Beruflich Dokumente
Kultur Dokumente
On
By
RASAYANI– 410207
2019-2020
University of Mumbai
Certificate
As per the syllabus and in partial fulfillment for the completion Bachelor’s degree in
Mechanical Engineering from University of Mumbai, it is also to certify that this is
the original work of the students done during the academic year 2019-2020.
_________________ _________________
Project Guide Head of Department
_________________
Principal
ACKNOWLEDGEMENT
We would like to express our special thanks of gratitude to our guide Mr. Sagar Patil
for his expert guidance, encouragement and suggestion throughout the preparation of
this work. He helped us whenever we needed help or were stuck on a problem. He has
been a pillar of support and inspired us throughout this study, without him this would
not have been possible. We also express our heartiest thank to Dr. G. V. Patil, Head
of Mechanical Engineering Department for ensuring support throughout our project
studies.
We are grateful and offer our sincere thanks to Dr. Madhumita Chatterjee and to the
teaching faculty members of Mechanical Engineering Department for their valuable
suggestions and instruction regarding project work.
Group Members
List of Figures i
List of Tables ii
Chapter 1 Introduction 1
1.
Thermoelectric Principle 1
1
1.
Problem Defination 2
2
1.
Need and Scope 2
3
Chapter 2 Literature Review 3
2.
Thermoelectric Materials 3
1
2. Heat sink
4
3
2.
Objectives 7
5
Chapter 3 Thermoelectric cooling 10
3.
Thermoelectric System 10
1
3. Seebeck effect 10
2
3.
The Peltier Effect 15
3
3.
The Thomsan Effect 16
4
Chapter 4 Working and Fabrication 19
4.
Layout design 19
1
4.1.1 Peltier Cooling in N type Semiconductor 21
4.1.2 Peltier cooling in P type Semiconductor 21
4.1.3 Peltier Cooling with P and Nmype semiconductore
Introduction
World’s energy demand is continuously increasing day by day and convention source
of energy have limited stock. Also, conventional sources of energy have many issues
of carbon emission; it is main cause of global warming. The thermoelectric (TE)
system is quite suitable due to its renewable energy feature (means no carbon
emission) and eco-friendly behaviour. Only green technologies such as wind power,
solar power and other renewable energy sources can control the emission of
greenhouse gases and play important role for sustainable development. Many
countries are trying to control emission of carbon by forming new rules for industries.
In recent few years, thermoelectric equipments have come out with potential as
alternative eco-friendly applications. Applications of thermoelectric energy extended
in various areas such cooling or heating, refrigeration, electricity generation,
ventilation, air conditioning etc. due to its eco-friendly features and distinct
advantages. Thermoelectric energy has potential to convert thermal energy into
electrical energy and vice-versa. Due to solid state (no fluid/rotating part) mechanism
of thermoelectric devices, it has variety of small applications for cooling of central
processing units (CPU) and produce electricity in automobiles from waste heat.
Fig.1.1Thermoelectric Principle.
(wikipedia)
The need of development of new type of refrigeration system which is portable and is
environment friendly. It should not impact the environment by using alternate
techniques which use harmful CFC refrigerants. According to Kyoto Protocol CFC
based refrigerants which have high Ozone Depletion Potential are banned from usage.
As we can observe from the drastic environmental change that environment is getting
harmed from all our human deeds. So we need to change the harmful deeds like we
can change the use of refrigerants that harm the environment and we can use
Thermoelectric Refrigeration system. And there will be need for this refrigeration in
the future.
Chapter 2
Literature Review
This section contains all the research papers published and all the related things which
would aid us in the development of the Thermoelectric Refrigerator. In view of the
above-mentioned facts, different journals and internet have been explored to find
research papers and activities regarding Thermoelectric modules, Thermoelectric
Application.
Electrical conductivity
For figure of merit to be high, electrical conductivity must be high. Metals are
typically good electrical conductors, but the higher the temperature, the lower the
conductivity. This tendency can be explained in terms of the Drude conductivity
formula
Where,
Thermal conductivity
According to the Wiedemann–Franz law, the higher the electrical conductivity, the
higher becomes. Therefore, it is necessary to minimize . In semiconductors, so it is
easier to decouple K and σ in a semiconductor and K can be improved by working on
Kphonon.
