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FOCUS ON CATALYSTS

pultrusion and sheet moulding compound cooking oil, animal fat, and residues from the pulp
processes, something that was more difficult to do and paper sector or waste. Total has committed to
Dow retrofitting cracker in
in the past. CELLOBOND ultra-low formaldehyde consume less than 300,000 tonne/y of crude palm Plaquemine with technology to
(ULF) resins are used to manufacture composite oil.
parts that meet and exceed the most demanding
produce propylene
fire, smoke and toxicity standards in aerospace Original Source: Oils and Fats International, Jun 2019,
(FAR 25.852), automotive (GB/T 31467), 35 (5), 13 (Website: http://www.oilsandfatsinternational. Dow Chemical Co is retrofitting its proprietary
construction (ASTM E84) and rail (EN45545-2 HL3, com) ã Quartz Business Media Ltd 2019. fluidized catalytic dehydrogenation (FCDh)
BS 6853 Class 1A, and NFPA130) applications. technology into one of its mixed-feed crackers in
Plaquemine, LA, US, to produce on-purpose
Original Source: Hexion, 12 Mar 2019, (Website: http:// propylene. The retrofit-which comes as part of the
www.hexion.com/) ã Hexion 2019. company’s current slate of low-capital intensity,
Chevron Australia starts up Gorgon high-return incremental growth investments-will
enable production of more than 100,000 tonne/y of
LNG carbon-capture project additional on-purpose propylene at full run-rate,
further back-integrating Dow’s derivative facilities to
McDermott buys tech firm Siluria Chevron Australia has started up the carbon cost-advantaged propylene while also maintaining
dioxide-capture system at its Gorgon LNG project the unit’s current ethylene production capacity,
McDermott has acquired Siluria Technologies, a on Barrow Island off the Western Australian coast. Dow said. The project is scheduled to begin
San Francisco-based start-up company that The system takes CO2 removed from the gas producing on-purpose propylene by end-2021. Dow
develops catalysts for oxidative coupling of supply coming in from offshore Gorgon field and said the retrofit will enable the company to
methane into ethylene. reinjects it into deep reservoirs under the island. continue meeting rising demand for its businesses
The carbon-capture programme was originally serving consumer, infrastructure, and packaging
Original Source: Chemical and Engineering News, 12 scheduled for start-up in Mar 2017 soon after the end-markets, while also remaining within its stated
Aug 2019, 97 (32), 14 (Website: http://www.cen-online. LNG plant came on stream a few months earlier, near-term capital expenditure targets. The
org) ã American Chemical Society 2019. however technical issues resulted in several proposed Plaquemine retrofit follows Dow’s 2016
delays. The problems are believed to have expansion of ethylene capacity of this same
involved valves and pipeline equipment and were cracker by more than 225,000 tonne/y, which
discovered during the commissioning phase of the added the ability to crack ethane while maintaining
$1.7-bn injection system. The delays have meant the flexibility to crack propane, butane, and
that about 10 M tonnes of CO2 have been released naphtha. Dow, however, did not disclose current

