Beruflich Dokumente
Kultur Dokumente
h i g h l i g h t s
< We prepared MWCNTs nano-coating and applied to heat dissipation for projection lamp.
< The temperature, power consuming and illumination of the fixture were evaluated.
< The internal temperature of the fixture adopting halogen lamps reduces 5.4% at most.
< The internal temperature of the fixture adopting LED lamps reduces 3.2% at most.
< The power consumption reduces 12.9% at most for LED lamps with MWCNTs nano-coating.
a r t i c l e i n f o a b s t r a c t
Article history: In this study, we used two-step synthesis method to prepare nano-coating containing multi-walled
Received 17 March 2012 carbon nanotubes (MWCNTs) of different concentrations and applied the MWCNTs to heat dissipation
Accepted 7 November 2012 for the projection lamp fixtures. We quantitatively coated the nano-coating on the inner surface of the
Available online 15 November 2012
housing of the fixture and evaluated its effects on the internal temperature, power consumption, and
luminous output of the fixture for different conditions. The results show that both concentration of the
Keywords:
MWCNT nano-coating and the projecting angle of the fixture affect the internal temperature and power
Heat dissipation
consumption. With the MWCNT nano-coating of concentration at 1.328 wt.% and the projecting angle of
Illumination
Multi-walled carbon nanotubes
0 , the internal temperature of the fixture adopting the halogen lamp and that adopting the LED lamp
Nano-coating reduce 5.4% 2.1% and 3.2% 2.1% at most, respectively; the power consumption reduces 12.9% 2.1% at
Power consumption most for the LED lamp; the luminous output has no significant difference for either the halogen or LED
lamp. This study demonstrates MWCNT Nano-coating has great feasibility for heat dissipation of the
lighting fixture. Further, this concept can also be applied to the cases requiring non-contact heat dissi-
pation. Therefore, this study can widely contributes to energy saving and carbon emission reduction.
Ó 2012 Elsevier Ltd. All rights reserved.
1359-4311/$ e see front matter Ó 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.applthermaleng.2012.11.006
T.-P. Teng, T.-C. Teng / Applied Thermal Engineering 51 (2013) 1098e1106 1099
Nomenclature Subscripts
a ambient
$
q heat flux, W bs back surface
A area, m2 c convection
h heat transfer coefficient, W/m2 C ex external
Int intensity, counts i inner
k thermal conductivity, W/m C in internal
L thickness, m o outer
lx illumination, lx r radiation
pc power consumption, W T total
R thermal resistance, C/W or ratio w wall
Rs reflection, %
T temperature, C
Experimental results indicated that at least up to 20% of the thermal a good suspension performance for a long period, the dispersants
conductivity as compared with the base fluid. Garg et al. [4] reported that generally have low thermal conductivity wrap the nano-
the enhancement of thermal conductivity about 3%e5% at 25 C for particles to lead increase of the contact resistance on the solide
the MWCNT nanofluid of 1.0 wt.% that was ultrasonicated for 20e liquid interface. Therefore, overdosing surfactant or dispersant
80 min. Chen et al. [5] prepared the MWCNT/ethylene glycol nano- will decrease the thermal conductivity of nanofluids.
