Beruflich Dokumente
Kultur Dokumente
itance diode with largefigure-of-merit,” IRE Trans. Electron [SI P. Brook andC. S. Whitehead,“Hyperabruptjunctions in
Devices, vol. ED-8, pp.370-377, Sept. 1961. Au-Si Schottkydiodesbyion-implantation,” Electron. Lett.,
[j] M . Shinoda, “Capacitance of the hyperabrupt junction fabri- vol. 4,no. 16, pp. 335-337, 1968.
cated with alloy diffusion technique,” J . Inst. Electron. Commun. 191 M. P. Lepselter and S. M. Sze, “Silicon Schottky barrier diode
Eng., Jup. (Abstracts), vol. 47, no. 3, pp. 14-15, 1964. with near-ideal I-V characteristics,” Bell Syst. Tech. J., vol.
[6] T. Sukegawa, K. Fujikawa,and J . Nishizawa,“Siliconalloy- 47, p. 195, 1968.
diffused variable capacitance diode, ’I Solid-state Electron., vol. [lo] J. W. Mayer, L. Eriksson, and J. A. Davies, Ion-Implantation in
6, no. 1, pp. 1-24, 1960. Semiconductors. Kew York: Academic Press.
[7] S. Nakanuma, “Siliconvariablecapacitancediodes with high [ l l ] R. A. Moline, “Ion-implantedphosphorus in silicon:Profiles
voltage sensitivity by low temperature epitaxial growth,”IEEE using C-Vanalysis,” J. Appl.Phys., Aug. 1971.
Trans. Electron Devices, vol. ED-13, pp. 578-559, July 1966. [12] R. W. Treible and R.A. Moline, unpublishel.
Absfracf-A theoretical low-frequency noise modelforthe [18]. In adopting McWhorter’s tunneling model, these
epitaxial-channel surface field-effect structure is presented where authors assumed that carriers in conduction or valence
random modulation of the channel conductance arises from fluctua-
tion of charges trapped at the oxide trap states near the Si-SiOz
bands tunnel directly into the surface states which are
interface. In this model, charge fluctuation in the oxide traps arises located at some energy in the semiconductor bandgap
from c,arrier tunneling between the fast interface surface states and and at some distance away from the hterface in the
the oxide trap states. A second fluctuation, at higher frequencies, surface oxide. Electron energyof about half of the semi-
arises from the random thermal emission and capture of electrons conductorgap (-0.5 eV) mustbedissipated. I t was
and holes at the fast interface states through the thermal or Shockley-
Read-Hall process. Different oxide trap densities were introduced
shownbyKane [19] thatneithertheauger-impact
into the interfaceregion of the metal-oxide-siliconfield-effect mechanism, nor the photon mechanism, nor the multi-
structures using a carefully controlled and reproducible oxygen heat photon processes are plausible. Thus, an intermediate
treatment technique. Energy distributions of the oxide trap densities s t a t e is essential.
are obtained from capacitance measurements. Humps are observed Inthispaper, a newmodel of carriertunneling
betwelen theflatbandandtheonset of strongsurfaceinversion
(lower half of the bandgap) in both the noise power and the oxide
throughanintermediatestate is
proposed t h a t is
trap density versus gate voltage(or surface band bending) plots. analogous to the tunnelingmodel used earlier to explain
Theoretical noise power calculations using the experimental oxide the excess currents observed in gold-doped silicon tun-
trap densityprofile fromthe capacitance-voltage data agree verywell nel diodes [20]. In this model, the carriers in conduction
with theexperimentalnoisehumpsinbothmagnitudesand fine orvalencebandscommunicatewiththe fast surface
structures. It is shown that the frequency spectra of noise depend
strongly on the oxide trap density profile in theoxide. It issuggested
states located at the interface through the Shockley-
that theoxide traps are due to the excess oxygen at theSiOz-Si inter- Read-Hall (SRH) process. T h e carriersthentunnel
face. into or out of the oxide traps located a t some distance
away from the interface elastically. This model is more
I.INTRODUCTION plausible than early models since it is well known that
thethermal SRH processis very efficient andthat
HE 1,’snoise has been studied by many investi-
continuous (in energy)distribution of fastsurface
gators. Early studies were primarily on germani-
states at the interface is a commoncharacteristic of
umfilamentswhosesurfaceswereexposed to
silicon-silicon-dioxide interface. In t.his model, a
differentambients.nlanydifferentmodelshavebeen
separate time constant for the tunneling process is then
proposed to explain the noise d a t a [1]-[9]. McWhorter
obtained, in addition to the Shockley-Read time con-
[ l o ] proposed -the tunneling model to explain the wide
stant. This is in contrast to the earlier models just re-
range of frequency spectrum observed in Ge filaments,
ferredtowherethetunnelingprocess is tacitlyab-
which has beenused by many authors to account for
sorbedintotheShockley-Readthermalcapturerate
the surface l/f noise in RlOS field-effect devices [11]-
coefficients.
