MID SEMESTER

ACADEMIC YEAR 2009/2010

Subject : Chemistry
Class/ Program : XII exact / 1
Day, Date : Wednesday, 14th October 2009
Time allocation : 07.30 – 09.30 (120 minutes)

I. OBJECTIVE TEST.
Choose the correct answer in the following question by give cross symbol (X) on
the alphabet A,B,C,D or E in the answer sheet!
1. The molality of 20% weight of NaOH ( 40 gram/mole) is …. Molal
a. 8,25 b. 7,25 c. 6,25 d. 5,25 e. 4,25

2. Among the solution below, the one that has the lowest freezing point is ….
a. CO(NH2)2 0,05 M c. BaCl2 0,03M e. Fe2(SO4)3 0,02M
b. NaCl 0,03M d. AlCl3 0,02M

3. Following a freezing point (Tf) data in various electrolyte and non electrolyte
solutions.
Solution Concentration Freezing point
Sugar 0,1 m -0,1860C
Urea 0,2 m -0,372oC
NaCl 0.1 m -0,372oC
MgSO4 0,2 m -0,744oC
K2SO4 0,1 m -0,588oC
Base on above data, it can be concluded that ….
a. electrolyte solution in equal concentration has equal freezing point
b. freezing point of solution is influenced by type of dissolved and solvent
substance.
c. Freezing point of electrolyte solution is higher than non electrolyte solution
d. The higher the substance concentration is the higher the freezing point
solution occurs.
e. In similar concentration, freezing point of electrolyte solution is lower point
than non electrolyte solution.

4. Into 600 grams of water 27 grams non electrolyte compound is dissolved. The
solution boils at temperature of 100,130C. If given that Kb of water = 0,520C/m,
the moleculer relative mass of the compound is ….
a. 60 b. 90 c. 120 d. 180 e. 342

5. Into 500 grams of water there is dissolved 40 grams Fe2(SO4)3(α=0,8). If Kb of

water =0,520C/m, the boiling point elevation of solution is ….
a. 0,3330C b. 0,3540C c. 0,4160C d. 0,4370C e. 0,4960C

6. A solution which is isotonic to KBr 0,3 M solution at the same temperature is ….

a. Na2SO4 0,3M c. K2CrO4 0,2M e. H2SO4 0,1M
b. (NH4)2SO4 0,1M d. Glukose 0,5M
7. A solution is obtained by dissolving 6 grams of urea (Mr=60) in 1 liter of water.
The other solution is obtained by dissolving 18 grams of glucose (Mr=180) in 1
liter of water. At the same temperature, the ratio of osmotic pressure of the first
solution to the second is ….
a. 1:3 b. 3:1 c. 2:3 d. 1:1 e. 3:2

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8. 7,2 grams of glucose (Mr=180) is dissolved in water until the volume is 40 mL. At
temperature of 270C, the osmotic pressure of the soution is ….(R=0,082
L.atm/mol.K)
a. 6,24 atm b. 3,18 atm c. 2,46 atm d. 0,82 atm e. 0,04 atm

9. As much as 17 grams of non lectrolyte X is dissolved in water until the volume is

1 L. At temperature of 270C, the osmotic pressure is 1,5 atm (R=0,082
L.atm/mol.K)
The moleculer relative mass of the substance X is ….
a. 278,8 b. 200,8 c. 190 d. 150 e. 125,5

10. How many grams of NaCl which must be dissolved in 100 grams of water in
order to the solution freezes at -20C (Kf water = 1,86oC/m)
a. 0,034 g b. 0,318g c. 1,075g d.. 2,925g e. 3,145g

11. As much as 5,85 grams of NaCl is dissolved in 100 mL water. If Kf of

water=1,86oC/m, the freezing point depression is ….
a. 0,0370C c. 0,1860C e. 3,720C
0 0
b. 0,074 C d. 0,372 C

12. Benzoic acid(Mr=122) of 12,2 grams is dissolved in 122 grams of ethanol causes a
boiling point elevation of 10C. The value of the mola boiling point elevation
constant (Kb) of the ethanol is ….
a. 2,240C/m b. 1,830C/m c. 1.710C/m d. 1,550C/m e. 1,220C/m

