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Meat technology update

00/6 – December 2000


Reprinted November 2006

Frozen meat: loss of


Water and Freezer Burn
Freezing does not prevent ‘evaporative’ other quality attributes are not affected,
loss of water from meat products. moisture migration has a significant
Desiccation through the inadequate use quantitative (and economic) effect in the
of packaging materials can be a major form of weight loss. For instance, the
problem with frozen meat and other New Zealand experience was that typical
foods. Moisture migration occurs in weight losses during conventional meat
frozen foods and can have major effects processing amounted to 1 to 2% during
on their chemical and physical properties. chilling, 1% during freezing and about
It can lead to several consequences, 0.5% per month during storage and
depending on the food: transport unless the product was
wrapped in an impervious film.
• moisture loss by sublimation (direct
conversion from ice to water Freezer burn
vapour);
Freezer burn can occur when freezing,
• moisture absorption and storing and distributing bone-in beef,
redistribution; sheep or goat meat in single or double
stockinette—or in stockinette-hessian,
• recrystallisation of ice;
unless considerable care is taken. It can
• drip loss during thawing. also occur when plastic bags or
wrappings around individually wrapped
This publication focuses mainly on pieces or cartoned meat are not tight
moisture loss from meat and meat enough to prevent air pockets adjacent to
products, and the more significant the meat surface, or when they are torn.
manifestations of that loss.
If the surfaces of frozen meat are
exposed and, therefore, subjected to
Moisture loss drying, the ice evaporates directly from
the frozen state. Vapourisation from ice
Historically, moisture loss, leading to
crystals results in voids where the
desiccation was the main limiting factor in
crystals were and a honeycomb structure
the storage life of frozen beef and lamb
of minute air pockets in the meat surface.
carcases. Even when appearance and
This results in the light-coloured blemish
known as freezer burn.

In the early stages of freezer burn, most


blemishes disappear on thawing and
more severe burns sometimes disappear
on cooking. Extensive freezer burn is
completely irreversible, as the meat proteins pressure between the meat surface and the
have been denatured and will not rehydrate. wrap. Moisture within the fibres of the meat
This denaturation is often accompanied by will sublime and diffuse to the wrap until the
the development of off-flavours from the meat itself equilibrates to the new
concurrent oxidation of fat. temperature. When the freezer environment
warms slightly again, the ice on the wrap will
Moisture loss and freezer burn are usually sublime and should, in theory, diffuse back
caused by a combination of conditions during into the meat. However the fibres constrict
freezing and storage. or are capped by ice, preventing further
resorption. Thus, after a cooling-warming
Freezing cycle, there may be a net migration of water
from the inside toward the surface and the
Rapid freezing causes less weight loss then wrap. This ‘cavity ice’ is a common
slow freezing, but very rapid freezing makes occurrence in wrapped food after storage.
the meat more susceptible to freezer burn Consequently, it is most important to control
during subsequent storage. freezer store air temperature to give
minimum variation of product temperature.
The storage period before freezer burn
appears may be increased by avoiding It is also important that the product should
freezing the product quickly while its surface enter the freezer store at the same
is still wet. The surface water creates a thin temperature as that of the store. If the meat
layer of ice with small crystals just under the temperature is higher than that of the
surface. This ice layer predisposes the surfaces and refrigeration coils in the freezer
surface meat to early onset of freezer burn. store, then water will evaporate from the
warmer meat into the air stream and
Storage condense on those colder surfaces and coils.
The greater the temperature difference, the
During storage, any condition or activity that faster water will be transferred and the
causes evaporative weight loss can lead to quicker the meat will dehydrate.
freezer burn. Evaporative weight loss is
reduced at relatively low air temperature and Products with a large surface area, such as
air velocity and comparatively high relative frozen hamburgers, are particularly
humidity. susceptible to freezer burn caused by heat
flow into or out of a carton. Most of the heat
Both fluctuations in temperature and transfer occurs where the patties are in
elevated temperatures relative to normal contact with the carton surface exposed to
storage conditions can increase dehydration. freezer air.
Typical values for the rate of weight loss
from exposed meat carcases during frozen In a well-designed freezer store, temperature
storage suggest that the rate of sublimation variations are minimised and air temperature
(evaporation) is halved for every 10°C fall in is constant throughout the store. Minimising
temperature. To minimise dehydration of the heat entering the freezer store can
frozen meat in freezer stores, the product reduce drying. Common sources include:
temperature must be kept constant. In
theory, the effects of small temperature • heat transfer through the insulation;
fluctuations (e.g. 1-2°C) should be negligible.
• heat from lights and fans;
However, several physical phenomena may
contribute to magnification of the effect of
• heat generated by people and
temperature fluctuations. One of these is
equipment working in the store; and
irreversibility. For a porous food such as
meat in a vapour-tight film, a small drop in • most importantly, heat entry through
the freezer temperature will cool the wrap. open doors or poorly sealed closed
Water vapour will frost onto the inside of the doors.
film. This causes a drop in water vapour