I n gettingacorrelationbetweenthesurfacestates
Manuscript received March 23, 1971; revised September 18,1971. oroxidetrapsandthe l/f noise, themain difficulty
This work was supported in part by the U. S. Air Force Office of
ScientificResearch andthe AdvancedResearch Projects Agency. encounteredinthepreviousinvestigations lies in the
The work is based in part on the doctoral thesis of H. S. F u sub- lack of detailed data on the spatial and energy distribu-
mitted to the Graduate College of the University of Illinois, Urbana,
Ill. tions of the surface states. A certain type of spatial or
The authors are with the Department of Electrical Engineering energy distribution was generally assumed a priori in
and the Materials Research Laboratory, University of Illinois, Ur-
bana, Ill. 61801. the earlier work. Recently, Sah and Hielscher [ l l ] have
274 IEEE TRANSACTIONS ON ELECTRON DEVICES,
FEBRUARY 1972
shownexplicitly t h a t a linearrelationshipbetwcm
surfacestatedensityandthe l/f noise exists. Th.:y DrainSection
Metal Semiconductor
Oxide
terminologies used here. Surface states which occur 11
a n infinitesimally thin layer a t t h e interface (x=O, ; J ) Fig. 3. Energy band diagram and charge changing
processes in the epitaxial n-channel MOS transistor.
are known as fast surface states or interface states a r d
they can exchange charges readily with the conductic.111
and valence bands. Those states which are located at :i surface state can also tunnel into an empty oxide trap
certain distance away from the interface ( x = x , y ) a -13 located in the oxide at some distance away from the
known as slow surface states or oxide traps since t h t y interfaceandviceversa.Consideranemptysurface
cannot readily exchange charges directly with the co:1- state located at (x = 0 , y). It can capture an electron
duction or valence bands. The transition processes a r d from the conduction band at the same position in the
theenergybanddiagram of thedeviceareshown 11 channel[process (a)] and becomenegativelycharged.
Fig. 3. Thesetransitionmechanismsarediscussed 11 At the same time, an electron from the n+ source con-
more detail in the following sections. tact will drift into the channel to maintain the same
number of electrons. Since
electrons are
majority
A . Charge Trapping Mechanism carriershere,theelectrondrifttime is thedielectric
A fast surface state with energy level at ET with.11 relaxation time,
which is of the order of s [21].
the energy bandgap will act as a Shockley-Read-H::Il T h e foregoing capture processthereforecauses a net
recombinationcenter. I t will thermallycapture ele':- charge fluctuation at ( x = 0, y ) . The electrons captured
trons from the conduction band or emit trapped ele:- by the surface states can also be thermally excited to
trons to the conduction band. Similarly, holes will mal..^: the conduction band [process (b)] or recombine with a
transitions between the surface states and the valen1::e hole captured [process (c) ] from the valence band at
bandstates. A trappedelectronin t h e fastinterfa#::(: ( x = 0 , y). If the trapped electron is thermally excited
PU AND SAH: SURFACE I / ~ N O I S ~ 275
into the conduction band, i t will be swept away rapidly The net rate of change of electron and hole concen-
from ( x = 0, y) to (x‘, y ) by the surface electric field in trations in the conduction and vaSence bands, due to
the x’ direction, causing a net charge change a t (x = 0, y). capture and emission processes at the fast surface states
However, if a hole from the valence bandis captured by (neglecting all
other
generation--recombination
pro-
occupiedsurfacestates,there will be no netcharge cesses), and the net rate of change of trapped electrons
change a t (x = 0 , y)sinceholescannotcommunicate at the surface states and oxide traps (located from x to
with the external circu.it due to the large barrier from x+Ax fromtheinterface)canbeobtainedfromthe
surfacebandbending.Thesameapplies if a hole is rates of these processes. They are
thermallyexcitedfrom a surfacestate[process(d)].