fluid of 1.0 vol.% by a wetemechanical reaction without using From the above literature we can realize the CNTs can improve
surfactant or dispersant. The thermal conductivity of the MWCNT/ heat transfer in either the fluid or solid state if it is well dispersed. In
ethylene glycol nanofluid was 17.5% higher than the base fluid. Chen this study we tried to apply MWCNTs to heat dissipation for another
and Xie [6] adopted the wetemechanochemical reaction method to important practical case–lighting fixtures because of eco-
produce the single, double-walled carbon nanotubes (SWCNTs and consciousness. Recently, energy saving and carbon emission reduc-
DWCNTs) and MWCNTs. The enhancement of thermal conductivity tion is a very important topic. So-called ‘energy saving and carbon
was 15.6%, 14.2%, and 12.1% for the SWCNTs, DWCNTs, and MWCNTs emission reduction’ focuses on how to efficiently utilize energy, use
at 0.2 vol.%, respectively. Phuoc et al. [7] adopted the cationic chi- less fossil energy, and reduce carbon emission. In addition, energy
tosan as a dispersant to stabilize the MWCNT/water nanofluid. The saving and carbon emission reduction should also include extending
thermal conductivity was enhanced from 2.3% to 13% for the nano- the product lifetime to reduce the wasted material. The lighting
fluid containing the MWCNTs at 0.5 wt.% to 3 wt.%. industry is one of the world’s great industrial sectors. It sells annually
Although most research has demonstrated that the nanofluid about 20 billion lamps of the three major types: incandescent lamp,
containing CNTs has enhancement of the thermal conductivity as fluorescent lamp, and high intensity discharge lamp. Operating
compared with the base fluid, the effect of CNTs on coating needs to those lamps is estimated currently to consume over 2700 TW-h
be further studied. When the coating material containing nano- (nearly 20% of total global electricity production, or approximately
particles (called ‘nano-coating’ hereafter) is dried to become the 3% of total energy consumption) and thus to produce about 2000
solid state, some mechanisms that enhance the thermal conduc- Megatons of CO2 emission [25]. Therefore, how to improve luminous
tivity through the particle motion will disappear. Some studies efficiency to reduce lighting energy consumption is a very important
demonstrated that adding CNTs in solid materials could enhance the task. Regarding the above concern, the light emitting diode (LED)
thermal conductivity of the base material [8,10,12,15], in which lighting is expected as a potential replacement for the traditional
Biercuk et al. [12] pointed that adding 1 vol.% SWCNTs to epoxy could lamp (especially for the incandescent lamp) due to its advantages
improve its thermal conductivity up to 125%. In contrast, some such as long lifetime, energy efficiency, wide range of colors, low-
studies showed that adding CNTs into the solid materials did not voltage power supply, and environmental compatibility [26,27].
enhance the thermal conductivity of the base materials [11,16,17]. Particularly, the development of LED technology has driven effi-
The main reasons are due to some factors such as interface thermal ciency and luminous output of LED to rise exponentially. For
resistance between the base materials and CNTs, increased porosity, example, a laboratory prototype LED achieving 208 lumens per watt
inhomogeneous distribution, agglomeration of CNTs, and incom- at room temperature was also announced in 2010 [28,29]. Therefore,
plete consolidation processing [11]. Therefore, the nanoparticles LED has prospect of providing the majority of light sources by 2035
must be uniformly dispersed into coating liquid, and the coating film [30]. Despite the above advantages of LED, LED still has the serious
after drying must be closely integrated with the coating substrate. problem that efficiency and lifetime falls sharply with heat rising to
Generally, the ultrasonic vibrator, electromagnetic stirrer, be resolved [31,32]. So, how to manage heat dissipation for LED is
homogenizer, and other physical dispersion are most commonly a study-worthy topic; consequently many related researches have
used to mix nano-materials into base fluid for better suspension been proposed [33e37]. In this study we selected a projection lamp
[4,18,19]. However, it is difficult for these physical dispersion fixture as the experiment subject, and this fixture can adopt either
methods to resolve agglomeration problem resulted from the van the LED lamp or halogen lamp. We coated the inner housing wall of
der Waals interaction forces, non-reactive surface properties, very the fixture with the MWCNT nano-coating to improve its heat
large specific surface areas, and aspect ratios of CNTs [7,20e22]. dissipation and then investigated the effect on both the internal
Therefore, many researchers add the surfactant or dispersant in temperature and power consumption of the fixture that adopted the
order to improve dispersion in nanofluids. The commonly used LED lamp. In addition, since the traditional light sources still play
dispersant contains nitric/sulfuric acid mixture, potassium a role in the immediate future through developments in the design
hydroxide group [5,23], and various surfactants such as sodium and control of lighting installations to provide substantial energy
dodecylbenzene sulphonate (SDBS), sodium dodecyl sulfate (SDS), saving opportunities [38], the projection lamp fixture adopting
and gum Arabic (GA) [18,24]. Although adding dispersants can halogen lamps was also tested as comparison group in this
improve dispersion of nano-materials in the base fluid to maintain experiment.