2
Defrost procedures should also be checked. a significant factor in moisture removal.
Shallow coil depth with large face area will
‘Hot spots’ near the walls and floors of minimise moisture loss.
freezer stores can be avoided by the use of
pallets or dunnage. This allows air to The presence of significant quantities of
circulate and remove the incoming heat. cartoned product in the same freezer store
as naked carcases can accelerate
The higher the heat gain from the desiccation if the cartons have the capacity
surrounding environment, the greater the to absorb moisture from the circulating air.
operational period of the freezer store The differential moisture levels between
refrigeration system, which leads to naked carcases and carton materials can
increased moisture loss. The rate of lead to the transfer of moisture from the
moisture loss is known to be higher in carcases to the cartons. Naked or
summer than in winter. The better the stockinette-/hessian-wrapped carcases
insulation of the freezer store, the lower the should not be stored with packaged frozen
heat gain. foods in cartons or other packaging capable
of moisture absorption.
The type of heat entering a freezer store is
signification in determining the extent of The absolute weight loss from goods stored
moisture loss from meat. ‘Dry’ heat – from in a freezer store or shipping container is
sources such as lights, electric motors and almost independent of the actual amount of
heat conduction through walls, floors and product in that store. This arises from the
ceiling – has a greater effect than ‘wet’ heat following facts:
which is heating accompanied by a high
humidity. Sources of wet heat include that • Heat gain into the store or container is
resulting from interchange or air at independent of the product load.
doorways. The fan motors of forced-draft
evaporators are a significant heat-load • The evaporation capacity from frozen
component in a freezer store. In older style meat is considerable.
stores, refrigeration of the room was
achieved via pipe coils adjacent to the walls • Evaporator coil capacity is constant.
or ceiling. This construction had the
beneficial effect of shielding product from Thus, for a given set of freezer store/
radiant heat transmitted through the walls. container operating conditions, a given
The result was less moisture loss from the amount of water can be evaporated if it is
product. Successful efforts have also been available. If a freezer store is only partially
made to eliminate dry heat by using jacketed loaded, and the product in it is packaged in a
freezer stores in which cold air is circulated way that permits some loss of water vapour,
inside the double layer wall so as to remove the evaporative loss per unit weight of
the heat before it reaches the product. product will be greater from that partial load
Although effective, such stores are than from a full freezer load.
expensive to build. In stores of conventional
Consequently, it follows that a minimum
construction, the floor is the most likely
weight loss can be attained only when:
source of dry heat. Heat that is conducted
through walls generally has only local effects • the freezer store/container is loaded to
while the heat conducted through the ceiling capacity with stockinette/hessian-
is quickly removed via air flow. wrapped product and the product is
stacked with maximum compactness;
High air velocity or low humidity around
or
naked meat and stockinette-and/or hessian-
wrapped meat will lead to increased weight • product is sealed in moisture-
loss. The smaller the temperature impermeable materials.
differential between the air and the
evaporator, the higher the humidity. As in The practice of CO2 snow-shooting of meat
carcase chilling, the evaporator coil depth is
3
wrapped in stockinette or stockinette-hessian evaporate from the surface of the warmer
in containers is also conductive to the piece and be deposited on the cooler piece.
development of freezer burn. This can lead to freezer burn.

