Beruflich Dokumente
Kultur Dokumente
Type 1 contains 15 Single Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONLY ONE CHOICE is correct.
Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong answer]
Type 2 contains 5 Multiple Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE OR MORE CHOICES may be correct.
Marking scheme [5 Marks for All Correct answers & –2 NEGATIVE MARKING for wrong answer]
4. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
5. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
6. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group properly in the space given in the ANSWER SHEET.
7. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty
in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
8. Do not fold or make any stray marks on the Answer Sheet.
9. No one will be permitted to leave the test room before the end of the test, i.e. 01:00 PM
SECTION-I/Type-1
SINGLE CORRECT ANSWER
This section contains 15 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:
1. For which of the following reaction enthalpy change of reaction is equal to standard enthalpy of
formation of product?
I. S(rhombic)(s) + 3F2(g) SF6(g) II. P4(white)(s) + 5O2(g) P4O10(s)
III. C(graphite)(s) + 2S(rhombic)(s) CS2(l) IV. C(diamond)(s) + O2(g) CO2(g)
The correct choice is :
(A) Only I (B) I, II, IV (C) II, III, IV (D) I, II, III
For Questions 4 - 7
(A) Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
SPACE FOR ROUGH WORK
4. Statement 1 : Among E1, E2 and E1CB mechanism, E1CB is least favourable for a 2° alkyl iodide
with ethanolic KOH and E2 is most favoured.
Statement 2 : The general order of activation energy for a 2° alkyl halide is E1CB > E1 > E2.
5. Statement 1 : Enthalpy changes are positive when Na2SO4. 10 H2O and salts like NaCl, KCl etc.
Which do not form hydrates, are dissolved in water. But enthalpy changes are negative
when anhydrous salts capable of forming hydrates are dissolved in water.
Statement 2 : The difference in the behaviour is due to large difference in the molecular weights of
hydrated and anhydrous salts. The substances with larger molecular weights usually
show positive enthalpy change on dissolution.
6. Statement 1: B(g) + C(g) is not affected by changing volume of the
The equilibrium of A(g)
system.
Statement 2: KC for the reaction does not depend on volume of the container.
10 11
7. Statement 1: Boron has two isotopes 5 B and 5 B and their relative abundance is 19% and 81%
respectively.
Statement 2: Boron has relative atomic mass of 10.81 amu.
(A) (B)
CH 3
| CH 3 C H CH 2 NH 2
(C) CH 3 C CH 2 NH 2 (D) |
| CH 2
CH3
10. For the above reaction at two temperature. T1 T2 , the relation(s) that hold true free is :
I. K f T2 K f T1 II. K f T2 K f T1
III. K b T2 K b T1 IV. K b T2 K b T1
The correct choice is :
(A) I, IV (B) II, IV (C) I, III (D) II, III
11. For the above reaction at two temperature T1 T2 , the relation with respect to K f and K b is :
K f T2 K b T2 K f T2 K b T2
(A) (B)
K f T1 K b T1 K f T1 K b T1
K f T2 K b T2
(C) (D) Can’t be determined using the given data
K f T1 K b T1
SPACE FOR ROUGH WORK
The orbitals with lower energy are called t 2g orbitals and those with higher energy are called eg orbitals.
In octahedral complexes, positive metal ion may be considered to be present at the centre and negative ligands
at the corner of a regular octahedron. As lobes of d 2 2 and d 2 lie along the axes, i.e., along the ligands the
x y z
repulsions are more and so high is the energy. The lobes of the remaining three d-orbitals lie between the axes
i.e., between the ligands. The repulsion between them are less, so lesser the energy. In the octahedral
complexes, if metal ion has electrons more than 3 then for pairing them, the options are :
(i) Pairing may start with 4th electron in t2g orbitals.
(ii) Pairing may start with normally 6th electrons when t2g and eg orbitals are singly filled.
12. In which of the following configurations, hybridization and magnetic moment of octahedral complexes
are independent of nature of ligands.