NEW PLANTS into the atmosphere since Dec 2016. Despite this,
Chevron says the capture facility will reduce
Gorgon’s total greenhouse gas emissions by 40%
production capacities of existing crackers at the
Plaquemine site. The Plaquemine retrofit comes
amid Dow and other US cracker operator’s growing
when it is fully operational. This will mean capture consumption of ethane instead of heavier feed
and injection of 3.4 M-4 M tonne/y of CO2, which
Successful startup of world’s equates to about 100 M tonnes over the 40-year
slates, resulting in a reduction of coproduct
production, including propylene. This reduction in
largest dehydrogenation plant using life of the LNG project. The company is now propylene has created a supply-demand gap in the
monitoring the system performance and plans to
Clariant’s CATOFIN catalyst ramp-up injection volumes during the next few
US that requires additional on-purpose propylene
sources to meet the needs of downstream
technology months. It did not specify a timetable for when the derivatives, according to the operator. Alongside
project will be operating at full capacity. The enabling production of reliable and cost-efficient
Clariant announced the successful startup of its Australian government has paid A$60 M towards on-purpose propylene from cost-advantaged US
CATOFIN catalyst at Hengli Group’s new mixed- the capital cost of the project. Australia emitted shale gas feedstocks to supply Dow’s integrated
feed dehydrogenation plant in Dalian, China. The 538.2 M tonnes of CO2 equivalent in 2018, an derivative units in Louisiana, the FCDh technology
new unit combines propane dehydrogenation increase of 0.7% from 2017, mainly due to an retrofit also will allow reduced capital outlay by up
(PDH) with iso-butane dehydrogenation (BDH) increase in LNG exports. The Gorgon project is to 25% and lower energy usage and greenhouse
process technologies, and it will produce over 1 M operated by Chevron. Other JV partners are gas emissions by up to 20%, thereby improving
tonne/y of olefins - becoming the world’s largest ExxonMobil Corp, Royal Dutch Shell PLC, Osaka overall sustainability when compared to
plant using CATOFIN catalyst technology. The Gas, Tokyo Gas, and JERA. conventional propane dehydrogenation
state-of-the-art process pairs Clariant’s CATOFIN technologies, the company said. Dow also recently
catalyst together with McDermott’s Lummus Original Source: PennWell Corporation, 8 Aug 2019, licensed its FCDh technology to PetroLogistics ll
process technology and is proven to enable high (Website: http://www.ogj.com/index.html) ã Pennwell LLC for its planned 500,000-tonne/y propane
reliability and yields, cost efficiency and simplicity. Corporation 2019. dehydrogenation unit to be built on the US Gulf
In addition to the CATOFIN catalyst, the facility is Coast.
using Clariant’s innovative Heat Generating
Material (HGM) to produce its on-purpose olefins. Original Source: PennWell Corporation, 20 Aug 2019,
CATOFIN is an extremely reliable technology for (Website: http://www.ogj.com/index.html) ã Pennwell
light paraffin dehydrogenation. Operating at PetroLogistics lets contract for Corporation 2019.
thermodynamically advantaged reactor pressure proposed USGC PDH unit
and temperature to maximize yield, the process
relies on Clariant’s highly selective CATOFIN PetroLogistics ll LLC, a portfolio company of
catalyst and the company’s patented metal-oxide Quantum Energy Partners, Houston, has let a
HGM to deliver high conversion rates. With the contract to McDermott International Inc to perform Hazer secures ARENA funding to
successful startup of the Hengli plant, this now front-end engineering design services for a recently
marks Clariant’s 21st CATOFIN unit in operation, proposed 500,000-tonne/y propane
construct hydrogen production
totaling over 9 M tonnes of olefin production dehydrogenation (PDH) unit to be built at the US facility
capacity globally. Gulf Coast. Valued at $150 M, McDermott has
reflected the FEED contract award in its 2Q 2019 On behalf of the Australian government, the
Original Source: Clariant, 15 Aug 2019, (Website: http:// backlog, the service provider said. McDermott Australian Renewable Energy Agency (ARENA)
www.clariant.com) ã Clariant 2019. revealed no further details regarding the contract, has approved up to A$9.41 M (£5.2 M) investment
including a timeframe for when FEED services to Hazer Group for the development and operation
would be completed. This latest contract follows of an advanced hydrogen production unit in
PetroLogistics II’s previous award to Dow Chemical Munster. Clean energy company Hazer is planning
Total to start up biorefinery in Co to provide technology licensing for the new to construct an A$15.8 M (£8.8 M), 100 tonne/y
PDH unit, which will be equipped with Dow’s project. This facility will include its advanced
France proprietary fluidized catalytic dehydrogenation hydrogen production technology that transforms
technology that uses a novel reactor design based biogas from sewage treatment into graphite and
Total will launch its 500,000 tonne/y biorefinery in on fluidized catalytic cracking for on-purpose hydrogen using iron ore as a catalyst. This
La Mede, France, following a number of delays propylene production. PetroLogistics II has yet to technology forms an alternative hydrogen pathway
and controversy regarding its imported palm oil decide between two alternative USGC sites under to the conventional ways of steam methane
feedstock. In 2015, the company said it would evaluation for the project’s precise location. Neither reforming and electrolysis. Hazer is planning to sell
spend $223 M to convert the plant into a a budget nor timeline for projected commissioning clean hydrogen for industrial purposes and is
renewable diesel facility employing Axens’ Vegan of the PDH unit has been disclosed. exploring markets for graphite. It has chosen
process technology. Vegetable oil from soyabean, Western Australian Water Corporation (WA Water
carinata, sunflower, rapeseed, and palm would Original Source: PennWell Corporation, 12 Aug 2019, Corporation)’s Woodman Point Wastewater
constitute 60-70% of feedstock supply, while the (Website: http://www.ogj.com/index.html) ã Pennwell Treatment Plant in Munster as the location of the
remaining 30-40% would be sourced from used Corporation 2019. hydrogen facility. It has reached a Memorandum of

November 2019 5

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