good potable water facilities. Most of the villages (about
100%) having Hand Pumps (HP) as potable water facility. Out of total twenty-eight (28)
revenue villages/towns eleven (11) villages (39.3%) are served with River/Canal water in
the study area. As per the census records of 2011, about Six (6) villages (21.4%) are
being served with Tank/Pond/Lake in the study area. In most of the villages, hand pumps
are commonly observed in the study area. Good potable water facilities are available in
the study area.
Apart from Post &Telegraph (P & T) services, transport is the main communication
linkage in the study area. About five (05) villages (17.9%) out of twenty-eight (28) are
served with Post Office facilities in the study area, remaining villages are depending upon
these five (05) villages and towns of the study area. The study area has average rail and
road network, passes from the area. Two (02) villages named Madya and Delanthabettu
itself are served with railway station facility in the study area and remaining villages
depend upon these villages/towns with this facility. Nearest town/city is Mangalore (MC)
at about 10.0-km away from the project site. Bajpe Airport is about 10-kms away from the
proposed site in East direction. Most of the villages are served with Pucca road facility in
the study area. The villages in the study area which do not have such facility can reach
within 5 to 10-km range. Mainly five (05) towns named Mulki (TP), Mangalore (MC),
Mudbidri (TMC), Bantval (TMC) and Beltangady (TP) are available within the distance
range of 5 to 26-kms from the villages of the study area. Approach by pucca road facility
is available to 100% of villages of the district. Post office facility is available for 81.6% of
villages in the district. The study area has almost all the schedule commercial banks with
ATM facility at urban areas and the district HQ. Majority of the villages have banking
facility at a distance of 5-10 km.
Power Supply
It is revealed from the compiled information on Amenities availability as per the census
record of 2011; most of the villages and towns (about 100%) are electrified for all purpose
in the study area. Village/town wise ‘Basic Amenities’ availability data for the entire study
area is compiled and presented in Table 3.29.
Village/town wise ‘Basic Amenities’ availability data for the entire study area is compiled
and presented in Table 3.29.
Village Name Educational Medical Drinking Water P&T Communication Approach to Power Nearest Town &
Village Supply Distance, km
P M SS PHC PHSC MCWC FWC T W HP TW R Tk PO Tele. Mob. BS RS PR KR FP EA
Kulur 1 0 0 0 1 0 1 1 2 1 1 2 2 2 1 1 1 2 1 1 1 1 Mulki ,5.0km
Madya 1 1 1 0 1 0 1 1 2 1 1 1 1 2 1 1 1 1 1 1 1 1 Mangalore, 25.0km
Chelliru (O.G) Urban Part
Panja 1 0 0 0 0 0 0 2 2 1 1 1 1 2 1 1 2 2 1 1 1 1 Mulki, 16.0km
Surinje 1 1 1 0 1 0 1 2 2 1 1 1 2 2 1 1 1 2 1 1 1 1 Mangalore, 15.0km
Kilenjur 1 1 0 0 0 0 0 2 2 1 1 2 1 2 1 2 2 2 1 1 1 1 Mulki, 9.0km
Delanthabettu 1 0 0 0 1 0 1 2 2 1 1 1 2 2 1 1 1 1 1 1 1 1 Mangalore, 17.0km
Tenkayekkar 2 1 0 0 1 0 1 2 2 1 1 1 1 2 1 1 2 2 1 1 1 1 Mulki, 13.0km
Permude 2 1 0 0 1 0 1 2 2 1 1 2 2 1 1 1 1 2 1 1 1 1 Mulki, 15.0km
Hosabettu 2 0 1 0 2 0 2 2 2 1 1 2 2 1 1 1 2 2 1 1 1 1 Mudbidri, 10.0km
Kuthethur (OG) Urban Part
Bala (OG) Urban Part
Kavathar 1 0 0 0 1 0 1 1 2 1 1 2 1 2 1 1 1 2 1 1 1 1 Mulki, 4.0km
Attur 1 1 1 1 0 1 0 2 2 1 1 1 2 2 1 1 2 2 1 1 1 1 Mulki, 16.0km
Nadugodu 1 1 1 0 0 0 0 2 2 1 1 1 2 2 1 1 1 2 1 1 1 1 Mulki, 9.0km
Boliyar 3 2 0 1 0 1 0 2 1 1 1 1 2 1 1 1 1 2 1 1 1 1 Bantval, 12.0km
Kolambe (CT) Urban Part
Kenjar (CT) Urban Part
Thokur-62 (CT) Urban Part
Bajpe (CT) Urban Part
Kandavara 2 0 0 0 2 0 2 1 1 1 1 1 2 1 1 1 1 2 1 1 1 1 Mudbidri, 20.0km
Adyapady 1 1 1 0 1 0 1 2 2 1 1 1 1 2 1 1 1 2 1 1 1 1 Mudbidri, 24.0km
Malavoor 2 2 0 0 1 0 1 1 1 1 1 2 2 2 1 1 2 2 1 1 1 1 Mangalore, 6.0km
Mudushedde (CT) Urban Part
Mangaluru (MC & OG) Urban Part
Aliake Urban Part
Navoor (CT) Urban Part
Bandaru 4 3 1 0 1 0 1 2 2 1 1 1 2 1 1 1 1 2 1 1 1 1 Beltangady,26.0km
TOTAL 27 13 7 2 14 2 14 Status for Availability and Non-Availability is shown as A (1) & NA (2) respectively
Source-http://www.censusindia.gov.in/2011census/dchb/DCHB.html
Panambur Beach (Mangalore Taluk): is a good picnic spot and holiday resort in the
vicinity. The Panambur New Mangalore Port is also located at about 10-km away from
Mangalore and this is an “All Weather Port.”
Someshwara Beach (Mangalore Taluk):This Beach is a good picnic spot and moreover
beautiful sunset view can be seen from this beach. Fishing is another attraction in this
beach. Somanatheshwara temple near the beach is another religious center.
Gorakhnath Temple Kudroli (Mangalore Taluk): This Temple is situated at 3.0-km from
the heart of the city Hampanakatta, and dedicated to Lord Shiva. This temple was
constructed by Sri Narayana Guru in 1912 AD.
St. Aloysius Church Chapel & Museum (Mangalore Taluk): This Church was
constructed in 1885 A.D. by Rev. Fr. Joseph Willy. It has a marvelous gallery of painting
done by Br. Anthony Moschemi from 1902-1904 A.D.
St. Milegris Church (Mangalore Taluk): This Church was established in 1834 A.D., is
one of the Christian momentums of the city.
St. Rosario Cathedral (Mangalore Taluk): Situated 1.0-km away from the heart of city
Hampanakatta, the dome of the St. Rosario Cathedral built in 1910 A.D. is said to have
been modeled on St. Peter’s Basilica in Rome.
Sultaan Bathery (Mangalore Taluk): This fort situated at Boloor, 4.0-km away from the
heart of city Hampanakatta. Sulthan Bathery a watch tower, built by rough blocks of
laterite, in the last remaining bastion of Tippu Sultan’s fort built by him to block the entry
of British warships through the Gurpur river.
Light House Hill Idgah (Mangalore Taluk): This Idgah was built by Tippu Sultan.
Village:Baikampady
Time (Hrs.) Two wheelers Three and Four wheelers Light vehcals Bus Heavy vehicals Total
6:00 128 119 38 95 134 514
7:00 206 242 55 166 178 847
8:00 344 308 68 235 208 1163
9:00 370 441 104 311 312 1538
10:00 428 516 132 188 206 1470
11:00 526 318 95 202 286 1427
12:00 432 241 145 84 335 1237
13:00 678 405 98 150 405 1736
14:00 616 510 164 126 258 1674
15:00 348 424 202 98 219 1291
16:00 306 491 142 182 242 1363
17:00 512 602 106 209 145 1574
18:00 488 505 167 194 130 1484
19:00 519 782 226 155 126 1808
20:00 441 530 153 232 170 1526
21:00 278 416 87 164 95 1040
22:00 226 304 72 104 175 881
23:00 147 218 119 95 195 774
0:00 68 105 144 66 164 547
1:00 25 78 59 46 128 336
2:00 31 46 15 34 70 196
3:00 16 30 34 18 45 143
4:00 56 82 48 54 75 315
5:00 144 155 84 105 112 600
Total 7333 7868 2557 3313 4413 25484
Name of the Location: NH-66 (Near MCF Gate)
Direction of Monitoring: Suratkal to Mangalore
Date of Monitoring: 22.02.2017
Road width: 15 meters
Road Lane: 4
Time (Hrs.) Two wheelers Three and Four wheelers Light vehicles Bus Heavy vehicles Total
6:00 110 148 30 122 142 552
7:00 134 206 50 172 190 752
8:00 322 345 93 188 228 1176
9:00 409 457 121 318 344 1649
10:00 500 258 135 260 207 1360
11:00 408 504 155 186 311 1564
12:00 336 378 117 172 344 1347
13:00 502 425 176 140 406 1649
14:00 399 406 145 108 253 1311
15:00 531 328 80 124 234 1297
16:00 408 540 73 246 244 1511
17:00 381 515 127 144 161 1328
18:00 492 416 140 75 160 1283
This chapter provides the study of impacts which are likely to be caused by the proposed
project and their suggested mitigation measures. To study the intensity of impacts on
environment during operation phase modeling process was carried out at the proposed
project site.
4.1. Introduction
One of the important elements of EIA study is the identification of impacts, as it helps in
quantification and evaluation of impacts. Although, in general, a number of impacts have
been identified while describing the baseline environmental status, it is necessary at this
stage to identify the critical impacts positive/negative on various components of the
environment that are likely due to installation of proposed fertilizer plant.
Generally, the environmental impacts can be categorized as either primary or secondary.
Primary impacts are attributed directly to project activities whereas secondary impacts
are indirectly induced and typically include the associated investment and changed
patterns of social and economic activities due to the proposed project activities.
The construction and operational phase of the proposed expansion project at MCF;
Mangalore, Karnataka comprises various activities, each of which may have either
positive or negative impact on some or other environmental attributes.
The proposed project activities would impart impact on the environment in two distinct
phases:
During construction phase which may be regarded as temporary or short term and
reversible effect; and
During operational phase which may have long term effects.
The evaluation of environmental impacts due to installation of main plants namely
Ammonia and Urea within a radius of 10 km around the MCF; Mangalore, Karnataka
fertilizer complex and the mitigation measures are as under:
Noise Environment
Water Environment
Solid Waste Generation
Terrestrial & Aquatic Ecology
The impact of the proposed activities on each of the above environmental components is
discussed in following paragraphs.
compliant. In case of dust emission in the command area of the factory, shall be
controlled by sprinkling water with or without chemicals / de-dusting agent.
It is, therefore, concluded that the proposed facilities shall have a little impact on land
environment, during construction & operation phase which shall remain well within the
buffering limit of the environment.
emissions will be within the project area, the effect of emissions from the point sources is
a major concern as it will have impact on the ambient air quality in the surrounding area.
An atmospheric dispersion modeling and the prediction of ground level pollutant
concentration has great relevance in estimating the impact of these pollutants.
The prescribed emission norms nevertheless assessment of ground level concentrations
(GLC) of the possible pollutants is carried out for control purposes. The significant point
sources that contribute to the air pollution incidence from the proposed plant are provided
below in Table. 4.1.
Air Dispersion Modeling Methodology (Modeling Approach)
The assessment methodology for the air dispersion modelling exercise follows the
guidance specified in the United States Environmental Protection Agency (USEPA). The
detailed model recommended for air dispersion modelling in the ambient air is AERMOD.
The model of selection was the commercially available AERMOD View dispersion model,
developed by Lakes Environmental. This model is used extensively to assess pollution
concentration and deposition from a wide variety of sources. AERMOD View is a true,
native Microsoft Windows application and runs in Windows applications. The AMS/EPA
Regulatory Model (AERMOD) was specially designed to support the EPA’s regulatory
modeling programs.
AERMOD is a regulatory steady-state plume modeling system with three separate
components:
AERMOD (AERMIC Dispersion Model), AERMAP (AERMOD Terrain Preprocessor),
and
AERMET (AERMOD Meteorological Preprocessor). The AERMOD model includes a
wide range of options for modeling air quality impacts of pollution sources, making it
a popular choice among the modeling community for a variety of applications. Some
of the modelling capabilities of AERMOD include the following:
The model may be used to analyze primary pollutants and continuous releases of
toxic and hazardous waste pollutants.
Source emission rates can be treated as constant or may be varied by month,
season, hourof- day, or other optional periods of variation. These variable emission
rate factors may be specified for a single source or for a group of sources. For this
project all emission rates were treated as constant.
The model can account for the effects of aerodynamic downwash due to buildings
that are nearby point source emissions.
Receptor locations can be specified as gridded and/or discrete receptors in a
Cartesian or polar coordinate system.
For applications involving elevated terrain, the U.S. EPA AERMAP terrain
preprocessing program is incorporated into the model to generate hill height scales
as well as terrain elevations for all receptor locations.
The model contains algorithms for modeling the effects of settling and removal
(through dry and wet deposition) of large particulates and for modeling the effects of
precipitation scavenging for gases or particulates.
AERMOD requires two types of meteorological data files, a file containing surface
scalar parameters and a file containing vertical profiles. These two files are provided
by the U.S. EPA AERMET meteorological preprocessor programme
Model Inputs (Source Emissions)
A critical step for conducting air dispersion modeling is to quantify the emissions from the
sources at the facility. The emission rates from the sources identified were estimated in
accordance with the standard guideline.
Meteorological Data
The AERMOD model requires hourly surface data values for wind speed, wind direction,
temperature, rainfall, relative humidity, pressure, cloud cover and ceiling height and solar
radiation and at least once daily mixing height data.
The data files for the surface and mixing heights were then used to generate the
meteorological file required by the AERMOD dispersion model using the AERMET
meteorological preprocessor programme. The AERMET programme has three stages to
process the data. The first stage extracts meteorological data and assesses data quality
through a series of quality assessment checks. The second stage merges all data
available for 24-hour periods and writes these data together in a single intermediate file.
The third and final stage reads the merged meteorological data and estimates the
necessary boundary layer parameters for dispersion calculations by AERMOD.
Model Domain, Receptor Network and Terrain Considerations
The selected model domain was 10 km in both the east-west and north-south directions,
with the centre of the domain being the centre of the proposed facility site, with
coordinates 12°56′11.11″N and 74°49′27.36″E with 19 to 27 amsl. Figure 4.1 shows the
model domain that was utilized in the project, including the receptor grid and the plant
boundary. The model domain is overlain on a Google image.
Receptor Network
The selection and location of the receptor network are important in determining the
maximum impact from a source and the area where there is significant air quality impact.
