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is adsorption potential
is the pressure difference and k is the solution dielectric constant
(Presence of large anomalies associated with topography could be responsible for
electrokinetic potential.)
Where R is the gas constant (8.31 J/𝑜𝐶 ), F is faraday constant (9.65 × 104 𝐶/
𝑚𝑜𝑙), Ɵ 𝑖𝑠 𝑡ℎ𝑒 𝑎𝑏𝑠𝑜𝑙𝑢𝑡𝑒 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒, 𝑛 𝑖𝑠 𝑡ℎ𝑒 𝑣𝑎𝑙𝑒𝑛𝑐𝑒, 𝐼𝑎
𝑎𝑛𝑑 𝐼𝑐 are mobilities of ions and cations and C1 and C2 are solution concentrations
.
3. Shale potential: When two identical metal electrodes are immersed in a
homogeneous solution, there is no potential difference between them. If, however,
the concentrations at the two electrodes are different, there is a potential
difference given by:
Electrical Conduction
• Electronic: material containing free electrons
• Electrolytic: current is carried by ions
• Dielectric: Conduction take place in poor conductor
Electric Resistivity Method
• Resistivity methods employ an artificial source of current which is introduced
into ground through point electrodes or long line contacts
Ron D. Barker
Application of Electrical Resistivity Methods to Determine the Lithological
Parameters:
OHMS LAW
• All other factors being constant, the voltage drop between the potential
electrodes is proportional to the resistance of the subsurface.
V
a 2a
I
Telford (1976)
Ohm’s Law
Ohm’s Law describes the electrical properties of any medium. Ohm’s Law, V = I R,
relates the voltage of a circuit to the product of the current and the resistance. This
relationship holds for earth materials as well as simple circuits. Resistance,
however, is not a material constant. Instead, resistivity is an intrinsic property of the
medium describing the resistance of the medium to the flow of electric current.
Resistivity is defined as a unit change in resistance scaled by the ratio of a unit
cross-sectional area and a unit length of the material through which the current is
passing. Resistivity is measured in ohm-m, and is the reciprocal of the conductivity
of the material.
The first step towards this is the measurement of the resistance of the ground by
passing an electrical current into it through a metal stake (electrode), which acts as
the current source. Of course, current can only pass into the ground if it can also
exit through a second electrode (or current sink) so that the circuit is completed.
The expression for the electrical potential is probably the most important in
resistivity surveying and that on which the few equations presented below are
based. The potential, V, at a distance, r, from a point current source, I, on the
surface of the earth of resistivity, , is given by:
where K is known as the geometric factor and depends on the spacing between
electrodes and their arrangement and is the resistivity of a homogeneous earth.
Two Current Electrodes at Surface
In Wenner array, the four electrodes are placed collinearly and are
equally spaced.
Wenner spread: The electrode separation is kept constant and
moved along profiles while apparent resistivity is measured.
R1=a R2=2a
R3=2a R4=a
Schlumberger configuration:
a a a
R = 2a V/I Wenner array
Dipole-dipole
R = n(n+1)(n+2)a V/I array
Apparent Resistivity
• Before discussing the various electrode spreads, it is necessary to consider
what is actually measured by an array of current and potential electrodes.
• Data are termed apparent resistivity because the resistivity values measured
are actually averages over the total current path length but are plotted at one
depth point for each potential electrode pair.
• The data on current flow and potential drop are converted into resistivity
values. In case of an inhomogeneous earth, the measured resistivity is
influenced in varying proportions by material from a wide depth range in the
region covered by the electrodes and therefore, the field resistivity values are
apparent (ρa) rather than true.
• The electrical resistivity of a dry formation is much higher than that of the same
formation when it is saturated with water
• The arrangement of the four electrodes on the ground (two current and two
potential) is referred to as the electrode ‘array’ or configuration.
• The current and potential electrodes are moved along a profile with
constant spacing between electrodes.
• The most common array types used for CST are wenner, dipole-dipole
and pole-dipole arrays, where a dipole is a pair of current or potential
electrodes.
• The most common array used for VES is the Schlumberger array.