Power factor
To increase the ZT value for this material, research is going to decrease thermal
conductivity without affecting electrical conductivity.
As we have seen, The thermal conductivity of the material can be decomposed into
two principle components. The first is the lattice contribution, related to thermal
conduction by phonons (lattice vibrations). The second is the radiative contribution
related to thermal conduction by photons (electromagnetic radiation). Now, decrease
in thermal conductivity can be achieved about through a reduction in the lattice
component of the thermal conductivity. Researchers have developed some techniques
for doing so, includes :
1. Superlattices
3. phonon-liquid electron-crystal
3. Micro-channels
Table 2.1
Results of this experiment are shown below. Figure 23 shows the comparison of COP
for ambient temperature at 21 C and 32 C. As we can see, carnot COP of TEC is
highest, but due to electrical irreversibility its actual COP is much lower that other
system.
Fig-2.1
Figure 2.1 shows the comparison of second law efficiency of all the refrigerators,
which indicates internal efficiency of thermoelectric cooler is very less, means that
the internal irreversibilities in the thermoelectric module can be quite high. Indeed,
this combined with the comparatively large value of its internally ideal coefficient of
performance confirms the need for improvement of the thermoelectric properties of
the thermoelectric cooler.
Fig-2.2
2.5 Objectives
Thermoelectric Effect
The Seebeck effect is the conversion of heat directly into electricity at the
junction of dissimilar electrical conductors. It is named for the Baltic German
physicist Thomas Johann Seebeck.
Fig- 3.2
In Figure 3.2 , the circuit is modified to obtain a different configuration that
illustrates the Peltier Effect, a phenomenon opposite that of the Seebeck Effect. If a
voltage (Ein) is applied to terminals T1 and T2, an electrical current (I) will flow in
the circuit. As a result of 4 the current flow, a slight cooling effect (QC) will occur at
thermocouple junction A (where heat is absorbed), and a heating effect (QH) will
occur at junction B (where heat is expelled). Note that this effect may be reversed
whereby a change in the direction of electric current flow will reverse the direction of
heat flow. Joule heating, having a magnitude of I2 x R (where R is the electrical
resistance), also occurs in the conductors as a result of current flow. This Joule
heating effect acts in opposition to the Peltier Effect and causes a net reduction of the
available cooling. The Peltier effect can be expressed mathematically as
Qc or QH
Fig - 3.3
Chapter 4
The Peltier effect occurs whenever electrical current flows through two dissimilar
conductors; depending on the direction of current flow, the junction of the two
conductors will either absorb or release heat. In the world of thermoelectric
technology, semiconductors (usually Bismuth Telluride) are the material of choice for
producing the Peltier effect because they can be more easily optimized for pumping
heat. Using this type of material, a Peltier device (i.e., thermoelectric module) can be
constructed in its simplest form around a single semiconductor “pellet” which is
soldered to electrically-conductive material on each end (usually plated copper). In
this configuration, the second dissimilar material required for the Peltier effect, is
actually the copper connection paths to the power supply. [10] It is important to note
that the heat will be moved in the direction of charge carrier movement throughout the
circuit (actually, it is the charge carriers that transfer the heat).
Fig-4.1
With a DC voltage source connected as shown, electrons will be repelled by the
negative pole and attracted by the positive pole of the supply; due to this attraction,
electrons at Fermi level move towards positive terminal by releasing heat and creating
the holes in the Fermi level. Now, due to continuous supply of current, electrons
move from valance band (lower energy band) to Fermi level by absorbing energy
from the junction. With the electrons flowing through the N-type material from
bottom to top, heat is absorbed at the bottom junction and actively transferred to the
top junction. [10] So we can say that, in Peltier cooler using N-type of semiconductor,
heat is absorbed at the junction near negative terminal and heat is rejected at the
junction near positive terminal.
