IIT-JEE (2006)

(Memory Based Question Paper)

PHYSICS
Section I:Multiple Choice Questions with one (a) πr2 ∝ f
correct answer. (b) πr2 ∝ f2
Q.1 A student performs experiment to determine g (c) lens is covered half so half image is formed
4 π2 l (d) on increasing focal length, brightness of the
using formula g = ; here l (length of the image increases
T2
Ans. (b)
wire) is approximately equal to 1m, ∆l
represents error in measurement of length l,
∆T represents error in measurement of time, n Q.5 Time constant for the given circuits are.
is total number of oscillation. Then for which of
the data of the measurement of g will be most
1Ω 4µ f
accurate ? 2µ f 4µ f 2µ f
∆l ∆T n Amplitude of 2Ω 1Ω 2Ω
oscillation
(a) 5 mm 0.2sec 10 5mm
(b) 5 mm 0.2 sec 20 5mm 2µ f
(c) 5 mm 0.1 sec 20 1 mm
(d) 1 mm 0.1 sec 50 1mm
Ans. (d)
1Ω 2Ω 4µ f
Q.2 Focal length of the shown plano-convex lens is
15 cm. Plane surface of the lens is silvered.
An object is kept on the principal axis of the
lens at a distance 20 cm. Image of the object 8 8
(a) 18 µs, µs, 4 µs (b) 18 µs, 4 µs, µs
will form. 9 9

8 8
(c) 4 µs. µs, 18 µs (d) µs, 18 µs, 4 µs
object 9 9
Ans. (a)
20 cm
(a) 60 cm, left (b) 60 cm, right Q.6 In the system shown if the inextensible string
(c) 12 cm, left (d) 30 cm, right connecting 2m and m is cut, the accelerations
Ans. (c) of mass m and 2m are
\\\ \\\ \\ \\\ \\\\\ \\\ \\\\\ \\\ \\ \\\ \\\

Q.3 Half life of a radioactive sample is 4 days. Find

the probability that a particular nucleus of the
radioactive material decays after 2 half life is
1 3 3
(a) 1 (b) (c) (d)
2 2 4 2m
Ans. (d)
Q.4 The image of sun is formed on focal plane of m
string
lens which is a circular in shape of radius r and
area πr2. g g g
(a) , (b) g,
2 2 2
g
(c) ,g (d) g, g
2
Ans. (b)

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Q.7 In the figure shown length of each wire is l /2 Q.10 Wire 1 is vibrating in first harmonic: Wire 2 is
and their radii are 2r and r. Then vibrating in second harmonic : What is the
P (2r) Q position x of mass m
(r) R // / /// // // /// // /// / /// / /// // // // /// // // /// / /// / /// // //

I I

l/2 l/2 1 2
(a) current density in both wires is same
(b) power dissipated in QR is 4 times that in
the PQ x
(c) ratio of potential drops on PQ & QR is 4
(d) resistance of PQ is 4 times that of QR m
Ans. (b)
4L L
(a) (b)
5 5
Q.8 Graph of position of image vs position of a point
object from a convex lens is shown in the figure. L 3L
Then focal length of the lens is (c) (d)
4 4
Ans. (b)
v (cm )
31
30 Q.11 A double star system having two stars of
masses m1 and m2, is rotating about common
center of mass in radius r1 and r2, with periods
T1 and T2 , then
10
3
 T1   r1 
u(cm ) –31 –30 –10 (a)   =  
 T2   r2 

(a) (0.50 ± 0.05) cm (b) if T1 > T2 then R1 > R2

(b) (0.50 ± 0.10) cm (c) if T1 > T2 then m1 > m2
(c) (5.00 ± 0..05) cm (d) T1 = T2 Ans. (d)
(d) (5.00 ± 0.10) cm Ans. (c)
Q.12 The circular divisions of shown screw gauge are
Q.9 Moment of inertia of solid sphere of mass m 50 It moves 0.5 mm on main scale in one
and radius R about axis passing through center rotation. The diameter of the ball is -
of mass is Ι as shown in figure 1. The sphere is
moulded in the form of disc of radius 'r' and
0
thickness 't'. The moment of inertia of disc about 10
5
the axis shown in figure 2 is Ι. 0

r
t

0 30
25
Fig.1 Fig.2 20

The radius of disc is

2R 2R
(a) (b)
15 5

R R (a) 2.25 mm (b) 2.20 mm

(c) (d) (c) 1.20 mm (d) 1.25 mm
15 5
Ans. (c)
Ans. (a)
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Section II: Multiple Choice Questions with one or (a) friction force is dissipative
more correct answer(s). (b) on decreasing θ, frictional force decreases
(c) friction force does help in rotation and
Q.13 An infinite wire carrying current Ι passes through opposes translation
point O perpendicular to the plane containing (d) friction force is necessarily µmgcosθ
a current carrying loop ABCD as shown in the Ans. (b, c)
figure.
C
Q.16 The given figure shows lines of force of a
B particular field. Out of the following option, the
field line can not represent.

I
O
A
D

(a) Net force on the loop is zero

(a) An electrostatic field
(b) Net torque on the loop is zero
(b) A magneto static field
(c) The loop rotates in anticlockwise direction
(c) A gravitational field
as seen from O
(d) An induced electric field
(d) The loop rotates in clockwise direction as Ans. (a, c)
seen from O Ans. (a, d)

Q.17 The adjacent figure shows variation of electric

Q.14 A ball is rolling on the track as shown in the potential with distance for a spherical symmetric
figure. AB is rough surface and BC is smooth. charge distribution system and given as
Ball reaches to the height C. KA, KB and KC
are the kinetic energies at A, B and C. q
φr = (r ≥ R0 )
4 πε0r

q
A φr = (r ≤ R 0 )
C 4 πε0R0

hA hC Which of the following option is/are correct ?