Impacts were assessed at locations beyond the site boundary. Consequently, the
receptor locations were selected as a multi-tier grid that is defined by discrete Cartesian
receptors, square in shape and uniform polar grid receptors, circular in shape and with
origin at the centre of the proposed facility.
The entire receptor network locations include a 100-meter spaced grid within 10 km from
the subject source. A total of 621 receptors were considered, and receptor grid is
graphically depicted in Figure 4.1.
Terrain Considerations
The classification of the land use in the vicinity of the proposed facility is needed because
dispersion rates differ based on the land use type. The topography in the region of the
proposed fertilzer manufacturing facility is defined as either simple terrain (terrain lying
below the stack top elevation) or complex terrain (terrain above the top of the stack).
Measurements of the terrain in the area surrounding the proposed facility were made
using terrain data obtained from Digital Elevation Maps derived from the United States
Geological Survey (USGS).
The terrain data obtained was shown in the Figure 4.2. It was determined that the
topography from the west to the eastern directions up to 10 km have terrain elevations
above 19 to27 m .Therefore, since terrain elevations extend above the facility’s highest
top stack elevation, complex terrain algorithms were included as part of the dispersion
modeling analysis.
Model Results and Impact Assessment
With the various sources identified, a model domain established of 10 km in the North
East direction and 10 km in the north-south direction and centred in the middle of the
proposed facility, and the necessary input files created, model predictions were made for
the pollutants SO2, NOx, PM10 and NH3 for averaging periods for which there are
National Ambient Air Quality Standards.
4.2.3 Post Project Scenario (Projected)
Predicted maximum ground level concentrations considering micro meteorological data of
Winter 2016-17 are superimposed on the maximum baseline concentrations obtained
during the study period to estimate the post project scenario, which would prevail at the
post operational phase. The overall scenario with predicted concentrations over the
maximum baseline concentrations is shown in the following Table 4.2 & 4.3.
Table–4.2 Ground Level Concentrations (GLCs)
S.No. Parameters Max (µg/m3) Distance (Km.) Direction
Existing Stack
1 SOx 14.7 2.4 NNE
2 NOx 12.3 1.0 E
3 NH3 6.7 1.5 E
4 SPM 14.4 1.0 E
5 HF 0.2 0.2 E
Proposed Stack
1 SOx 2.8 1.5 NNE
2 NOx 12.4 0.337 NE
3 NH3 9.4 0.8 E
4 SPM 6.2 1.2 E
5 HF 0.6 1.0 E
The Summary of cumulative GLC by the proposed project for Sox, PM, NOx, NH3 and
HF observed 18.8 µg/m3 (Baikampady), 97.3 µg/m3 (Lalbag), 36.6 µg/m3 (Project Site)
and HF was not detected in base line as well as proposed project mostly in North East
direction.
The predicted ground level concentrations obtained when superimposed on the maximum
baseline concentrations observed during study period resultant concentrations are within
the prescribed NAAQ Standards. The details are as per Table 4.3 below
AERMOD Output
The isopleths representing pollutant concentrations representing 10 km x 10 km grid are
presented in Figures – 4.3 to 4.5
The existing emission load from stack already covered at the time of base line data
collection. The Maximum predicted GLC by the proposed project for Sox, SPM, NOx,
NH3 and HF observed 2.8 µg/m3 (Baikampady), 6.2 µg/m3 (Kulur), 12.4 µg/m3 (Project
Site) 6.5 µg/m3 (Kulur) and 0.4 µg/m3 (Project Site) detected in base line as well as
proposed project mostly in North East direction
The Summary of predicted GLC by the proposed project with baseline data for Sox, SPM,
NOx, NH3 and HF observed 5.9 µg/m3 (Lalbag), 92.1 µg/m3 (Lalbag), 19.8 µg/m3
(Project Site) 23.8 µg/m3 (Project Site) and 0.4 µg/m3 (Project Site) detected in base line
as well as proposed project mostly in North East direction
The predicted ground level concentrations obtained when superimposed on the maximum
baseline concentrations observed during study period resultant concentrations are within
the prescribed NAAQ Standards. The details are as per Table 4.3 below
National Ambient Air Quality Standards (2009)
Pollutants Time Concentration in Ambient Air
Weighted Industrial, Residential, Ecologically
Average Rural, other areas Sensitive Area
(Notified by MOEF)
Sulphur Dioxide (SO2), Annual * 50 20
μg/m3 24 Hours ** 80 80
Nitrogen Dioxide (NO2), Annual * 40 30
μg/m3 24 Hours ** 80 80
PM10, μg/m3 Annual * 60 60
24 Hours ** 100 100
PM2.5, μg/m3 Annual * 40 40
24 Hours ** 60 60
Lead (Pb) μg/m3 Annual * 0.50 0.50
in particulate matter 24 Hours ** 1.0 1.0
Arsenic (As), ng/m3 Annual * 06 06
in particulate matter
Nickel (Ni), ng/m3 Annual * 20 20
in particulate matter
SPM SOX HF
NOx NH3
Figure 4.1 Isopleths for Proposed Stack
HF NH3 SPM
NOx SOx
Figure 4.2 Isopleths for Existing Stack
Provisions of the Safety Systems in the design with redundancy, reliability and
defense in depth are considered.
Regular monitoring by Environmental Cell to demonstrate the compliance with
Statutory limits in the public domain.
Mitigation measures of Fugitive Emissions:
The following measures shall be adopted to control fugitive emissions:
Bagfilter with extraction system shall be provided at raw material area. Scrubber
system shall be installed at product bagging area
All vehicles and their exhausts will be well maintained and regularly monitored for
emission generated from the vehicle exhaust;
Venturi Scrubber and cyclones will be provided in the process plant
Regular dust suppression with water sprinkler on the haul roads will be practiced
The green belt development in the plant will be undertaken.
confined to the day hours. The general mitigation measures for the attenuation of noise
are given below:
Noise will be reduced by preventing leakages from steam lines, compressed air
lines and other high pressure equipment.
Suitable padding will be provided at required locations to avoid rattling due to
vibration
Noise generating equipment will be encased to control noise.
Noise proof cabins will be provided to operators wherever remote control for
operating noise generating equipment is feasible.
The air compressor, process air blower, pneumatic valves etc, will be provided with
acoustic enclosure;
Design/installation precautions will be taken as specified by the manufacturers with
respect to noise control and will be strictly adhered.
High noise generating sources will be insulated adequately by providing suitable
enclosures.
Sound attenuation panels will be installed wherever required around noise
generating equipment.
Noise control will form an integral part of the plant design.
Other than the regular maintenance of various equipment, ear plugs/muffs will be
provided to personnel working close to the noise generating units.
All openings like covers and partitions will be designed properly
Inlet and outlet mufflers will be provided wherever required.
All rotating equipment / parts will be well lubricated and provided with enclosures
as far as possible to reduce noise transmission.
There is no additional liquid effluent generation from the plant. The plant will remain
zero liquid effluent discharge plant. It is proposed to replace the present low pressure
stripper with medium pressure (MP) stripper which will ensure removal of Ammonia
from process condensate. The gases from the MP stripper will be carried by the
steam going to primary reformer. The effluent generated in the plant shall be treated
in the existing effluent treatment facility and recycled back to the system.
There will not be any additional effluent generation by the proposed energy
improvement project. Wastewater generation will reduce because of the
implementation of various energy improvement schemes.
Water treatment plant ion exchange regeneration effluent streams, the cooling tower
blow down and backwash water effluent from water treatment plant sand filter and
cooling tower side stream filter were treated in the wastewater recovery unit and
treated water is reused as cooling water makeup.
Water treatment plant resin regeneration and cooling tower blow down effluents
containing high dissolved solids is treated by Reverse Osmosis technology.
The high dissolved solids effluent stream containing water treatment plant resin
regeneration effluent and cooling 'tower blow down is passed through clarifier, pressure
sand filter and Ultra Filtration (UF) units to remove suspended solids and colloidal
particles. Then it is treated in Reverse Osmosis (RO) units to remove dissolved solids.
Treated water is reused in cooling tower as makeup.
The high dissolved solids effluent streams are collected in an equalization tank. This
stream after dosing with NaOCI, Coagulant, Lime, Dolomite & Polymer is pumped to
High Rate Solids Contact Clarifier (HRSCC). The clarified water from HRSCC is passed
through Multi Grade' filter for reduction of suspended solids.
Then the filtered water is fed into the Ultra filtration unit (UF) to remove colloidal silica
and related colloids of iron and aluminium in water causing fouling, scaling and poor
performance of the plane the stream which is free from suspended and colloidal particles
will be passed through Reverse Osmosis unit (RO). The Dissolved solids are removed in
2 stages of RO unit. In the first stage R01 about 75 % of desired quality water will be
recovered and reject is fed to second stage R02 wherein further 10% is recovered. The
R02 reject containing high dissolved solids is used in DAP plant.
The recovered water is used in cooling tower as makeup. The sludge collected in the
HRSCC is pumped to centrifuge to remove water. The separated liquid is recycled to
equalizing tank and thickened slurry is used in DAP plant.
4.10. Ecology
4.10.1. Terrestrial Ecology
The floristic component of the study area does not include any rare or endangered
species. Thus, impact on rare and endangered species of flora is not envisaged. The
project does not envisage destruction or displacement of any fauna species. Thus,
indirect impact on fauna due to loss of habitat is not foreseen.
The impact of proposed project on vegetation in the study area may occur through two
ways:
Clearing of vegetation from the proposed site for plant setup
Effects on terrestrial ecosystem due to stack emissions.
Construction Phase
The proposed expansion plants would be installed within premises of MCF Unit. The
land earmarked for proposed project is full of small herbs & shrubs. Clearing of land will
lead to generation of biodegradable waste which shall be composted for use in green
belt maintenance in the plant premises. No fruit bearing and costly/timber trees exist
within the plant premises hence, clearance during construction period is not required.
Removal of small shrubs & herbs shall not impart adverse impact on terrestrial ecology
during construction phase.
Operation Phase
The impact on terrestrial ecology due to marginal increase in the concentration of air
pollutants from the proposed project will be in the form of solid pollutants namely PM 10 &
PM2.5 and there will be a drastic reduction in the emission level of gaseous pollutants
such as SO2 and NOx due to the usage of Natural Gas as feed/ fuel in the ammonia
plant.
But on the whole, the ambient air and water quality will not change significantly. Thus, no
impact on terrestrial ecology is envisaged.
4.10.2. Aquatic Ecology
The effluent from different plants shall be suitably treated in wastewater recovery unit.
Zero Liquid Discharge (ZLD) concepts shall be implemented for the proposed project.
The treated effluent shall be recycled and re-utilized within the premises for de-dusting
and maintenance of green-belt. Thus, no impact on the aquatic ecology is envisaged.
4.11 Impact on Socio-economic Environment
The development due to proposed project will have marginal impacts on local socio-
economic condition of the people residing in the area. The construction of different
plants would provide temporary employment to the people residing in adjoining villages.
This would improve the socio-economic condition of the local population.
The operation of the proposed project would result in positive impacts such as industrial
and economic development, generation of employment opportunity.
Reduction in import of Urea will save the foreign currency of the country. General Public
will be attracted towards rural area due to the use of fertilizer which will enhance the
crop production and thus, the living conditions in the area.
The impact of the proposed plant on socio economic conditions of the study area
expected to be positive as follows.
Increase in floating population.
Increase in demand of services including hotels, lodges, public transport (including
taxis), etc.
Economic up-liftment of the area.
Rising of infrastructure and financial aspects in the study area.
Beneficiation of the civil construction and transportation companies as they are
procured from the local area.
Expanding of services like retail shops, banks, automobile workshops, school,
healthcare facilities, etc.
The local population will have employment opportunities in related service activities like
petty commercial establishments, small contracts/sub-contracts and supply of
construction materials for buildings and ancillary infrastructures etc. consequently, this
will contribute to economic up liftment of the area.
The construction activity will benefit the local population in a number of ways, which
include the increase in requirement of construction skilled, semi-skilled and un-skilled
workers, tertiary sector employment and provision of goods and services for daily needs
including transport. In line with the above, following recommendations are made:
Local people will be given preference for employment depending on their suitability; All
the applicable guidelines under the relevant Acts and Rules related to labour welfare and
safety will be implemented during the construction phase;
4.12. Transport
NG shall be received through pipeline proposed to be laid by GAIL (INDIA). The finished
products urea shall be dispatched from plant premises through rail networks. Hence,
transportation of raw material and finished products shall not produce any measurable
adverse impact on the environment as well as existing traffic network.
Mitigation measures for traffic
The trucks transporting raw materials and finished goods will be covered.
It will be assured that vehicles are PUC certified.
Adequate measures will be taken to avoid spillage or leak of raw material and
drivers will be instructed to control leakages and collection of spilled material.
Temporary new approach road can be constructed, if required, for smooth and
hassle free movement of personnel;
Ensuring the availability of valid Pollution Under Control Certificates (PUC) for all
vehicles used on site.
site. The following safety measures need to be taken while handling the chemicals.
Requisite personnel Protective Equipment shall be provided to the workers.
Instruction/Notice to wear the same will be displayed. Further, it will be insisted to use
the same while at work.
Provision of water shower with Eye washer and display of notice accordingly.
MSDS of all hazardous chemicals will available at Office and responsible persons.
Antidotes for all chemicals being used as per MSDS will be kept ready at the site.
Booklet on “Disclosure of Information on Hazardous Chemicals to the workers” will
be prepared and educated them.
Provisions of First Aid Box and trained person in first aid.
Prohibition on eating or drinking at work-area.
Any leakage/spillage of liquid chemical shall be immediately attended and
provision of urgent cleaning.
Work area will be monitored to maintain work environment free from any
dust/chemicals fumes/ vapours and keep within below permissible limit.
Provision of adequate Fire Extinguishers at site and training will be imparted to the
workers also.
Maintaining the Fire-Protection System adequately.
Availability of Self Breathing Apparatus at site.
Provisions of immediate accident/incident reporting and investigation.
Instructions on Emergency/Disaster will be displayed.
Safety Posters and slogans will be exhibited at conspicuous places.
Arrangement of Periodical Training to workers/operatives, supervisors.
Work permit systems will be strictly followed.
Safety Committee will be constituted and safety, health and environmental
matters/issues will be discussed in the meeting and enlighten the participants in
these respect.
The occupational health care and safety plan incorporated in the EMP and the
Emergency Preparedness Plans will ensure that the probability of undesired events and
consequences are taken care. The overall impact on human health will be minimum.
This Chapter provides an alternative analysis, including site and technology, considered
for the proposed expansion project.
Mangalore has special strengths in Chemical and mineral related industries, now
diversifying into machineries and other manufacturing industries. Regional wise, industrial
accumulation as well as population concentration can be found in major cities.