13. The solution of 0,1 moles of glucose, NaCl, and Na3PO4 each in 1 gram of water
are boiled. The correc expression if the boiling point elevation of those solutions
compared with Na2SO4, solution for equal in concentration is ….
a. ∆Tb Na2SO4 = 3/2∆Tb NaCl
b. ∆Tb Na2SO4 = 4/3∆Tb Na3PO4
c. ∆Tb Na2SO4 = 1/3∆Tb C6H12O6
d. ∆Tb Na2SO4 = 2/3∆Tb NaCl
e. ∆Tb Na2SO4 = ∆Tb molal

14. 60 grams of urea (Mr=60) is dissolved in 72 grams of water (Mr=18).If the vapor
pressure of pure water at 20o C is 22,5 mmHg, the vapor pressure of solution at
that temperature is ….
a. 4,5 mmHg
b. 9 mmHg
c. 18 mmHg
d. 22,5 mmHg
e. 19 mmHg

15. If the vapor pressure of water at 29oC is 27 mmHg, the vapor pressure of
solution of 30 grams of urea (Mr=60) in 81 grams of water (Mr=18) at that
temperature is ….
a. 4 mmHg
b. 6 mmHg
c. 11 mmHg
d. 24 mmHg
e. 36 mmHg
16. Among of these five solutions having the lowest boiling point is ….
a. C6H12O6 0,03M
b. Mg(NO3)2 0,02M
c. NaCl 0,02M
d. Al2(SO4)3 0,01M
e. KAl(SO4)2 0,03M

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17. If 10 grams of each substance below is dissolved in 1 kg of water, the substance
giving a solution the freezing point of which is the lowest is ….
a. ethanol C2H5OH
b. glyserin, C3H8O3
c. glucose, C6H12O6
d. methanol, CH3OH
e. urea, CO(NH2)2

18. A glucose solution in water bois at 100,26oC. If Kb= 0,52oC/m and Kf =1,860C/m
the solution will freeze at ….
a. 1,860C b. 0,93oC c. 0oC d. -0,93oC e. -1,860C

19. 3,1 grams of glycol (C2H6O2) is dissolved in 250 grams of water and mixed with
17,1 grams of sucrose (C12H22O11) in 500 grams of water. If given that Kf of water
= 1,860C/m. (Ar H=1, O=16, C=12). The freezing point of solution produced is ….
a. +0,372oC b. +0,248oC c. 0,186oC d. -0,248oC e. -0,372oC

20. An anorganik substance of 0,645 grams disssolced in 50 grams CCl4, gives ∆Tb
=0,645oC. If Kb of solvent =5,03 , the moleculer relative mass of the substance is
….
a. 100 b. 90 c. 80 d. 70 e. 50

21. Diagram below shown pressure diagram (P) and temperature diagram (T) of
glucose solution 0,01M and glucose solution 0,015M. that shown line of boiling
point of glucose solution 0,015M is ….
L DA C F M a. L-M
Atm cair b. E-M
c. E-F
B d. G-H
E e. O-M
Padat O gas

KG H I J N T(oC)

21. Equation below classify in to redox equation .....

a. 2HCl + Ca(OH) 2 → CaCl2 + 2H2O
b. CaCO3 + 2HCl → CaCl2 +CO2 + H2O
c. 2N2O5 →2NO2 + 3O2
d. C2H4O + H2O2 →C2H4O2 + H2O
e. C12H22O11 + H2O → 2C6H22O6
22. Amount Fe2+ ionic are needed to oxidation 1 mole Cr2O72- become Fe3+ andCr3+
is…
a. 1 mole b. 2 mole c.3 mole d. 4 mole e. 6 mole
23. The change oxidation number of nitrogen in this reaction:
CuS + NO3- →Cu2+ + S + NO is…..
a. -3 b. +3 c.-2 d. +2 e.+5
24. In reaction below:
CrCl3 + KOH + Cl2 → K2CrO4 + KIO4 + KCl + H2O
The specie as oxidator in this reaction is…..
a. CrCl3 b. KOH c. Cl2 d. K2CrO4 e.KIO4