1100 T.-P. Teng, T.-C. Teng / Applied Thermal Engineering 51 (2013) 1098e1106
2. Theories for heat transfer value, T2 closer to T1 represents the lower total thermal resistance
between space A and B.
Fig. 1 shows the heat transfer process from space A to B based on According to the above-mentioned concept of heat transfer,
$
the concept of steady-state heat transfer, the heat flux (ðqT Þ) can be reducing the thermal resistance can increase the heat transfer
expressed as: performance. The thermal resistance of radiation is mainly deter-
mined by both the shape factor and surface optical properties of
$
qT ¼ hT AðT1 T2 Þ ¼ ðT1 T2 Þ=RT ; (1) materials; the thermal resistance of convection depends mainly on
both the airflow rate and surface properties; thermal conductivity
where hT is total heat transfer coefficient; A is area of heat transfer; is determined by the thermal conductivity of the material itself.
T is temperature; RT is total thermal resistance; the subscripts 1 and Therefore, using the higher absorption coating or anti-reflective
2 refer to space A and B, respectively. In the process of heat transfer, structure on the wall can reduce the thermal resistance of radia-
the relationship of heat transfer coefficient (h) and the thermal tion; increasing the airflow vents can reduce the convective
resistance (R) in the conduction, convection, and radiation are thermal resistance; using the material with high thermal conduc-
sequentially expressed as: tivity to make the wall can effectively reduce the thermal resistance
of heat conduction. Similarly, coating a film containing the
Rw ¼ ð1=hw AÞ ¼ ðL=kAÞ; (2) MWCNTs that has both high thermal conductivity and high optical
absorption properties on the either inner or outer surface of
Rc ¼ ð1=hc AÞ; (3) a closed or semi-enclosed lampshade can also both enhance the
heat dissipation performance of the lighting fixture and extend
lifetime of the lamp.
Rr ¼ ð1=hr AÞ; (4)
where the subscripts w, c, and r refer to conduction, convection, 3. Preparation of MWCNT nano-coating and experimental
and radiation, respectively. design
The convection and radiation occur simultaneously at a surface,
and both the thermal resistance of convection and radiation can be 3.1. Preparation of test samples
combined into a single thermal resistance. The total thermal
resistance based on the concept of electrical series and parallel Fig. 2 and Fig. 3 are the photographs of Multi-walled carbon
resistance can be expressed as follows: nanotubes (MWCNTs, Cheap Tubes Inc.) through the high-
resolution field emission scanning electron microscope (HR-
RT ¼ R1;c ==R1;r þ Rw þ R2;c ==R2;r : (5) FESEM, S4800, Hitachi) and transmission electron microscope
(TEM, H-7100, Hitachi), respectively. According to the specification
The heat flux is constant when the heat transfer from space A to provided by the manufacturer, the MWCNTs have an outside
B under steady state conditions, and then the Eq. (1) can be diameter of 20e30 nm, inside diameter of 5e10 nm, length of 10e
rewritten as follows: 30 mm, average density of 2.1 g/cm3, and thermal conductivity of
$ about 300e400 W/mK. As we can see from those figures, the
qT ¼ ðT1 Ts1 Þ= R1;c ==R1;r ¼ ½ðTs1 Ts2 Þ=Rw MWCNTs aggregate, and their primary outside diameter is
¼ ðTs2 T2 Þ= R2;c ==R2;r : (6) approximately in line with the specification.