This chapter provides the proposed environmental monitoring programme for the
proposed project to access the environmental attributes for both the construction and
operation stages
6.1. Objectives
Regular monitoring program of the environmental parameters is essential to take into
account the changes in the environment. The monitoring program for the proposed
project will allow for prompt implementation of effective corrective measures. The main
objectives of environmental monitoring are:
To assess the change in the environmental conditions,
To monitor the effective implementation of mitigation measures,
* All Plant discharges including blow downs, cooling water blow down etc. are routed
through combined effluent treatment plant. Hence during normal operation of plant, the
system as such is Zero Liquid Discharge (ZLD) basis.
6.2.3. Noise Quality Monitoring
Ambient Noise monitoring includes monitoring during day time as well as night time. The
monitoring shall be carried out as per CPCB guidelines and in consultation with
Karnataka SPCB using standard instruments and methodology. The noise monitoring in
work zone and at surrounding villages shall be done once in 6 months.
The MCF is having the NABL approved laboratory for chemical testing, the copy of the
certificate is given in Figure 6.1. Details of testing equipment available for monitoring
Water, Wastewater and Air / Emissions. For Water and Wastewater testing:
control equipment. The group reports to head of the station. The same group will continue
as nodal department for the proposed project also when in operation, with following
functions.
Obtaining Consent Order from SPCBs;
Environmental monitoring;
Analysis of environment data, reports preparation and transmission of report to
statutory authorities and Corporate Centre etc.;
Compliance with guidelines and statutory requirements;
Coordination with statutory bodies, functional groups of the station, Corporate level
etc.;
Interaction for evolving and implementation of modification programs to improve the
availability / efficiency of pollution control devices / systems;
Environmental Appraisal (Internal) and Environmental Audit;
This Chapter provides the details about the Risk Assessment, Disaster Management
Plan (DMP) and on-site emergency plan as proposed for the proposed project.
7.1. Introduction
The word 'disaster' is synonymous with 'emergency' as defined by the Ministry of
Environment and Forests (MoEF). An emergency occurring in the proposed Energy
improvement project of Ammonia and Urea plant 1 million t/y DAP/NPK project, Poly
Carboxy Ether (PCE) project of 18000 t/y, at Mangalore, Karnataka is one that may affect
several sections within it and / or may cause serious injuries, loss of lives, extensive
damage to environment or property or serious disruption outside the plant. It will require
the best use of internal resources and the use of outside resources to handle it
effectively.
It may happen usually as the result of a malfunction of the normal operating procedures.
It may also be precipitated by the intervention of an outside force such as a cyclone,
flood, earthquake or deliberate acts of arson or sabotage. This chapter deals with the
risks associated with the Plant, its mitigation and the Disaster Management Plan.
7.3. Objectives
The specific objectives of the study are to identify:
Hazardous materials associated with the project
Potential consequences of identified threats
Recommend risk prevention and reduction measures to ensure that all risks are
within ALARP.
Defines the actions to be taken in case of emergencies.
The primary step of the Hazard identification is the risk analysis and entails the process
of collecting information on:
the types and quantities of hazardous substances stored and handled at the plant,
the location of storage tanks & other facilities, and
Potential hazards associated with the spillage and release of hazardous chemicals.
7.4.1. Identification of Hazards
The main hazard potentials in the proposed Plant are categorized as below:
Material hazards; Associated with Hazardous Materials Storage Facilities.
Process hazards due to loss of containment during handling of hazardous
materials or processes resulting in fire, explosion, etc
Mechanical hazards due to "mechanical" operations such as welding,
maintenance, falling objects etc. - basically those NOT connected to hazardous
materials.
Electrical hazards: electrocution, high voltage levels, short circuit, etc.
Out of these, the material and process hazards are the one with a much wider damage
potential as compared to the mechanical and electrical hazards, which are by and large
limited to very small local pockets.
Stage Description
human errors, or single spontaneous failures of tanks or process vessels.
Minor Impact limited to the local area of the event with potent for ‘knock – on- events’
Incidents
Serious One that could cause:
Incident 1. Any serious injury or fatality on/off site;
2. Property damage of $ 1 million offsite or $ 5 million onsite.
Extensive One that is five or more times worse than a serious incident.
Incident
Assigning a relative risk to each scenario provides a means of prioritising associated risk
mitigation measures and planned actions.
7.6.1. Thermal Hazards
In order to understand the damages produced by various scenarios, it is appropriate to
understand the physiological/physical effects of thermal radiation intensities. The thermal
radiation due to tank fire usually results in burn on the human body. Furthermore, inanimate
objects like equipment, piping, cables, etc. may also be affected and also need to be
evaluated for damages. Tables 7.4, 7.5 and Table 7.6 (below), respectively give tolerable
intensities of various objects and desirable escape time for thermal radiation.
Thermal hazards could be from fires or explosion. Fire releases energy slowly while
explosion release energy very rapidly (typically in micro seconds). Explosion is rapid
expansion of gases resulting in rapidly moving shock wave. Explosion can be confined
(within a vessel or building) or unconfined (due to release of flammable gases).
BLEVE (boiling liquid expanding vapour explosion) occurs if a vessel containing a liquid at
a temperature above its atmospheric boiling point ruptures. The subsequent BLEVE is the
explosive vaporisation of large fraction of its vapour contents; possibly followed by
combustion or explosion of the vaporised cloud if it is combustible range.
Thermal hazards have been considered for various scenarios including: Fire in fuel storage
tank.
Table 7.4. Effects due to Incident Radiation Intensity
Incident Radiation
Damage Type
kW/m2
0.7 Equivalent to Solar Radiation
1.6 No discomfort on long duration
Sufficient to cause pain within 20 sec. Blistering of skin (first degree burn
4.0
are likely).
9.5 Pain threshold reached after 8 sec. Second degree burn after 20 sec.
Minimum energy required for piloted ignition of wood, melting of plastic
12.5
tubing etc.
Minimum Energy required for piloted ignition of wood, melting, plastic
25
tubing etc.
37.5 Sufficient to cause damage to process equipment.
Number of Persons
Department
General Shift Each Shift
Process Technology & Engg. (Admn Bldg.) 3
Procurement (Admn Bldg) 13
Projects (Admn Bldg) 3
Quality Control & Environment 12 4
Safety 9 4
Security 4 5
Shutdown, Planning & Contracts (Technical Bldg.) 8
SNF-Production 2 4
Speciality Fertilizers 5
Stores 13
Sulphuric Acid Plant 2 2
Support Services (Admn Bldg.) 2
Systems (Admn Bldg.) 1
Urea Bagging 1 4
Urea Plant 3 7
Water Treatment/Utilities 3 7
CONTRACTORS
Mechanical ( in General shift)
Ammonia 5
Urea 5
Utilities 5
DAP 10
SAP 5
Bagging 5
Speciality fertilizer 5
CPP 5
IAT 5
Civil (in General shift)
Ammonia 5
Urea 5
Utilities 5
DAP 5
Bagging 5
CPP 5
Painting 10
Electrical (In General shift) 20
Janitorial services 40
Garden and Green belt 10
Railway 10
Contractors Per Shift
SNF 10
DAP 10
Bagging 5
Number of Persons
Department
General Shift Each Shift
Speacilitly ferilizer 10
CPP 3
Security 15
Canteen 15
Loaders 25
Railway 2
Payloader operators 7
The population in surrounding area is estimated as about 10,000 over 1 km radius.
The general correlation between wind speed and atmospheric stability is shown in
Table 7.11.
Table 7.11. Relationship between wind speed and atmospheric stability
Wind speed Day-Time: Night-Time
Solar Radiation Cloud Cover
(m/s) Strong Medium Slight Thin Medium Overcast
<3/8 >3/8 >4/5
<2 A A-B B - - D
2-3 A-B B C E F D
3-5 B B-C C D E D
5-6 C C-D D D D D
>6 C D D D D D
Category D (neutral) is the most probable at sites in moderate climates and may occur
for up to 80 % of the time at relevant sites. Stability F (very stable) represents the most
adverse condition in which dispersion extends over longer distances horizontally.
Normally, stability F occurs for short periods in the year, mainly during winter nights.
Weather data (monthly average maximum & minimum temperature and rain fall) for
Indore are indicated in Table 7.12.
Table 7.12. : Monthly average weather data for Mangalore
Month Temperature (°C) Relative Humidity (%)
Daily Max. Daily Min. Highest in the Lowest in the Max. Min.
Month Month
January 31.4 21.7 34.1 19.5 71 61
February 31.1 22.8 33.9 20.9 75 66
March 31.7 24.5 33.7 22.2 75 67
April 32.4 26.1 33.6 22.9 73 69
May 32.1 26.0 33.6 22.4 77 72
June 29.4 23.9 32.1 22.0 89 85
July 28.5 23.5 30.7 21.9 91 88
August 28.5 23.6 30.1 22.1 91 87
September 28.7 23.5 30.1 22.1 89 83
October 29.8 23.8 32.0 21.9 85 79
November 31.1 23.2 33.5 20.7 77 69
December 31.7 21.9 33.6 9.2 69 62
Wind rose diagram for distribution of direction from which wind is blowing and wind
speed is shown in Figure 7.1.
January February March
Leak
Material & Temp. Pressure
S.No. Description Leak size Frequency
Phase (C) (kg/cm2g)
(per year)
(Proposed Tank Outlet pipe
1.0E-05
in new DAP failure
Plant) Catastrophic
2.5E-08
Failure of Tank
Dyke spill 2.8E-03 each
Naphtha Tank
4. Naphtha 30 Atm. Full surface fire 9.0E-05 each
Farm
Tank failure 6.0E-06
Dyke spill 2.8E-03 each
Furnace Oil
5. Furnace Oil 50 Atm. Full surface fire 9.0E-05 each
Tanks
Tank failure 6.0E-06
Amm. Receiver 5 mm Leak 9.0E-04
Liquid
6. (Storage 40 15 25 mm Leak 4.0E-04
Ammonia
Refrigeration) 100 mm Leak 9.0E-05
5 mm Leak 1.2E-03
Ammonia Liquid
7. (-)33 29 25 mm Leak 3.5E-04
Transfer Pump Ammonia
100 mm Leak 7.0E-05
Methacrylic Acid Dyke spill 2.8E-03
Methacrylic
8. Tank (proposed 30 Atm. Full surface fire 9.0E-05
Acid
PCE Plant) Tank failure 6.0E-06
Table 7.15. Results of Consequence Analysis for MCF Plants
S. No. Description Down Wind Distance (m)
Weather Category → D; 3 m/s D; 2 m/s
1. Imported Ammonia Tank – Liquid Outlet Pipe Leak (25 mm)
Ammonia Cloud Footprint
Gas IDLH concentration (300 ppm) 230 100
Dispersion ERPG-3 concentration (1100 ppm) 50 35
2. Imported Ammonia Tank – Transfer Pump Discharge Pipe Leak (25 mm)
Ammonia Cloud Footprint
Gas IDLH concentration (300 ppm) 490 435
Dispersion ERPG-3 concentration (1100 ppm) 240 185
3. New Ammonia Tank in DAP Plant – Liquid Outlet Pipe Leak (25 mm)
Ammonia Cloud Footprint
Gas IDLH concentration (300 ppm) 230 100
Dispersion ERPG-3 concentration (1100 ppm) 50 35
4. Naphtha Storage Tank – Roof Failure
Tank Radiation Intensity
Surface Fire 4 kW/m2 56 52
12.5 kW/m2 19 18
37.5 kW/m2 Not reached Not reached
Flash Fire Flash fire envelope
LFL concentration (1.05%) 54 59
5. Naphtha Storage Tank Failure
Dyke Fire Radiation Intensity
4 kW/m2 129 120
12.5 kW/m2 52 52
37.5 kW/m2 Not reached Not reached
Flash Fire Flash fire envelope
LFL concentration (1.05%) 163 173
(1) Imported Ammonia Tank – Liquid Outlet Pipe Leak (25 mm): Cloud Foot Print: IDLH
(300 ppm) & ERPG-3 (1100 ppm)
Figure 7.2 : Imported ammonia tank outlet line leak –Ammonia Dispersion
(2) Imported Ammonia Tank Transfer Pump – Discharge Pipe Leak (25 mm): Cloud Foot
Print: IDLH (300 ppm) & ERPG-3 (1100 ppm)
Figure 7.3 : Imported ammonia tank outlet line leak –Ammonia Dispersion
(3) New Ammonia Tank (Proposed) – Liquid Outlet Pipe Leak (25 mm)
Cloud Foot Print: IDLH (300 ppm) & ERPG-3 (1100 ppm)
Figure 7.4 : New ammonia tank outlet line leak –Ammonia Dispersion
Plant
The maximum value of individual risk to plant personnel in the MCF Capacity
Enhancement Project is 1.7E-05 per year.
The values of maximum individual risk to public and plant personnel in MCF Capacity
Enhancement Project in comparison with the risk tolerance criteria are shown in Figure
7.13.
Acceptable Risk
7.13. Recommendations
Based on the results of this QRA study, the following recommendations are made to
ensure that the risks at proposed projects are maintained at low level.
1. In order to limit the quantity of ammonia released due to accidental leak, it is
necessary to provide ammonia leak detectors and emergency push buttons to
stop the ammonia transfer pumps and close the shut-off valve at tank outlet.
2. Mechanical integrity assurance is critical to prevent leakage of hazardous
material from equipment, tanks and piping. This includes the following systems:
o Maintenance system to ensure use of correct material and procedure
covering fittings, gaskets, welding etc.
o Monitoring of equipment and piping with non-destructive testing (NDT), leak
detection & repair (LDAR), etc.
3. The following safety and fire protections measures are to be ensured for the
Naphtha tanks as per OISD standards.
o Hydrocarbon gas detectors and medium expansion foam generators for dyke.
When workers have been informed accordingly, they should use the equipment
provided throughout the time they may be exposed to the risk that requires the use
of PPE for protection.
The PPE should not be used for longer than the time indicated by the
manufacturer.
Workers should make proper use of the PPE provided, and maintain it in good
condition, consistent with their training and be provided with the proper means for
doing so.
Head Protection
Any helmet that has been submitted to a heavy blow, even if there are no evident
signs of damage, should be discarded.
If splits or cracks appear, or if a helmet shows signs of ageing or deterioration of
the harness, the helmet should be discarded.
Where there is a hazard of contact with exposed conductive parts, only helmets
made of non-conducting material should be used.
Helmets for persons working overhead should be provided with chin straps.
In addition to safety, consideration should also be given to the physiological
aspects of comfort for the wearer.
The helmet should be as light as possible, the harness should be flexible and
should not irritate or injure the wearer and a sweatband should be incorporated.
All protective headgear should be cleaned and checked regularly.
Face & Eye Protection
Face shields or eye protectors should be used to protect against flying particles,
fumes, dust and chemical hazards.