φr
B

(a) hA > hC ; KB > K C

(b) hA < h C ; KB > KC
(c) hA = hC ; KB = KC
R0
(d) hA > hC ; KA < K C Ans. (a, d) r

Q.15 A solid cylinder is rolling over an inclined plane (a) For spherical region r ≤ R0 total electrostatic
as shown in the figure. energy stored is zero
(b) Within r = 2R0 , total charge is q.
(c) There will be no charge anywhere except at
r = R0
(d) Electric field is discontinuous at r = R0
Ans. (a, b, c, d)
θ

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Q.18 f(t) = Asin2ωt + Bcos2ωt + Csinωtcosωt
The above function represents SHM
(a) for all values of A and B, with C ≠ 0
(b) A = –B, C = 2B; with amplitude √2 B
(c) A = B, C = 2B; amplitude |B|
(d) A = B, C = 0
Section III:Questions based on comprehensions
with one correct answer.
PASSAGE - 1
A tank has a cylindrical opening as shown of
diameter 2r. A cylinder of diameter 4r and density
ρ/3 is placed on the top of the opening as shown in
Ans. (b, c) figure. Liquid of density ρ is to be filled in the tank.

1 h1 disc
Q.19 The graph between and stopping potential 4r
λ
h h2
(V) of three metal having work functions φ1 , φ2
and φ3 in an experiment of photo electric effect 2r
is plotted as shown in the figure which of the
following statement(s) is/are correct ?
(λ represents wavelength of the incident ray.)
Q.21 What is the height h1 of the liquid level for the
mass to be lifted.
m etal 1 m etal 2 m etal 3 5h 5h
v (a) h1 = (b) h1 =
4 3
2h 5h
θ (c) h1 = (d) h1 =
1 –1 3 2
0 .0 0 1 0 .0 0 2 0 .0 0 4 nm
λ Ans. (b)
Q.22 The disc is kept pressed and water is lowered
(a) Ratio of work functions φ 1 : φ2 :φ3 = 1: 2 : 4 in the tank upto the height 'h 2' as shown, what
(b) Ratio of work functions φ1 : φ2 : φ3 = 4:2 : 1 is the height h2 for the disc to be again lifted.
(c) tan θ is directly proportional to hc/e, where h 4h
h is plank's constant and c is the speed of (a) (b)
3 9
light
2h
(d) the violet color can eject photoelectrons from (c) (d) h Ans. (b)
3
metal 2 & 3. Ans. (a, c)
Q.23 Water is still lowered in the tank, what is the
Q.20 A black body at temperature T is kept in a dark another height h'2 , for the disc to be lifted ?
room with surrounding temperature T0. Sun h h
rays are allowed to fall on the black body through (a) (b)
3 4
a hole in the roof of the room while T and T0 are
h
maintained. Assuming that there is no change (c)
5
in the surrounding temperature of the room,
(d) no height h'2 at which disc will be lifted
select the correct statement(s).
Ans. (d)
(a) The quantity of radiation absorbed by the
PASSAGE-2
black body per unit time will increase
Equations of two waves are given as
(b) The quantity of radiation emitted by black y1 = A cos[0.5πx - 100 πt)
body per unit time will increase
y2 = A cos[0.46πx - 92 πt)
(c) Black body radiates more energy per unit
time in the visible spectrum Q.24 How many maximum will a stationary observer
(d) The reflected energy per unit time by the hear ?
black body remains same Ans. (d) (a) 4 (b) 5
(c) 6 (d) 7
Ans. (a)
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Q.25 Resultant wave is given as yR = y1 + y2 at x = 0.
How many times is the resultant yR zero in 1
sec.
(a) 100 (b) 192
(c) 46 (d) 96
Ans. (d)
Q.26 Maximum velocity of the wave having maximum
intensity.
(a) 200 m/s (b) 180 m/s
(c) 192 m/s (d) 100 m/s
Ans. (a)
PASSAGE-3
The capacitor of capacitance C can be charged
(with the help of resistance R) by a battery of
e.m.f. V while keeping switch S2 open. The
capacitor can be connected to an inductor of
inductance L by closing switch S2 and opening
S 1.
V Ans. (b)
S1
R C
S2
L ferromagnetic materials. In Japan the magnetic
Q.27 Initially the capacitor was uncharged, Now
switch S1 is closed and S2 is kept open. If time
constant of the given circuit is τ then
(a) After 1 time constant, charge on the
capacitor is CV/2
(b) After time interval 2τ, charge on the capacitor
is CV(1 – e–2)
(c) The work done by the voltage source will be
half of the heat dissipated, when the
capacitor is fully charged
(d) After 2 time constant, charge on the
capacitor is CV(1 – e–1)
Ans. (b)
Q.28 After the capacitor gets fully charged, S1 is
opened, and S2 is closed so that the inductor
is connected in series with the capacitor, then
(a) at t = 0, energy stored in the circuit is purely
in the form of magnetic energy
(b)direction of current is same for any time t
(c) at t > 0, there is no exchange of energy takes
place between the inductor and capacitor
C (c) Magnetic force
(d) maximum current in the circuit is v
L (d) Induced electric field
Ans. (d)
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Q.29 If maximum charge stored on the capacitor in
LC circuit is Q0 then for t ≥ 0.
(a) the charge on the capacitor
π 1 
Q = Q0cos  2 − t 
 LC 
d 2Q
(b) the charge on the capacitor is Q = –LC
dt 2
(c) the charge on the capacitor is
π 1 
Q = Q0cos  2 + t
 LC 
(d) the charge on the capacitor is
d2Q
1
Q=– 2
LC dt
PASSAGE - 4
A number of designs have been developed for
magnetic leviation. In one of the designs
electrodynamic system (EDS) is used. This model
is conceptually simple because it depends only on
the attractive force between magnets and
levitated trains run based on the EDS model which
uses Lenz's Law in the simplest form. The train
carries a magnet. As the magnet passes over a
metal plate or coils of wire currents are induced in
the plates or coils that tend to oppose the original
change this results in repulsive force which lifts the
train. This model has a stabilizing feature that if the
train drops the repulsion becomes stronger and
pushes the train back up. If the train rises the fore
decreases and the train drops down. In Maglev Train
the dissipative forces against friction are absent. The
disadvantage of this modal is that induced current
results in drag force as well as lift force. This requires
more power for propulsion The drag force is larger
than the lift force for small speed, but the drag force
maximizes at some speed and then begins to
decrease. The lift force continues to increase as the
speed increases. Thus it is advantageous to travel
at high speed, but the significant drag force at low
speed must be overcome as the train starts up.
Q.30 What causes the train to lift up -
(a) Electrostatic force
(b) Time varying electric field
Ans. (c)
# PAPER - IIT-JEE-2006
Q.31 The limitation of E.D.S model is that Q.35 A thermally insulated container has 0.43 kg of
(a) The train experiences upward force due to ice at –20ºC. Steam at 373 K is passed through
Lenz's law. the ice. Find the final temperature of mixture.
(b) Friction force creates a drag on the train Ans. 0273
(c) Retardation is caused
(d) By Lenz's law train experiences a drag force Q.36 In a hydrogen like atom (z = 11), nth line of
Ans. (d) Lyman series has wavelength λ equal to the
deBroglie's wavelength of electron in the level
from which it originated, what is the initial energy
Q.32 The advantage of the train is that - level of electron. Ans. 0025
(a) Electromagnetic force draws the train
(b) Gravitational force is zero Section V:This section consists of 4 questions. Each
(c) Electrostatic force draws the train having two columns with 4 entries in
(d) Resistive forces due to friction are absent each column. Entries of column I are to
Ans. (d) be matched with column II. One entry
of column I may have more than one
matching in column II.
Section IV:This section consists of 4 questions.
Answers are to be given in between 0000
to 9999 in the form of nearest integer. Q.37 Column-I Column-II
(A) Nuclear Fusion (P) Some matter
Q.33 'n' balls per second per unit area of mass m converted into
collide elastically with plate of mass m on the energy
half shaded region as shown. If the plate (B) Nuclear Fission (Q) Generally occurs
remains in equilibrium. Find the velocity of balls. in nuclei having
(n = 100, m = 0.01 kg, M = 3kg, b = 2m, a = 2m low atomic
g = 10 m/s2.) Ans. 0010 number.
(C) β-decay (R) Generally occurs
in nuclei having
b higher atomic
number.
a (D) Exothermic reaction (S) Essentially occurs
due to weak
nuclear force.

