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(c) (d)
4. Which of the following electronic transitions requires that the greatest quantity of energy be
absorbed by a hydrogen atom?
(a) n = 1 to n = 2 (b) n = 2 to n = 4
(c) n = 3 to n = 6 (d) n = ∞ to n = 1
6. The expression for the wave number of second line of Balmer series in the hydrogen atom is
16 3R H
(a) (b)
3R H 16
5R H 36
(c) (d)
36 5R H
9. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon?
(a) 3s (b) 2p
(c) 1s (d) 3d
10. In the electronic configuration of nitrogen has 1s7, it would have energy lower than that of the
normal ground state configuration 1s22s22p3 because the electrons would be closer to the nucleus.
Yet 1s7 is not observed because it violates
(a) Heisenberg uncertainty principle (b) Hund’s rule
(c) Pauli’s exclusion principle (d) Bohr postulates of stationary orbits
11. A 1 W radio transmitter operates at a frequency of 880 Hz. How many photons per second
does it emit?
(a) 1.71 × 1021 (b) 1.71 × 1030
(c) 6.02 × 1023 (d) 2.85 × 1026
12. The de−Broglie wavelength (in m) of the electron ejected out when the radiation of energy ‘E’
strikes on the metal surface having threshold frequency equal to half of incident frequency is
− −
(a) 0.6947 × 10 18/ E (b) 0.6947 × 10 18 × E
− −
(c) 6.6 × 10 34 E (d) 6.6 × 10 34/ E
13. The energy of an electron in the first Bohr orbit of H atom is −13.6 eV. The possible energy value(s)
of the excited state(s) for electron in Bohr orbits of hydrogen is(are)
(a) −3.4 eV (b) −4.2 eV
(c) −6.8 eV (d) −6.8 eV
14. An electron has a spin quantum number +1/2 and magnetic quantum number −1. It cannot be
present in
(a) d−orbital (b) f−orbital
(c) s−orbital (d) p−orbital
15. The difference in angular momentum associated with the electron in two successive orbits of
hydrogen atom is
(a) h/π (b) h/2π
(c) h/2 (d) (n −1) h/2π
16. When the frequency of light incident on a metallic plate is doubled, the KE of the emitted
photoelectrons will be
(a) doubled
(b) halved
(c) increased but more than double of the previous KE
(d) unchanged
17. Which of the following postulates does not belong to Bohr’s model of the atom?
h
(a) Angular momentum is an integral multiple of
2π
(b) The electron stationed in the orbit is stable.
(c) The path of an electron is circular.
(d) The change in the energy levels of electron is continuous.
18. By what factor the velocity of an electron in a Bohr’s orbit for a hydrogen atom will change if the
value of principal quantum number is doubled?
(a) Velocity is halved (b) Velocity is doubled
(c) Velocity is quadrupled (d) Velocity remains unchanged
19. The total number of spectral lines obtained in the Lyman series when an electron jumps from
6th level are
(a) 15 (b) 6
(c) 10 (d) 4
20. Number of waves made by a Bohr electron in one complete revolution in its fourth orbit is
(a) 2 (b) 3
(c) 4 (d) ∞
21. Total number of transitions of an electron from nth shell to 2nd shell will be
( n −1) (n − 2) n ( n −1)
(a) (b)
2 2
n ( n +1) n
(c) (d)
2 2
22. Frequency of an electron increases with
(a) increasing radius (b) decreasing radius
(c) increasing charge (d) decreasing principal quantum number
23. How fast is an electron moving, if it has a wavelength equal to the distance it travels in one second?
h m
(a) (b)
m h
h h
(c) (d)
P 2( K.E )
24. A sample of hydrogen atoms all in the same energy state absorbed a certain amount of energy and
got exited to n = 4. Finally the electrons returned to the ground state. In this process they emitted
energy equal to, less than and more than the energy they had absorbed. The electrons had been
initially in
(a) n = 2 (b) n = 3
(c) n = 1 (d) n = 4
27. In an atom two electron move around the nucleus in circular orbits of radii R and 4R. The ratio of
the time taken by them to complete one revolution is
(a) 1 : 4 (b) 4 : 1
(c) 1 : 8 (d) 8 : 7
28. An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E respectively.
What is the qualitative order of their de−Broglie wavelengths?
(a) λ e > λ p = λ α (b) λ p = λ α > λ e
(c) λ p > λ e > λ α (d) λ α < λ e >> λ p
29. The radius of H atom in ground state is 0.53 Å. The radius of Li2+ ion in its ground state is
(a) 0.176 Å (b) 0.265 Å
(c) 0.53 Å (d) 0.53 Å × 3
31. If the shortest wavelength of H atom in Lyman series is x, the longest wavelength in the Balmer
series of He+ would be
x 5x
(a) (b)
4 9
9x 36 x
(c) (d)
5 4
Answers:
1) a
2) a
3) d
4) a
5) b
6) b
7) a
8) a
9) c
10) c
11) b
12) a
13) a
14) c
15) b
16) c
17) d
18) a
19) a
20) c
21) a
22) a
23) a
26)d
27)c
28)a
29)a
30)d
31)c