Face shields should be used in boiler operations and other hot work involving
exposure to high-temperature radiation sources. Protection is also necessary
against sparks or flying hot objects. Face protectors of the helmet type and the
face-shield type are preferred.
With the use of face and eye protectors, due attention should be paid to greater
comfort and efficiency.
The protectors should be fitted and adjusted by a person who has received training
in this task.
Comfort is particularly important in helmet and hood type protectors as they may
become almost intolerably hot during use. Air lines can be fitted to prevent this.
Face and eye protectors should give adequate protection at all times even with the
use of corrective vision devices.
Eye protectors, including corrective lenses, should be made of appropriate high-
impact material.
Respiratory Protective Equipment
When effective engineering controls are not feasible, or while they are being
implemented or evaluated, respirators, appropriate to the hazard and risk in
question, should be used to protect the health of the worker.
When the hazard and risk cannot be assessed with sufficient accuracy to define
the appropriate level of respiratory protection, employers should make positive
pressure air supplied respiratory protective devices available.
When selecting respirators, an appropriate number of sizes and models should be
available from which a satisfactory respirator can be selected. Different sizes and
models should be available to accommodate a broad range of facial types.
Workers should be fit-tested for respirators.
Respirators should be cleaned and sanitized periodically. Respirators intended for
emergency use should be cleaned and sanitized after each use.
The user should be sufficiently trained and familiar with the respirator in order to be
able to inspect the respirator immediately prior to each use to ensure that it is in
proper working condition. Inspection may include the following :
tightness of connections;
the condition of the respiratory inlet and outlet covering;
head harness;
valves;
connecting tubes;
harness assemblies;
hoses;
filters;
cartridges;
end of service life indicator;
electrical components;
shelf life date;
The proper function of regulators, alarms and other warning systems.
Respirators should be properly stored. Damage may occur if they are not protected
from physical and chemical agents such as vibration, sunlight, heat, extreme cold,
excessive moisture or damaging chemicals.
Each respirator should be used with an understanding of its limitations, based on a
number of factors such as the level and duration of exposure, the characteristics of
the chemical and the service life of a respirator.
Workers should be medically evaluated for their ability to wear a respirator safely
before they are required to do so.
Hearing Protection
When effective engineering controls are not feasible or while they are being
implemented or evaluated, hearing protection should be used to protect the health
of workers.
Hearing loss of speech frequencies may occur with elevated long-term exposure to
noise. The use of hearing protectors gives the best results to users who are well
informed of the risks and trained in their use. If earplugs are used, special attention
should be paid to the proper fitting technique.
Hearing protectors should be comfortable, and the users should be trained to use
them properly. Special attention should be paid to possible increased risk of
accidents due to the use of hearing protectors. Earmuffs reduce the capacity to
locate sound sources and prevent warning signals from being heard. This is
especially true for workers with considerable hearing loss.
No model is suitable for all persons. Those wearing hearing protectors should be
able to choose from alternative products that meet the attenuation criteria.
Earplugs should not be the only solution as not all people can wear them.
Hearing protectors should be made available at the entrance to the noisy area and
they should be put on before entering the noisy area. Noisy areas should be
indicated by appropriate signs.
The attenuation of hearing protector’s works well only if they are well maintained.
Good maintenance consists of cleaning, changing replaceable parts such as
cushions, and overall monitoring of the state of the hearing protector.
Hearing protectors should be evaluated through an audiometric test programme for
exposed workers.
Protection from fall
When other measures do not eliminate the risk of falling, workers should be
provided with and trained in the use of appropriate fall protection equipment, such
as harnesses and lifelines. Workplaces and traffic lanes in which there are fall
hazards or which border on a danger zone should be equipped with devices which
prevent workers from falling into or entering the danger zone.
Devices should be provided to prevent workers from falling through floors and
openings.
Safety harnesses should be worn where required and the lifeline should be
attached to an adequate anchor point.
Harnesses should be chosen that are safely used with other PPE that may be worn
simultaneously.
Appropriate and timely rescue should be provided when using fall-arrest equipment
to prevent suspension trauma.
Protection while handling Ammonia
Adequate number of SCABA apparatus to be provided while handling ammonia
manually or during repairs to ammonia handling equipment.
Fully covered body suit should be worn while handling ammonia.
Adequate number of PPE is to be made available in the plant premises.
or serious disruption outside the works. It will require the use of outside resources
to handle it effectively.
Disaster: Disaster is a sudden calamitous event, bringing great damage, loss or
destruction.
Hazards: Hazard may be defined as “the potential of an accident”. Hazard exists in
man and the system of materials and machines.
Chemical Hazards: It is a hazard due to chemical(s) (including its storage, process,
handling, etc.) and it is realized by fire, explosion, toxicity, corrosively, radiation, etc.
Risk: Risk may be defined as the combination of consequence and probability or
likelihood of an accident being caused in a given man-material – machine system.
On-Site Emergency plan: It deals with measures to prevent and control
emergencies within the factory and not affecting outside public or environment.
Off-Site Emergency plan: It deals with measures to prevent and control
emergencies affecting public and the environment outside the premises.
7.17.2. Objective of the Disaster Management Plan
The primary purpose of this Disaster Management Plan is to equip the Plant with required
resources and information for prompt implementation of the set of actions to be undertaken
in the event of an accident posing hazards to the people and community after
commissioning of the plant.
The objective of Disaster Management Plan (DMP), for the plant is to be in a state of
perceptual readiness through training, development and mock drills, to immediately control
and arrest any emergency situation so as to avert a full fledge disaster and the
consequence of human and property damage and in the event of a disaster still occurring,
to manage the same to that the risk of the damage consequences to life and property are
minimized and thereafter, proper rehabilitation, review and revisions of the DMP to
overcome the shortcomings noticed are undertaken.
The DMP document is prepared keeping in view and to conform the requirements of the
provisions of The Factories Act 1948 under section 41 B (4), Guidelines issued by the
Ministry of Environment and Forests, Govt. of India and Manufacture, Import and Storage
of Hazardous Chemicals Rules, 1989 amended in 2000, Schedule 11 under Environmental
Protection Act 1986.
Following are the main objectives of the plan to:
Defined and assess emergencies, including hazards and risk
Control and contain incidents.
Safeguard employees and people in vicinity.
Minimize damage to property and/or the environment.
Minimization of risk and impact of event accident.
Preparation of action plan to handle disasters and to contain damage.
Inform employees, the general public and the authority about the hazards/risk
assessed and to provide safeguard, and the role to be played by them in the event
of emergency.
Be ready for 'mutual aid' if need arises to help neighboring unit.
Inform authorities and mutual aid centers to come for help.
Effect rescue and treatment of casualties.
Effective rehabilitation of the affected persons and prevention of damage to the
property.
Identify and list any fatalities.
Inform and help relatives.
Secure the safe rehabilitation of affected areas and to restore normalcy.
Provide authoritative information to the news media.
should be easy access from the factory to this Emergency Control Room. Keeping this in mind,
we have located two Emergency Control Rooms. The First Emergency Control Room (ECR-1)
is near the Security Gate. The second one (ECR-2) is the Mini Conference Room in
Administrative Building. Both these rooms are sufficiently spacious and the size of the rooms
are given below:
1) ECR-1 7.6 M long and 5.8 M wide.
2) ECR-2 (alternate) 6.7 M long and 4.7 M wide.
3) Incident Control Room 9.7 M long and 7.3 M wide
Both the above ECRs comply with the prescribed size given by the Task Force set up by
Karnataka State Government. During general shift hours there will always be vehicles at both
these rooms which can be utilised in emergency. Moreover, the Safety Section and Security
Gate are nearer to the Emergency Control Room-I. The other facilities that are being provided at
both the Control Rooms are given below:
1. Emergency lights
2. Public Address System
3. Hotline between plants
4. Hotline to MRPL & OMPL Fire Station
5. Direct phones for external communication
6. Internal telephones
7. Walkie Talkie
8. Mobile phones
In addition to the above facilities, the following documents connected with the Emergency Plan
are kept in almirahs in both these Control Rooms.
1. Copies of On-site and Off-site Emergency Plans.
2. Factory layout.
3. Emergency telephone numbers.
4. Directory of Internal Telephones.
5. Directory of External (P & T) Telephones.
6. Data on the number of people working in different plants/sections.
7. Data on population around the factory.
The Emergency Control Rooms are suitably located so that there will be least traffic
congestion and approach to the rooms by Emergency Coordinators will be easy.
7.18.3. Fire & Toxicity Control Arrangements
The plant will be well equipped with suitable numbers of firefighting and personnel
protective equipment. The staff will be trained regularly to handle the various emergency
situations.
7.18.4. Medical Arrangements
Availability of first aid facilities in sufficient quantity will be always ensured. In case of
emergency arrangements will be made to avail outside medical help immediately.
Emergency transport facility will be available.
The worker or supervisor who works in the spot or nearby will be the first man to notice the
hazardous condition which may turn out to be a Major Hazard. This worker/supervisor will
inform the situation to the Shift-in-Charge (SIC) who is responsible for all the activities in
the shift. The SIC will inform the hazardous condition to the Chief Emergency Coordinator
(CEC) personally or by Walkie Talkie or by telephone or by a messenger. The CEC will
study the situation and declare the Emergency as it may be an 'OFF-SITE' or 'ON-SITE'. If
the Shift-in-Charge feels the situation is On-Site, he will declare so by sounding the siren.
Declaration of Emergency and functions of Chief Emergency Coordinator
After getting information form Shift-in-charge, the Chief Emergency Coordinator will rush to
the factory and assesses the situation. If he finds the situation could result in an 'On-Site' or
'Off-Site' emergency, he would immediately declare the emergency by a coded siren. All
the employees who are working inside the factory will thus know that an emergency
situation has occurred. The plant production personnel will shut down the plants as per
their Supervisor's instructions. Other non plant personnel are required to vacate the
workspots as early as possible and move into predesignated safe places like G-Rooms or
Assembly points. In case the emergency is 'Off Site', the declarer will use his discretionary
powers and decide about the nature of Emergency. In case of ‘Off Site' emergency, the
declarer will contact or get in touch with predecided authority who will be the 'Off Site'
Emergency Coordinator who will take over the management of emergency situation. The
management of emergency will be conducted from an Emergency Control Room or its
alternate. The State Govt. has constituted the District Crisis Group Committee. In our case
the Deputy Commissioner (D.K.) has been designated as the Chief Emergency
Coordinator.
The Chief Emergency Coordinator has many roles to play once he arrives at the work spot
and takes charge of emergency coordination. He will coordinate the action of two groups
viz., Emergency Operations Group and Emergency Services Group which will be headed
by Emergency Operations Coordinator (EOC) and Emergency Services Coordinator (ESC).
The Emergency Operations group will coordinate the activities required for emergency shut
down of the plants and for effective containment of the hazardous situation. They will also
evacuate the injured personnel to Occupational Health Center. For effective coordination of
safety squads/ fire tenders etc., the group will also coordinate with safety section and
ensures that all the personnel trapped in the affected area are brought to safe places.
The Emergency Services group will co-ordinate the activities such as immediate treatment
to the injured personnel which includes First Aid, transfer of injured personnel to the
designated hospitals, nursing homes, coordination of procuring external medical aid if
necessary, coordinating with local service organisations for assistance in these actions,
evacuation of people from affected areas to safe places, transport arrangement and traffic
control inside the factory area.
Both the above groups will have all the protective equipment that will be readily available in
the Incident control room and other designated places ear-marked for this purpose. The
groups connected with the above said operations and services would have already been
properly trained. This is possible because the nature of various possible hazards and
accidents have been identified by the HAZOP studies and risk analysis studies done
earlier.
7.19.2. Types of Sirens
Emergency Siren has been installed at two places to alert employees inside the Factory
and the general public in case of an emergency involving fire or toxic gas release. The
siren for emergency alarm is different from the siren meant for time indication and is
located at a distinctly different place. Following is the emergency siren code for different
emergencies like Fire or Toxic gas release.
Following post emergency actions will be carried out to study in detail and preventive
measures to be taken.
Collection of records.
Inquiries
Insurance claims
Preparation of reports comprising suggestion and modification.
Rehabilitation of affected personnel.
Normalization of plant.
7.20.1. Evacuation and Transportation
In case of emergency, evacuation and transportation of non-essential workers will be
carried out immediately. The affected personnel will be transported for medical aid.
7.20.2. Safe Close Down
During emergency plant shut down will be carried out if situation warrants. This will be as
per the instruction of site main controller under guidance of incident controller.
7.20.3. Use of Mutual Aid
Mutual aid agreement with nearby industries will be ensures to provide help to each other
in the emergency,
7.20.4. Use of External Authorities
As and when necessary, statutory authorities, police, pollution control personnel, medical
aid/ center, ambulance etc. will be contacted.
7.20.5. Medical Treatment
The affected personnel will be brought to safer place immediately to give them first aid.
Immediate medical attention will be sought.
7.20.6. Accounting for Personnel
Proper accounting for personnel will be laid down in all the shifts. The number of persons
present inside the plant premises, their duty etc. will be available with the Security, HR &
Admin. This record will be regularly updated and will be made available.
7.20.7. Access to Records
The relatives of affected personnel will be informed. The details regarding all
employees will be made available to Administration building.
7.20.8. Public Relations
In case of emergency, GM- HR will be available for official release of information
pertaining to the incident.
7.20.9. Rehabilitation
The affected area will be cleared from emergency activities only after positive
ascertaining of the system in all respects. The entry to affected area will have to be
restricted until statutory authorities visit and inspect the spot of incident. Nothing
should be disturbed from the area till their clearance. The site main controller will
be in charge of the activities to be undertaken.
The plan will cover emergencies, which can be brought under control by the works
with the help of emergency team/fire services. The DISASTER CONTROL PLAN
for gas leak and fire will be prepared for entire factory.
Corporate Office
Regd. Office
Insurance the plant
Regional Officer, KSPCB
d. Seeking Help From Neighbouring Industries / Sources For Fire Engine
e. Advise for evacuation of other areas
Since the effect of fire/gas emission shall be contained within the area of the plant advice of
evacuvation of other areas is not necessary.
Response Time-Minutes
Hazard Fire Fighting Police Medical Services
Fire & Immediate with whatever facilities 10 10 minutes
Explosion available with the plant minutes
External Help within 15 minutes
This chapter provides mitigation and control measures to attenuate and/or eliminate
environmental impacts, which are likely to be caused by the proposed project. An
Environmental Management Plan (EMP) has been developed to mitigate the potential
adverse impacts and to strengthen the beneficial impacts during the construction and
operation phase.
8.1. General
Environmental Management Plan (EMP) is the key to ensure a safe and clean
environment. A project may have taken proper pollution control measures, but without a
proper management plan, the desired results may not be obtained.