Vertical Electrical Sounding (VES) is applied to near horizontal layered
medium, e.g. sedimentary terrain or weathered zones over hard rocks. It is
used to determine variations in electrical resistivity with depth. In VES (also
loosely called electrical drilling), the distances between electrodes are
increased so that the electric current penetrates to deeper and deeper levels,
which allows resistivity measurement of a deeper and deeper and larger
volume of the earth.
• The interpretation can be refined
through forward or inverse
modelling.
45°
• Data acquisition proceeds by combining Depth Sounding and Lateral Profiling to obtain data
from a 2D section of the subsurface.
• The horizontal location of a data point is at the mid-point of a set of electrodes used.
• The vertical position (pseudo-depth) of a data point is at a depth proportional to the
electrode spacings.
Site investigation for proposed tunnel,
courtesy of Hyundai Construction Company, Korea
Pole-pole 3D command file
It is easy to create a pole-pole 3D command file by using the
“Create command file” option in the UserLoad software
3D resistivity image
Survey (pole-pole) performed over a horizontally layered limestone.
Displayed high resistive area is caused by unknown structure within
the limestone.
Membrane polarization:
• in clays, electrolytic current flow is impeded by positive ions (attracted to
negatively charged clay particles)
• charges accumulate, voltage builds up
• on release of current, charges drift back to equilibrium, voltage decays
Mechanisms causing the IP effect
Electrode polarization:
• metallic mineral grains conduct electronically, electrolytic ions accumulate at pore
restrictions causing a buildup of voltage
IP - Main Applications:
disseminated metallic ores
⁻ porphyry coppers,
⁻ bedded lead/zinc
⁻ sulphide-related gold deposits
environmental related studies
geothermal exploration
current is injected into the ground it also acts as a capacitor (or actually a battery),
which stores electrical charge. The two phenomena can be depicted in an equivalent
circuit as shown here on the right, where R is the earth resistance and C describes
the capacitance. Upon turning off the (polarising) DC-current, the ground gradually
discharged and returns to equilibrium which is the observed IP effect.
Induced Polarisation
“equivalent circuits”
• DC Resistivity • Induced Polarisation
- I
+ - I
+
completely described +
by Ohm’s law - C
𝑼 resistance R “capacitance ”
𝑹 =
(charge / voltage)
𝑰
IP Effect
charge time
Steady state voltage: Vp
(primary voltage)
IP effect
Residual voltage: Vs
(secondary voltage)
• The rate of decay depends on the electrical properties of the ground and the presence of
metallic minerals
• The decay voltage is the result of storage of energy by the ground during the period when
the DC current is on
• The effect cannot be explained in terms of the atomic or molecular structure of the
material, but depend on the macro-structure.
Principally with the same equipment as Resistivity
Measurements:
C1 P1 P2 C2
• The greater the exposed metallic surface area, the stronger the effect
• Enhanced effect for disseminated mineral grains
• Often these are cases in which standard resistivity response is weak
• In mineral exploration, the effect of near-surface clays complicates the
measurement
Time-domain IP measurement
• IP methods
→direct electrical connection (electrodes)
→ flow of current switched off
→ decay of electrical potential
Induced Polarisation
DC / IP data are DC
gathered together
Least-Squares
Inversion
Invert for chargeability
models
observed data
2D inversion
observed data
2D inversion
IP Data Interpretation
2D resistivity Section
Log Resistivity (𝛺 ∙ 𝑚)
2D IP Section
EDB (100)
Chargeability Anomalies
(Contaminants ?)
Chargeability (mV/V)
The Self-Potential (Spontaneous-Potential) Method
Self Potential (SP) geophysical surveys measure the potential difference between
any two points on the ground produced by the small, naturally produced currents
that occur beneath the Earth's surface.
The SP method is passive, non-intrusive and does not require the application of an
electric current. Small potentials of the order of a few millivolts are produced by two
electrolytic solutions of differing concentrations that are in direct contact, and by
the flow of groundwater through porous materials (streaming potential). Larger
ground potentials are produced by conductive mineralised ore bodies partially
immersed below the water table.
SP SURVEY OPERATION
Readings are typically taken with one electrode fixed at a base station
and a second, mobile 'field' electrode that is moved around the survey
area.