Ans. A → P, Q
Q.34 A disc having a groove as shown in kept on B → P, R
smooth horizontal plane. A block of mass m C →P, S
can slide in the groove. The disc move with D → P, Q, R
acceleration a0 = 25 m/s2 as shown in figure.
The coefficient of friction between block and
groove is 2/5 and sinθ = 3/5. Find the Q.38 ∆W-represents work done by the system and
acceleration of block relative to the disc. ∆Q represents heat absorbed by the system

A
2
a 0 = 25m /s P D

B C
V
m
Column I Column II
)θ
(A) AB (P) ∆W > 0
(B) BC (Q) ∆W < 0
Ans. 0010 (C) CD (R) ∆Q > 0
(D) DA (S) ∆Q < 0
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 Ans. A→S Q.40 Focal length of objective & eyepiece of a
B → P, R telescope are fO & fe respectively.
C→R Column - I Column - II
D → Q, S (A) Intensity of the image (P) Radius of
curvature (R)
Q.39 Column-I Column II (B) Angular magnification (Q) Dispersion of lens
(A) A stationary uniformly (P)Time independent (C) Length of telescope (R) Focal length fO & fe
charged dielectric ring electrostatic field (D) Sharpness of image (S) Spherical
out of system aberration
(B) Dielectric ring (Q) Magnetic field Ans. A → P
uniformly charged B →R
rotating with angular C →R
velocity ω. D → P, Q, S
(C) Constant current in (R) Induced electric
ring i0 field
(D) i = i0 cosωt (S) Magnetic moment
Ans. A → P
B → P, Q, S
C → Q, S
D → Q, R, S

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 IIT–JEE (2006)
(Memory Based Question Paper)
CHEMISTRY

Section I : Multiple Choice Questions with one Q.4 CH3NH2 + CHCl 3 KOH
→ Product,
correct answer. Product is :

(a) CH – ⊕ Θ .. ⊕
(b) CH –N
SO 3 H 3 N C: 3 .. C:
Q.1 NaHCO
  3
→ (c ) CH3 - NH - CH3 (d) CH3 - C ≡ N
Ans. (a)
(I)
Q.5 Order of boiling point for the following compounds
NO2
is :
 → (B )
Na HCO 3

OH
OH OH OH
OH OH
(II)
Gases released in reaction (I) and (II) are : OH OH
( 1)
(II) 11)
((III) 18)
((I)
(a) CO2, CO2 (b) SO 2, NO2 111))
((IV
(c) SO2, CO2 (d) SO2, NO
Ans. (a) (a) (I) < (II) < (III) < (I V)
(b) (I) < (II) < (IV) < (III)
(c) (IV) < (I ) < (II) < (III)
O
|| (d) (II) < (I) < (III) < (I V)
Q.2 IUPAC name of C 6H5 − C − Cl Ans. (c)
(a) Benzoylchloride
(b) Benzenecarbonylchloride Q.6 On dilution with H 2O and after boiling results in
(C ) Chlorophenyl ketone (d) the formation of white ppt. The formation of white
phenylchloroketone gelatenous ppt. take place OH treating it with
Ans. (b) excess mixture of NH4OH & NH 4Cl. Identify the
ppt. which dissolves in NH4OH/NH 4Cl :
(a) Zn(OH)2 (b) Al(OH)3
NOCl
Q.3 CH3 - CH = CH2 
→ Product (c) Ca(OH)2 (d) Mg(OH)2
Product is : Ans. (a)
(a) CH 3 − CH − CH 2 − NO
| Q.7 Express molar specific heat in terms of R, given
Cl that P/ V at any instant is constant and is equal
to 1.
(b) CH3 − CH − CH2 − Cl 3 5
| (a) RT (b) RT
NO 2 2