We used the MWCNTs/water nanofluid produced by two-step
In the Eq. (6), we can find that the smaller temperature differ- synthesis method as the dilute liquid. First, we added 0.2 wt.% of
ence represents the lower thermal resistance of the interface when cationic dispersant (water-soluble chitosan) into distilled water as
the heat flux is constant. In contrast, when T1 keeps at a constant the base liquid in order to obtain good dispersion performance for
the MWCNTs/water nanofluid. Chitosan is widely used in medicine,
agriculture, chemical, and food processing areas without causing
Fig. 1. The diagram of heat transfer process. Fig. 2. HR-FESEM images of MWCNTs.
T.-P. Teng, T.-C. Teng / Applied Thermal Engineering 51 (2013) 1098e1106 1101
(80 80 0.3 mm) to form the sample 2, 3, and 4 under the spray
pressure at 2.0 kg/cm2. After each spraying process was finished,
the samples were dried in an oven for 3 h at 50 C. We measured
the thickness of the coating films on the samples by thickness
meter (LZ-370, KETT) at accuracy of 2%, and the thickness
measured 70 5 mm. We also measured reflection spectra of each
sample by VIS-NIR spectrometer (BRC112E, B&W) at a resolution
of 2 nm.
Table 1
Preparation parameters of MWCNTs nano-coating.
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
um;pc ¼ ðDpc=pcÞ2 þðDTa =Ta Þ2 (8)
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
um;T ¼ ðDT=TÞ2 þðDTa =Ta Þ2 (9)
Fig. 5. The structure of projection lamp fixture at different projecting angle. (a) 90 ,
(b) 0 . The accuracy of the illuminometer is within 3.0%. The accuracy
of the digital power meter is within 0.35%. The accuracy of the
First, we turned on the three fixtures with a halogen lamp (Decostar thermocouple for internal and external temperature of the
51/50W/12V/38deg., OSRAM) for 70 min as background experi- projection lamp is within 0.1 C. The accuracy of the temperature
ment, and then replaced the lamp with a LED lamp (MR-16/3.5W/ controller of DC inverter air conditioner for ambient temperature is
12V/50deg., China Electric mfg. Corporation) for the same back- within 0.5 C. Therefore, the uncertainty of the illumination,
ground experiment. The temperature data were averages of the power consumption, and temperature experiment is within 3.6%,
data measured in the last 10 min of the background experiment. 2.1%, and 2.1%, respectively.
When the illuminating time reached 60 min, we started to measure
both the illumination and power consumption of each fixture by an 3.4. Data analysis
illuminometer (TES-1336A, TES) with accuracy of 3.0% and
a digital power meter (WT230, Yokogawa) with accuracy of 0.35% The measurement data of heat dissipation performance, illu-
for different lighting sources (halogen lamps and LED lamps) and mination, and power consumption for the lamp fixture with
projecting angles (0 and 90 ) in order to obtain the differences in uncoated housing are referred as baseline values (Db), and the
power consumption and illumination on the surface at a fixed measurement data for the lamp fixture with housing coated by
distance below the fixture. The data of illumination and power paint containing the MWCNTs are marked as Dc. For explicit
consumption were averages of the ten measurements with an investigation, the experimental data Dc were compared with Db.
interval of 1 min during the last 10 min in the experiment. Next, the The differences between Dc and Db are presented as proportions (R)
inner surfaces of the cylindrical housing of the three fixtures were and are expressed as follows:
coated with the paint containing the MWCNTs of three different
concentrations at 0.332, 0.664, and 1.328 wt.%, respectively. In
R ¼ ðDc =Db Þ 100%: (10)
order to obtain the uniform coating on the inner surface and reduce
the thickness differences between the samples, we fixed the
cylindrical housing horizontally and concentrically at a motor shaft 4. Results and discussion
to let the housing rotate at 600 rpm for 20 min to make the coated
paint dry and uniform after the paint was quantitatively brush Fig. 6 shows the reflection spectra of the samples. The sample 1
(1.0 ml) by quantitative dropper and rubber spatula. Then, the is bare galvanized steel plate without coating, sample 2e4 are
samples were dried in the oven at 50 C. Next, we conducted the coated by the paint containing the MWCNTs of 0.332, 0.664, and
heat dissipation experiment on the projection lamp fixtures whose 1.328 wt.%, respectively. In the Fig. 6, we can find that adding
T.-P. Teng, T.-C. Teng / Applied Thermal Engineering 51 (2013) 1098e1106 1103
Fig. 6. Reflection spectra of the test samples. Fig. 8. Internal temperature trends of halogen lamp at different projecting angles.
