Análisis de picos con Xpert muestra M1

(110 ZnO )
(002 ZnO )

(102 ZnO )
(101 ZnO )
(100 ZnO )

(220) S i

(311) S i
(110) S i

M9
M6
M5
M3
M1

30 40 50 60 70
2 teta

Muestras con picos indexados según patrones (ver anexos)

M1

M1

30 35 40 45 50

2 teta

Difractograma parcial de 30 a 50 con ajuste en origin.

rad
FWHM cristalito
Pos. [°2Th.] teta FWHM plano
[°2Th.] (nm)
37,3949 0,3807 0,326332 0,006644 28 [100]

40,4109 0,357 0,352652 0,006231 31 [002]

42,5458 0,5992 0,371282 0,010458 18 [101]

66,2805 0,2034 0,57840648 0,00355 60 [110]

74,6677 0,4815 0,6515986 0,00840376 27 [103]

81,0821 0,6866 0,7075748 0,01198343 20 [112]

M3
 M3
1400

1200

1000

800

600

30 35 40 45 50

2 teta

Difractograma parcial de 30 a 50 con ajuste en origin.

FWHM
Pos. [°2Th.] [°2Th.] teta FWHM cristalito (nm) plano
37,1246 0,8048 0,323973 0,014046 13 [100] *
37,19 1,35 0,324544 0,023562 8 [100] ajuste origin
40,3088 0,8566 0,351761 0,014950 13 [002]
42,5055 1,2791 0,370930 0,022325 9 [101]

M5
 2000

M5

1500

1000

500
30 35 40 45 50

2 teta

Difractograma parcial de 30 a 50 con ajuste en origin.

FWHM
Pos. [°2Th.] [°2Th.] teta FWHM cristalito (nm) plano
37,2327 0,6282 0,324917 0,010964 17 [100]
40,3586 0,7506 0,352195 0,013100 15 [002]
42,6256 0,4475 0,371979 0,007810 25 [101]

M6
 1500

M6

1000

500
30 35 40 45 50

2 teta

Difractograma parcial de 30 a 50 con ajuste en origin.

FWHM
Pos. [°2Th.] [°2Th.] teta FWHM cristalito (nm) plano
37,2429 0,6235 0,325006 0,010882 17 [100]
40,4087 0,5292 0,352632 0,009236 21 [002]
42,5848 0,9126 0,371622 0,015928 12 [101]

M9
 1500

M9

1000

500
30 35 40 45 50

2 teta

Difractograma parcial de 30 a 50 con ajuste en origin.

FWHM
Pos. [°2Th.] [°2Th.] teta FWHM cristalito (nm) plano
37,1037 0,7135 0,323791 0,012453 15 [100]
40,3528 0,3774 0,352145 0,006587 29 [002]
42,4412 0,8422 0,370369 0,014699 13 [101]
M2

30 110
002
101
25
tam aٌ o cristal (nm )

20

15

10

5
M1 M3 M5 M6 M9

m uestra

Resumen tamaño cristalito calculado por plano

ANEXOS PATRONES ZnO Y Si

Name and formula
Reference code: 01-075-0576

ICSD name: Zinc Oxide

Empirical formula: OZn

Chemical formula: ZnO

Crystallographic parameters
Crystal system: Hexagonal
Space group: P63mc
Space group number: 186

a (Å): 3,2427
b (Å): 3,2427
c (Å): 5,1948
Alpha (°): 90,0000
Beta (°): 90,0000
Gamma (°): 120,0000

Calculated density (g/cm^3): 5,71

Volume of cell (10^6 pm^3): 47,31
Z: 2,00

RIR: 5,53

Subfiles and Quality

Subfiles: Inorganic
Alloy, metal or intermetalic
Corrosion
Pharmaceutical
ICSD Pattern
Quality: Calculated (C)

Comments
ICSD collection code: 029272

References
Primary reference: Calculated from ICSD using POWD-12++, (1997)
Structure: Sabine, T.M., Hogg, S., Acta Crystallogr., Sec. B, 25,
2254, (1969)

Peak list
No. h k l d [A] 2Theta[deg] I [%]
 1 1 0 0 2,80826 37,148 56,2
2 0 0 2 2,59740 40,288 41,2
3 1 0 1 2,47039 42,457 100,0
4 1 0 2 1,90683 55,953 21,5
5 1 1 0 1,62135 66,968 30,9
6 1 0 3 1,47393 74,729 27,2
7 2 0 0 1,40413 79,145 4,1
8 1 1 2 1,37538 81,139 22,7
9 2 0 1 1,35549 82,586 11,2
10 0 0 4 1,29870 87,066 1,8
11 2 0 2 1,23520 92,801 3,5
12 1 0 4 1,17875 98,727 1,8
13 2 0 3 1,09063 110,204 7,1

Stick Pattern

Name and formula

Reference code: 01-089-2955

ICSD name: Silicon

Empirical formula: Si
Chemical formula: Si

Crystallographic parameters
Crystal system: Cubic
Space group: Fd-3m
Space group number: 227

a (Å): 5,4303
b (Å): 5,4303
c (Å): 5,4303
Alpha (°): 90,0000
Beta (°): 90,0000
Gamma (°): 90,0000

Calculated density (g/cm^3): 2,33

Measured density (g/cm^3): 2,33
Volume of cell (10^6 pm^3): 160,13
Z: 8,00

RIR: 4,55

Subfiles and Quality

Subfiles: Inorganic
Alloy, metal or intermetalic
ICSD Pattern
Quality: Calculated (C)

Comments
Additional pattern: See PDF 01-075-0589.
ICSD collection code: 043610
Test from ICSD: No R value given.
At least one TF missing.

References
Primary reference: Calculated from ICSD using POWD-12++
Structure: Straumanis, M.E., Borgeaud, P., James, W.J., J. Appl. Phys.,
32, 1382, (1961)

Peak list
No. h k l d [A] 2Theta[deg] I [%]
1 1 1 1 3,13518 33,155 100,0
2 2 2 0 1,91990 55,539 55,4
3 3 1 1 1,63729 66,232 30,0
4 2 2 2 1,56759 69,588 0,1
5 4 0 0 1,35757 82,432 6,9
6 3 3 1 1,24579 91,783 9,5
7 4 2 2 1,10845 107,605 11,5
Stick Pattern