4
(c ) CH3 - CH2 - CH2 - Cl (c) RT (d) 0
2
(d) NO - CH2 - CH2 - CH2 -Cl
Ans. (c)
Ans. (a)

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Q.8 B(OH)3 + NaOH NaBO2 + Na[B(OH)4] (c) The catalyst will increase the rate of forward
+ H2O reaction by α and that of backward reaction β.
The reaction can be made to proceed in the (d) If the reaction is carried out at 400 K then
forward direction by adding : forward rate constant remains unaffected
(a) cis 1,2 diol (b) borax while the backward rate constant is
(c) trans 1, 2 diol (d) Na2 HPO4 decreased.
Ans. (a) Ans. (a)

Q.9 The conversion A to B is carried out by the Section II : Multiple Choice Questions with one or
following path : more correct answer(s).
C D Q.13 The bond length of CO is 1.128Å. The bond
Given : ∆S(A →C) = 50 e.u. , ∆S (C → length of CO in Fe(CO) 5 is (in Armgostrons)
A B (a) 1.76 (b) 1.128
D) = 30 e.u. , ∆S(B → D) = 20 e.u. (c) 1.15 (d) 1.118
Where e.u. is entropy unit then ∆S(A → B) is : Ans. (d)
(a) +100 e.u. (b) + 60 e.u.
(c) –100 e.u. (d) – 60 e.u. O
Ans. (b) Q.14 CH 3 – C – C H 3 + next homologue

Q.10 CuSO4 decolorizes on addition of KCN the NH 2 OH

product is : m ixture
(a) [Cu(CN)4]2–
(b) Cu2+ get reduced to form [Cu(CN) 4)]3– Following statements is/are correct about
(c) CuCN mixture :
(d) Cu(CN)2 (a) mixture is 3-types of oximes
Ans. (b) (b) mixture is 2-types of oximes
(c) all are optically active
Q.11 Ag + + NH 3 [Ag(NH3)+] ; K1 = 1.6 × 103 (d) one is optically active.
Ans. (a)
[Ag(NH3)]+ + NH3 [Ag(NH3 )2 ]+
K2 = 6.8 × 10 3

The formation constant of [Ag(NH3)2]+ is C H 3– C H 2– C H 2– C l (i) O 2/ ∆

Q.15 P + Q +
(a) 6.08 × 106 (b) 1.08 × 107 A lC l 3 (ii) H 3 O
(c) 1.08 × 10 3 (d) 3.8 × 105 + Phenol
Ans. (b)
P & Q are :
Q.12 In the Haber process which of the following is O
correct if the reaction is carried out in a vessel
of constant volume (a) and CH 3 – C H 2 – C – H
N2 + 3H2 2NH3
(a) If N2 is added the equilibrium will shift to O
right. Because according to II law of (b) and CH 3 – C – C H 3
thermodynamics entropy must increase in
the direction of spontaneous reaction. O
(b) The condition for equilibrium is
(c) and CH 3 – C – C H 3
G N 2 + 3G H 2 = 2G NH 3 where G is Gibbs
free energy per mole of the gaseous species
measured at that partial pressure. The O
condition of equilibrium is unaffected by the (d) and CH 3 – CH 2 – C – H
use of catalyst which increases the rate of
both the forward reaction by α and that of Ans. (c)
backward reaction by β.
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 CH 3 Q.20 The reaction of MgSO4 and NH4OH + Na2HPO4
Q.16 C l 2/h v N (no. of Isomers) results in the formation of white ppt. The ppt.
CH 3 –CH– CH 2 –C H 3
Fractional distillati on
are of :
→ (F), (a) MgNH4PO4 (b) Mg3 (PO4)2
(N) and (F) are : (c) MgSO 4.MgCl2 (d) MgSO 4. 2MgCl2
(a) 6,4 (b) 4,4 (c) 6,6 (d) 3,3 Ans. (a)
Ans. (a)
Section III : Questions based on comprehensions
O
with one correct answer.
C
Q.17 O The above reagent can be Passage : 1
The reaction sequence given below represents
synthesis from the following compounds in Hoffmann bromamide reaction in which RCONH2
alkaline medium following by acidification : is converted into R - NH2 :
CH O CO O H
(a) (b) O
CH O CH O O
O Θ
C – NH2 C – N H –Br C–N
.. –Br
CO O CH 3 CO O CH 3
(c) (d)
CH 3 CO O H
Ans. (a) Cl
Cl Cl ΙΙΙ
Q.18 Which of the following is the only incorrect
Ι ΙΙ
statement ?
A
C
Ideal gas H O
z
N H2 N=C= O
B N–C–O
–