I. d3 configuration of any metal cation
II. d6 configuration of IIIrd transition series metal cation
III. d8 configuration of Ist transition series metal cation
IV. d7 configuration of any metal cation
Select the correct code :
(A) I, II, IV (B) III, IV (C) I, II, III (D) I, III, IV
SECTION - I/Type-2
MULTIPLE CORRECT TYPE
This section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE OR MORE CHOICE may be Correct:
19. Consider the following simultaneous equilibrium and identify correct relation.
CO 3H 2
CH 4 H 2 O K1
CO 2 4H 2
CH 4 2H 2 O K2
CO H 2 O
CO 2 H 2 K3
3CO 2 CH 4
4CO 2H 2O K4
K2 K1 K 32
(A) K3 (B) K3 (C) K4 (D) K 4 K 32 K14
K1 K2 K14
SECTION-I/Type-1
SINGLE CORRECT ANSWER
This section contains 15 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:
1. In a metre bridge experiment, null point is obtained at 20cm from one end of the wire when resistance
X is balanced against another resistance Y. If X < Y, then where will be the new position of the null
point from the same end, if one decides to balance a resistance of 4X against Y ?
(A) 50 cm (B) 80 cm (C) 40 cm (D) 70 cm
2. When the gap is closed without placing any object in the screw gauge whose least count is
0.005 mm, the 5th division on its circular scale coincides with the reference line on main scale and zero
of pitch scale is not hidden. When a small sphere is placed, reading on main scale advances by
4 divisions, whereas 25th division of circular scale coincides with reference line on main scale.
There are 200 division on the circular scale. The radius of the sphere measured is :
(A) 4.10 mm (B) 4.05 mm (C) 2.10 mm (D) 2.05 mm
3. Men are running along a road at 8 m.p.h. behind one another at equal intervals of 20 yards. Cyclist are
riding in the same direction at 15 m.p.h. at equal intervals of 30 yards. At what speed an observer travel
along the road in opposite direction so that whenever he meets a runner he also meets a cyclist?
(A) 7 m.p.h. (B) 6 m.p.h. (C) 5 m.p.h. (D) 8 m.p.h.
4. In an electron gun, emission current from the cathode is given by the equation,
I AT 2 e
B ( KT )
[K = Boltzmann constant, A = constant]
The dimensional formula for AB2 is same as
IK 2
(A) KT (B) IT2 (C) IK2 (D)
T
5. A resistor and a capacitor are connected to an ac supply of 200 V, 50 Hz in series. The current in the
circuit is 2A. If the power consumed in the circuit is 100 W then the capacitive reactance in the circuit
is :
(A) 100Ω (B) 25 3 Ω (C) 25 15 Ω (D) 400 Ω
6. Three rods of same dimensions are arranged as shown in Figure. They have
thermal conductivities K1 , K2 and K3. The points P and Q are maintained at
different temperatures for the heat to flow at the same rate along PRQ and
PQ. Which of the following options is correct ?
1
(A) K3 K1 K 2 (B) K 3 K1 K 2
2
K1 K 2
(C) K3 (D) K 3 2 K1 K 2
K1 K 2
7. Three capacitor A, B and C are connected in a circuit
as shown in Figure. What is the charge in C on the
capacitor B ?
(A) 1/3 (B) 2/3
(C) 1 (D) 4/3
8. A constant force F is applied on a body. The power (P) generated is related to the time elapsed (t) as :
(A) P t2 (B) P t (C) P t (D) P t3 / 2
9. A black body at 200 K is found to emit maximum energy at a wavelength of 14µm. When its
temperature is raised to 1000 K, the wavelength at which maximum energy is emitted is
(A) 14 µm (B) 70 µm (C) 2.8 µm (D) 1.4 µm
10. A wooden block is floating in a water tank. The block is pressed to the bottom. During the process, a
work is done. Which of the following statements are false?
