Beruflich Dokumente
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for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D1835 − 18
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Residual matter:G
One of the following requirements shall be met:
(1) Residue on evaporation of 100 mL, mL, max, 0.05 0.05 0.05 0.05 D2158I
and
Oil stain observation passH passH passH passH D2158I
or
(2) Residue by gas chromatography, mg/kg, max 350 350 350 350 D7756
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J J J
Density at 15 °C or relative density at 15.6/ ... D1657 or D2598
15.6 °C (60/60 °F)
Sulfur, mg/kg (ppm by mass), max 185L 140L 140L 123L D6667
M M
Free water content ... none none ... ...
A
Equivalent to Propane HD-5 of GPA Standard 2140.
B
The permissible vapor pressures of products classified as PB mixtures shall not exceed 208 psig (1435 kPa) and additionally shall not exceed the pressure calculated
in psig from the following relationship between the observed vapor pressure at 100 °F (37.8 °C) and the observed relative density at either 60 °F or 15.6 °C:
Vapor pressure, psig, max
51167 2 1880 s relative density at 60 °F/60 °F d (1)
51167 2 1880 s relative density at 15.6 °C/15.6 °C d (2)
A specific mixture shall be designated by the vapor pressure at 100 °F in pounds per square inch gauge. To comply with the designation, the vapor pressure of the mixture
shall be within +0 psi to −10 psi of the vapor pressure specified.
C
In case of dispute about the vapor pressure of a product, the value actually determined by Test Method D1267 shall prevail over the value calculated by Practice D2598
or measured by Test Method D6897.
D
See X1.2.2.3.
E
“Butane and heavier” includes all hydrocarbons (including olefins) with 4 or more carbon atoms.
F
“Pentane and heavier” includes all hydrocarbons (including olefins) with 5 or more carbon atoms.
G
See X1.2.4 for information about residues in LPG and for information about gas chromatographic tests for residues in LPG.
H
An acceptable product shall not yield a persistent oil ring when 0.3 mL of solvent residue mixture is added to a filter paper, in 0.1 mL increments and examined in daylight
after 2 min as described in Test Method D2158.
I
In case of dispute, Test Method D2158 shall be the referee test method.
J
Although not a specific requirement, the density or relative density can be needed for other purposes and should be reported. Additionally, the relative density of PB
mixture is needed to establish the permissible maximum vapor pressure (see Footnote B).
K
This method may not accurately determine the presence of reactive materials (for example, H2S, So) in liquefied petroleum gas if the product contains corrosion inhibitors
or other chemicals which diminish the reaction with the copper strip.
L
The total sulfur limits in these specifications do include sulfur compounds used for stenching purposes.
M
The presence or absence of water may be determined by visual inspection of the samples on which the density or relative density is determined.
(Nonmandatory Information)
such as fuel cells and microturbines without some form of tor. Test Methods D5504 and D5623 can be modified to
remediation. measure COS in liquid LPG samples.
X1.2.4.1 Gas chromatographic residue Test Methods D7756 X1.2.6 Sulfur Content—Limits are provided to more com-
and D7828 offer alternative ways to quantitatively analyze an pletely define liquefied petroleum gas products. Historically
LPG sample for soluble residues. LPG users who encounter these products were lower in sulfur content than most other
residue problems should consider analyzing the suspect LPG petroleum-derived fuels. This is generally no longer the case in
by Test Method D7756 or D7828 to gain information about the areas where gasolines are typically below 30 mg ⁄kg (ppm by
composition and identification of residues. mass) sulfur and diesel fuels are less than 15 mg/kg (ppm by
X1.2.4.2 Test Method D7756 may be used as an alternative mass) sulfur. The limit on sulfur content minimizes sulfur
means of residual matter measurement for LPG samples within oxide emissions and limits potential corrosion by exhaust gases
the range that has been validated in Test Method D7756. A from combustion of LPG.
residue limit of 350 mg ⁄kg using Test Method D7756 has been X1.2.7 Moisture Content—Limits the percent saturation of
found satisfactory to meet the requirements for both the residue the product with water. This measurement using Test Method
on evaporation and oil stain observation as measured by Test D2713 is a requirement only on the commercial and special
Method D2158. The residue limit of 350 mg ⁄kg relates par- duty propane types of liquefied petroleum gas which must be
ticularly to the oil stain observation limit of Test Method subsaturated with water at temperatures above about –26 °C.
D2158, which is more restrictive than the residue limit of The purpose of moisture content control is to provide assurance
0.05 mL per 100 mL of LPG. that pressure-reducing regulators and similar equipment will
X1.2.5 Copper Corrosion—Limits are for the purpose of operate consistently without troublesome freeze-ups caused by
providing assurance that difficulties will not be experienced in the separation of dissolved water from the product. The
the deterioration of the copper and copper-alloy fittings and presence of an antifreeze agent such as methyl alcohol which
connections which are commonly used in many types of prevents separated water from freezing can allow use of
utilization, storage, and transportation equipment. The copper propane containing excessive dissolved water in many appli-
corrosion test will detect the presence of elemental sulfur and cations.
hydrogen sulfide, which is highly toxic. Experience has shown NOTE X1.1—Commercial propane and special duty propane should be
that the combination of H2S and elemental sulfur even at produced to comply with the moisture content requirement, and de-icer
concentrations of less than 1 ppm can be very corrosive additives should not routinely be used to pass dryness test requirements.
towards copper. The copper corrosion limits also provide That is, these products must be so dry that they are subsaturated with
water at most ambient temperatures. They should be maintained dry
assurance that the LP-Gas will not contain H2S in such during storage and distribution. A de-icer such as methyl alcohol (metha-
quantities as to present a health and safety hazard if it is known nol) should not be added to these products without specific agreement and
that the product does not contain corrosion inhibitors or other approval of the purchaser. During short-term upsets in production, or
SUMMARY OF CHANGES
Subcommittee D02.H0 has identified the location of selected changes to this standard since the last issue
(D1835 – 16) that may impact the use of this standard. (Approved Aug. 1, 2018.)
(1) Deleted reference to Test Method D2784, Sulfur in LPG, in (7) Revised subsection X1.2.4 to add a comment about exces-
Section 2 and Table 1. sive use of methanol possibly attacking elastomers, leading to
(2) Revised subsection 1.3, units statement. residue problems.
(3) Corrected the vapor pressure of Commercial Propane and (8) Deleted Test Method D1837, test method for volatility of
Special Duty Propane in Table 1 from 1434 kPa to 1435 kPa to LPG, from Referenced Documents and from Table 1; the term
align with the reporting requirement of Test Method D1267; ‘volatility’ has been replaced by ‘heavier hydrocarbon con-
moved Footnote ‘C’ to D1267. taminants’ in Table 1 and subsections X1.2.2 and X1.2.3.
(4) Clarified Footnote ‘B’ of Table 1 to show that the equations (9) Revised subsection X1.2.2.2 to replace ‘volatility’ by
are in units of psig. ‘heavier hydrocarbon contaminants.’
(5) Added Footnotes ‘E’ and ‘F’ to Table 1 to clarify the (10) Added new subsection X1.2.2.3 to identify the possible
requirements “butane and heavier” and “pentane and heavier.” use of Test Method D1837 for investigation of suspected
(6) Added new 3.1.4, the definition for liquefied petroleum gas contamination incidents in areas that still allow use of mercury
(LPG). thermometers.
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