P
(a) For the gas (A) ; a = 0 and it varies linearly
with P
(b) For the gas (B), b = 0 & it varies linearly with Cl
Cl Cl
pressure. Ι8
81 8
(c) C represent a typical real gas for which
neither a nor b is equal to 0. If minima & the
point of intersection is known with Z = 1, a &
b can be calculated. Electron donating groups attached to phenyl
(d) C will represent a typical vander Waals gas activates the reaction. The above reaction
whose a & b not equal to zero. If minima of sequence is interamolecular reaction.
the curve is known then value a & b can be
determined. Q.21 The reagent used to convert (I ) to (II) is :
Ans. (d) (a) Br2/NaOH (b) KBr/NaOH
(c) NBS (d) KBr
Q.19 When CO 2 is passed through water which one Ans. (a)
the species present :
(a) CO2,H2 CO3,HCO3– , CO32– Q.22 Rate determining step of reaction is :
(b) HCO3– , CO3 2– (a) formation of (II ) (b) formation of (III)
(c) CO 2,H2CO3 (c) formation of (IV) (d) formation of (VI )
(d) H2CO3,HCO3– Ans. (c)
Ans. (a)
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 Q.25 With the increase in concentration of NH3 pH
O O increases to 11. Consider there is no change in
15 concentration of C 6 H12 O 6 & C 6 H12 O7 on
Q.23 C–N H 2 C–N H 2
addition of NH3.
D Which of the following is correct ?
(A) (B)
(a) Eox increases by 0.65V from Eºox
Products formed when mixture (a) and (b) (b) Eox decreases by 0.65V from Eºox
undergo Hoffmann bromamide degradation ? (c) Ered increases by 0.65V from Eºred
(d) Ered decreases by 0.65V from Eºred
NH2 Ans. (c)
(a) NH2 +
Q.26 Ammonia is always added in this reaction.
D Which of the following must be incorrect ?
15 (a) NH 3 easily forms complex with Ag+
NH2 NH2 (b) Ag (NH3)2+ is a strong oxidising reagent
+
D + than Ag+.
(c) In absence of NH3 silver salt of gluconic acid
15
NH 2 is formed
(b) NH 2
+ (d) NH3 has affected the standard reduction
potential of glucose/gluconic acid electrode.
D Ans. (d)
Passage : 3
15 NiCl2 + KCN(excess) → [Cyano Complex]
(c) NH 2 NH 2 (I)
+ NiCl2 + KCl (excess) → [Chloro Complex]
(II)
D
In the product Ni has the coordination number
as 4.
15
NH 2 NH –D Q.27 The IUPAC name of the products formed are :
(d)
+ (a) Potassium tetracyano nickelate ( II ) &
Ans. (b) Potassium tetrachloro nickelate (II)
D (b) Tetracyano potassium nickelate &
Passage : 2 Tetrachloro potassium nickelate
Tollen's reagent is used for the detection of (c) Potassium tetracyano nickel (II) & Potassium
aldehyde when a solution of AgNO3 is added to chloro nickel (II)
glucose with NH 4OH then gluconic acid is (d) Tetracyano nickel (II) & Tetrachloro nickel (II)
formed Ans. (a)
Ag + + e – → Ag E0 = 0.8 V Q.28 Hybridisation in I and II is :
C6H12O6 + H2 O → C6H12O7 + 2H+ + 2e– (a) dsp2 , sp3 (b) sp3 ,sp3
E0 oxi = –0.05V 2
(c) dsp , dsp 2 (d) sp3d2 , d2sp3
Ag (NH3 )2 + e → Ag (s) + 2NH3
+ –
Ans. (a)
Eº = 0.337V
Q.29 Which of the following is correct about I and II
Q.24 For the following reaction (a) Both are diamagnetic
K eq .
Glucose + H2O + 2 Ag+ (b) Both are paramagnetic
Gluconic acid + 2 Ag (c) I st is diamagnetic & II is paramagnetic with
Determine the value of ln Keq : two unpaired electrons
(a) 58.8 (b) 46.2 (d) Ist is diamagnetic & II is paramagnetic with
(c) 28.3 (d) 66.13 one unpaired electrons
Ans. (a) Ans. (c)

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492  PAPER - IIT-JEE-2006
Passage : 4 Q.32 A nuclear explosion has taken place leading to
Carbon-14 is used to determine the age of increase in concentration of 14C in nearby areas.
organic material. The procedure is based on the 14C concentration is C in nearby areas and C
1 2
formation of 14 C by neutron capture in the upper in areas far away. If the age of the fossil is
14 determined to be T1 and T2 at the places
14 14C
atmosphere 7 N +0 n1 →6 C +1 p1 , is respectively then :
absorbed by living organisms during (a) The age of the fossil will increase at the place
photosynthesis. The 14C content is constant in where explosion has taken place and
living organism once the plant or animal dies, 1 C1
the uptake of carbon dioxide by it ceases and T1 − T2 = ln
λ C2
the level of 14C in the dead being, falls due to
the decay which 14 C undergoes (b) The age of the fossil will decrease at the
place where explosion has taken place and
14
6
C → N + β − . The half life period of 14C is
1 C1
5770 years. The decay constant (λ) can be T1 − T2 = ln
λ C2
calculated by using the following formula
(c) The age of fossil will be determined to be
0.693 same.
λ=
t1/ 2 . The comparison of the β activity
–

T1 C1
of the dead matter with that of the carbon still in (d) T = C
2 2
circulation enables measurement of the period
of the isolation of the material from the living Ans. (b)
cycle. The method hoever, ceases to be
accurated over periods longer than 30,000 years. Section IV : This section consists of 4 questions.
The proportion of 14C to 12C in living matter is 1 Answers are to be given in between
: 1012. 0000 to 9999 in the form of nearest
integer.
Q.30 Which of the following is correct ?
(a) In living organism, circulation of 14C from Q.33 For a cubical system the following information
atomosphere is high so the carbon content are available.
is constant in organism Edge length = 5Å ; density = 2 gm/cm3, Atomic
(b) Carbon dating can be used to find out the wt. = 75
age of earth crust and rocks Determine the radius of the atom in pm ?
(c) Radioactive absorption due to cosmic Ans. 0217
radiation is equal to the rate of radioactive
decay, hence the carbon content remains Q.34 75.2 g phenol is added in (1kg) of the solvent .
constant in living organism. The depression in freezing point is 7. Calculate
(d) Carbon dating can not be used to determine the percentage association if phenol undergoes
concentration of 14C in dead beings. dimerisation (kf = 14).
Ans. (c) Ans. 0075

Q.31 What should be the age of fossil for meaningful Q.35 2 moles of CO are mixed with 1 mole of O2 in a
determination of its age ? container of 1l. They completely to form 2 moles
(a) 6 years of CO2. If the pressure in the vessel changes
(b) 6000 years from 70 atm to 40 atm, what will be the value of
(c) 60,000 years ∆U in kJ at 500 K (The gases deviate
(d) It can be used to calculate any age appreciably from ideal behaviour.)
Ans. (b) 2 CO + O2 → 2CO2 ; ∆H = -560 kJ/mol,
1 L atm = 0.1 kJ
Ans. ∆U = 0557