dns-
- j N
Because the hole pocket is isolated from the external - (b) - (a) - -
circuit (there is no hole current), holetransitionsbe- at 4
tween the surface states and valence band states will
notinducenetchargefluctuationintheconduction
channel and thereforewill not give low-frequency noise.
A trap located in the oxide close to the interface can
exchange charge with the fast surface states or the band
states at the interface through tunneling. An electron
capturedbyafastsurfacestate will tunnelintoan
oxide trap at the same energy level [process (e)] located
a t a distance from the interface and induce a charge of wherejN is the density of electron drift current due to
q ( x , - % ) / x , a t (x = 0, y), where x. is the thickness of the the presence of the electric field, resulting in a shotnoise
oxide.Similarly,thereverseprocess[process(f)] will spectrum.
induce a net charge of - q ( x , - x ) / x , in the conduction
band. B. Charge Trapping Time Constants
In order to calculate the trapping time constants for The fluctuating components of ns, Psl nss, and nTO‘
thechargefluctuationsinthefastsurfacestatesand can be obtained from the foregoing equations by sepa-
oxide traps, the following parameters will be defined. rating the steady-state components. Let
Surfacedensities of electronsandholes,
respectively, a t t h einterface x = 0, in num-
ns = Ns + 6ns (34
ber/cm2. ps = Ps $. sps (3b)
Captureprobabilitiesforelectronsand nss = Nss +6nss (3 4
holes, reslpectively, by a sheet of interface
states, in cm2/s.
%TO‘ = 1VTO’ + &%TO‘ (3d)
Emissionratesforelectronsandholes, j~ = J N + sjN (34
respectively, from the interface states, in where NE, PB,NSS,NTO’,and J N are the sLeady-state
number/s. quantities and S denoted the fluctuating component.
Densities of electronsandholes,respec- The time dependence of 6ns, 6 p , ~&ass,
, and 8nTO’ can
tively,trapped in a sheet of interface beobtained by substituting (3a)--(3e) into (2a)-(2d).
states, in number/cm2. This involves four time constants whose exact solutions
Electronand holeconcentrations in the are tedious to obtain. However, the time constant for
oxide traps, innUmber/Cm.’(n’To( = nToAx) the conduction electron fluctuation 6ns is much shorter
and $TO’( = p r o a x ) are the sheet densities than those of the trapped charges 6p8, Gnss, and 6nTo’;
of electrons and holes, respectively, in the thus, this problem can be simplified by considering the
oxidetrapslocatedfrom x t o x + A x , in slower time constants only since we are interested in
number/cm2.) thelow-frequencynoise. The algebra is giveninAp-
Tunnelingprobabilitiesforelectrontun- pendix I. The time constants associated with 6nss and
neling into or out of a trap, in cmz/s. 6nTo’ are given by
The rates (number/cm2.s) of processes (a), (b), (c), 1
= .___
(d) , (e), and (f) in Fig. 3 can then be expressed as 78s
+$ ~-sI
c ~ ~ ~ ens - 4- eps
cPsPs
(44
I
region. I t is showninAppendix I that the domin2nt those of the drain section. 8 v d is the open-circuit noise
low-frequency term in ( 5 ) is the first term which con ICS voltage at the drain electrode, due to the fluctuationin
from electron tunneling into or out of the oxidetr:.p the thin slab at y , and is given by
states located a t a region from x t o %+Ax. Therefore,
the charge fluctuationS Q N is given by
TABLE I
PARAMETERS
OF THE N-CHANNELDEVICES HEATTREATMENT
AND OXYGEN (OHT) CONDITIONS
I
1-
b
I
i
I
4
I
I -1 I.2 x 10j1
*r
-8 -7 .E -5 -4 -3 -2 - 1 0 1 I
'6 dol's I
I
/ a
IO" * I
Fig. 5. Low-frequency and high-frequency capacitance vers
..