EMP is a tool for planning and implementation of various pollution abatement measures
for any proposed project. It is required to ensure environmentally and ecologically
sustainable developmental activities in the study area. The EMP brings transparency
related to environmental degradation between the project proponent and pollution control
regulatory agency at State & Central level. It has been evaluated that the environment
and the eco-system of the study area will not be affected adversely due to the proposed
project. Mitigation measures at the source level and an overall EMP are elicited so as to
improve the sustaining capacity of the area in concern and also to preserve the
assimilative capacity of the receiving bodies.
The EMP Action Plan aims at controlling pollution at the source level to the possible
extent with the best techno-economically feasible & available methodology before the
pollutants are discharged into atmosphere.
While implementing the project MCF will follow guidelines specified by KSPCB/MoEF
under the Corporate Responsibility for Environmental Protection (CREP) for related
plants. The following environmental management plan has been suggested during
construction and operation phase.
Development of Environmental Policy for the Industry relevant to the operations and
support it
Implementation of Pollution mitigation measures
Monitoring of pollution control equipment for the effectiveness and documentation of
observations for formulating improvements in the systems.
Making institutional arrangements like installing Environment Cell & review committee
Making budget provisions for Environmental Management Activities
Budgetary allocation for Environmental Activities
Identify and evaluate the environmental effects arising from the industry's proposed
activities, products and services
Identify and evaluate the environmental effects arising from incidents, accidents and
potential emergency situations;
Identify the relevant legislative and regulatory requirements;
enable priorities to be identified and pertinent environmental objectives and targets to
be set;
facilitate planning, control, monitoring, auditing and review activities to ensure that the
policy is complied with; and
Allow periodic evaluation to suit changing circumstances so that it remains relevant
8.2.2. Environmental Policy
The proponent shall formulate its policy with the following aspects
However, once the construction job related to the proposed project is completed and
operation of proposed units started, the operation stage impacts would overlap the
impacts due to the construction activities. Following factors shall require due
consideration during construction phase:
Stock piling of earthen material would be required during foundation works of the
proposed project. The earth work will generate dust which will be controlled by periodical
sprinkling of water during day time working period.
Cleaning of site
Removal of abandoned installations and buildings
Installation of drainage improvement and storm water drainage
Excavation of built area
Installation of environmental protection facilities
Preparation of access roads to each plant
Constructing support facilities
Installation of utilities (water, sewage etc.)
8.3.2. Construction Equipment & Waste
Care shall be taken to prevent accidental spillage of any oil from construction equipment.
Combustible waste and other wastes shall be disposed-off by adopting environmentally
compatible methodology. The earthy materials will be generated during erection of walls,
pilings etc. The generated waste shall be used in dressing / leveling of low lying areas,
etc.
During construction of plants and laying of pipes, some solid waste materials will be
generated. These materials will be sold through CPCB / SPCB registered scrap dealers.
The gas cylinders used for welding shall be returned back to the supplier. Cement bags,
coal tar drums and other containers used during construction and discarded as wastes,
shall be auctioned through registered vendors as per standard practices. Similarly, the
damaged tools shall also be disposed in the above manner.
On-site recycling of all waste solvents / thinners & oils and off-site recycling of paint
thinner solvent wastes & waste oil.
Separate storage for waste paints and thinners, contaminated rags and brushes to
facilitate recycling and reuse. Rags could be laundered for reuse.
Vehicle maintenance area shall be selected properly to prevent contamination of soil
and ground water by accidental spillage of oil and other wastes.
Wastes generated from construction and demolition activities shall be handled as per
guidelines / notification issued by MoEF&CC in Construction & Demolition Waste
Management Rules, 2016. The waste generated shall be segregated as construction and
demolition wastes and deposited at designated collection centers and handed over to
authorized processing facilities.
8.4. Management Plan during Operation Phase
8.4.1. Air Environment
Ammonia Plant
There will not be any increase in pollution load due to increase in production. This is
achieved by the energy improvement schemes which will be implemented in the plant.
The total firing in the primary reformer will be lower resulting in reduction of fuel
consumption. Also there will be reduction in steam and power requirement for the plant.
Urea Plant
There will not be any significant increase in pollution load after the implementation of
energy improvement project. Capacity of Urea plant will be increased from 4,29,000 t/y
to 5,69,400 t/y after the availability of NG in Mangalore.
The existing modified design prill bucket known as the “Tuttle prill” bucket will be replaced
with “vibropriller” bucket which has special features in the spray hole orientation which
gives prills of very uniform size of improved crushing strength and thereby helps in
reducing the dust formation inside the prilling tower. Also the configuration of louvers with
well-maintained induced draft fans has ensured adequate flow and temperature control.
Prill Tower having internal diameter of 17 m and free fall height of 49.14 M has been
provided for prilling. The highest point of the structure is 72 M from the ground level.
The emission of Particulate matter from the urea prill tower will be about 110 mg/Nm³
which is well within standard of 150 mg/Nm³.
DAP/NPK Plant
The proposed project will not have any significant adverse impact on the existing
environment as sufficient pollution control measures are incorporated in the process
technology and plant design. The technology also incorporates special scrubbing
equipment like Dual Mole Scrubbing System and also Dedusting system. In DAP / NPK
plant Air pollution control equipment viz. Cyclone, Scrubber, Mist eliminator etc. shall be
installed during the commissioning of the plant itself.
The flow of gaseous emission from the stack (3 No. 45 m each) is expected to be
maximum 720000 Nm³/hr., particulate Matter 50 Mg/Nm³, fluorine 20mg/Nm³ and
Ammonia 150mg/Nm³.
POLY CARBOXYL ETHER (PCE) Plant
There will not be any gaseous emissions from the proposed PCE plant.
Air Pollution control Systems with Stack Details
There will be no emission from the proposed PCE Plant.
The major gaseous emissions which will generate inside the plant are usually from
Production of Ammonia, Urea, and DAP/NPK plant and DG set.
The impact on air quality due to the operation of the proposed project will be mainly due
to the following sources:
Emission of particulate matter from the Urea and DAP/NPK Plant.
Fugitive emissions
produced is separated in the second desorption column. The liquid outlet of second
desorption column contains less than 10 ppm of ammonia and urea. The ammonia
vapours from the second desorption column is fed to the first desorber. The desorber
overhead vapours are condensed in a condenser and reused in Urea plant. The treated
effluent from urea hydrolyser stripper is reused as cooling tower makeup water.
NPK Plant
No trade effluent generation from the proposed DAP/NPK plant. No solid waste will be
generated. Any spillage will be recycled and reused in the proposed plant. There will not
be any additional water drawl from the Mangalore City Corporation for the proposed
project. The marginal increase in the water requirement after the commissioning of
DAP/NPK plant will be met by effluent water recovery unit installed.
Since no liquid effluent and solid waste will be discharged from the plant there will not be
any significant adverse impact on the aquatic ecosystem. The vegetation and aquatic
systems of the area will be protected by adopting the above environmental protection
measures.
POLY CARBOXYL ETHER (PCE) Plant
There will be no liquid effluent generated in the plant. The spillages if any from the plant
floor will be collected in and recycled back to soil conditioners section.
8.4.3. ETP Facility
In Mangalore Chemicals & Fertilizers Ltd., (MCF), the Liquid Effluent streams generated
are only from Ammonia, Urea and Water Treatment Plants. The Ammonium Bi-
carbonate and Di-Ammonium Phosphate Plants are designed to have zero effluent
discharge. In Di-Ammonium Phosphate (DAP) Plant a part of ammonia and urea bearing
effluent from Urea/Ammonia plant is used as process condensate.
8.4.4. STP Facility
With the aim of reusing the treated sewage effluent, sewage effluent treatment system
has been upgraded by adapting Membrane Bio Reactor (MBR) Technology during
2010.The treated sewage effluent is reused in the cooling tower as make up water.
8.4.5. Rainwater Harvesting & Management
The rain water collected from the roof of the permanent buildings shall be harvested for
ground water recharge as a compensation for meeting the requirement due to loss of
permeable area promoting ground water recharging, maintenance of existing hydro-
dynamic pattern of the area and to conserve the salinity of ground water of the area.
Implemented the schemes for harvesting roof water at township and recharge the bore
wells. Total roof area covered is about 3500 m2.
The excess rainwater shall be sent to the trap through storm water drain and attempts
shall be made not to mix any process waste with the storm water. The trap shall have
two compartments one consisting of sized boulders and the other sized hard coke. The
excess water from sized hard coke shall be collected in another tank before discharge in
to natural drainage system. The drainage system of project area shall be aligned as per
the existing natural drainage pattern of the area.
8.4.6. Water Conservation Measures
MP Condensate stripper:
A medium pressure condensate stripper will be installed in place of LP condensate
stripper. Existing LP stripper consumes 6.5t /h of steam. The proposed MP condensate
stripper recovers heating steam and overhead vapors are generated at higher pressure
and it is consumed in reformer. Hence no venting of steam.
Lower steam demand:
Steam demand from Auxiliary boiler will reduce to 7.5 t/h from present 20 t/h due to
higher heat recovery in the proposed revamp. This will reduce Furnace oil consumption
in auxiliary boiler by about 1.1 t/h which in turn will reduce 3.5 t/h of CO2 emission.
Replacement of Syn Gas Compressor:
Existing Motor and steam Turbine driven Syn Gas compressor will be replaced with
steam turbine driven, higher efficiency compressor. This replacement will reduce
compressor energy consumption by about 2.9 MW even after an increase in the plant
load by 25%. Optimization of steam- electrical energy consumption due to converting
motor and back pressure turbine drive to backpressure and condensing turbine drive will
reduce overall electrical power consumption by 8 MW. This reduction will reduce NG/FO
consumption in Captive power plant. (1.8 t/h of FO or 1.5 t/h of NG)
Addition of Heat NG Feed Preheat Coil and Mixed Feed Coil in Reformer Convection
Section:
Addition of heaters in reformer convection section recovers additional heat from reformer
flue gas. This will reduce flue gas temperature from present 175°C to 126°C.
8.5. Hazardous / Solid Waste Management
8.5.1. Generation of Solid / Hazardous Wastes
As per Hazardous & other waste (management & trans-boundary) rules-2016 of MoEF,
the following items under “Schedule-I [See Rule 3(I), “List of Processes Generating
Hazardous Waste” following items have been declared hazardous waste as per serial
number 18 of the above list:
* In place of Chromate based cooling water formulation, new generation cooling water formulation
based on polymers (bi/ter polymers) non-oxidising biocides and Chlorine dioxide in place of
chlorine shall be used
8.5.2. Hazardous Waste
As per the Rules, hazardous waste is defined as any waste which by reasons of its
physical, chemical, reactive, toxic, flammable, explosive or corrosive characteristics
causes danger to health or environment, whether alone or when in contact with other
waste or substances.
According to above criteria, the following wastes are considered to be hazardous from
proposed project:
and characteristics of the hazardous wastes. Since, the spent catalysts contain precious
metals and have market value; they will be packed in sealed containers and sold to
CPCB approved recyclers. In case it is not possible to sell the hazardous wastes, it shall
be stored in inert and leak proof containers.
8.6. Green Belt Development
Trees and plants are an essential component of healthy environment. In addition to
maintaining the oxygen-carbon dioxide balance in the atmosphere through
photosynthesis, trees and plants control air and noise pollution, control soil erosion,
provide food and shelter to domestic and wild animals including birds and insects, and
improve the aesthetic value of the environment. The utility of the green belt
predominantly lies in its capacity to attenuate the fugitive emissions and spillage. Thus,
the objectives of the proposed green belt program are as follows:
To control air pollution due to fugitive emissions and spillage.
To attenuate noise generated by various machines.
To attenuate the effect of accidental release of toxic gases.
To reduce the effect of fire and explosion.
To improve the general appearance and aesthetics of the area.
To provide food and habitat for wildlife.
To control soil erosion.
To obscure the proposed facilities from general view.
8.6.1. Areas to be Afforested
MCF plant established in about 192 Acres inclusive of 64 Acres of green belt, which is
33% of existing plant area.
There exists a thick green belt around the existing fertilizer plant. While proposing the
layout plan (upcoming facility) for locating the different facilities, extreme care has been
exercised to preserve the existing plantation to the extent possible. Trees, lawns and
gardens developed within the premises to cover all the vacant areas. Extreme care shall
be taken to utilize all available areas for afforestation.
8.6.2. Species for Afforestation
The general approach for selection of species for green belt development is their
potential for attenuation of fugitive emissions and noise, diversity of vegetation,
introduction of species attracting birds and animals, and to create a natural habitat. It is
proposed to develop trees of different heights so as to provide cover from ground level
up to the canopy of tall tree species. Further, trees with big foliage and those known to
prosper well in the area will be developed. Preference will be given to fruit bearing trees
so as to provide food and shelter to birds and insects.
Efforts would be made by M/s MCF in collaboration with Forest Department to explore
mutual areas of interest in the area of identifying trees/ plants to maintain/ enhance the
current biodiversity index.
township area and three nos. in the factory area. Rainwater harvesting system will
consist of the following units:
Rainwater Collection System
Rainwater Filtration System
Rainwater Recharging Pond including an active well of depth 20m and dia 100-
150mm
The scheme of rain water harvesting and aquifer recharging is presented below:
Prior to the initiation of excavation activities, work area perimeters will be secured to
restrict or prohibit public access as required. Work zones, decontamination corridors,
and staging areas will be established and posted as required in cooperation with the
selected excavation contractor. All necessary permits and erosion control measures
shall be kept in place prior to disturbing the site. Trees and bushes may be chipped and
disposed of onsite or offsite.
All work at the site is proposed to be conducted in accordance with the provisions of Site
Safety and Health Plan (SSHP) to be developed and submitted to the local body prior to
the initiation of field activities. Excavated materials will be segregated for any deemed
reuse onsite or for offsite disposal at an appropriate facility specific to the characteristics
of the material. It is anticipated that only crushed concrete and stone, and geo-
technically suitable soils that are not contaminated will be reused in the project. If other
materials are to be reused, appropriate reuse scenarios will be developed on a case by
case basis in consultation with the local body.
A storage area for reusable soil and recycled concrete product close to its presumptive
area of end use will be provided. It is anticipated that any unusable debris (wood, tires,
appliances, scrap metal, concrete with rebar, etc.) that may be present at the site will be
handled according to the guidelines specified under Hazardous & other waste
(management & trans-boundary) rules-2016 of MoEF and Construction & Demolition (C
& D) waste rules 2016.
8.10.2. Action Plan To Follow NAAQS
Environmental monitoring plays an important part in environmental management. In
some instances, it is in the interest of the project and environment as well, to perform
continuous monitoring. This can lead to rapid detection and recognition of irregular
conditions and give the operating staff the possibility to correct and restore the optimum
standard operating condition as quickly as possible. Environmental monitoring by regular
spot checking (by manual methods) will suffice to know the status and performance of
equipment and record the emission levels, if any. In general, the frequency of regular
monitoring depends on process technology, type of process equipment, stability of the
process, and reliability of the analytical methods.