Fig-4.2
Now, when DC current is applied through the circuit as shown in Figure 7; holes
get attracted towards negative terminal of source. By this attraction, holes move to
negative terminal by releasing heat. Due to continuous supply of current, holes from
conduction band moves to Fermi level by absorbing heat from the junction.
Fig-4.4
Fig-4.5
By arranging the circuit as like in Figure 8, it is possible to release heat to the one
side and absorb from another side. Using these special properties of the TE “couple”,
it is possible to team many pellets together in rectangular arrays to create practical
thermoelectric modules as in
Fig-4.6
Fig-4.7
Fig-4.8
4.2.2 Materials
Let’s look at this in terms of real numbers. Imagine that we have to pump 25 watts
from a box to bring its temperature to 3 oC from 20 oC (ambient). To accomplish this,
we might well have to take the temperature of the cold side sink down to 0° C. Using
a Peltier device which draws 4.1 amps at 10.4 V, the hot side of the system will have
to dissipate the 25 watts from the thermal load plus the 42.6 watts it takes to power
the TE module (for a total of 67.6 watts). Employing a hot side sink and fan with an
effective thermal resistance of 0.148 C°/W. The temperature of the hot side sink will
rise approximately 10°C above ambient. It should be noted that, to achieve the 17° C
drop between the box temperature and ambient, we had to create a 30° C (54°F)
temperature difference across the Peltier device.
Chapter 5
5.1 Designing
The idea for making a Thermoelectric Refrigerator came after looking at the
advantages of thermoelectric module. The module is so small and easy to use that it
can fit in easily and can be used anywhere. In order to design the complete
refrigerator first of all we required to find the volume of the refrigerator. Our purpose
is To cool 6 bottles of 6 liters each. According to our observation most of the people
use a bottle ranging from diameter of 7-8 cm . the height of the bottle range between
30-40 cm so accordingly we designed the refrigerator.
It was observed that when bottles where placed horizontally it was occupying a
lot of width and due to this there was less place for the thermoelectric module on the
back. So we decided to place the bottles in vertical position . this save alot of space
and gave a lot of space at the back to mount the complete setup of thermoelectric
modules , sink , fans.
For designing purpose we also have to consider various aspects as how much
outer temperature will be . we completed our design of the model in Solidworks then
we made a prototype of the model to see how large it will actually be.
5.2 Components
The cooling effect completely depends on the peltier module that we are using
there are various peltier module available in the market . We are going to use TEC1-
12707 which is a 7 amp peltier module .
Components used
1. Thermoelectric Modules.
2. Heat sink
3. Cooling Fans
6. Wood
7. Screws
8. Glass
9. Bottles
10. Hinge
Fig-5.2
Fig-5.3
Chapter 6
Expected Result
The expected result from using 3 peltier module is that we will obtain a cooling
down to 10 degree celsius . And the 6 bottles will get a complete cooling in nearly 3
hours. If we get this results we will try to improve the efficiency of the module by
modifying in the module. This will be a portable refrigerator so we can be able to
move it anywhere .
This will be a good alternative for the conventional VCR system . advancement
is needed in this field .
Conclusion
The coefficient of performance of this refrigerator is much smaller than that of a
conventional compressor-type refrigerator when the required cooling capacity is high,
whereas the coefficient of performance of the conventional unit falls off rapidly as the
cooling capacity is decreased and that of thermo electric unit remains constant. Thus a
conventional refrigerator is preferred when the required cooling capacity is high and a
thermoelectric refrigerator should be chosen when a low cooling capacity is needed.
The cold side of the thermoelectric module was utilized for refrigeration purposes
whereas the rejected heat from the hot side of the module was eliminated using heat
sinks and fans
As the cooling units are of small size, silent, contains no liquids or gases, have no
moving parts and have a long life. It is very simple to control the rate of cooling by
adjustment of the current, the response to changes in the supply is very rapid, while
reversal of the direction of the current transforms a cooling unit into a heater with a
coefficient of performance in excess of unity i.e. a heat pump for oven. In this work, a
portable compressor less refrigerator unit was fabricated and tested for the cooling
purpose
References
12. Marc H., Thermoelectric Modules: Principles and Research, InterPACK july 6-8,
2011, Portland