1:3
the gate voltage curves for devices (4a), (l),and (5). \: o;,
.bZ
0 ?*
-7 -6 -5 -4
vc volts
":
7
6t
B. Total Density of States p
The total (all time constants) oxide trap and surface
state density, p(states/cm*.eV), is obtained using the
Termantechnique [26] whichinvolvesthegraphical
5[
4 differentiation of the high-frequency C-V curves. T h e
resultsfortypical (111) samples with OHT at 600°C
jl
2-
__I.. I-L
_L-_.,..
Argon I
(units4aand4b)areshowninFig.
peakedsurfacestates
7 whichindicate
of 5 X l 0 l 1 states/cm2.eVat
E,+0.3 eV and 2.8X10" states/cm2.eV at E,+0.4 eV.
The larger peak at0.3 eV+E, compares favorably with
500 700 900 I100
thatobserved on theverythin oxidecapacitance
T"C
previously reported [ 2 7 ] .
Fig. 6. Fixed oxide charge density versus the temperatureof oxy;.en
heattreatment. 0 (111) n on p+; A (100) n on p; (1 I) w C. Oxide Trap Density
n-type(argon annealmg); 0 (111) n-type; A (100) n on p. PTTO
I
'1
10-20
A typical result of pTTo(w) is shown in Fig. 8 fora
(111)device O H T a t 600°C (unit 4a) where the total
density of states p(al1 w ) from Fig. 7 is also shown as
dashedlines.Humpsareobservedbetweentheflat
bandand
the
onset of strong surface
inversion
10-21
( U S = %Up). T h e secondary peak of p ( w ) a t E,+0.4 eV
is not
evident
in
the ~ T T O ( W )data
duetothe decreasing -
N
resolution a t higher
frequencies
(16).
using
when E
I
y -z
'v. EXPERIMENTA.L
RESULTSON 1/f NOISE e, A
lo-=
T h e noise power (short-circuit rms noise current) of
the devices was measured a t a drain voltage V Dof SO
mV, using a Hewlett-Packard 302-A wave analyzer, A
high-gain
low-noise
preamplifier
was
designed
for
these measurements. The drain voltage of SO mV cor-
respondstoabout 1.5 kT (at roomtemperature) of
energyspread.The noisemeasuredheretherefore is
d
I000
2
1
1000
f Hz f tJ2
I I I I I I I (a> (b)
-7 -6 -5 -4 -3 -2 -I 0
v, VOltS
Fig. 12. Noise power versus frequency a t different surface
potential ranges. (a) Device (4a). (b) Device (8).
Fig. 11. Noise humps versus gate voltage for devices (device n 1rn-
bers labeled as shown) fabricated on (111) surfaces (solid li 18,:s)
and (100) surfaces (dashed lines) and oxygen heat treated a t clif-
ferent
temperatures. @ 600°C; A 800°C; X 1000°C; 0
control.
t
thesimilar,plots fordevices fabricated on (100) 5;ur-
faces. Note that the noiselevels of the (100) devices
are lower than those of the (111) devices due to a lo-f.er
number of surface states. No significant noise h u m / ) is
observed for the control sample (unit 5) which also llad
no hump in theC-V plot (Fig. 5).
B. FrequencyS@ectrunz
-20 -I5 -I0 -5 0
T h e frequencyspectra of the noisewere obtailed v, vo115
for fixed gate and drain voltages. Fig. 12(a) shows the Fig. 13. Noise humps versus gate voltage a t f=20 Hz for devices
log-log plots of noisepower versus frequency for the (9) and (10). Curve @)-original; Curve @)-afterapositive
bias-temperaturetest;curve (c)-after sequentialpositiveand
(111) device O H T at 600°C (unit4a).Gatevoltage negative bias-temperature tests.