A monitoring schedule, prepared in consultation with Karnataka State Pollution Control
Board (KSPCB), shall be maintained for the following environmental parameters:
Ambient air quality: Adequate number of monitoring stations shall be established
for monitoring of ambient level of PM10, SO2, NOx & NH3. The measurements shall
be performed regularly with the frequency of twice per week to evaluate 24-hourly
concentration.
Stack Emissions: Stack emissions from Ammonia- Urea plants, DG Sets shall be
monitored by NABL accredited laboratory.
Well equipped Occupational Health Centre with a full time doctor and qualified /
experienced nurses.
OHC is totally air conditioned and there are 6 beds which are connected with
centralised oxygen supply system.
Showers and Eye wash fountains are provided at OHC for decontamination.
Each employee working in the factory shall be given the following items:
Safety Helmet Safety Goggles Cotton Hand gloves Ear Plug
Following items are proposed to be kept ready in each plant control room to take care of day to day work
as well as emergencies:
Breathing Set Rescue stretchers Canister Type Gas Mask Extra Canisters
(NH3,, Acid gases and
Organic vapour)
PVC Suit Gum Boots PVC Hand Gloves Hand Gloves
Hood Airline Breathing Set
Safety appliances to be available in the Fire and Safety dept are as under:
Powered Respirators Rescue Sets Breathing Apparatus PVC Suit
Asbestos Suit Hand Gloves Canister Type Gas Mask Line Sets
(NH3, Acid gases and
Organic vapour)
Cartridge Type Gas Dust Respirators
Mask
In addition, Safety equipments shall be available in Stores Department in adequate
quantity. Most of the safety equipments will be codified and a minimum fixed number of
quantities will be maintained in Stores Department. Safety Board and Safety Posters
mentioning hazardous, explosive, toxic and flammable gases, corrosive liquids, NO
SMOKING OR NAKED FLAME and other precautions shall be displayed in vulnerable
areas.
Gas Detectors and smoke detectors shall be provided in vulnerable areas of the plants.
Safety showers and eye wash fountains shall be provided in relevant sections of the
plants.
equipment and other safety appliances shall be kept ready, for use during disaster and
emergency situations. The disaster management plan has been included in Chapter-8.
8.13. Environmental Policy of MCF
The Company’s policy shall integrate the conservation and protection of the environment
and safety of the workmen. The main points in the policy shall be:
Always striving for the safety of the workmen, public around and betterment of the
Environment.
Regular and continuous monitoring of ambient air, stacks, work place, etc.
Healthy Operating Practices.
Compliance with all National and State Environmental and Safety regulations.
Responsibility for Environment and Safety compliance as a line function.
Survey and monitoring of the employees’ health at regular intervals.
Training at all levels inclusive of contract employees.
Technical audits to cover environmental aspects, safety, health and energy.
Environment and Safety policy covering the interests of employees, customers,
community.
Quantitative Risk Assessment, Disaster Management Plan, Emergency
Preparedness Plan, Accident Investigation, Analysis and Reporting System, Safety
Inspection.
Environmental Impact Assessment.
Providing personal protective equipments and their periodic review for
effectiveness and up-gradation.
Active participation in mutual aid committee. Health survey and monitoring.
8.14. Measures for Protection of Environment
8.14.1. Energy Saving Measures
A well equipped Energy Management Cell with qualified auditors with great deal of
expertise in Energy management and Power conservation shall be set-up in MCF.
Detailed schemes shall be planned by all plants and service groups to arrive at
practicable minimum energy and Power consumption. This will result in significant
improvement in plant performance with added zeal for resource conservation and
environment for upkeep Energy conservation. Few important proposed measures are
presented below:
a) In Waste Heat Recovery Boiler (WHRB), waste/ flue gases shall be used for pre-
heating BFW and power generation.
b) Corro-coating: Corro-coating shall be done in various major energy consuming
sources like cooling tower pumps in main plants and utility plant, fire water pump leading
to substantial amount of power savings.
c) Evaporating cooling for Process Air Compressor (PAC): Through-put in PAC shall
increase due to evaporating cooling resulting in more ammonia production contributing
to less energy consumption.
d) Use of Automated Control System (ACS) in Ammonia plant: ACS leads to
accurate control of load optimization, steam carbon ratio, CO2 maximization leading to
production maximization which amounts to 0.05 MKcal/ton of energy in ammonia
manufacturing.
e) Use of VFDs: Variable Frequency Drives shall be installed in Ammonia, Steam
generation, Urea plant etc to operate the equipment during various plant requirements at
low RPM to reduce energy consumption to the tune of 25-30%.
f) Use of solar water heaters: Solar heaters shall be installed at strategic locations like
Canteen, Guesthouse etc. to reduce energy consumption.
g) Solar Lighting: Energy saving shall be achieved with lower wattage alternatives
using solar power panels for street lighting, plant lighting, lighting at offices with LED
lamps.
8.14.2. Miscellaneous Energy Saving Programs
MCF shall pay proper attention for implementation of following energy saving programs.
The programs are as under:
Green Light Program
It involves installation of energy efficient lighting system which reduces indirectly
generation of oxides of Carbon, Nitrogen and Sulphur. However, there shall not be any
comprise with required illumination at working places.
Energy Star Program
Use of energy efficient electrical appliances including computers shall be practiced.
8.14.3. Fund allocation for EMP
A fund of about 2.5 % of total project cost has been earmarked against the
environmental management and related expenses. MCF shall also pay proper attention
to improve the working environment by adopting the principle of Ergonomics in the
following line of action:
“In order to maximize the working and skill capability of the work-men, the Environmental
Management Plan considers the strategy and goal of Ergonomics. The application of
ergonomics will reduce the Muscular Skeletal Disorder (MSD)”.
The capital cost for environmental measures related to proposed project is worked out
for implementation of environmental management plan and is given in Tables 8.5 The
total capital cost for EMP is calculated as approximately 56 crores and the recurring cost
is aprox 3 crores.
This chapter concludes on the findings that emerged from the environmental assessment
study and summarizes the key points to be addressed to ensure the environmental
sustainability of the project during the construction and operation phases.
The status of the environment at the project site and within the study area of 10 km radius
is delineated with respect to air, noise, water, land, biological and socioeconomic
environment. The different project activities during the construction and operation phases
are identified. To identify the impacts, the interaction between the project activities and
different components of environment are classified phase wise. A summary of the
identified impacts are given in the following paragraphs.
During the constructional phase, the transportation of construction material may have an
impact, especially on air, noise, vibration, and soil. At the time of construction and
operation stage, there will be minor impact on environment.
The additional strength of labourers could temporarily increase the pressure on the
resources of the area. During the operational phase, there could be minor change in air
quality .Transportation of raw material, storage and handling of hazardous material and
the production process could cause a temporary disturbance to environment variables
which will be prevented with the proposed mitigation measures proposed in Chapter 4.
With respect to occupational health, minimal impacts are anticipated on the health of the
employees during operation phase.
In general, expansion of project shall help in enhancement of productivity in the region as
well as generate direct and indirect employment in the area.
The project is yet at its technical investigation stage. Prior to its implementation, it will be
necessary to acquire all the necessary clearance from the Government of India, as per
the applicable national regulations. Key clearances include obtaining No Objection
Certificate from the Karnataka State Pollution Control Board (KSPCB) under The Water
(Prevention and Control of Pollution) Act, 1974 and Rules, 1975; The Air (Prevention and
Control of Pollution) Act, 1981 and Rules, 1982. In addition to that Manufacture, Storage
and Import of Hazardous Chemicals (MSIHC) Rules, 1989 and amendments thereafter,
Hazardous and Other Wastes (Management and Trans-boundary Movement) Rules,
2016, Bio Medical Waste (Management & Handling) Rules, 2016 and Municipal Solid
Waste (Management & Handling) Rules, 2016 will also be applicable to the industry.
The monitoring of the existing environmental conditions of the proposed project site and
of its close vicinity have been established with respect to physical, biological and human
environment.
The air quality of the area meets the prescribed National Ambient Air Quality Standards
applicable for the Industrial, Residential & Rural Areas. The background noise levels
were also found well within the standards.
The ground water quality prevails in the study area were in good agreement with IS:
10500 permissible limit. Overall the surface water quality of canal, pond and minor is
meeting the Class ‘C’ , Class ‘D’ of BDU Criteria of CPCB for its suitability for wild life and
fisheries.
Ambient noise level of the study area is within the prescribed National Ambient Noise
Quality Standard for respective residential, commercial and industrial category at all the
monitored locations.
The project entails various impacts on the study area, lots of positive and some negative.
There is going to no adverse impact on water quality or water demand due to proposed
project. There will be no additional water drawl from the Mangalore City Corporation as
the water requirement for the proposed projects will be met by reusing the treated
wastewater.
The impact (incremental GLC) due to the new stacks were computed and all pollutants
post project GLC will be well within NAAQ norms
There will be no adverse impact on land or noise level due to proposed project.
MCFL has taken adequate measures for EHS aspects for the proposed project. In
addition recommendations have been made to further strengthen the EHS measures,
energy conservation and other EMP aspects.
9.5. Recommendations
reporting shall be adopted during the operation period to ensure that the system
adheres to the EMP.
The project proponent and its team of consultants and contractors are urged to
develop a strategy for effective communication with local people. The construction
team/ developer should effectively follow the suggestions made in the EMP and/
or any other environmental measures so as not to damage the environment of the
project area.
CSR activities should be taken up in association with district authorities.
ON
OCTOBER 2017
Page 1 of 31
1. PREAMBLE
Mangalore Chemicals & Fertilizers Ltd (MCF) is an 'Adventz' Group Company, a large and
diversified business house. The main products of MCF are Urea, Di-Ammonium Phosphate (DAP),
NP 20:20:00:13, Ammonium Bi-Carbonate (ABC) - Food grade, Sulphuric Acid, Specialty Mixtures
of Plant Nutrients consisting of Water Soluble Fertilizers, Micronutrients & Soil Conditioners and
an Industrial Product called Sulphonated Naphthalene Formaldehyde (SNF) used in construction
industry.
MCF is the only manufacturer of chemical fertilizers in the state of Karnataka. The factory is
strategically located at Panambur, 9 km north of Mangalore City, on the banks of the Gurpur River,
along the National Highway 66, opposite to the New Mangalore Port Trust. MCF is an ISO 14001,
OHSAS 18001 and ISO 22000 certified Company.
The main products are Urea, Di-Ammonium Phosphate (DAP), NP 20:20:00:13, Ammonium Bi-
Carbonate (ABC) - Food grade, Sulphuric Acid, Speciality mixtures of plant Nutrients consisting of
Water Soluble Fertilizers, Micronutrients & Soil Conditioners and an Industrial Product called
Sulphonated Naphthalene Formaldehyde (SNF) used in construction industry.
While fertilizers and Plant nutrient products are marketed in all the Southern States and
Peninsular India, the food grade ABC, which is used mainly in Confectionery Industries is marketed
in domestic as well as international market. The requirement of power for the production facility
(process plants) is met by a Captive Power Plant. Ammonia & Phosphoric Acid, the raw materials
required for DAP & NP production are imported.
Page 2 of 31
The consented capacity for the intermediates and products manufactured are as below:
Sl. No. Product t/y
1 Ammonia 2,40,900
2 Urea 4,19,750
3 DAP & NP (16:20 & 20:20) 4,01,500
4 Ammonium Bicarbonate (ABC) 24,750
5 Sulphuric Acid 1,46,000
6 Sulphonated Naphthalene Formaldehyde 85,000
Construction of Ammonia and Urea plants commenced in 1972 and commercial production
started in 1976. Di-ammonium Phosphate (DAP) production commenced during 1986.
Commercial production of Ammonium Bicarbonate started in 1982. Sulphuric Acid Plant was
commissioned during March 2006. Captive Power Plant commissioned during 1986.
MCF Intends to modernize the existing facilities & expand by putting up the following plants in
existing location at Mangalore.
1. Energy Improvement Project of Ammonia & Urea Plants by modernization and capacity
enhancement of Ammonia from 2,47,500 t/y to 3,28,500 t/y and Urea from 4,29,000 t/y
to 5,69,400 t/y.
2. 1 million t/y DAP / NPK Project.
3. Poly Carboxyl Ether (PCE) Project of 18,000 t/y.
Page 3 of 31
2. NEED FOR THE PROPOSED PROJECTS
2.1) Energy improvement Project of Ammonia & Urea plants by modernization and capacity
enhancement of Ammonia from 2,47,500 t/y to 3,28,500 t/y and Urea from 4,29,000 t/y to
5,69,400 t/y. : MCF intends to do energy improvement revamp of existing Ammonia / Urea
plants. The revamp is necessitated due to recently announced new urea GOI policy No.
12012/1/2015-FPP dated 25-05-2015. All Ammonia/Urea manufacturers are mandated to
improve their energy norms to particular levels by 2018-19 to keep themselves in black. The
norms prescribed for MCF vintage is 6.5 Gcal/t of urea. As the operation profitability depends
only on energy and payment of all subsidy costs are energy dependent, it becomes necessary
for manufacturers like MCF to bring down energy norms to best achievable industry levels to
continue operation.
The existing Ammonia and Urea plants are running efficiently and scope for energy
improvement is seen due to vintage of plants.
Also, Urea is an important fertilizer segment. The supply/demand gap is huge and more than
8 million tons of urea imports are done as of now. The estimated total demand supply gap
in 2015-2016 was 8.2 Million MT of urea alone. Government of India is bound to support this
industry through conducive policies/subsidies. All southern states of India namely Karnataka,
Tamilnadu, Kerala and Andhra Pradesh have enough demand for Urea. The capacity
enhancement proposed by MCF will help towards filling the supply/demand gap.
2.2) 1 Million t/y DAP/NPK Plant. : DAP/NPK Fertilizer Complex is an important area of fertilizer
segment. India is the third largest producer and second largest user of DAP/NPK and has one
of the largest areas under Irrigation. Complex Fertilizers includes DAP (Di Ammonium
Phosphate) and NPK Fertilizers. There is huge demand for Phosphatic fertilizers in the
country. India has produced, 10.5 million tonnes of DAP/NPK during 2013-14 and imported
6.7 million tonnes of DAP/NPK. In India, DAP is the major product contributing 63% of the
total phosphate consumption. The estimated total demand supply gap by 2017-18 would be
11 Million MT of DAP alone. DAP & NPK fertilizers are in great demand and there is huge gap
between availability and supply. India is a net importer of DAP & NPK fertilizers. DAP/NPK is
an important fertilizer and Government of India is bound to support this industry through
Page 4 of 31
conducive policies/subsidies. All southern states of India namely Karnataka, Tamilnadu,
Kerala and Andhra Pradesh have enough demand for DAP/NPK fertilizers.