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492  PAPER - IIT-JEE-2006
Q.36 Ksp of AgBr = 12 × 10–14. To the saturated Q.40 Match the following
solution of AgBr, AgNO3 is added at the conc.
of 10–7(M) λ∞ of Ag+ = 6 × 10–3 ohm–1 m2 mol–
1, λ of NO – = 7 × 10–3 ohm–1 m2 mol–1, λ
(A) Ph –CH 2 –C H 2 –Br (P) E 1 re action
∞ 3 ∞
of Br– = 8 × 10–3 ohm–1 m2 mol–1 & Ph –CD 2 –C H 2 –Br
Ans. 55 × 10 7 Rea cts with the
–1
ohm m . –1 sam e ra te
2
(B) Ph –CH– CH 3 reacts (Q) E reaction
Section V : This section consists of 4 questions. Each
having two columns with 4 entries in Br
each column. Entries of column I are faster th an
to be matched with column II. One
entry of column I may have more than Ph –CH– CD 3
one matching in column II. Br

Q.37 (a) SiO44– → Si2 O7 4– (P) Heat (C) Ph –CH 2 –C H 2 –Br (R) E 1 C B Re action
(b) B4 O7 2– → B (OH)3 (Q) Hydrolysis
(c) Bi3+ → [BiO]+
–
(R) Acidification C 2 H 5 O D/C 2 H 5 O
(d) AlO 2- → Al(OH)3 (S) Dilution by
water Ph –CD = CH 2
Ans. (a) → P ; (b) → Q & R ; (c) → Q ; (d) → R Br
st
(S) 1 order
Q.38 Match the extraction process listed in Column (D) CH 3 –CH –CD 3 re action
I with metals listed in Column II :
Column I Column II alc. KO H
(a) Self reduction (P) lead CH 2 =C H– CD 3
(b) Carbon reduction (Q) Silver (M ajor Pro duct)
(c) Complex formation and (R) Copper
displacement by metal Ans. (a) → (P) & (S) ; (b) → (Q) ; (c) → (R) ;
(d) Decomposition of iodide (S) Boron (d) → (Q)
Ans. a - P , R ; b - P, R ; c - Q ; d - S

Q.39 According to Bohr's theory ,

En = Total energy ; Kn = Kinetic energy
Vn = Potential energy rn = Radius of nth orbit
Match the following :
Column I Column II
(a) Vn/Kn = ? (P) 0
(b) If radius of nth orbital (Q) –1
∝ En x , x = ?
(c) Angular momentum in (R) –2
lowest orbital
1
(d) ∝ Zy , y = ? (S) 1
rn
Ans. → Q; c→
→ R ; b→
a→ → P; d→
→S

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 ! PAPER - IIT-JEE-2006
 IIT-JEE (2006)
(Memory Based Question Paper)
Mathematics

Section I:Multiple Choice Questions with one

correct answer. Q.5 Let a, b, c be sides of a triangle and any two
Q.1 If t1 = (tanθ)tanθ, t2 = (tanθ)cotθ , of them are not equal and λ∈R. If the roots
t 3 = (cotθ)tanθ , t 4 = (cotθ) cotθ and let of the equation. tx 2 + 2 (a+b+c)x+
3λ(ab+bc+ca) = 0 are real, then
π
θ ∈ (0, ) then
4 4 5 1 5
(a) < λ< (b) < λ<
(a) t4 < t2 < t1 < t3 3 3 3 3
(b) t4 < t1 < t3 < t2
5 4
(c) t4 < t3 < t2 < t1 (c) λ > (d) λ <
3 3
(d) t2 < t1 < t3 < t4 Ans. [d]
Ans. [d]
Q.6 For which interval for θ, the inequation
Q.2 The axis of parabola is along the line y =x (2 sin2 θ – 5 sin θ + 2) > 0. When 0< θ < 2π
and the distance of vertex from origin is 2
and that from its focus is 2 2 . If vertex and  13 π   π   π 5π 
(a)  , 2π  (b)  0,  ∪  , 
focus both lie in the first quadrant, so the  48   8 6 6 
equation of parabola is –
(a) (x–y)2 = 8 (x+ y– 2)
(b) (x–y)2 = 4 (x+ y– 2)  π 5π   π   5π 
(c)  8 , 6  (d)  0, 6  ∪  6 , 2 π 
(c) (x –y) 2 = (x + y– 2)      
(d) (x– y)2 = (x – y– 2) Ans. [d]
Ans. [a]
x2 − 1
Q.7 ∫ x3 2 x 4 − 2x 2 + 1
dx is equal to

 1
sin x 
 1
Lim  (sin x ) +  
x
 , for x > 0
Q.3 x →0  x  2 x 4 − 2x 2 + 1
  (a) + c
2x 2
(a) 0 (b) –1
(c) 2 (d) 1 Ans. [d] 2x 4 − 2x 2 + 1
(b) + c
x3
Q.4 Given an isoscels triangle, whose one angle
is 120° and inradius is 2 x 4 − 2x 2 + 1
3 . So the area of (c) + c
triangle is– x2

(a) 4π (b) 12 + 7 3 2x 4 − 2x 2 + 1
(d) + c
x
(c) 7+12 3 (d) 12 – 7 3
Ans. [a]
Ans. [b]