parameters are V c ( E - E E , )= -3.0 (1.0 eV), -5.6 :1,9.4
e17 main hump) and -8.0 (0.0 eV) V, which corresp m d
the noise peak. This implies t h a t devices fabricated on
to the surface accumulation, weak inversion, and strmg
(111) and (100) surfaces have different pZrTOdistribution
inversionregions,respectively. T h e slopes of the dot
since theslope of the power spectra (i,v2 versus f) is
tendtochangefrom 1.0 to about 2.0 asthesurace
sensitive to p r T o versus x in the oxide.
changesfromaccumulationtostronginversion.'The
slope a t V O= - 5.6 V (near the peak of the noise ve ':jus
V c curve) is about1.57.Forgatevoltages betv,c:en C. E f e c t of the Bias-Temperature Test and Phosphorous
-5.0and-6.0 V, the slopesfluctuatebetween 1.08 Gettering
to 1.62, as can be understood from Fig. 9. Slopes gre ater Because of the ion drift or the slow trapping effect,
t h a n 1.0 are attributed to the large spatial variatiorl of the bias-temperature test will cause the C- V curve (and
pTTo in the oxide. These slopes do not change sigr1,ifi- hence the noise humps) to shift along the gate voltage
cantly as the drain voltageof the device is increase1:l u p axis. T h e noise profiles of the device are measured be-
toandbeyondchannelcurrentsaturation (5.0 V). fore and after electrically stressing the device a t 250°C
This indicates that the noise measured beyond current for about 10 min under an electric field of lo6 V/cm.
saturation is generated mainly in the channel re :ion The results are shown in Fig. 13 for unit 9 (no phos-
nearthen+sourcecontact.The noisegeneratelf in phorous gettering)andunit 10 (withphosphorous
this region is amplified by the whole transitor.Fig. gettering[28]-[30]);both were (100) devices O H T
12(b) shows thesimilarplotsfor a (100) device Jiith a t 600°C. Curve ( a ) is the originalnoiseprofile, and
600°C OHT (unit 8). The gate voltages here also cor- curves ( b ) and ( c ) are the profiles after sequential posi-
respond to surface accumulation, weak inversion, m d tive and negative bias tests. Very different results are
strong surface inversion.A slope of 1.35 is observed near observed between these two devices. First, the magni-
FU A N D SAH: SURFACE 1/f NOISE 28 1
tude of the noise for unit 10 is much lower than that for
unit 9 [curves ( a ) ] ,Second, the direction of the shifts
on the noise curves (as well as C- V curves) are different.
For unit 9 (not gettered), a positive gate bias causes
the curve to shift to a more negative direction, and a
negative gate bias causes the curve to shift to a more
positive direction. For unit 10 (gettered), there is prac-
tically no shift. Third, the noise is essentially constant
(in fact i t decreases slightly for the nongettered unit 9)
after drift. The second and third observations indicate
that positive ion (sodium [31]) drift toward the inter- I
face does not affect the noise so that these ions are not .I
1 0 4 L -
the noise source, and the drift of negative ions, which IO" 10'2 1010 !O" 1012
tI
t
6x
1 I
4.
I
V G "Oll5 vg "0115 10151 I I I I
6 4 2 0
(a> ( b') (c) x i
Fig. 15. Experimental correlations between noise power and ox de Fig. 16. Relative oxide trap concentration versus distance from the
traps for device (44. (a) Noisepowerversus gatevoltage. :I)) interfacefordevice ( 4 4 withgatevoltage as aparameter.
Oxide trap densitiesversusgatevoltage. (c) Totaldensity 'If
states versus gatevoltage.
T h e doubleandsharphumpsinthetotalsurfaze
statedensitydata of Fig. lj(c)comparedwitht!le
broader noise hump indicate that the surface states it
the main peak of E,+0.3 eV are probably rather f a s t
s t a t e s a troom temperature and hence do not contribu
:I
to much of the low-frequency noise observed. This i'j
also consistent with our earlier data for this peak which
had to be taken a t 130°K instead of 300°K to increa:r:
the time constants to a convenient range [27].