• Moisture will evaporate from the When each unit of meat is packed in
warmer meat surfaces into the dry, cold moisture-proof material, neither air velocity
atmosphere produced by CO2. nor humidity is important with respect to
dehydration, since the packaging acts as a
• This same atmosphere lowers the meat barrier. Under these conditions the
surface temperature. Then, as the packaging material, product temperature and
surface temperature subsequently variation in temperature are the major
rises, as the product and environment determinants of dehydration.
equilibrate, moisture is again lost.
Where trade allows, packaging materials
This also applies for snow-shooting of with low water vapour permeability (WVP)
product that has a torn outer plastic cover. should be used to wrap or bag the product.
A very long period of protection against
Packaging freezer burn can then be expected provided
the following precautions are taken.
Moisture-proof packaging (e.g. meat
completely enclosed and sealed in • Always use a low WVP tight-fitting film
polyethylene of appropriate thickness) such as polyethylene.
greatly reduces weight loss, and therefore
freezer burn, by preventing the escape of • Ensure that sealing is adequate.
water vapour but dehydration can still occur
inside the packaging if voids are present. • Minimise voids by ensuring maximum
intimate contact between the packaging
It the temperature fluctuates, ‘frosting’ occurs film and the product surfaces.
on the inside of the packaging material when
the air temperature fakks. Successive cycles • Ensure careful handling of packaging
of increasing and decreasing temperature films at low temperatures, as their
cause the accumulation of ice on the inside flexibility decreases with temperature.
of the packaging. This is due to moisture
Note that when plastic film is creased or
progressively evaporating from the meat and
sealed, its WVP increases at these points. If
condensing on the inside of the packaging.
cracks or splits occur in the film, freezer burn
If there are no plastic wrappers or if the
may result. For any type of film, the greater
packaging is punctured or torn, weight loss
the thickness, the lower the WVP.
will be higher. Frosting is minimised by very
tight packaging. It is eliminated in a skin Where the trade requires stockinette and
packaging system, as there is no air space hessian packaging, appropriate ‘weave’ and
between the meat surface and the packaging weight per unit area are barrier-relevant
film. properties.
Most of the frosting in cartons of boneless
meat occurs during the freezing process.
There is a slight weight loss from the frozen
meat but if the carton liner is tightly wrapped
Retail packs, including
around the meat, the weight loss from the comminuted and added-value
frozen meat after the initial equilibration with products
the freezer store air temperature is only
about 0.0025% per week. Although most retail meat is purchased
chilled rather than frozen, many consumers
Moisture is also transferred between pieces still freeze meat in the domestic freezer. A
of product in moisture-proof packages if 1980s survey in Brisbane indicated that
there are air gaps between product. If heat nearly three-quarters of consumers home-
flows from one piece of product to another, freeze. Some of this meat will be stored for
e.g. in a stack of patties, water can
4
some months before being consumed. • temperature differential between
Freezer burn and weight loss almost product and air;
certainly occur to this meat.
• freezer stores subject to high ‘dry’
Mince, burger patties, reformed steaks heat gain, particularly through the
and related products have high surface floor;
area-to-thickness ratios. In addition,
their rapid rates of manufacture and • high air velocity over the product;
freezing can mean that ice may still be
present within meat particles. In these • low occupancy of freezer store;
cases, further ice formation will take
• naked (or stockinette-wrapped)
place around these nuclei. These frozen
meat products are particularly vulnerable carcases stored with cartons or
to thawing and deterioration. For this other moisture-absorbent
reason they need to be packaged and packaging;
transferred to cold stores as quickly as
• carbon dioxide (CO2) snow-
possible.
shooting of containers;
It is not usual to pack patties and similar
• inadequately packaged added-
products before freezing because of
value and retail packs.
their soft nature and because of the
decrease in rate of heat transfer caused
by packaging and the air present in the
pack.

It is well know that the development of


freezer burn and other quality defects
varies according to the type of freezing
employed (cryogenic – with carbon
dioxide or nitrogen; or mechanical) and
according to how elaborate the
packaging is.

Major issues
If excessive moisture loss and/or freezer
burn occurs, they are commonly caused
by combination of conditions such as:

• inadequate packaging;

• high freezer storage temperature


and extended storage period;

• variable storage temperature;

Contact us for additional information


Meat Industry Services is supported by the Australian Meat Processor Corporation (AMPC) and Meat & Livestock Australia (MLA).

Brisbane: Sydney: Adelaide:


Food Science Australia Bill Spooncer Chris Sentance
PO Box 3312 PO Box 181 PO Box 178
Tingalpa DC QLD 4173 KURMOND NSW 2757 FLAGSTAFF HILL SA 5159

Ian Eustace Neil McPhail Alison Small


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