MCF intends to put a unit of DAP/NPK along with associated facilities. Bagging plant, bulk
silo, raw material storages, offsite and utilities etc. are part of associated facilities.
This is an expansion project. Accordingly, required site infrastructure and utilities are
available. MCF has vacant land of about 50 acres in the existing fertilizer complex and layout
is developed. The present fertilizer complex is located in Baikampady Industrial Estate
notified by Karnataka Industrial Area Development Board, (KIADB) Karnataka. The site is well
connected and has advantage of good infrastructure facilities like roads, water, power,
effluent treatment facilities and good green belt.
The site selected for the project is currently available at the premises of MCF, which makes
integration of utilities like power and steam generation with existing fertilizer plant very cost
effective. The geographical proximity of the plant with the New Mangalore Port offers
excellent logistic advantage for import of raw material with cost advantage.
2.3) Poly Carboxyl Ether (PCE) Project of 18,000 t/y. : At present we are manufacturing and
supplying Sulphonated Naphthalene Formaldehyde (SNF) which is mostly used in
Construction Chemical Industry to manufacture water reducing Admixtures also known as
super plasticizers. In India now due to recent developments in construction technology high
strength concrete started coming in to play. SNF was workable till the concrete of M45
grade. But the concrete which is more than M45 grade requires different type of admixtures
known as hyper plasticizers. To formulate hyper plasticizer the basic raw material required
is Poly Carboxylate Ether (PCE).
Page 5 of 31
ADVANTAGES OF PCE:
a. Produces concrete with high levels of workability without segregation.
b. Provides significantly higher strengths and normal setting time.
c. High early strength and 28 day’s strength increase obviously, especially for high dosage fly
ash concrete.
d. Has excellent concrete rheology and handling properties.
e. Provides improved finish ability and surface finishes.
f. Has superior air entrainment control.
g. Provides standard water reduction at normal addition rates and significant water reduction
at higher addition rates.
h. Has no chloride ions and non-corrosion to steel bar.
i. Improves the frost resistance and carbonation resistance of the concrete. Lower drying
shrinkage of the concrete by 20% or more compared to Naphthalene-based admixture.
j. Green product, this product don’t generate pollution in the production process, and meets
the requirements of ISO 14000.
To summarize, Poly carboxylates are sophisticated high end super plasticizers component for
concrete application, are considered superior to any other super plasticizers component.
As a part of growth/diversification strategy, various projects were studied based on MCF’s core
competency and available infrastructure. However it is identified that there is an excellent growth
potential for Poly Carboxylate Ether (PCE) also known as next generation water reducer which is
next to Sulphonated Naphthalene Formaldehyde (SNF).
Page 6 of 31
3. PROCESS DESCRIPTION
Energy improvement Project of Ammonia & Urea plants by modernization and capacity
enhancement of Ammonia from 2,47,500 t/y to 3,28,500 t/y and Urea from 4,29,000 t/y to
5,69,400 t/y.
b. Reforming section:
Reforming of the feed naphtha is carried out in primary and secondary reformer. In the primary
reforming process naphtha is reacted with the steam in the reformer tubes where the
hydrocarbon is converted to hydrogen, methane, carbon dioxide, carbon monoxide in the
presence of the nickel catalyst. The overall reaction is endothermic and heat is supplied by means
of burners on the top of the reformer. There are four rows of 56 tubes each and 5 rows of burners
with 12 burners in each row. In the secondary reforming the process gas from the primary
reformer is made to react with the preheated air. Here the methane content is reduced to say
0.30% and the nitrogen which is required for the ammonia synthesis is added to the process.
Page 7 of 31
c. Shift Conversion:
The process after giving the heat for steam generation in the waste heat boilers enters the high
temperature and the low temperature shift conversion vessels where Carbon monoxide in the
process gas is converted to carbon dioxide in two steps. The catalyst used is copper promoted
iron oxide. At the end of the shift conversion, the CO in the process gas is reduced below 0.20%.
e. Methanation:
In this process the residual Carbon monoxide from the shift conversion process and the carbon
dioxide from the C02 removal process is converted to methane in the nickel catalyst bed as these
are poisons for the synthesis catalyst.
f. Compressors:
Synthesis gas compressor increases the pressure of the make-up gas to the synthesis pressure as
well as it is used to recirculate the recycle gas. The synthesis section operates at pressure of 200
kg/cm2 as the ammonia reaction is favored by high pressure. Air compressor is used to compress
the air and supply it to the secondary reformer. A refrigeration compressor is used to cool the
synthesis convertor outlet gases to condense and separate the product ammonia.
g. Synthesis:
Synthesis converters are Haldor-Topsoe design S200 configuration. Here the process gas
containing hydrogen and nitrogen in the ratio of 3.0 is passed over the iron catalyst in the two
beds arranged in series with intercoolers and quenches to control the reaction temperatures. The
conversion to ammonia is only partial and hence the requirement of the recirculation.
Page 8 of 31
h. Purge gas recovery:
Purge gas recovery is a cryogenic process, where in the hydrogen from the purge gas is recovered
and recycled to the compressor suction. This helps to increase the production and the process
efficiency. Purge is generally given to maintain the inert in the circulating gas to the converter.
Page 9 of 31
3.2. Revamp Process: Ammonia Plant.
The plant is currently operating with naphtha as feed and fuel and operates with an energy
consumption of around 9.6 GCal/t. The plant is already converted in year 2014 to operate on
Natural gas as feed and fuel. In the revamped process, production of the ammonia plant will be
increased with a decrease in the energy consumption to around 8.0 Gcal/t when operated on
natural gas. However, the plant can be operated on Naphtha also and in naphtha based operation,
plant capacity will remain at present level, but energy consumption will reduce to 8.5 Gcal/t. The
revamping process will include the following modifications.
Revamp details.
a) Reformer section:
In the reformer section in the convection side two coils will be added. One is for preheating the
feed NG before it enters the fired heater and the other is to heat the NG and the steam mixture
before it enters the primary reformer. This will increase the inlet temperature to the primary
reformer by heat recovered from flue gases thereby bringing down firing and the heat flux in the
tubes. This calls for the replacement of the cross over line and the inlet pig tails. It also calls for
replacement of some of the coils in the super heater section and replacement of the tubular
combustion air heater with a plate heat exchanger. The temperature to stack will be brought
down to 136°C versus the current value of 170°C.
c) Compression section:
a. Synthesis gas compressor
A completely new set of compressor and drive turbine will replace existing Motor + turbine
driven compressor.
Page 10 of 31
b. Air compressor
The new compressor purchased for the gas conversion project along with the existing
compressor will be adequate for the revamped requirements.
c. Refrigeration compressor
To optimize the load on the refrigeration compressor, additional high pressure ammonia
chiller, an interstage cooler and a parallel flash drum will be added.
d) Synthesis section:
An Additional synthesis converter will be added in series (downstream) with the existing S200
converter. The synthesis loop will operate at 186 kg/cm2a. The additional converter will be of a
single bed with a feed-effluent cooler and will have catalyst volume of 45m³. This additional
converter will increase the per pass conversion. This converter will be a cold walled. Additional
BFW heater is provided for heat balance.
e) PGRU
The current PGRU though may not be able to take the additional load and hence will be left
untouched. The additional purge will be used as fuel in the primary reformer.
f) Naphtha Pre-treatment:
The whole revamp is considered with the NG as feed and fuel, hence the pretreatment of Naphtha
section is not considered for any change.
g) MP stripper:
Process condensate from the plant will be stripped using a medium pressure stripper. The treated
condensate produced from this stripper can be used as a make up to the de-aerator thereby
bringing down the fresh DM water requirement for Boiler feed water.
For increasing the capacity of the urea plant to 1560 MTPD, recovery of CO2 from the stack will
also be considered to meet additional CO2 requirement.
Page 11 of 31
4. Process Description – UREA Plant
4.1) Existing Plant
Urea is produced by reacting liquid ammonia and gaseous carbon dioxide at about 180-
185o C and 140-150 kg/cm2 abs. according the following reactions:
2 NH3 + CO2 <====> NH2COONH4 + heat (1)
NH2COONH4 <====> NH2CONH2 + H2O (2)
In the first reaction carbon dioxide and ammonia are converted into ammonium carbamate. This
reaction is fast and exothermic. In the second reaction, which is slow and endothermic, the
ammonium carbamate dehydrates to produce urea and water.
Urea Plant is designed based on CO2 striping process licensed by Stamicarbon. Vs. Netherlands.
Ammonia (NH3) and Carbon Dioxide (CO2) are the main raw materials for Urea production.
Initially, NH3 and CO2 are passed through a High Pressure Condenser where Ammonium Carbonate
is formed. This is sent to autoclave where a portion of it is converted to Urea. The unconverted
Ammonium Carbonate is stripped into NH3 and CO2 gases in a High Pressure Stripper using fresh
CO2 and recycled back to the HP condenser along with fresh Ammonia and dilute Ammonium
Carbonate to again form concentrated solution of Ammonium Carbonate. This cycle thus
continues.
The Urea solution thus coming from the Stripper is separated and concentrated in low pressure
section consisting of a rectification column, a flash vessel, Pre-evaporator and two stages of
evaporation. The molten Urea solution coming from the final evaporator is sent to a revolving
prill bucket at the top of the Prill Tower. The Urea solution is sprayed in the form of fine droplets
by rotation of the prill bucket. The droplets solidified into prills before reaching the bottom of
the Prill Tower as they come in contact with an upward flow of air. The prills are collected and
sent for bagging or storage in silo.
Page 12 of 31
BLOCK DIAGRAM UREA PROCESS
HP-Carbamate Compressed
Condensation
NH3
to Atmosphere
Compressed Stripping
CO2
LP Carbamate
Rectification
Condensation
Liquid
Storage
Gas
Page 13 of 31
4.2) Revamp of Urea Plant.
Stamicarbon being the process licensor has come up with a new concept called EVOLVE for
revamp and same shall be adopted. Main objectives of the revamp are:- a) Reduce HP steam
consumption in HP stripper - using Stamicarbon low energy concept to achieve 550 - 600 kg/t (38
bara & 400°C). b) Capacity expansion from 4,19,750 t/y to 5,69,400 t/y. c) To improve the quality
of the prilled Urea product.
Process retrofit concepts to fulfil the revamp objectives
Urea is produced by reacting liquid ammonia and gaseous carbon dioxide at about 170 - 185 C
and 135 - 145 bar according to the following reactions:
2 NH3 + CO2 <=====> NH2COONH4 (1)
NH2COONH4 <=====> NH2CONH2 + H2O (2)
In the first reaction, carbon dioxide and ammonia are converted into ammonium carbamate. This
reaction is fast and exothermic. In the second reaction, which is slow and endothermic, the
ammonium carbamate dehydrates to produce urea and water.
Ammonia and Carbon dioxide compression
Liquid ammonia is supplied from battery limits to the high pressure ammonia pump and
compressed to about 165 bar. It is then sent to the pool condenser via the high pressure ammonia
ejector. Additional ammonia is supplied to the MP section. Carbon dioxide from battery limits is
supplied, together with a small amount of air, to the carbon dioxide compressor before it is
compressed to synthesis pressure. The dehydrogenated carbon dioxide is introduced into the
bottom part of the high pressure stripper. Additional carbon dioxide is supplied to the LP section
via the newly installed LP CO2 compressor. Additional air is supplied to this compressor and a
hydrogen converter is placed in the discharge. The two feedstocks, ammonia and carbon dioxide,
are fed to the synthesis section at a molar ratio of 2 : 1.
Synthesis
The dehydration of ammonium carbamate into urea and water takes place in the new
poolcondenser and subsequently in the reactor. The reactor effluent is partially distributed over
the tubes of the high pressure stripper, which is a falling film type shell and tube heat exchanger.
Here, the reactor effluent is contacted counter-currently with carbon dioxide, causing the partial
ammonia pressure to decrease and the carbamate to decompose. The heat is supplied by
saturated high pressure steam.
The urea solution from the high pressure stripper, flows to the low pressure recirculation section
whilst the high pressure stripper off gases are sent to the poolcondenser which is special design
U-tube type heat exchanger. In the pool condenser, condensation of stripped gasses takes place
through the principle of poolcondensation, i.e. the gases are dispersed into a pool of liquid, where
the heat of condensation is being dissipated by submerged heat exchanger tubes. This heat of
condensation is used for two purposes: 1: to dissociate carbamate from the urea solution in the
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MP stage (in the lower bundle). 2: to generate low pressure steam of 4.5 bar (in the upper bundle).
This steam is used for heating and desorption as well as for the vacuum.
The pool of liquid in the poolcondenser allows for a considerable amount of urea formation to
take place here. The formed urea, non-converted carbamate, excess ammonia and some non-
condensed ammonia and carbon dioxide are subsequently introduced into the bottom of the
reactor where further conversion of carbamate into urea takes place. The heat, required for the
conversion and for heating the solution in the reactor, is supplied by additional condensation of
ammonia and carbon dioxide.
The reactor discharge goes through the downcomer to the high pressure stripper. The inert,
introduced with the carbon dioxide and part of the unreacted ammonia and carbon dioxide, go
overhead to the high pressure scrubber which contains a shell and tube heat exchanger in the
lower part and a packed bed in the upper part. In the lower part of the high pressure scrubber the
bulk of the ammonia and carbon dioxide are condensed, the heat of condensation being
dissipated into tempered cooling water. This heat is recovered in the pre-evaporator. In the upper
part of the scrubber the gases, leaving the bottom section, are contacted counter currently with
the carbamate solution coming from the medium pressure recirculation section. The gases,
substantially consisting of nitrogen and oxygen and containing only small amounts of ammonia
and carbon dioxide, are vented to the atmosphere via a LP absorber.
The carbamate solution from the high pressure scrubber flows to the high pressure ammonia
ejector.
Medium pressure recirculation section
Liquid leaving the stripper is flashed to MP conditions. The liquid from this flash is led through the
bottom bundle of the pool condenser where the supplied heat enables the dissociation of
carbamate into ammonia and carbon dioxide. The gas from this dissociation is combined with the
off gas from the flash and is led to the first stage evaporation heater, which acts as a MP
carbamate condenser. The heat of condensation of the carbamate is used to evaporate water
from the urea solution. The formed carbamate is sent to the HP scrubber. Small amounts of non-
condensed ammonia and carbon dioxide as well as inerts are sent to the existing LP absorber.
Liquid, leaving the dissociation heater is counter-currently contacted with the off gas from the MP
flash and then discharged to the existing LP section.
Low pressure recirculation section
In this section essentially all of the small amounts of non-converted ammonia and carbon dioxide
are recovered from the urea/ carbamate solution, leaving the MP section. This solution is
expanded to about 4 bar. As a result a portion of the carbamate, left in the solution, decomposes
and evaporates. The remaining liquid is divided onto a bed of Pall rings in the rectifying column.