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 " PAPER - IIT-JEE-2006
Q.8 If ω = α+iβ where β ≠ 0 and z ≠ 1 satisfies Section II:Multiple Choice Questions with one or
 ω − ωz  more correct answer(s).
the condition that   is purely real,
 1− z 
then set of z is – Q.13 If f(x) = min{1, x 2, x3 }, then
(a) {z : z = z } (b) {z : |z| = 1, z ≠1} (a) f ′(x) > 0 ∀ x ∈ R
(c) {z : z ≠ 1} (d) {z : |z| = 1} (b) f(x) is continuous ∀ x ∈ R
Ans. [b] (c) f(x) is not differentiable for two values of x
(d) f(x) is not differentiable but continuous
Q.9 A plane passes through (1, –2, 1) and is ∀x ∈ R Ans. [b, d]
perpendicular to two planes 2x – 2y + z = 0
and x – y + 2z = 4. The distance of the Q.14 If a hyperbola passes through the focus of
plane from point (1, 2, 2) is –
(a) 2 2 x2 y2
(b) 0 the + = 1 and its transverse and
25 16
(c) 1 (d) 2 Ans. [a]
conjugate axes coincide with the major and
minor axis of ellipse, and product of
Q.10 If f ′′ (x) = –f (x) and g(x) = f′(x) and eccentricities is 1, then
2 2 (a) Focus of hyperbola is (5, 0)
  x    x 
F(x) =  f    +  g   and given that
  2    2  (b) Focus of hyperbola is (5 3 , 0)
F(5) = 5, then F (10) is
x2 y2
(a) 15 (b) 0 (c) The equation of hyperbola is − =1
9 25
(c) 5 (d) 10 Ans. [c]

x2 y2
(d) The equation of hyperbola is − =1
Q.11 Let a = î + 2 ĵ + k̂ , b = î – ĵ + k̂ 9 16
Ans. [a, d]
and c = î + ĵ – k̂ . A vector in the plane Q.15 The equation(s) of common tangent(s) to the
parabola y = x 2 and y =–(x–2)2
of a and b whose projection on c is of
(a) y = – 4 (x–1) (b) y = 0
1
length unit is – (c) y = 4(x–1) (d) y = – 30x–50
3 Ans. [b, c]

(a) 4 î + ĵ – 4 k̂ (b) 4 î – ĵ + 4 k̂
Q.16 Internal angle bisector of ∠A of triangle ABC,
meets side BC at D. A line drawn through D
(c) 2 î + ĵ – 2 k̂ (d) 3 î + ĵ – 3 k̂
perpendicular to AD intersects the side AC
Ans. [b] at P and the side AB at Q. If a, b, c represent
the sides of ∆ABC then.
Q.12 If r, s, t are prime numbers and p, q are the
postive integers such that the LCM of p,q is 2bc A
(a) AD = cos
r2t4 s2, then the number of ordered pair (p,q) b+c 2
is –
4bc A
(a) 224 (b) 225 (b) PQ = sin
b+c 2
(c) 252 (d) 256
(c) The triangle APQ is isosceles
Ans.[b] (d) AP is HM of b and c
Ans.[a, b, c, d]

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 # PAPER - IIT-JEE-2006
Q.17 A tangent at P(x,y) point on the curve y =
f(x) intersects to the axes at A and B points Section III :Questions based on comprehensions
respectively such that AP : BP ≡ 1 : 3, with one correct answer.
given that f(1) = 1, then– Passage – I
(a) normal at (1, 1) is x + 3y = 4 Now we define the definite integral using the
(b) equation of curve is 3y + xy′ = 0
b b−a
(c) curve passes through (2, 1/8) formula ∫a f ( x) dx =
2
(f(a) + f(b)), for more
(d) equation of curve is xy′ – 3y = 0
accurate result for c ∈ (a,b) ,
Ans. [b,c]
b − a  b − c 
Q. 18 f(x) is a cubic polynomial such that f(3) = 18, F (c) =  2 (f (a ) + f (c )) +  2 (f (b ) + f (c ))
f(–1) = 2 and f(x) has local maximum at    
x = –1. If f ′(x) has local maximum at x =
0, then a+b
when c = ,
2
(a) f(x) is increasing for x ∈ [1, 2, 5 ]
b b − a
(b) the distance between (–1, 2) and (a, f(a))
where x = a is the point of local minimum ∫a f ( x) dx =  
4  (f(a)+ f(b) + 2f(c))

is 2 5
(c) f(x) has local minima at x = 1 π

(d) the value of f(0) = 5 Q.21 Evaluate

∫0
2 sin x dx

Ans. [b c]
π π
(a) (1 + 2 ) (b) (1 + 2 )
Q.19 Let A is a vector parallel to line of 8 2 8
intersection of planes P1 and P2 through
π π
origin. P 1 is parallel to the vectors 2 ĵ +3 k̂ (c) (1 + 2 ) (d) (1 + 2 2 )
4 4
and 4 ĵ – 3 k̂ and P 2 is parallel to ĵ – k̂ Ans [b]

and 3 ĵ +3 k̂ than angle between vectors

Q.22 If f ′(x) < 0, ∀ x ∈ (a,b) and c is a point
A and 2 î + ĵ –2 k̂ is– such that a < c < b, and (c, f (c)) is the
point lying on the curve for which F(c) is
π π maximum, then f ′(c) is equal to
(a) (b)
2 4
π 3π f (b ) − f (a) 2(f (b ) − f (a ))
(a) (b)
(c)
6
(d)
4 b−a b−a

2 f (b ) − f (a )
Ans [b, d]
e x (c) (d) 0
0 ≤x< 1 2b − c
 x −1 1< x ≤ 2
−
Let f(x) = x − e
2 e Ans [a]
Q.20 2<x≤ 3 and


t  t – a
∫a f ( x) dx – 
x
g(x) = ∫0 f ( t ) dt , x ∈ [1, 3] than g(x) has
Q.23
Lim 2 
(f (t ) + f (a))
exists,
t→a
(a) local maximum at x = 1 and local (t – a )3
minimum at x = 2
then which of the following is the atmost
(b) No local maximum degree of function f(x) is
(c) No point of local minimum (a) 1 (b) 2
(d) Local maximum point is x = 1 + log 2 (c) 3 (d) 4
and local minimum at x = e Ans [a, d] Ans [d]
CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 $ PAPER - IIT-JEE-2006
Passage – II Q.28 A variable circle touches to the line L and
Total n urns each containing (n+1) balls such circle C1 externally such that both circles
that the ith urn contains i white balls and are on the same side of the line, then the
(n + 1 – i) red balls. locus of center of variable circle is –
Now u i be the event of selecting ith urn, (a) ellipse (b) circle
i = 1, 2, 3 .... n and w denotes the event of (c) Hyperbola (d) parabola
getting a white ball. Ans. [d]