25. Potential electrode Al3+ + 3e→ Al E0 =-1,66 volt

Co2+ +2e → Co E0 = -0,28 volt

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 Calculate E sell from reaction Al + CoCl2 → Co + AlCl3 are….
a. 1,10 V b. 1,38V c. 1,94V d. 2,20V e. 2,28V

26. In reaction Zn2+ +2e →Zn E0 =-0,76 Volt

Fe2+ + 2e → Fe E0 = -0,44V Sn2+ +2e → Sn E0 = -0,14 V
2+ 0
Ni + 2e → Ni E = -0,28 V Cu2+ + 2e → Cu E0 = +0,34 V
CuSO4 solution can be entered in this place which are made from ….
a. Zn b.Fe c. Ni d. Sn e. Cu

27. 30 cm3 of on 0,1M solution of a stable cation of an element Q react exactly with
12cm3 of 0,1M acidified potassium manganate(VII).
MnO4- + 8H+ + 5e → Mn2+ + 4 H2O
Which one of the following equations could represent the change in oxidation of
Q correctly?
a. Q+ → Q2+
b. Q+ → Q3+
c. Q+ → Q4+
d. Q2+ → Q3+
e. Q4+ → Q2+

Voltmeter
V
28. Mg o Zn
l
t
m
Salt
e
bridge
t
e
r
MgSO4(aq) ZnSO4(aq)
1,0 M 1,0 M
In The electrochemical cell shown above ….
a. The reaction at the zinc electrode is Zn → Zn2+ + 2e
b. Electrons flow through the wire from the zinc to the magnesium electrode
c. A tiny current flows even when the salt bridge is removed
d. Magnesium ions migrate into the salt bridge
e. The concentration of Mg2+ ions will decrease in the left-hand beaker

29. 0,01 moles of a compound K2XO4 will just oxidize 0,04 moles of Fe2+ to Fe3+.
The final oxidation state of X is therefore….
a. +6 b. +5 c. +4 d. +3 e. +2

30. The standard electrode potential for the metals L and M :

L2+(aq) + 2e → L(s) E0 = +0,40 V
M2+(aq) + 2e → M(s) E0 = -0,60 V
Salt bridge

L(s) M(s)

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 L2+(aq) 1M M2+(aq) 1M
Metals L and M were combined together to make the cell shown in the diagram.
Which one of the following correctly describes the cell?
Electrode at which positive cell voltage(V)
Ions enter the solution
a. L 0,2
b. M 0,2
c. M 1,0
d L 1,0
e. M 1,4

31. Aqueous copper (II) sulphate was electrolysed using different electrodes as
shown in the diagram below.
II II II II II

+ - + - + - + - + -
C Pt C Cu Pt Cu
Cu Cu Pt Pt

A B C D E
In which experiment, did the concentration of aqueous copper(II) sulphate
remain Constant….
a. A b. B c. C d. D e. E

32. The table below shows some results of electrolysis experiment

Electrolyte anode cathode Product anode Product

cathode
Aqueous Carbon Platinum X Hydrogen
sodium
chloride
Aqueous copper copper Anode dissolves in Y
copper(II) the solution
sulphate
Which one of following would complete the above table?
X Y
a. chlorine copper
b. chlorine oxygen
c. oxygen copper
d. sodium copper
e. sodium oxygen

Questions 33 to 34 refer to the table of standard redox potentials below.

E0(Volt)
Ce3+ (aq) + 3e → Ce(s) -2,33
Th4+ + 4e → Th(s) - 1,90
2+
Ni + 2e → Ni(s) - 0,25
Cu2+ + 2e → Cu(s) + 0,34

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 Tl3+ + 2e → Tl+(aq) + 1,25

33. Which of the following species is the most powerful reducing agent?
a. Ce3+ b. Ni2+ c. Tl3+ d. Th4+ e. Cu2+

34. The potential cell between electrodes connecting the two standard half-cells
Pt(s)/ Ti+(aq),Ti3+(aq) and Ni(s)/Ni2+(aq) is ….
a. 2,00 V b. 1,50 V c. 1,00 V d. 0,75 V e. 0,50 V