(A) Work done is equal to work done against up thrust exerted by the water
(B) Work done is equal to work done against upthrust plus loss of gravitational potential energy of
the block
(C) Work done is equal to work done against upthrust minus loss of gravitational potential energy
of the block
(D) Work done is equal to loss of gravitational potential energy of the block
SPACE FOR ROUGH WORK
11. A particle moves in a circle of radius 20 cm. Its linear speed is given by v = 2t where t is in seconds and
v in ms–1. Then which of the following is not correct ?
(A) The radial acceleration at t = 2s is 60 ms–2
(B) Tangential acceleration at t = 2s is 2 ms–2
(C) Net acceleration at t = 2s is greater than 80 ms–2
(D) Tangential acceleration remains constant in magnitude
12. Two particles performing SHM have same amplitude and time period. Their positions at certain instants
are shown in the figure. The phase difference between them is:
x A x0 x A/ 2 x A
(A) 0 (B) π/2
(C) 3π / 2 (D) 5π / 3 x A x A / 2 x0 x A
13. A disc of mass m and radius R moves in the x-y plane as shown in
y
the figure. The angular momentum of the disc about the line v R
through the origin and parallel to rotation axis of the disc at the
instant shown is :
5 7 3R
(A) mR 2 ω (B) mR 2 ω
2 3
9 3 x
O
(C) mR 2 ω (D) mR 2 ω 4R
2 2
14. A wedge of mass 2 m and a cube of mass m are shown in figure. Between cube and
wedge, there is no friction. The minimum coefficient of friction between wedge and
ground so that wedge does not move is :
(A) 0.20 (B) 0.25 (C) 0.10 (D) 0.50
15. Two particles are thrown from the same point in the same vertical
plane, as shown in figure simultaneously. Then indicate the incorrect
statement.
(A) Time of flight for B is less than that of A
(B) Projection speed of B is greater than that of A
(C) Horizontal component of velocity for B is greater than that of A
(D) The vertical component of velocities of both A and B are always equal throughout the duration
for which both the particles are in air
SECTION - I/Type-2
MULTIPLE CORRECT TYPE
This section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE OR MORE CHOICE may be Correct:
17. In the figure shown two ideal voltmeters and an ammeter which
are connected across the various circuit elements. If the voltmeter
connected across 9 resistance reads 4.5 V, then
(A) The current through 12 resistance is 0.5A
(B). The reading of the voltmeter connected across 20
resistance, is 20 V
(C) The reading of the voltmeter connected across 20
resistance, is 15 V
(D) The reading of the ammeter is 2.25 A
18. Kinetic energy of a particle moving in a straight line is proportional to the time t. The magnitude of the
force acting on the particle is :
(A) Directly proportional to the speed of the particle (B) Inversely proportional to t
(C) Inversely proportional to the speed of the particle (D) Directly proportional to t
19. A particle of mass 2 kg and charge 1mC is projected vertically with a velocity 10ms 1 from a level
horizontal surface. There is uniform horizontal electric field of 10 4 N/C.
(A) the horizontal range of the particle is 10m
(B) the time of flight of the particle is 2s
(C) the maximum height reached is 5m
(D) the horizontal range of the particle is 0
20. A block B of mass 0.6 kg slides down the smooth face PR of a wedge A
of mass 1.7 kg which can move freely on a smooth horizontal surface.