the MWCNTs can reduce the reflectivity within UVeNIR band because the MWCNTs have both excellent optical absorption and
(350e950 nm), and the reflectivity decreases with increase in high thermal conductivity (about 300e400 W/mK) to reduce
concentration of the MWCNTs. This phenomenon is mainly because thermal resistance in both radiation and conduction. As seen from
the MWCNTs have excellent optical absorption within UVeNIR Fig. 6, MWCNT nano-coating has high optical absorption such that
band. However, when concentration of the MWCNTs exceed the thermal resistance in radiation can be reduced. Further, because
above 0.664 wt.%, there is no significant difference in reflectivity the overall thermal conductivity of the mixture depends on the
because absorption reaches saturation. thermal conductivity of each ingredient, adding the material with
Fig. 7 shows the heat transfer performance of the samples. In high thermal conductivity into the bulk material can increase the
Fig. 7, we can find that adding the MWCNTs can increase the overall thermal conductivity [39,40]. Therefore, the total thermal
temperature of the back surface of the sample, and the temperature resistance also reduces when the thermal resistance decreases in
increases with increase in concentration of the MWCNTs. For the both radiation and heat conduction.
same heating temperature of the hot plate, the higher back surface Fig. 8 and Fig. 10 show the temperature of the lamp socket
temperature means that there is greater heat flux through the (called ‘internal temperature’ hereafter) of the lamp fixtures at
sample, and the sample has lower thermal resistance; consequently different projecting angle in the background test, and the related
providing better heat dissipation. This phenomenon is mainly data can be referred to Table 2. Figs. 9 and 11 show the temperature
Fig. 7. Heat transfer performance of the samples. Fig. 9. External temperature trends of halogen lamp at different projecting angles.
1104 T.-P. Teng, T.-C. Teng / Applied Thermal Engineering 51 (2013) 1098e1106
Table 2
Experimental results of initial condition for baseline.
Fig. 11. External temperature trends of LED lamp at different projecting angles.
during the experiment. Since the filament temperature was not Fig. 13. Power consumption ratio of fixtures at different projecting angles.
affected in the experiment, the power consumption does not
change. In contrast, for the LED lamp, Fig. 13 shows the MWCNT
nano-coating has some effect on the power consumption. Espe- can also reduce the junction temperature of LED chip. Further, since
cially for the higher concentration of the MWCNT nano-coating, the LED needs DC electricity power, the related rectifier electronics are
power consumption reduces 12.9% 2.1% at most. It is mainly due integrated on the bottom of the LED lamp. Thus, lower temperature
to both the characteristic of LED chip and rectifier electronics of the lamp socket also can reduce the power consumption and
integrated in the LED lamp. The junction temperature quite impacts benefit the lifetime of the electronics. Based on the above reasons,
the luminous efficiency and lifetime of the LED chip; the luminous the MWCNT nano-coating has more obvious effect on power
efficiency and lifetime exponentially decreases as the junction consumption of the LED lamps.
temperature increases. Because LED is a ‘cold light’ source, the most Similarly, in order to investigate the effects of the MWCNT nano-
heat generated from the LED chip is conducted out through the coating on the illumination, the illumination of each fixture with
substrate. Thus, cooling down the temperature of the lamp socket coated housing is compared with that of the same fixture before its
Fig. 12. Internal temperature ratio of fixtures at different projecting angles. Fig. 14. Illumination ratio of fixtures at different projecting angles.
1106 T.-P. Teng, T.-C. Teng / Applied Thermal Engineering 51 (2013) 1098e1106
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