35. A car accumulator has Pb and PbO2 electrode, when the accumulator works, the
changes that occur are ….
a. Pb becomes PbSO4, whereas PbO2 remains the same
b. Pb becomes PbO2, whereas PbO2 become Pb3O4
c. Pb and PbO2 become PbSO4
d. Pb becomes Pb3O4, whereas PbO2 become PbO
e. Pb and PbO2 become PbO

36. We have redox reaction equation :

a Cr2O72- + b H+ + c Cl- → d Cr3+ + eH2O + f Cl2
Reaction coefficienct value for a, b, and c respectively is ....
a. 1,2,4 b. 2,7,4 c. 1,2,2 d. 1,14,2 e. 1,14,6

37. The thallium ion, Tl3+(aq), oxidizes iodide ions according to the half-
equation :
I-(aq) → ½ I2 + e-
In an experiment 0,2 mole of Ti3+ reacts with 200 cm3 0f 2M KI solution. What is
The oxidation number of thallium at the end of reaction?
a. +5 b. +4 c. +3 d. +1 e. 0

38. In which of following reactions does the oxidation state (number) of nitrogen
show the greatest increase ?
a. NH3(g) + HCl(g) → NH4Cl(s)
b. 2NH3(g) + 3CuO(s) → N2(g) + 3Cu(s) + 3H2O(l)
c. 2NO(g) + O2(g) → 2NO2(g)
d. 4NO2(g) + O2(g) + 2H2O(l) → 4HNO3(l)
e. 2NO3-(aq) + Cu(s) +4H+(aq) → 2NO2(g) + Cu2+(aq) + 2H2O(l)

39. When the cell operates normally ….

a. electrons flow through the voltmeter from silver to chromium
b. the silver terminal is more negative than chromium
c. the concentration of Cr3+(aq) will fall
d. both positive and negative ions move through the salt bridge
e. reduction occurs at the chromium terminal

40. It is known Eo cell of the reaction redoks are follows :

A(s) + B2+(aq) → A2+(aq) + B(s) E0 = 0,32 volt
2C(s) + 3D2+(aq) → 2C2+(aq) + 3D(s) E0 = 2,00 volt
2+ 2+
D(s) + B (aq) → D (aq) + B(s) E0 = 0,32 volt
Reducing power sequence of metal ion the stronger to the weaker one
subsequently is....
a. A-B-C-D b. D-A-B-C c. C-A-B-D d. D-B-A-C e. B-D-A-C
Essay.

41. Pheromon is compound that female animal from some insect species releases to
attract male animal. This compound contains 80,78% C, 13,56% H, and 5,66%
O. A solution for 1 g of pheromon in 8,5 g benzena freezes at 3,370C. How is the

UTS CHEMISTRY XII IPA SEM 1 09/10 Page 6 of 7

 molecule formula and how much is this compound molar mass? (freezing point
of pure benzene is 5,50C)

42. A solution is obatained by dissolving 17 g of NaCl in 250 g of water at certain

temperature. Vapour pressure drop from 19,76 atm into 19,00 atm. Calculate the
ionization degree of NaCl.

43. An acid solution HxA has mole fraction 0,05 and vapor pressure 25 mmHg at
temperature 28oC. If at the temperature the vapor pressure of pure water is
28mHg, so the value of X and the ionisation degree (α) of HxA is ….

44. Ni-Cd (Nicad) battery is mostly used for portable devices such as electric source
of wireless device, cellular phone (HP), handy cam, laptop, and still many others.
Nicad battery is relative cheap and durable. This battery needs no maintenance
cost and can be refilled until 2.000 times. Nicad cell contains the following two
and half cells:
Cd(OH)2(s) + 2e → Cd(s) + 2OH- E0 = -0,809 V
2NiO(OH)(s) + 2H2O + 2e → 2Ni(OH)2(s) +2OH- E0 = +0,490 V
a. Which does reaction occur at cathode
b. Which does reaction occur at anode
c. Write down the propotional equation that indicates spontaneous reaction
occuring when cell is used.
d. Calculate value E0 cell at 250C temperature.

45. In the electrolysis to CuSO4 solution by using the electrode C as anode, and
Cu as cathode, determine the redoxs reactions at the anode and cathode.

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