The inclination of the face PR to the horizontal is 45°. Then:
(A) the acceleration of A is 3g/20
(B) the vertical component of the acceleration of B is 23 g/40
(C) the horizontal component of the acceleration of B is 17 g/40
23g
(D) relative acceleration of B w.r.t. A is
40 2
SPACE FOR ROUGH WORK
SECTION-I/Type-1
SINGLE CORRECT ANSWER
This section contains 15 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:
2. Six-digit numbers are formed using the digits 0, 1, 2, 3, 4, 5. Let p be the number of numbers in which
even digits occupy even places and let q be the number of numbers in which even digits occupy odd
places. The value of p + q is :
(A) 72 (B) 48 (C) 60 (D) 600
4. A rectangle ABCD has its side AB parallel to the line y = x and vertices A, B and D lie on y = 1, x = 2
and x 2 respectively. Locus of vertex C is :
(A) xy5 (B) x5 (C) x y5 (D) y=5
1/ n
6. The value of : Lt
n 2 1 n 2 1 3 n 2 1 3 5 ....2n terms
is :
n n4 n
(A) 25e
2 tan1 24 (B) e
2 tan1 24 (C) e
2 tan1 24 (D) 25e2 tan
1
24
7. The vertex of right angle of a right angled triangle lies on the straight line 2 x y 10 0 and the two
other vertices, at points 2 , 3 and 4 , 1 then the area of triangle in sq. units is :
(A) 10 (B) 3 (C) 33/5 (D) 11
sin 2 x cos 2 x
8. The area bounded by the curve y 1 / 8 sin 1
t dt 1 / 8 cos t dt 0 x 2
1
and
1/ 3
y 2 x and y-axis will be :
4 4
3 1 3
(A) sq. units (B) sq. units
16 8 16
4
1 1 3
(C) sq. units (D) sq. units
8 4 16
1 / 10
x x
8
9. The value of the integral 2
x 2 x 9 dx is :
5 11 / 10 5
(A)
11
x 2
2x c (B)
6
x 111 / 10 c
6 11 11 / 10
(C)
7
x 111 / 10 c (D)
5
x 2
2x c
x 3 y 2 z 1 x 2 y 3 z 2
10. Two lines whose equations are and lie in the same
2 3 3 2 3
plane, then the value of sin 1 sin is equal to :
(A) 3 (B) 3 (C) 4 (D) 4
11. If ‘P’ is any arbitrary point on the circumcircle of the equilateral triangle of side length l units,
2 2 2
then PA PB PC is always less than :
12. A robot is at zero position on a straight number line. Each second, it randomly moves either one unit in
the positive direction or one unit in the negative direction, the probability being 0.6 in positive
direction. The probability that at the end of 5 seconds the robot is 1 unit away from its initial zero
position, is :
72 144 216 18
(A) (B) (C) (D)
125 625 625 25
2 2
13. Let z cos i sin , then equation whose roots are z z3 z5 z 7 and
9 9
z 2 z 4 z 6 z 8 , is :
(A) 4 x 2 4 x sec 2 0 (B) 4 x 2 4 x cos 2 0
9 9
(C) 2 x 2 2 x sec 2 0 (D) 4 x 2 x cos 2 0
9 9
14. If f (x) > 0, x R, f (3) = 0 and g(x) = f (tan2 x –2 tan x + 4), 0 < x < , then g (x) is increasing in
2
(A) 0 (B) , (C) 0, (D) ,
4 6 3 3 4 2
1
15. The range of the function f defined by f ( x) where [ ] and { } respectively denote the
sin{x}
greatest integer and the fractional part functions, is :
(A) Z, the set of integers (B) N, the set of natural numbers
(C) W, the set of whole numbers (D) N {1}
SECTION - I/Type-2
MULTIPLE CORRECT TYPE
This section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE OR MORE CHOICE may be Correct:
b cos x b sin x
16. Let , b R . Which of the following is(are) correct ?
2 cos 2 x 1 cos 2
x 3 sin 2 x . tan x
1 1
(A) Equation has solution if b , 1, 0 ,
2 3
1 4
(B) Equation has solution if b , 1,
2 3
(C) Equation has no solution if b = 10
(D) Equation has no solution if b 10
20. Equation of chord of the circle x 2 y 2 3 x 4 y 4 0 which passes through origin such that origin
divides it in the ratio of 4 : 1 is :
(A) y0 (B) 24 x 7 y 0 (C) 7 x 24 y 0 (D) 7 x 24 y 0