Q.24 If P (u i) ∝i, where i = 1, 2, 3 , ...... n, then

Q.29 A line M through A is drawn parallel to BD.
lim Locus of point R, which moves such that its
n → ∞ P(w) is equal to distances from the line BD and the vertex A
2 are equal, cuts to line M at T 2 and T 3 and
(a) (b) 1 AC at T1 , then area of triangle T1T 2T 3 is
3
1
3 1 (a) (sq.units) (b) 2(sq.units)
(c) (d) 2
4 4
Ans [a] 4
(c) 1 (sq.units) (d) (sq.units)
3
Q.25 If P (ui ) = c, where c is a constant then
P (un /w) is equal to Ans. [c]

2 n Passage – IV
(a) (b)
n +1 n +1
1 0 1 
1 1 If A = 0 1 − 1 , if U 1, U2 and U3 are
1 1 0 
2 (n + 1)
(c) (d)
n +1
Ans [a] column matrices satisfying

Q.26 If n is even and E denotes the event of 1 2 3

A U1 =  0  , AU2 =  3  , AU3 = 2 , and
choosing even numbered urn and also 0 0 1
1
P(ui) = , then find the value of P (w/E) U is 3×3 matix whose columns are U 1, U 2,
n U3 then answer the following questions.
n+2 n+2
2(n + 1)
(a) (b) Q.30 The value of |U| is –
2n + 1
(a) 2 (b) 3
n 1 (c) 6 (d) 12
(c) (d)
n +1 n +1 Ans. [b]
Ans [a] Q.31 Sum of the elements of U –1is –
Passage – III (a) 1/12 (b) 1/6
Let C 1 is a circle touching to all the sides of (c) 1/3 (d) 1/4
square ABCD of side length 2 units internally Ans. [c]
and C 2 circle is passing through the vertices Q.32 Find the value of –
of square. A line L is drawn through A.
3
Q.27 Let P is a point on C 1 and Q is on C 2, then [3 2 0] U 2 is -
0
PA 2 + PB 2 + PC 2 + PD 2
= (a) 13 (b) 26
QA 2 + QB 2 + QC 2 + QD 2
(c) 12 (d) 24
(a) 0.75 (b) 0.5 Ans. [a]
(c) 1.25 (d) 1
Ans. [a]
CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 % PAPER - IIT-JEE-2006
Section IV :This section consists of 4 questions. Ans.–
Answers are to be given in between (a) → (p)
0000 to 9999 in the form of nearest (b) → (s)
integer.
(c) → (r)
(d) → (q)
Q.33 If roots of x2 –10cx –11d = 0 are a, b and the
roots of x2–10ax –11b = 0 are c, d, then the
value of a+b+c+d is equal to (a,b,c,d are Q.38 Column I
different numbers) …………………………. (a) Area bounded by (p) 0
2
–4y = x and x–1= – 5y 2
Ans. [1210]
(b) cosine of the angle (q) 6 ln 2

∫0 (1 − x ) dx
1 50 100 of intersection of curves
y= x x–1 and y = 3x–1 log x
∫0 (1 − x ) dx
Q.34 The value 5050 1 50 101 is equal to

(sin x )cos x (cos x. cot x – log(sin x )sin x )dx

π/2

…………………..... Ans [5051]

(c) ∫0
(r) 4/3,
(d) Not available (s) 1,
2 3
3 3 3
Q.35 Let a n = –   +  – ………………
4 4 4 Ans.–
(a) → (r)
n
3 (b) → (s)
(–1) n–1   and bn = 1–an then find the
4 (c) → (s)
natural number n0 such that b n >an , n > n0.
is………. Ans [0005]
∞
 1 
Q.36 If f(x) is twice differentiable and f(a) = 0,
Q.39 (a) ∑ tan – 1 2i 2  = t , (p) 0
i= 1
f(b) = 2, f(c) = –1, f(d) = 2, f(e) = 0,
then tan t =
where a < b < c < d < e then the minimum
number of zeroes of g(x)= {f ′(x)}2 + {f ′′(x) 5
f(x)} in [a,e] is ? Ans.[0006] (b) A line perpendicular to (q)
3
x + 2y + 2z = 0 and passes
Section V: This section consists of 4 questions. through (0, 1, 0) then the
Each having two columns with 4
perpendicular distance of
entries in each column. Entries of
column I are to be matched with the line from origin is
column II. One entry of column I may (c) Not available (r) 1
have more than one matching in (d) Not available (s) 2/3
column II.

Q.37 Three normals drawn at P,Q and R on the Ans.–

parabola y2 = 4x intersect at (3, 0). Then (a) → (r)
Column I Column II (b) → (s)
(a) Radius of circumcircle (p) 5/2
of ∆ PQR
(b) Area of ∆ PQR (q) (5/2, 0)
(c) Centroid of ∆ PQR (r) (2/3, 0)
(d) circumcentre of ∆ PQR (s) 2

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 & PAPER - IIT-JEE-2006
 Column I
Q.40(a) Two rays in the Ist quadrant ax–y = 1
and x + y = |a| cut each other in the
Interval a ∈ (a 0, ∞) the value of a0 is
(b) sinA sinB sinC + cosAcosB = 1
then sinC =

1 0
∫0 (1 − y + ∫1 ( y − 1)dy
2 )dy 2
(c)

(d) Let a = α î + β ĵ + γ k̂ , k̂ ×( k̂ × a ) = 0
and a point (α,β,γ) lies on plane
x + y + z = 2, then γ =

Column II
(p) 4/3

1 0
(q) ∫0 1 − x dx +
∫–1 1 + x dx

(r) 1
(s) 2
Ans.–
(a) → (r)
(b) → (r)
(c) → (p) & (q)
(d) → (s)

CAREER POINT, 112, SHAKTI NAGAR , KOTA (RAJ) PH. 2500492 ' PAPER - IIT-JEE-2006