OF EXPERIMENTAL
VII. COMPARISON AND
THEORETICAL
NOISE CURVES
T o compute the theoretical noise power of the device
using (1j), the spatial distribution of the oxide tra 2,
concentration N T T ~ ( must x) be known. This is evaluate41
fromtheexperimentaloxidetrapcapacitancedate, -7 -6 -5 -4 -7 -6 -5 -4
shown in Fig. 8, which gave P T T O ( O ) and then NTTO(CO) v, v o l t 5 v, volts
= 4 0 k T p T T ~ ( w )Since
. most of the contributions to th': Fig. 17. Theoretical noisepower versus gate voltagecurvesusing
p ~ ~ o ( come
w) from the oxide traps a t OTTO = 1, we haw: experimental oxide trap concentrations given in Fig. 16 and ex-
perimental noise power versus gate voltage curvesfor device (4a).
NTTO(W)'VNTTO(~/'TTO). Hencefrom T T O = T O exp (20%'
and NTTo(u)= NTTO[ T ~ - , exp (- 20x) 1, the position o '
APPENDIXI
Since I or1
, the reciprocal of the time constant for the
Shockley-Read-Hallrecombinationprocesses(a),(b),
DERIVATION
OF ’TIME CONSTANTS AND ~ Q N (c), and (d), is much larger than that of the tunneling
I t waspointed out inSection 11-A thatthetime
1
process y ] , we have1 011 >>I I.
y Hence in the inversion
constant of 6ns is much shorter than those of 6 $ ~ ,8n58,
range, we have l o r 1 -1
E l >>/PI, 171, Thetime 1111.
constants for Gnss and &??TO‘ can be approximated by
and 6 n ~ o ’ .Using (2a)-(2d), and neglecting an,, we have
-X
8QX = qsnTO’(0)
cw
cw
+ co [-
X0
X0
EO + y
X
- a1
X0
X
--dP+
X0
Y + E - S)a2]. (26)
APPENDIXI r
CIRCUITOF A N MO!:
SMALL-SIGNAL EQUIVALENT
STRUCTURE INCLUDING
THE TUNNELING PROCESI.:
T h e small-signal equivalent circuit which includes the
SRH process between the interface states and the con-
duction or valence band states and the tunneling prol::ess
betweentheoxidetrapstates(locatedfrom x to
x + A x ) andtheinterfacestatescan bederivedfrom r
(2c) and(2d)using(la)-(lf).Thedetailedmathe-
maticalderivations will bepresentedelsewhere. '!'he
effect of bulkgenerationandrecombinationin che
depletion layer is neglected here since i t was pointed out
by Nicollian and Goetzberger [ 3 6 ] that this effect 7,QilI
cause a constant high conductance in the strong invm- Fig. 18. Small-signal equivalent circuits for a n MOS structure in-
cluding thetunneling mechanism.(a) Withtraps located at x
sion range, which was not observed in this study. Fig. t o % + A x . (b) Equivalent parallel capacitance and conductance
18(a) shows the equivalent circuit for the traps local.t:d for the entire MOS structure.
in the range of Ax a t x . T h e circuit elements are gi-c,c:n
as follows: the equivalent parallel capacitance and conductance of
the oxide traps. They are given by
(..'9)
(37)
(23 )
By taking the derivativeof CTOwith respect to w and
using (34), (16) can be obtained.
ACKNOWLEDGMENT
(33) Theauthors wouldlike tothank M. J. McNuttand
P. S. Chung,whohaveassistedinthetedious noise
q2 (3 L) measurements.
Ct, = - A ' ~ ~ o f t O (-ftD)
1 F/cm3
kT
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Correspondence
Manuscript received August 23, 1971. This work was supported in part by the
l/l = l / A + l/li.
Air Force Systems Command, Rome Air Development Center, Griffiss Air Force
Base, N. Y . I t is noted that an exact relation m&+eH) =exp (enD)m&) is used
The author was with the School of Electrical Engineering, Cornel1 University, instead of the commonly used Taylor expansion. The value of Zi is
Ithaca, N. Y . He is now with the Department of Electrical Engineering, University
of Pittsburgh, Pittsburgh, Pa. 15213. to be regarded as infinite for energy below ei. In the Case where the