Coordinated Science Revision

Moles

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Key points:
1. The mole is a large number: 6.02 x 1023

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m
2. n=
M

3.

4. 1 mol of any gas is 24L

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Steps to solve Stoichiometry:
1. Mass to moles of A
2. A:B
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3. Moles to mass of B
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1. Molar mass

Find the molar masses of the following compounds:

1) NaBr

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2) PbSO4

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3) Ca(OH)2

4) Na3PO4

5) (NH4)2CO3
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6) C6H12O6

7) Fe3(PO4)2
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8) (NH4)2S

9) Zn(C2H3O2)2
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10) AgF
2. Mole calculations

Answer the following questions:

1) How many moles are in 25 grams of water?

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2) How many grams are in 4.5 moles of Li2O?

3)
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How many molecules are in 23 moles of oxygen?
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4) How many moles are in 3.4 x 1023 molecules of H2SO4?
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5) How many molecules are in 25 grams of NH3?

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6) How many grams are in 8.2 x 1022 molecules of N2I6?

3. More mole calculations

1) How many grams does 0.500 moles of CuBr weigh?

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2) How many molecules are there in 0.655 moles of C6H14?

3)
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How many moles are there in 2.35 x 1024 molecules of water?
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4) How many grams does 5.60 x 1022 molecules of SiO2 weigh?
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5) How many molecules are there in 21.6 grams of CH4?

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4. Stoichiometry

Solve the following stoichiometry grams-grams problems:

1) Using the following equation:

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2 NaOH + H2SO4
2 H2O + Na2SO4

How many grams of sodium sulfate will be formed if you start with 200 grams of
sodium hydroxide and you have an excess of sulfuric acid?

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2) Using the following equation:

Pb(SO4)2 + 4 LiNO3
Pb(NO3)4 + 2 Li2SO4

How many grams of lithium nitrate will be needed to make 250 grams of lithium
sulfate, assuming that you have an adequate amount of lead (IV) sulfate to do
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the reaction?
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5. Solutions

For the questions on this worksheet, consider the following equation:

Ca(OH)2(s) + 2 HCl(aq)
CaCl2(aq) + 2 H2O(l)

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1) What type of chemical reaction is taking place? _____________________

2) How many liters of 0.100 M HCl would be required to react completely with 5.00 grams
of calcium hydroxide?

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3)
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If I combined 15.0 grams of calcium hydroxide with 75.0 mL of 0.500 M HCl, how many
grams of calcium chloride would be formed?
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4) What is the limiting reagent from the reaction in problem #3? __________

5) How many grams of the excess reagent will be left over after the reaction in problem 3
is complete?
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6. Gases

For all of these problems, assume that the reactions are being performed at a pressure of 1.0
atm and a temperature of 298 K.

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1) Calcium carbonate decomposes at high temperatures to form carbon dioxide and
calcium oxide:

CaCO3(s)
CO2(g) + CaO(s)

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How many grams of calcium carbonate will I need to form 3.45 liters of carbon dioxide?

2) Ethylene burns in oxygen to form carbon dioxide and water vapor:

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C2H4(g) + 3 O2(g)
2 CO2(g) + 2 H2O(g)

How many liters of water can be formed if 1.25 liters of ethylene are consumed in this
reaction?
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3) When chlorine is added to acetylene, 1,1,2,2-tetrachloroethane is formed:

2 Cl2(g) + C2H2(g)
C2H2Cl4(l)

How many liters of chlorine will be needed to make 75.0 grams of C2H2Cl4?
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ANSWERS:

1. Molar mass 2. Mole calculations

1) 102.9 g/mol 1) 1.39 moles
2) 303.3 g/mol 2) 134.1 grams

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3) 74.1 g/mol 3) 1.38 x 1025 molecules
4) 164.0 g/mol 4) 0.56 moles
5) 96.0 g/mol 5) 8.85 x 1023 molecules
6) 180.0 g/mol 6) 106.7 grams
7) 357.4 g/mol

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8) 68.1 g/mol 3. More mole calculations
9) 183.4 g/mol 1) 71.75 grams
10) 126.9 g/mol 2) 3.94 x 1023 molecules
3) 3.90 moles
4) 5.59 grams
5) 8.13 x 1023 molecules

4. Stoichiometry
1)
2)
355.3 grams of Na2SO4
313.6 grams of LiNO3

5. Solutions
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1) acid-base reaction
2) 2HCl + Ca(OH)2
CaCl2 + 2H2O
n(Ca(OH)2) = m/M = 5g/74g/mol = 0.0676 moles
2 mol HCl : 1 mol Ca(OH)2
x mol HCl : 0.0676 mol Ca(OH)2
Therefore x = 2 x 0.0877 = 0.135 mol Ca(OH)2
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C=n/V
0.100M = 0.135mol / V
V = 1.35L
Therefore it would take 1.35L of 0.1M HCl to neutralize 5g of Ca(OH)2
3) 2.08 grams
4) HCl
5) 13.6 grams of Ca(OH)2
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6. Gases
1) 14.1 grams
2) 2.50 liters
3) 21.8 L