The urea/ carbamate solution is sent from the bottom of the rectifying column to a new heater
where its temperature is raised to about 135 C in order to decompose the remaining carbamate.
The heat required is supplied by low pressure steam. In the separator (i.e. the bottom part of the
rectifying column) the gas phase is separated from the liquid phase. The gases are sent to the
rectifying column where they are cooled by the colder urea/ carbamate solution. This causes a
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portion of the water vapour contained in the gases to condense. The gases leaving the rectifying
column are introduced into the bottom part of the low pressure carbamate condenser where they
are condensed almost completely. The heat of condensation is dissipated into tempered cooling
water. From the level tank of the low pressure carbamate condenser, the carbamate solution
flows to the medium pressure carbamate pump where its pressure is raised and from where the
carbamate solution is carried to the MP section. The urea solution, leaving the bottom of the
rectifying column, flows to the atmospheric flash separator. Due to the adiabatic flash to about
atmospheric pressure, a portion of the water evaporates and some ammonia, carbon dioxide and
inert are liberated. These vapours are partly condensed in the flash separator condenser and the
remaining vapours are sent to the condensers of the evaporation section. Condensate from the
flash separator condenser is recycled to the LP carbamate condenser.
Pre-evaporation and evaporation
The solution from the atmospheric flash separator is sent to the flash separator heater. A portion
of the water in the solution is evaporated so as to increase the urea concentration. Finally, the
urea solution is sent to the urea solution tank from where, the urea solution is pumped to the
evaporators, where it is concentrated to about 99.5 % by weight and is called urea melt.
The urea melt is pumped to the prilling tower. The condensate, leaving the evaporator condenser
is sent to the ammonia water tank via a barometric leg.
Process condensate treatment
Process condensate from the evaporator condenser, containing ammonia, carbon dioxide and
urea, is collected in the ammonia water tank and used as absorbent in the LP absorber and the
atmospheric absorber. Next, the process condensate is pumped from the ammonia water tank to
the first desorber via a desorber heat exchanger. In the first desorber, the bulk of the ammonia
and carbon dioxide is stripped off by means of the overhead vapours of the second desorber and
hydrolyser. The bottom effluent of this first desorber is pumped via a hydrolyser heat exchanger,
where this condensate is heated, to the top of the hydrolyser column. In the hydrolyser, the urea
is decomposed into ammonia and carbon dioxide while being heated by means of live high
pressure steam. To obtain very small urea concentrations in the hydrolyser effluent, the process
condensate is countercurrently contacted with the live steam. On leaving the hydrolyser the
process condensate, containing traces of urea, goes via the hydrolyser heat exchanger to the
second desorber. The overhead vapours of the hydrolyser being sent to the first desorber. After
cooling the hydrolyser effluent in the hydrolyser heat exchanger, this condensate is fed to the top
of the second desorber. Here, the remaining ammonia and carbon dioxide is stripped off by means
of live low pressure steam. The process condensate, leaving the second desorber, is cooled in the
desorber heat exchanger and subsequently in the waste water cooler. It contains very small
amounts of urea and ammonia and can be used for several purposes i.e. for boiler feed water or
cooling water make up. The overhead gases from the first desorber are first partially condensed
in a pre-reflux condenser and after that in the reflux condenser and are transferred as a carbamate
solution to the low pressure carbamate condenser. The non-condensed vapours are sent to the
atmospheric absorber.
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4.3) SAILENT FEATURES OF ENERGY IMPROVEMENT PROJECT OF AMMONIA AND UREA
PLANTS.
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5. DAP/NPK PLANT
NH3 + H3PO4 --------------> NH4H2PO4 + Q2A
(Ammonia) (Phosphoric Acid) (Mono-ammonium Phosphate)
a) Dry Section
With reference to the simplified process flow diagram for the Dry Section of the Slurry Process, a
detailed description is furnished as follows:
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Phosphoric acid, gaseous Ammonia, and scrubber liquor enter into the Preneutralizer where it is
controlled at a specific gravity of 1.53 and a mole ratio of 1.5, which corresponds to moisture
content in the slurry of 18%. The Preneutralizer is maintained at a mole ratio of 1.5 to ensure
maximum solubility of the slurry. The Ammonium Phosphate slurry is pumped from the
Preneutralizer to the Pipe Reactor where it is combined with strong phosphoric acid, and gaseous
Ammonia and sprayed onto the bed of the Rotary Granulator at a mole ratio of 1.5 and moisture
of 10%. Underneath the bed in the Granulator is the Ammonia sparger that supplies liquid
Ammonia to raise the mole ratio of the fertilizer up to the desired value. The material leaves the
Granulator and enters into the Rotary Dryer where the DAP is dried, using hot gases leaving the
Combustion Chamber, to a moisture of 1.0-1.5% or even lower if needed. After exiting the Dryer
the material enters into the Primary Elevator to be distributed over the Oversize Screens. The
Oversize Screens are double deck screens where the oversize is sent to the chain mills, the
undersize falls onto the Recycle Belt along with the crushed material, and the product size
material is sent to the Product Screen Elevator for distribution on the Product Screens. The
purpose of the Product Screens is to remove the remaining fines that were not removed by the
Oversize Screens. The fines fall onto the Recycle Belt and the on spec material enters into the
Fluidized Bed Cooler or is recycled for control of the recycle ratio. The air entering into the
Fluidized Bed Cooler can be chilled using the Ammonia Air Chiller which will be discussed later.
Once leaving the Fluidized Bed Cooler the material enters into the Product Elevator and is
distributed onto the Polishing Screens. The on spec material then enters into the Coating Drum
and is then conveyed to the storage building. The gases leaving the Dryer, Product Cooler, and
Dedusting system are each sent through a separate set of cyclones. After the dedusting system
offgas exits the cyclones it is sent through a baghouse to be sent to the Combustion Chamber. If
this method of recycling dedusting offgases is not in place then the gases are sent to the RG
Scrubber. The gases leaving the Dryer Cyclones go to the Dryer Scrubber and the gases leaving
the Cooler Cyclones go the Tail Gas Scrubber.
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b) Wet Section
With reference to the simplified process flow diagram for the Wet Section of the Slurry Process,
a detailed description is furnished as follows:
Ammonia laden gases exiting the Preneutralizer and Granulator first enter into the Prescrubber
where they are scrubbed with liquor at a mole ratio of 1.4 where 60-70% of the Ammonia is
absorbed. Once exiting the Prescrubber the gases enter into the Reactor Granulator Scrubber
(RG Scrubber) where the gases are scrubbed with liquor at a mole ratio of 0.7. The gases exiting
the Dryer go through a cluster of cyclones and enter into the Dryer Scrubber where the gases are
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scrubbed with the same liquor that is used in the RG Scrubber. The liquor that is used in the RG
Scrubber and the Dryer Scrubber is circulated from the Scrubber Tank. Gases from the RG
Scrubber and Dryer Scrubber along with the gases that exit the Cooler Cyclones enter into the Tail
Gas Scrubber and then exit into the atmosphere. The circulating liquor in the Tail Gas Scrubber
is sent through a kettle type heat exchanger to vaporize Ammonia.
The process uses the reduced retention time Preneutralizer where the diameter at the bottom of
the tank is smaller than the top. The advantage of this design is that the Citrate Insoluble losses
are decreased while still maintaining the liquid level necessary to absorb Ammonia and not to
entrain liquid in the exiting gas. The Citrate Insoluble losses increase with increased retention
time so it is necessary to minimize the liquid volume in the Preneutralizer. The Preneutralizer is
much simpler to operate than the Pipe Reactor and when used in conjunction with the Pipe
Reactor it gives the plant a stable baseline and increased controllability.
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Using a Preneutralizer reduces the amount of water that is vaporized in the Granulator by the
Pipe Reactor. If less water is vaporized in the Granulator then less air is needed to keep the gas
leaving the Granulator below the saturation point. For a 120 MT/hr. plant, the required airflow in
the Granulator when a Pipe Reactor and Preneutralizer are installed is 44,000 ACFM and when
there is only a Pipe Reactor present is 88,000 ACFM. This reduced airflow reduces the size of the
Granulator, Prescrubber, RG Scrubber, RG Fan, Scrubber Pump and the Tail Gas Scrubber and
Pump.
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e) Recycling Dedusting System Offgas to the Combustion Chamber
Recycling Dedusting system offgas to the Combustion Chamber takes the heat given off by the
DAP throughout the plant and reuses it in the Dryer. There are various dedusting pickup points
within a DAP plant which mainly come from the belt conveyors, screens, and elevators.
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Annual Requirement of Raw Materials and Utilities
Ammonia 231700 MT
No trade effluent generation from the proposed DAP/NPK plant. No solid waste will be generated.
Any spillage will be recycled and reused in the proposed plant. There will not be any additional
water drawl from the Mangalore City Corporation due to requirement of proposed project. The
marginal increase in the water requirement after the commissioning of DAP/NPK plant will be met
by effluent water recovery unit installed.
The basic raw materials for Poly carboxylate production are Methoxy Poly Ethylene Glycol
(MPEG / PEGM 2000) and Meth acrylic Acid. The overall chemical reactions involved in the above
mentioned (a) & (b) process steps are schematically shown in Figure 7A and 7B below
MPEG-MAA
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MPEG-MAA
Evocating
Chain transfer agent
Agent Reactor
Polycarboxylate
superplasticizer
Finished Product
Steam
Product
Condensate Tank
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6.2) Salient Features Poly Carboxyl Ether Project
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7. ENVIRONMENTAL MANAGEMENT
There is no additional liquid effluent generation from the plant. The plant will remain zero liquid
effluent discharge plant.
It is proposed to replace the present low pressure stripper with medium pressure (MP) stripper
which will ensure removal of Ammonia from process condensate. The gases from the MP stripper
will be carried by the steam going to primary reformer and hence not let out.
The quantity of effluent generated in the plant shall reduce due to lower steam to carbon ratio in
the plant. This effluent shall be treated in the existing effluent treatment facility and recycled back
to the system as cooling tower make up.
There will not be any significant increase in pollution load after expansion of Urea plant capacity.
The emission of Particulate matter from the urea prill tower will be about 110 mg/Nm3 which is
well within standard of 150 mg/Nm³.
Net quantity of treated water generated from urea hydrolyser will reduce even there is a increase
in production. This will be achieved due to lower effluent generation in Ammonia plant. The
treated water will continued to be used as make up water in cooling tower.
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urea gets hydrolyzed to ammonia and carbon dioxide. Ammonia thus produced is separated in
the second desorption column. The liquid outlet of second desorption column contains less than
10 ppm of ammonia and urea. The ammonia vapours from the second desorption column is fed
to the first desorber. The desorber overhead vapours are condensed in a condenser and reused
in Urea plant. The treated effluent from urea hydrolyser stripper is reused as cooling tower
makeup water.
Static mixer, Lamella clarifier, centrifuge and sand filter are major equipment for treating the high
suspended solids effluent streams. Back wash water of sand filter and activated carbon filter
from water treatment plant and cooling 'tower side stream filter are treated in this unit. The
treated water is reused in cooling tower as makeup. The slurry containing solids is pumped to a
centrifuge for separating liquid which is recycled to static mixer. The thickened slurry is used in
DAP plant.
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2. Water treatment plant resin regeneration and cooling tower blow down effluents
containing high dissolved solids is treated by Reverse Osmosis technology.
The high dissolved solids effluent stream containing water treatment plant resin regeneration
effluent and cooling 'tower blow down is passed through clarifier, pressure sand filter and Ultra
Filtration (UF) units to remove suspended solids and colloidal particles. Then it is treated in
Reverse Osmosis (RO) units to remove dissolved solids. Treated water is reused in cooling tower
as makeup.
The high dissolved solids effluent streams are collected in an equalization tank. This stream after
dosing with NaOCI, Coagulant, Lime, Dolomite & Polymer is pumped to High Rate Solids Contact
Clarifier (HRSCC). The clarified water from HRSCC is passed through Multi Grade' filter for
reduction of suspended solids.
Then the filtered water is fed into the Ultra filtration unit (UF) to remove colloidal silica and related
colloids of iron and aluminum in water causing fouling, scaling and poor performance of the plane
the stream which is free from suspended and colloidal particles will be passed through Reverse
Osmosis unit (RO). The Dissolved solids are removed in 2 stages of RO unit. In the first stage R01
about 75 % of desired quality water will be recovered and reject is fed to second stage R02 wherein
further 10% is recovered. The R02 reject containing high dissolved solids is used in DAP plant.
The recovered water is used in cooling tower as makeup. The sludge collected in the HRSCC is
pumped to centrifuge to remove water. The separated liquid is recycled to equalizing tank and
thickened slurry is used in DAP plant.
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There will be no liquid waste and solid waste generation from the plant. All liquid spillages shall
be collected and recycled back to the process.
The flow of gaseous emission from the stack (3 no. 45 m each) is expected to be maximum of
720000 Nm³/hr., particulate Matter 50 mg/Nm³, fluorine 20 mg/Nm³ and Ammonia 150 mg/Nm³.
Since no liquid effluent and solid waste will be discharged from the plant there will not be any
significant adverse impact on the aquatic ecosystem. The vegetation and aquatic systems of the
area will be protected by adopting the above environmental protection measures.
There will be no liquid effluent generated in the plant. The spillages if any from the plant floor will
be collected in and recycled back to soil conditioners section.
There is no solid waste from the plant. The spillages if any from various points in the plant are
effectively collected and recycled back to the system.
MCF has put up a centralized sewage treatment unit. The combined sewage from the factory is
collected in the sump tanks and pumped to the bar screen chamber and oil trap to remove
floating solids and oil traces respectively. After this preliminary treatment the effluent is fed to
equalization tank.
Effluent from the equalization tank is fed to the Membrane Bio-Reactor (MBR) tank at constant
flow rate. The high amount of bacteria gives better and complete removal of organic matter from
the raw effluent in relatively small area. Aeration is done both to the equalization and MBR tanks
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through diffuser membranes by using blowers.
The suction pumps directly sucks permeate and the filtration is carried out by the membrane.
The suspended solids, turbidity, bacteria and viruses in permeate water are removed to the levels
required for reusing treated water. The treated water is reused in cooling tower as makeup.
By installation of the above wastewater treatment plants with latest technologies, MCF has
achieved the aim of reusing the entire treated wastewater and the target of zero wastewater
discharge.
9. Green Belt
MCF has already developed and maintained a green belt covering an area of about 64 acres.
The green belt contains around 63,000 trees of different species viz. Mangium, Casurina,
Subabul, Acacia, Gulmohar, Jack, Cashew, Mango, Banyan, Peepal, etc.
-------------------- x ---------------------
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